SCH4U Organic Chemistry Grade 11 Review SOLUTIONS 1. Complete the following chart: Formula Atom Lewis Dot Diagrams # of Valence Electrons Lewis Structure of Compound IUPAC Name Na2S NBr3 2. Name or determine the formulas for the following: a. lithium oxide Li2O i. C2H6 dicarbon hexahydride or ____________*** b. Na2CO3 Sodium carbonate j. nickel (II) nitrate c. carbon tetraflouride CF4 k. NH4OH d. P2S3 l. diphosphorous trisulphide Ni(NO3)2 Ammonium hydroxide dinitrogen sulfide N2S Bonus****where is the error! e. HF(aq) hydrofluoric acid m. strontium bromate Sr(BrO4)2 f. HNO3 (aq) n. yttrium chlorate Y(ClO3)3 g. NiS Nickel (II) sulphide o. SO3 sulphur trioxide h. Ni2(SO4)3 Nickel (III) sulphate p. Ti(ClO4)3 nitric acid titanium perchlorate 3. Define electronegativity and explain the trend on the Periodic Table. EN = trend: up and right (F the highest EN) 4. Name and explain all of the Intermolecular forces. Use diagrams in your answers: H-bonding Dipole-dipole London dispersion (van der Waals) 5. Use the concepts of intermolecular forces and/or intramolecular bonds to explain why ionic compounds such as NaCl, MgCl2, and NaNO3 have generally high melting points. 6. a. Briefly explain what happens to the solubility of an ionic compound like KNO3 with increasing temperature. What happens for a gas like O2? In general: solids ↑ in solubility with ↑ temp gases ↓ in solubility with ↑ temp 7. Write the balanced equation, total ionic equation, and net ionic equation for the reaction between aqueous sodium phosphate and aqueous calcium chloride. 2 Na3PO4 (aq) + 3 CaCl2 (aq) → Ca3(PO4)2 (s) + 6 NaCl (aq) 6Na1+(aq) + 2PO43-(aq) + 3Ca2+(aq) + 6Cl1-(aq) → Ca3(PO4)2 (s) + 6Na1+(aq) + 6 Cl1-(aq) 2PO43-(aq) + 3Ca2+(aq) → Ca3(PO4)2 (s) 8. Briefly explain what you are looking for in order to classify the following reactions. Synthesis Decomposition Single Displacement Double Displacement Combustion of a Hydrocarbon 9. Four factors affect the rate of a chemical reaction. Identify each factor and explain how/why they each specifically affect the rate of a reaction. Temp Catalyst SA Conc ***Collision theory – more effective collisions means faster reaction 10. Develop the complete combustion reaction for butane. (C4H10). 2C4H10 (l) + 13O2 (g) → 8 CO2 (g) + 10 H2O(g) b. Butane is the fuel source in lighters. The combustion of butane is rarely a complete reaction. Explain this observation, and identify two other potential products for this reaction. CO & C