Chemistry 161. Test Four. May 01, 2015. Name _____________________________________________( /86) This test is pledged non-disclosure until it is returned. Part One. 33 points, 2 points each. _____1) For the following pairs of atoms – Cs or K, Na or Mg - which will have the greatest first ionization energy? a- K and Mg b- Cs and Mg c- Cs and Na d- K and Na _____2) For the following pairs – Br or Br1-, Co3+ or Co2+ - which will have the largest radius? a- Br and Co2+ b- Br1- and Co2+ c- Br1- and Co3+ d- Br and Co3+ _____3) The effective nuclear charge for the valence electrons in phosphorus is a- +1 b- +5 c- +3 d- -4 _____4) Which of the following species is an alkali metal? a- calcium b- carbon c- cesium d- chromium _____5) Which of the following states would not be expected for bismuth a- +3 b- 0 c- +5 d- +1 _____6) Which of the following species would we expect to be ionic? a- CO2 b- CaF2 c- SiO2 d- SF4 _____7) For the following pairs of atoms – S or As – Ca or Ni -which will have the greatest electronegativity? a- S b- As c- Sr d- Mo _____8) Which of the following compounds is polar? a- SeCl4 b- CCl4 c- BrF41d- NO2+ _____9) For which of the following molecules will the electron pair geometry be linear? a- SO2 b- H2O c- CS2 d- O3 _____10) Which of the following molecular geometries is not found in a species with an electron pair geometry of trigonal bipyramidal? a- T b- bent c- see saw d- linear _____11) Which of the following species is paramagnetic? a- Kr b- CO2 c- SO42d- NO2 _____12) Which of the following species is diamagnetic? a- Br1b- Ga c- NH3 d- O2 _____13) What is the maximum number of electrons that any orbital can hold? a- 2 b- 1 c- 3 d- will depend on the orbital _____14) A triple bond in a molecule is comprised of a- two bond and one bonds b- three bonds and no bonds c- no bonds and two bonds d- one bond and two bonds Part Two. 1) (9 points) Definitions Electronegativity Electron affinity Covalent bond 2) (8 points) Nomenclature. Name a- Ionic or Molecular Formula H2SO4 b- Cobalt(III) chloride c- P2S5 d- Ammonium sulfate 3) (15 points) Give the complete ground state electron configuration for each of the following species (no shortcut notation) Zn2+ Se2- Cd Ge2+ H1- 4) (21 points) For each of the following spcvecies-draw the proper Lewis dot structure -give the hybridization of the central atom -show the formal charge on each atom of the structure -give the electron pair geometry -give the molecular geometry -is the species polar BrF21- TeF51- NO31-