THE MOLE What a fun concept WHAT IS A MOLE? A burrowing critter? A skin pigmentation? A word that evokes an enormous number? 1 mole of any substance equals 6.02 x 1023 representative particles of that substance 6.02 x 1023 is known as Avogadro’s number WHAT IS A REPRESENTATIVE PARTICLE? It depends on what the substance is What can a substance be? Element Molecular compound Anything but the BrINClHOF elements which are diatomic molecules in nature Made of two or more nonmetals…includes BrINClHOF elements with their subscripts of 2 Ionic compound Made of a metal and a nonmetal or contains a polyatomic ion A HANDY LITTLE CHART Substance Representative Particle Smaller bits (rp) Element Atom Molecular Compound Molecule Atoms Ionic Compound Formula Unit Ions SO, HERE WE GO… 1 mol of Fe contains 6.02 x 1023 atoms of Fe 1 mol of Br2 contains 6.02 x 1023 molecules of Br2 1 mol of NaCl contains 6.02 x 1023 formula units of NaCl 1 mol of SO3 contains 6.02 x 1023 molecules of SO3 1 mol of Na2O contains 6.02 x 1023 formula units of Na2O AND WE MAKE THAT INFO USEFUL BY WRITING IT AS… 1 mol Fe 6.02 x 1023 atoms Fe 1 mol of Br2 6.02 x 1023 molec Br2 1 mol of NaCl 6.02 x 1023 fu NaCl 1 mol of SO3 6.02 x 1023 molec SO3 1 mol Na2O 6.02 x 1023 fu Na2O OR WE CAN FLIP THEM TO GET… 6.02 x 1023 atoms Fe 1 mol Fe 6.02 x 1023 molec Br2 1 mol of Br2 6.02 x 1023 fu NaCl 1 mol of NaCl 6.02 x 1023 molec SO3 1 mol of SO3 6.02 x 1023 fu Na2O 1 mol Na2O SMALLER BITS? Only for molecules and formula units 1 molec Br2 has 2 atoms of Br 1 fu NaCl has 1 Na1+ ion and 1 Cl1- ion 1 molec SO3 has 1 S atom and 3 O atoms 1 fu Na2O has 2 Na1+ ions and 1 O2- ion MOLAR MASS The mass of one mole of a substance Use average atomic masses from the periodic table and round their masses to the hundredths place for consistency Unit is g/mol 1 mol Fe = 55.85 g Fe …55.85 g Fe = 1 mol Fe 1 mol Fe 55.85 g Fe or 55.85 g Fe 1 mol Fe MOLAR MASS OF A COMPOUND For a compound, you must calculate the molar mass Molar Mass of Br2 Br---2 x 79.90 = 159.80 g/mol 1 mol Br2 159.80 g Br2 or 159.80 g Br2 1 mol Br2 MOLAR MASS OF A COMPOUND Molar Mass of NaCl Na---1 x 22.99 = 22.99 Cl--- 1 x 35.45 = 35.45 58.44 g/mol 1 mol NaCl 58.44 g NaCl or 58.44 g NaCl 1 mol NaCl MOLAR MASS OF A COMPOUND Molar Mass of SO3 S---1 x 32.06 = 32.06 O---3 x 16.00 = 48.00 80.06 g/mol 1 mol SO3 80.06 g SO3 or 80.06g SO3 1 mol SO3 MOLAR MASS OF A COMPOUND Molar Mass of Na2O Na---2 x 22.99 = 45.98 O--- 1 x 16.00 = 16.00 61.98 g/mol 1 mol Na2O 61.98 g Na2O or 61.98 g Na2O 1 mol Na2O MOLAR MASS OF A COMPOUND Molar Mass of Ca(OH)2 Ca---1 x 40.08 = 40.08 O--- 2 x 16.00 = 32.00 H--- 2 x 1.01 = 2.02 74.10 g/mol 1 mol Ca(OH)2 or 74.10 g Ca(OH)2 74.10 g Ca(OH)2 1 mol Ca(OH)2 MOLAR MASS OF A COMPOUND Molar Mass of Mg(C2H3O2)2 Mg---1 x 40.08 = 24.31 C--- 4 x 12.00 = 48.00 H--- 6 x 1.01 = 6.06 O--- 4 x 16.00 = 64.00 142.37 g/mol 1 mol Mg(C2H3O2)2 142.37 g Mg(C2H3O2)2 or 142.37 g Mg(C2H3O2)2 1 mol Mg(C2H3O2)2 ANOTHER HANDY CHART rp 1 mol mass AND NOW, YOU PUT IT ALL TOGETHER How many atoms of helium are in 4.50 mol of helium? Is helium an element, molecular compound, or ionic compound? What is its representative particle? Use your given information to begin your dimensional analysis or unit conversion…always write a number, unit, and substance 4.50 mol He x 6.02 x 1023 atoms He = 2.71 x 1024 atoms He 1 mol He SO, HAVE FUN If a sample of chlorine gas contains 2.97 x 1024 atoms of Cl, how many moles of chlorine gas are there? Is chlorine gas an element, molecular compound, or ionic compound? What is its representative particle? Use your given information to begin your dimensional analysis or unit conversion…always write a number, unit, and substance 2.97 x 1024 atoms Cl x 1 molec Cl2 x 1 mol Cl2 = 2 atoms Cl 6.02 x 1023 molec Cl2 PRACTICING How many sulfide ions are present in 10.0 g of ferric sulfide? Is ferric sulfide an element, molecular compound, or ionic compound? What is its representative particle? Use your given information to begin your dimensional analysis or unit conversion…always write a number, unit, and substance 10.0 g Fe2S3 x 1 mol Fe2S3 x 6.02 x 1023 fu Fe2S3 x 207.88 g Fe2S3 1 mol Fe2S3 3 ions S21 fu Fe2S3 =