Stoichiometry • Stoichiometry is a section of chemistry that involves using relationships between reactants and products in a chemical reaction to determine desired quantitative data • In a balanced reaction, both sides of the equation have the same number of elements. The stoichiometric coefficient is the number written in front of atoms, ion and molecules to balance the number of each element on both sides of the equation • 6CO2(g) + 6H2O(l) 1C6H12O6(s) + 6O2(g) • The most common stoichiometric problem will present you with a certain amount of a reactant and then ask how much of a product can be formed. Here is a generic chemical equation: 3A+4B2D+1F Steps for solving Stoichiometry Problems 1. Balance the chemical equation 2. Convert the given mass to moles by using molar mass or the substance 3. Construct a molar proportion between the substances you are looking for 4. Using the molar mass of the unkown substance, convert the moles just calculated to mass. Stoichiometry Road Map aA + bB cC + dD Mass A Mass B Mol Ratio Mol A Atoms A Molecules Mol B Atoms B Molecules 3A+4B2D+1F How many moles of F are produced from 1.00 mol of A? 1 mol A 1 mol F 3 mol A How many moles of D are produced from 5.00 mol of B? 5 mol B 2 mol D 4 mol B = 2.50 mol D = 0.333 mol F Working a Stoichiometry Problem 6.50 grams of aluminum reacts with an excess of oxygen. How many grams of aluminum oxide are formed? 1. Identify reactants and products and write the balanced equation. 4 Al + 3 O2 2 Al2O3 a. Every reaction needs a yield sign! b. What are the reactants? c. What are the products? d. What are the balanced coefficients? 4 Al + 3 O2 1. What is your starting point? 2. What is your ending point? 6.50 g Al 2 Al2O3 6.50 g of Aluminum g of aluminum oxide 1 mol Al 2 mol Al2O3 101.96 g Al2O3 26.98 g Al 4 mol Al 1 mol Al2O3 6.50 x 2 x 101.96 ÷ 26.98 ÷ 4 = 12.3 g Al2O3 = ? g Al2O3 How many moles of lithium carbonate are produced when 5.3 mol CO2 are reacted? CO2(g) + 2LiOH(s) Li2CO3(s) + H2O(l) 1. What is your starting point? 2. What is your ending point? 5.3 mol CO2 1 mol Li2CO3 1 mol CO2 = 5.3 mol Li2CO3 5.3 mol of CO2 mol of Li2CO3 3A+4B2D+1F How many grams of F are produced from 1.00 mol of A? If MM of F is 10.0g/mol. 1 mol A 1 mol F 3 mol A 10 g F 1 mol F How many grams of D are produced from 5.00 mol of B? MM of D is 20.0g/mol 5 mol B 2 mol D 20 g D 4 mol B 1 mol D = 50.0g D = 3.33g F What is the mass of glucose (C6H12O6) produced from 3.00 mol of water (H2O)? 6CO2(g) + 6H2O(l) C6H12O6(s) + 6O2(g) 1. What is your starting point? 2. What is your ending point? 3 mol H2O 1 mol C6H12O6 6 mol H2O =90.1 g C6H12O6 180.81g C6H12O6 1 mol C6H12O6 3.00 mol of H2O g of C6H12O6 6CO2(g) + 6H2O(l) C6H12O6(s) + 6O2(g) What is the mass of oxygen (O2) produced from 2.50 mol of water (H2O)? 1. What is your starting point? 2. What is your ending point? 2.5 mol H2O 6 mol O2 32.0 g O2 6 mol H2O 1 mol O2 =80.0 g O2 2.50 mol of H2O g of O2 4NH3(g) + 5O2(g) 4NO(g) + 6H2O(g) How many moles of NO are formed from 824 g of NH3? 1. What is your starting point? 2. What is your ending point? 824 g NH3 1 mol NH3 4 mol NO 17.03g 4 mol NH3 = 48.4 mol NO 824 g of NH3 mol of NO 3A+4B2D+1F How many grams of F are produced from 5.00g of A? If MM of F is 10.0g/mol and MM of A is 25.0g/mol 5gA 1 mole A 1 mole F 10 g F 25 g A 3 mole A 1 mole F How many grams of D are produced from 5.00g of B? MM of D is 20.0g/mol and MM of B is 10.0g/mol 5gB 1 mole B 10 g B =5.00g D 2 mole D 4 mole B 20 g D 1 mole D = 0.677g F Sn(s) + 2HF(g) SnF2(s) + H2(g) How many grams of SnF2 are produced from the reaction of 30.00 g HF? 1. What is your starting point? 2. What is your ending point? 30.00g HF 1 mol HF 1 mol SnF2 20.01g HF 2 mol HF = 117.5g SnF2 30.00 g of HF g SnF2 156.71 g SnF2 1 mol SnF2 Real World Application STOICHIOMETRY • Think of a balanced chemical equation as a recipe; the number of moles of each particle input (reactants) indicates the amount of ingredients needed to prepare the food, and the number of moles of each particle output (products) indicates how much of each type of final food one will end up with. The type of input that will be used up first determines the maximum amount of possible output. Click Below for the Video Lectures Stoichiometry