Name to Formula ◦ 1. Write the cation first (include charge) ◦ 2. Write the anion second (include charge) ◦ 3. “Swap and drop” the charges to determine how many of each ion are needed ◦ 4. Make sure the total charge of the compound is 0 (The final formula will NOT have + or – in it.) ◦ 5. Rewrite the formula without charges Lithium oxide “Oxide” ends in –ide and is not found on the polyatomic ion chart. We know the charge is 2- because of where oxygen is found on the periodic table. ◦ 1. Cation (including charge): Li+ ◦ 2. Anion (including charge): O2◦ 3. Swap and drop charges: Li+ O2- Li+2 O2Li2O There is are two lithium cations and one oxide anion. 1 The formula is neutral: Li: +1 x 2 = +2 charge O: -2 x 1 = -2 charge 0 total charge Barium nitrate Ba2+ ◦ 1. Cation (including charge): ◦ 2. Anion (including charge): NO3◦ 3. Swap and drop charges: Ba2+ NO3 Ba2+1 NO3- 2 Ba(NO2)2 There is one barium cation and two nitrate anions. “Nitrate” is a polyatmic ion whose name you should have memorized. The formula is neutral: Ba: +2 x 1 = +2 charge NO3: -1 x 2 = -2 charge 0 total charge The parentheses show that there are two nitrate ions. Aluminum sulfate ◦ 1. Cation (including charge): Al3+ ◦ 2. Anion (including charge): SO42◦ 3. Swap and drop charges: Al3+ SO42 Al3+ 2 SO42- 3 “Sulfate” is a polyatmic ion whose name you should have memorized. The formula is neutral: Al: +3 x 2 = +6 charge SO4: -2 x 3 = -6 charge 0 total charge Al2 (SO4)3 There are two aluminum cations and three sulfate anions. The parentheses show that there are three sulfate ions. Sodium chloride ◦ 1. Cation (including charge): Na+ ◦ 2. Anion (including charge): Cl◦ 3. Swap and drop charges: Na+ Cl- Na+1 Cl-1 NaCl There is one sodium cation and one chloride anion. “Chloride” ends in –ide and is not found on the polyatomic ion chart. We know the charge is 1because of where chlorine is found on the periodic table. The formula is neutral: Na: +1 x 1 = +1 charge Cl: -1 x 1 = -1 charge 0 total charge Aluminum oxide ◦ 1. Cation (including charge): Al3+ ◦ 2. Anion (including charge): O2◦ 3. Swap and drop charges: Al3+ O2- Al3+ 2 O2- 3 Al2 O3 There are two aluminum cations and three oxide anions. “Oxide” ends in –ide and is not found on the polyatomic ion chart. We know the charge is 2- because of where oxygen is found on the periodic table. The formula is neutral: Al: +3 x 2 = +6 charge O: -2 x 3 = -6 charge 0 total charge Ammonium nitrate ◦ 1. Cation (including charge): NH4+ ◦ 2. Anion (including charge): NO3◦ 3. Swap and drop charges: NH4+ NO3 NH4+1 NO3- 1 NH4NO3 There is one ammonium cation and one nitrate anion. “Ammonium” and “nitrate” are polyatmic ions whose names you should have memorized. The formula is neutral: NH4: +1 x 1 = +1 charge NO3: -1 x 1 = -1 charge 0 total charge Parentheses are not needed because there is only one of each polyatomic ion. Calcium hydroxide Ca2+ ◦ 1. Cation (including charge): ◦ 2. Anion (including charge): OH◦ 3. Swap and drop charges: Ca2+ OH- Ca2+1 OH- 2 Ca(OH)2 There is one calcium cation and two hydroxide anions. “Hydrocide” is a polyatmic ion whose name you should have memorized. The formula is neutral: Ca: +2 x 1 = +2 charge OH: -1 x 2 = -2 charge 0 total charge The parentheses show that there are two hydroxide ions. Barium chloride ◦ 1. Cation (including charge): Ba2+ ◦ 2. Anion (including charge): Cl◦ 3. Swap and drop charges: Ba2+ Cl- Ba2+1 Cl- 2 BaCl2 There is one barium cation and two chloride anions. “Chloride” ends in –ide and is not found on the polyatomic ion chart. We know the charge is 1because of where chlorine is found on the periodic table. The formula is neutral: Ba: +2 x 1 = +2 charge Cl: -1 x 2 = -2 charge 0 total charge Magnesium oxide ◦ 1. Cation (including charge): Mg2+ ◦ 2. Anion (including charge): O2◦ 3. Swap and drop charges: Mg2+ O2- Mg2+2 O2-2 Mg2O2 MgO “Oxide” ends in –ide and is not found on the polyatomic ion chart. We know the charge is 2- because of where oxygen is found on the periodic table. The formula is neutral: Mg: +2 x 2 = +4 charge Cl: -2 x 2 = -4 charge 0 total charge The smallest possible ratio is 1:1, not 2:2. There is one magnesium cation and one oxide anion. Lead (II) nitride ◦ 1. Cation (including charge): Pb2+ ◦ 2. Anion (including charge): N3◦ 3. Swap and drop charges: Pb2+ N3- Pb2+3 N3- 2 Pb3N2 There are three lead (II) cations and two nitride anions. The Roman numeral tells us that lead has a charge of +2. “Nitride” ends in –ide and is not found on the polyatomic ion chart. We know the charge is -3 because of where nitrogen is found on the periodic table. The formula is neutral: Pb: +2 x 3 = +6 charge N: -3 x 2 = -6 charge 0 total charge Formula to Name ◦ 1. Determine the charge of the cation (+) ◦ 2. Determine the charge of the anion (-) ◦ 3. Write the name of the cation Use element name or polyatomic cation name Include Roman numeral if necessary D-block NOT Ag+, Cd2+, or Zn2+ ◦ 4. Write the name of the anion -ide or from the polyatomic ion chart Cation charge: Sr has a charge of 2+. We know this because it is located in Group 2 on the periodic table. Anion charge: ClO2 has a charge of -1. It is a polyatomic ion. There are two of them so the -1 charge balances out the 2+ charge of Sr2+. Name: Chlorite Name: Strontium Sr(ClO2)2 Strontium chlorite Strontium does NOT need a Roman numeral because it is found in the s-block. Only d-block elements and some p-block elements need Roman numerals. Cation charge: Cu is found in the d-block and can form more than one ion. Its charge in this compound will be +1 to balance Cl-. Name: Copper (I) Anion charge: Cl has a charge of -1. We know this because it is located in Group 17 on the periodic table. The name will end in –ide. CuCl Copper (I) chloride Copper DOES need a Roman numeral because it is found in the d-block. The +1 charge tells us what Roman numeral to use. Name: Chloride Cation charge: Pb is found in the lower-left p-block and can form more than one ion. Its charge in this compound will be +2 to balance the two NO3- ions. Name: Lead (II) Lead (II) nitrate Anion charge: NO3 has a charge of -1. It is a polyatomic ion. There are TWO of them for a total negative charge of -2. Pb(NO3)2 Lead DOES need a Roman numeral because it is found in the lower-left p-block. The +2 charge tells us what Roman numeral to use. Name: Nitrate Cation charge: Pb is found in the lower-left p-block and can form more than one ion. Its charge in this compound will be +3 to balance the two NO3- ions. Name: Lead (III) Lead (III) nitrate Anion charge: NO3 has a charge of -1. It is a polyatomic ion. There are THREE of them for a total negative charge of -3. Pb(NO3)3 Lead DOES need a Roman numeral because it is found in the lower-left p-block. The +3 charge tells us what Roman numeral to use. Name: Nitrate Anion charge: I has a charge of -1. We know this because it is located in Group 17 on the periodic table. The name will end in –ide. Cation charge: K has a charge of +1. We know this because it is located in Group 1 on the periodic table. Name: Iodide Name: Potassium KI Potassium Iodide Potassium does NOT need a Roman numeral because it is found in the s-block. Only d-block elements and some p-block elements need Roman numerals.