Friday, Nov. 2nd: “A” Day Monday, Nov. 5th: “B” Day Agenda Finish Section 3.3: “Electron Configuration” Quantum numbers, Pauli exclusion principle, electron configuration, aufbau principle, Hund’s rule Electron Configuration Movie/Worksheet Homework: Electron Configuration Movie Worksheet Quantum Numbers Quantum number: a number that specifies the properties of electrons Each electron has 4 quantum numbers: 1. Principal quantum number, n: The main energy level (row on periodic table) 2. Angular momentum quantum number, l: The shape of the orbital (s, p, d, f) 3. Magnetic quantum number, m: The orientation of the orbital around the nucleus 4. Spin quantum number, +½ or -½ (↑↓) Pauli Exclusion Principle Remember, each orbital can hold a maximum of 2 electrons. In 1925 the German chemist Wolfgang Pauli established a rule is known as the Pauli exclusion principle. Pauli exclusion principle: the principle that states that two particles of a certain class cannot be in the exact same energy state. In plain English: no two electrons in the same atom can have the same four quantum numbers. Electron Configuration Electron configuration: the arrangement of electrons in an atom. Like all systems in nature, electrons in atoms tend to assume arrangements that have the lowest possible energies. An electron configuration of an atom shows the lowest-energy arrangement of the electrons for the element. Shapes of s, p, and d Orbitals **Each Orbital Can Hold a Maximum of 2 Electrons** There is only 1 s orbital for each main energy level. The s orbital can only hold 2 electrons. There are 3 p orbitals for each main energy level. The p orbitals can hold 2 electrons each for a total of 6. There are 5 d orbitals for each main energy level. The d orbitals can hold 2 electrons each for a total of 10. There are 7 f orbitals for each main energy level. The f orbitals can hold 2 electrons each for a total of 14. An Electron Occupies the Lowest Energy Level Available Aufbau principle: the principle that states that the structure of each successive element is obtained by adding one proton to the nucleus of the atom and one electron to the lowest-energy orbital that is available. In plain English: electrons occupy orbitals that have the lowest energy first. Orbital Filling Chart This diagrams shows how the energy of the orbitals can overlap. Because the 4s orbital has a lower energy than the 3d orbital, it will fill first. Hund’s Rule Electron orbitals are filled according to Hund’s Rule. Hund’s rule: the rule that states that for an atom in the ground state, the number of unpaired electrons is the maximum possible and these unpaired electrons have the same spin. In plain English: all orbitals in a given energy level must have 1 electron each before any pairing occurs. Don’t HOG electrons! Writing Electron Configurations There are 2 different ways that electron configurations can be represented: 1. With arrows: ____ ____ ____ ____ ____ 1s 2s 2p 2p 2p Each horizontal line represents an orbital. Each arrow represents an electron with a different spin. Which element do you think this this? Writing Electron Configurations 2. With electron configuration notation: 1s22s22p5 The big numbers indicate the main energy level, n (row on periodic table) The letters indicate the orbital type. The superscripts show the number of electrons. Which element do you think this this? Electron Configuration Practice Use arrows to write the electron configuration for an atom of an element whose atomic number is 8. Atomic Number = # of protons # protons = # electrons = 8 Use the orbital filling chart to place the 8 electrons in their proper orbitals. Remember, the s orbital can only hold 2 electrons and the 3 p orbitals can hold 2 electrons each for a total of 6. ____ ____ ____ ____ ____ 1s 2s 2p 2p 2p Sample Problem C, pg. 98 Use arrows AND electron configuration notation to write the electron configuration for an atom whose atomic number is 20. Atomic Number = # of protons # protons = # electrons = 20 Use the orbital filling chart to place the 20 electrons in their proper orbitals: __ ____ ____ ____ ____ ____ ____ ____ ____ ____ 1s 2s 2p 2p 2p 3s 3p 3p 3p 4s 1s22s2sp63s23p64s2 Electron Configuration Practice Use arrows AND electron configuration notation to write the electron configuration for an atom that has 17 electrons. Use the orbital filling chart to place the 17 electrons in their proper orbitals: ____ ____ ____ ____ ____ ____ ____ ____ ____ 1s 2s 2p 2p 2p 3s 3p 3p 3p 1s22s22p63s23p5 Movie: “Writing Electron Configurations” Welcome back Mr. Sweatervest! Follow along and complete the student examples as they are being discussed in the movie. The rest of the worksheet, front and back, is homework. Homework Complete the rest of the movie worksheet. *Next time section 3.3 work day!*