Periodic Table Trends and Similarities Trends of the Periodic Table: At the conclusion of our time together, you should be able to: 1. Give a trend across and down the Periodic Table for metallic characteristics, reactivity, atomic radius and ion radius, electron affinity, ionization energy, electronegativity, density, melting point and boiling point 2. Define each of the terms above 3. Pick the element with the higher trend above from a list of several elements 15 Helpful Hints On The Lab Report from Mr. T’s Vast Lab Experience!!! Hint #7. In case of doubt, make it sound convincing. Trends In The Periodic Table: Ionization Energy Atomic Radius Electron Affinity Electronegativity, Etc. Periodic Trends Try to determine the trends by looking at the handouts provided. Metallic Characteristic Trends Top to Bottom Left to Right Increases Decreases Conductivity Shininess Malleability Ductility more reactive more reactive Reactivity Of Metals Reactivity Trends Top to Bottom Left to Right Increases with Metals Decreases with Nonmetals Decreases with Metals Increases with Nonmetals Redneck News: The minimum drinking age in Redneck Country has been raised to 32. It seems they want to keep alcohol out of the high schools. Atomic Radius Half the distance between the nuclei of two identical atoms that are bonded together. Electron – electron repulsion = larger Proton – electron attraction = smaller Energy level, n, more therefore = larger Atomic Radius Vs. Atomic Number Atomic Radius (pm) 250 K 200 Na Li 150 Mg Al Si Be 100 B C N OF 50 H Ca P S Cl Ar Ne He 0 0 2 4 6 8 10 12 Element 14 16 18 20 Atomic Radius Trends Periodic Table Trends Answers Atomic Radius Trends Top to Bottom Left to Right Increases Decreases Questions about teenage men answered by teenage women!!! Q: What do you call a handcuffed boyfriend? A: Trustworthy Ionic Radius 1. Cations lose electrons, therefore they tend to be Positive Ions – Metals 2. Anions gain electrons, therefore they tend to be Negative Ions – Nonmetals Ionic Radius Trends Electron gain = repulsion = Larger Electron loss = one less energy level = Smaller Ionic Radius Trends Metals Nonmetals Smaller Larger Happy Birthday Dirge Happy Birthday, Happy Birthday, So far Death you have bypassed. Don’t look back, he’s gaining fast. Happy Birthday, Happy Birthday! Electron Affinity The energy change that occurs when a neutral atom acquires an electron. Most electron affinity values are negative. Energy is released from the atom. Atoms that really want another electron tend to be more negative. Periodic Table Trends Answers Electron Affinity Trends Top to Bottom Left to Right Decreases (less negative) Increases (more negative) Noble Gases = 0 Ionization Energy The energy required to remove one electron from a neutral atom. The closer to the nucleus, the harder to pull the electron. The farther away, more interference from other electrons, therefore, the easier it is to pull the electron. Ionization Energy Vs. Atomic Number He Ionization energy (kJ/mol) 2500 Ne 2000 Ar F 1500 N H Be 1000 O Cl C P S B 500 Mg Si Al Li Ca K Na 0 0 2 4 6 8 10 12 Element 14 16 18 20 Ionization Energy Trends Ionization Energy Trends Top to Bottom Left to Right Decreases Increases Electronegativity A measurement of the ability of an atom in a chemical compound to attract electrons. Generally, Ionization energy + Electron Affinity = Electronegativity Most electronegative element – Fluorine (F) It is assigned the number 4 All other values are based on this value. Electronegativity Trends Electronegativity Trends Top to Bottom Left to Right Decreases Increases Density Mass of a Material Divided by Volume of that Material Density Trends Density Trends Top to Bottom Left to Right Increase Increases then Decreases Another Redneck Innovation!!! Boiling Point Temperature at which a system moves from the liquid state to the gaseous state. The external pressure pushing into the liquid is equal to the internal pressure pushing out of the liquid. Melting Point The temperature at which a solid becomes a liquid. The external pressure pushing into the solid is equal to the internal pressure pushing out of the solid. Boiling Point Trends Boiling/Melting Point Trends Top to Bottom Left to Right Increases except Groups 1, 2, 12, 13, 14 Increases then Decreases Trends of the Periodic Table: Let’s see if you can: 1. Give a trend across and down the Periodic Table for metallic characteristics, reactivity, atomic radius and ion radius, electron affinity, ionization energy, electronegativity, density, melting point and boiling point 2. Define each of the terms above 3. Pick the element with the higher trend above from a list of several elements Familiar Saying A member of the species commonly designated Homo Sapiens who exhibits an insufficiency of normal sagacity faces imminent separation from his spendable financial assets. A fool and his money are soon parted!! Which of the elements is the metalloid? 1 2 3 4 5 6 7 8 9 10 21 22 23 24 25 26 27 28 29 30 11 12 13 14 15 16 20% 17 18 fu r Su l siu m 20% M ag ne Al u m 5. or in e 4. 20% Ch l 3. Si li 2. in um Aluminum Silicon Chlorine Magnesium Sulfur 1. 20% co n 20% 19 20 Which of the elements would be the least reactive metal? 1 2 3 4 5 6 7 8 9 10 21 22 23 24 25 26 27 28 29 30 11 12 13 20% Su l siu ag ne fu r m 20% M Al u m 5. or in e 4. 20% Ch l 3. Si li 2. in um Aluminum Silicon Chlorine Magnesium Sulfur 1. 20% co n 20% 14 15 16 17 18 19 20 Which of the elements would be the most reactive nonmetal? 1 2 3 4 5 6 7 8 9 10 21 22 23 24 25 26 27 28 29 30 11 12 13 14 15 16 20% 17 18 fu r Su l siu m 20% M ag ne Al u m 5. or in e 4. 20% Ch l 3. Sil i 2. in um Aluminum Silicon Chlorine Magnesium Sulfur 1. 20% co n 20% 19 20 Which of the elements would have the largest radius? 1 2 3 4 5 6 7 8 9 10 21 22 23 24 25 26 27 28 29 30 11 12 13 20% Su l siu ag ne fu r m 20% M Al u m 5. or in e 4. 20% Ch l 3. Sil i 2. in um Aluminum Silicon Chlorine Magnesium Sulfur 1. 20% co n 20% 14 15 16 17 18 19 20 Which of the elements would have the highest electronegativity? 1 2 3 4 5 6 7 8 9 10 21 22 23 24 25 26 27 28 29 30 11 12 13 14 20% ag ne Su l siu fu r m 20% M Al u m 5. or in e 4. 20% Ch l 3. Sil i 2. in um Aluminum Silicon Chlorine Magnesium Sulfur 1. 20% co n 20% 15 16 17 18 19 20 Which of the elements would have the lowest ionization energy? 1 2 3 4 5 6 7 8 9 10 21 22 23 24 25 26 27 28 29 30 11 12 13 14 20% ag ne Su l siu fu r m 20% M Al u m 5. or in e 4. 20% Ch l 3. Sil i 2. in um Aluminum Silicon Chlorine Magnesium Sulfur 1. 20% co n 20% 15 16 17 18 19 20 Which of the elements would have the greatest electron affinity (the most negative number)? 1 2 3 4 5 6 7 8 9 10 21 22 23 24 25 26 27 28 29 30 11 12 13 14 20% ag ne Su l siu fu r m 20% M Al u m 5. or in e 4. 20% Ch l 3. Sil i 2. in um Aluminum Silicon Chlorine Magnesium Sulfur 1. 20% co n 20% 15 16 17 18 19 20 Which of the elements would have the highest metallic character? 1 2 3 4 5 6 7 8 9 10 21 22 23 24 25 26 27 28 29 30 11 12 13 14 15 16 20% 17 18 fu r Su l siu m 20% M ag ne Al u m 5. or in e 4. 20% Ch l 3. Sil i 2. in um Aluminum Silicon Chlorine Magnesium Sulfur 1. 20% co n 20% 19 20 Which of the following would have the larger radius? 50% 50% Chlorine Chlorine Ion 1. 2. ine or l Ch 1 2 3 4 5 6 7 8 9 10 21 22 23 24 25 26 27 28 29 30 11 12 13 14 Ch 15 16 17 n Io e in lor 18 19 20 Which of the following would have the smaller radius? 50% 50% Lithium Lithium Ion 1. 1 2 3 4 5 6 7 8 9 10 21 22 23 24 25 26 27 28 29 30 11 12 13 14 Lit hi u m Lit hi u Io n m 2. 15 16 17 18 19 20 Which of the following would have the smaller radius? 50% 50% Oxygen Oxygen Ion 1. 1 2 3 4 5 6 7 8 9 10 21 22 23 24 25 26 27 28 29 30 11 12 13 14 Ox yg e n Ox yg e Io n n 2. 15 16 17 18 19 20 Which of the following would have the larger radius? 50% 50% Sodium Sodium Ion 1. 1 2 3 4 5 6 7 8 9 10 21 22 23 24 25 26 27 28 29 30 11 12 13 14 So di u m So di u Io n m 2. 15 16 17 18 19 20 Rubidium (n=37) would have all of the following characteristics except: 20% 20% 20% 20% 20% High Conductivity High Malleability High Brittleness Solid at Room Temperature 1 Valence Electron 1. 2. 3. 4. 5. gh Hi n Co iv ct du ity al gh Hi M i ab lit y le gh Hi l So 1 2 21 22 3 4 5 6 7 8 9 10 11 12 13 14 15 16 Br id 17 it at n tle s es m m oo Te R 18 ra pe 1 re tu l Va ce en 19 c Ele tro n 20 Bromine (n=35) would have which of the following characteristics? s ro n ur e ct El e So l id at 7 Ro Va om le Te nc e m Br pe r it t le at ili ty le ab Hi gh Hi gh Co nd 5. M al 4. uc tiv 3. Hi gh 2. ity High Conductivity High Malleability High Brittleness Solid at Room Temperature 7 Valence Electrons 1. ne ss 20% 20% 20% 20% 20% 1 2 21 22 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 Which of the following would have the highest melting point? 1 2 3 4 5 6 7 8 9 10 21 22 23 24 25 26 27 28 29 30 11 12 13 14 15 16 in e e 17 20% As ta t Ch l Fl uo r 5. 20% Io di n 4. 20% in e 3. or in e 2. in e Fluorine Chlorine Bromine Iodine Astatine 1. 20% Br om 20% 18 19 20 Which of the following would have the lowest density? 1 2 3 4 5 6 7 8 9 10 21 22 23 24 25 26 27 28 29 30 11 12 13 14 15 16 in e e 17 20% As ta t Ch l Fl uo r 5. 20% Io di n 4. 20% in e 3. or in e 2. in e Fluorine Chlorine Bromine Iodine Astatine 1. 20% Br om 20% 18 19 20 Which of the following would have the highest density? 25% 25% 25% 25% 1 2 3 4 5 6 7 8 9 10 21 22 23 24 25 26 27 28 29 30 11 12 13 14 15 16 17 pt on Kr y Po ta s siu m 4. in e 3. Br om 2. Iro n Potassium Iron Bromine Krypton 1. 18 19 20 Which of the following would have the lowest boiling point? 25% 25% 25% 25% 1 2 3 4 5 6 7 8 9 10 21 22 23 24 25 26 27 28 29 30 11 12 13 14 15 16 17 pt on Kr y Po ta s siu m 4. in e 3. Br om 2. Iro n Potassium Iron Bromine Krypton 1. 18 19 20