TIMARU GIRLS’ HIGH SCHOOL SCIENCE DEPARTMENT Level 1 Science AS 1.8/90947 Investigate Selected Chemical Reactions Assessment – Internal 4 Credits Specific Learning Outcomes I can: Describe the structure of an atom in terms of Protons, neutrons, 1 electrons, shells, atomic number and mass number Write electron configurations for atoms 2 3 4 Discuss Chemical bonding in terms of electron loss/gain (ionic) or sharing (covalent) Relate metallic structure to physical properties of metals Use the collision theory to describe factors which affect the rate of a reaction Identify precipitation reactions(exchange reactions) including naming 6 precipitates formed Describe thermal decomposition reactions of carbonates and hydrogen 7 carbonates. Describe the displacement of metal ions in solution in terms of simple 8 electron transfer 5 Topic 1: Atomic Theory Matter is anything that has a mass and takes up space. Atoms are the basic unit of all matter. Everything from YOU to the book you are writing in is made of atoms. Matter has ______________________ and ________________________. Phases of Matter Matter exists in three different phases or states: ___________, ___________, ______ Solids Liquid Gas All matter is in motion!!! *Gas properties applet* Classification of Matter: Science 20 Centre High Campus 2 Atomic Theory: Neils Bohr (1885-1962) – Bohr Model Electrons can only exist at certain distances from the nucleus (called orbits, shells, or energy levels) Remember, all matter is made up of ATOMS!!!! What are elements? Give two examples Atom vs element?? Name the three subatomic particles that make up an element. 1. 2. 3. Complete the following table: Most of the volume an atom Particle Electron Location Charge Proton Most of the mass of an atom Neutron Draw a picture of a HELIUM atom including electrons, protons and neutrons. Science 20 Centre High Campus 3 Periodic Table of Elements: Metal vs. Nonmetals Groups Periods Lets look at a symbol on the periodic table: 11 Na Sodium 22.99 Na+ Definitions: Na + forms when Na loses 1 electron Atomic Number: Average Atomic Mass: Isotopes: Ex: Carbon-14 vs Carbon-12: Science 11 TGHS Uranium-235 vs Uranium 238: 4 Example: Fill in the chart below. Summary of Atomic Structure: 3 subatomic particles: _____________, ____________, ______________ Protons and neutrons are in ____________ _____________ orbit the nucleus and have a negligible mass Electrons participate in chemical reactions Protons & neutrons participate in nuclear reactions Atoms with the same atomic number but different atomic mass are called __________ Same as atomic number Fill in the following table on isotopes. Mass ― # of ptrotons Science 11 TGHS 5 Example: Determine the following for the element iron. 1. Atomic number? 2. Atomic mass? 3. Most common ion? 4. Number of electrons in atom? 5. Number of protons in atom? 6. Number of neutrons in most common isotope? 7. Number of valence electrons in least common ion? * Special Atoms: Name 3 naturally diatomic elements: Name 2 naturally polyatomic elements: Sketching Diagrams of Atoms: Remember that a nucleus consists of protons and neutrons that are held together by binding forces. Bohr and Rutherford’s models of an atom states that electrons are arranged in energy levels (orbits) around the nucleus. Bohr’s energy levels state that electrons are arranged as follows: _____ max in first energy level _____ max in second _____ max in third Electrons on outermost shell are called ________________________ Science 11 TGHS 6 Bohr Atomic Diagrams: Metal Atomic Diagrams: Beryllium: Sodium: Written as: Be ( ) Na ( ) Non-Metal Atomic Diagrams: Oxygen: Chlorine: Written as: O ( ) Cl ( ) Steps in Sketching Bohr Atomic Diagram: 1. Bohr Atomic Diagram 2. 3. – – – – – – – – Science 11 TGHS Group 1 has 1 valence electron (loses 1) Group 2 has 2 valence electrons (loses 2) Group 3 has 3 valence electrons (loses 3) Group 4 has 4 valence electrons…pretty stable *periodic table arrangement: Group 5 has 5 valence electrons (gains 3) atoms vs ions Group 6 has 6 valence electrons (gains 2) Group 7 has 7 valence electrons (gains 1) Group 8 has full outer energy level (8 valence)…..very stable!! • known as inert or noble gases 7 Naming Ions: Positively charged elements (cations) are named with their full name and then “_______” Negatively charged elements (anions) are named by dropping the suffix “ine”, and adding “_________” Fill in the following chart: Polyatomic Ions: Science 11 TGHS 8 Topic 2 (Part A): Compounds When two atoms come into close proximity of each other, their electrons are attracted to both nuclei • What part of the atom participates in chemical reactions? Compound Formation involves the sharing or transfer of valence electrons. Sodium wants to __________ its 1 valence electron to become a complete happy atom Chlorine wants to ____________ 1 valence electron to become a happy atom So… sodium gives away its 1 valence electron to chlorine and together they form a very stable compound called __________ (table salt). This is a very happy union called an ______________ bond. Science 11 TGHS 9 Pure Substances (Elements) Bond to Form Compounds: Some atoms tend to transfer or share outer electrons (valence electrons) by either trying to "give" them away or "take" them from other atoms. What is a compound? (vs a molecule?) Write the general formula for ionic and molecular compounds: Ionic Compound Molecular Compound Type of Compound Elements Electrons (transfer or sharing) Conductivity? Ionic Molecular In ionic compounds, which element loses electrons? Which gains electrons? Atoms come together in various combinations to form molecules and compounds. Both molecules and compounds are made of ___________________________ How do we know how many atoms there are? Science 11 TGHS 10 How many of each atom is there in the following: Examples: ***When brackets are used the subscript applies to everything inside the bracket. Examples: Compound Coefficients: Coefficients appear ___________________ of a formula to indicate how many there are. What is the total number of atoms in “A” and “B” above? Properties of Ionic Compounds (write down 3): Ionic compounds that dissolve in water and conduct electricity as solutions are called _____________________ Ionic compounds form 3-D grids called: ___________________. Science 11 TGHS 11 Writing Chemical Formulas (Ionic Compounds) Don’t forget, you must balance the charges of each element!!! POSITIVES = NEGATIVES Example 1: Write the chemical formula for barium fluoride. Example 2: Write the chemical formula for calcium sulfide. Example 3: Write the chemical formula for magnesium nitrite. Example 4: Write the chemical formula for iron (III) oxide. Homework: 1. Write the chemical formula for: a. Hydrogen sulfide _________________ b. Lithium nitride _________________ c. Rubidium oxide _________________ Science 11 TGHS 12 2. Combine the following pairs of ions to form a neutral compound (Show all your work). (a) Ca2+ Br- _______________ (b) Al3+ O2- _______________ (c) Zn2+ O2- _______________ (d) Na1+ N3- _______________ (e) Ba2+ S2- _______________ (f) Fe3+ Br- _______________ (g) Zn2+ N3- _______________ (h) K+ O2- _______________ (i) Pb4+ S2- _______________ (j) Al3+ N3- _______________ (k) Rb+ F- _______________ (l) Sn4+ Se2- _______________ Answers: a) b) c) d) e) f) g) h) i) j) k) l) Science 11 TGHS CaBr2 Al2O3 ZnO Na3N BaS FeBr3 Zn3N2 K2O PbS2 AlN RbF SnSe2 13 Naming Ionic Compounds: • When naming ionic compounds, the metal name stays the same, the second element (________________) always ends in “_______” Name the following compounds: • NaCl ____________________ • H2S _____________________ • Rb2O ____________________ • Li3N _____________________ Homework: Name the following compounds: (a) Na2S(s) _______________________ (b) Al2O3(s) _______________________ (c) AgCl(s) _______________________ (d) MgBr2(s) _______________________ (e) BaCl2(s) _______________________ Naming Special Ionic Compounds: Some ionic compounds are composed of a metal that can form more than one kind of ion • Ex. Copper has 2 ions Copper (I) Cu+ and Copper (II) Cu2+ Cu+ Cl- = CuCl Copper (I) chloride Cu2+ Cl- = CuCl2 Copper (II) chloride Always look at the number after the non-metal!!! Exercise: Name the following compounds: 1. CrBr3 ______________________________ 2. Fe2O3 _______________________________ 3. HgCl2 ______________________________ 4. NiO ______________________________ 5. SbN ______________________________ Science 11 TGHS 14 Write formulas for the following: 1. manganese II sulphide ____________________ 2. iron III oxide ____________________ 3. copper I chloride ____________________ 4. cobalt III nitride ____________________ 5. ruthenium III bromide ____________________ Naming Compounds with Polyatomic Ions: Now try naming these compounds: • NaHCO3 _________________ • NaC6H5COO ______________ Example: Al2(SO4)3 aluminum sulfate Name the following: l. Na2SO4 _______________________ 7. CuCO3 _______________________ 2. Ca(NO3)2______________________ 8. H2CO3 ________________________ 3. Fe3(PO4)2_____________________ 9. MnSO4 _______________________ 4. KClO3________________________ 10. Hg(NO2)2_____________________ 5. MnCrO4 _________________________ 11. Al(OH)3 _____________________ 6. K2SO4 _______________________ 12. Al(NO)3_________________________ Going backwards! Write the formula for the following compounds: 1. ammonium phosphate: __________________ 2. magnesium sulphate: __________________ 3. chromium chlorate: __________________ 4. sodium hydrogen carbonate __________________ 5. potassium cyanide Science 11 TGHS __________________ 15