The Chemistry of Acids and Bases Acids and Bases: Characteristics At the conclusion of our time together, you should be able to: 1. Give examples of acids and bases 2. List some properties of acids and bases 3. Compare and contrast the characteristics of acids and bases Hopefully, when we get done, you won’t be in this much trouble!! Acid and Bases Acid and Bases Acid and Bases Acids Have a sour taste. Ex. Vinegar is a solution of acetic acid. Citrus fruits contain citric acid. React with certain metals to produce hydrogen gas. React with carbonates and bicarbonates to produce carbon dioxide gas Bases Have a bitter taste. Feel slippery. Many soaps contain bases. Kid’s Letters to God: Some Properties of Acids þ Produce H+ (as H3O+) ions in water (the hydronium ion is a hydrogen ion attached to a water molecule) þ Taste sour, Corrode metals, Electrolytes þ React with bases to form a salt and water þ pH is less than 7, Turns blue litmus paper to red “Blue to Red A-CID” Some Properties of Bases Produce OH- ions in water Taste bitter, chalky, are electrolytes Feel soapy, slippery React with acids to form salts and water pH greater than 7 Turns red litmus paper to blue “Basic Blue” How Are a Texas Tornado And a Tennessee Divorce The Same? Somebody's Gonna Lose A Trailer. Acids and Bases: Characteristics Let’s see if you can: 1. Give examples of acids and bases 2. List some properties of acids and bases 3. Compare and contrast the characteristics of acids and bases Get Your Clicker!!! Which of the following is not a characteristic of an acid? 17% 17% 17% 17% 17% 17% 1 2 3 4 5 6 7 8 9 10 21 22 23 24 25 26 27 28 29 30 11 12 7 to n th a ba se er lo w Tu rn sl a ith w Re ac ts pH is Ta st es so ur form salt and water 4. Turns litmus paper blue 5. Produces H+ ions in water 6. All answers are correct 13 14 15 it m Pr fo od us .. uc pa es pe H+ rb lu io Al e ns la i n ns w w at er er sa re co rre ct 1. Tastes sour 2. pH is lower than 7 3. Reacts with a base to 16 17 18 19 20 Which of the following is not a characteristic of a base? 3 4 5 6 7 8 9 10 21 22 23 24 25 26 27 28 29 30 11 12 16 r.. . an sw er sa OH -i 18 17% Al l ce s us p 17 17% ... ... 17% Pr od u 15 Tu rn sl 14 it m ith ac ts w hi g is 17% an t. . . he r tte bi 13 Re 2 pH 1 Ta st es form salt and water 4. Turns litmus paper blue 5. Produces OH- ions in water 6. All answers are correct r 1. Tastes bitter 2. pH is higher than 7 3. Reacts with an acid to 17% ... 17% 19 20 The Chemistry of Acids and Bases Acids and Bases: Naming At the conclusion of our time together, you should be able to: 1. Name any acid or base 2. Determine if the acid is binary or ternary (oxy-acid) and use the appropriate naming system Naming Acids Binary Acids: Contain “H” and one other element To Name: Hydro + second element name + ic + acid Ex: HCl = Hydro chlorine – ine + ic acid Hydrochloric acid HF = Hydrofluoric acid Prefix Hydro- Stem or root of nonmetal < NM > Suffix -ic acid HCl is a binary acid – hydrogen - nonmetal HCl Hydro chlor ic HI Hydro iod ic acid H2S Hydro sulfur ic acid acid Naming Acids (cont.) Ternary Acids (oxyacids): Contain “H”, “O” and one more element To Name: Polyatomic ion “ate” “ic” + acid Ex: HNO3 = Nitr-ate ic + acid Nitric acid HClO3 = Chloric acid An easy way to remember which goes with which… “In the cafeteria, you ATE something ICky” Naming Acids (cont.) If the acid has one more oxygen than the root acid, the naming goes as follows: To Name: Per + Polyatomic ion “ate” “ic” + acid Ex: HNO4 = Per + Nitr-ate ic + acid Pernitric acid H2SO5 = Persulfuric acid Naming Acids (cont.) If the acid has one less oxygen than the root acid, the naming goes as follows: To Name: Ex: Polyatomic ion “ite” “ous” + acid HNO2 = Nitr-ite ous + acid Nitrous acid H2SO3 = Sulfurous acid Naming Acids (cont.) If the acid has two less oxygens than the root acid, the naming goes as follows: To Name: Hypo + Polyatomic ion “ite” “ous” + acid Ex: HNO = Hypo + nitr-ite ous + acid Hyponitrous acid HClO = Hypochlorous acid Acid Nomenclature Review Anion Ending No Oxygen w/Oxygen Acid Name -ide hydro-(stem)-ic acid -ate (stem)-ic acid -ite (stem)-ous acid “In the cafeteria, you ATE something ICky” Acid Nomenclature Flowchart ACIDS start with 'H' 2 elements 3 elements hydro- prefix -ic ending no hydro- prefix -ate ending becomes -ic ending -ite ending becomes -ous ending Summary of Naming Ternary Acids Acid Nomenclature Review • HBr (aq) • H2CO3 • H2SO3 hydrobromic acid carbonic acid sulfurous acid Name ‘Em! HI (aq) Hydroiodic acid HCl (aq) Hydrochloric acid H2SO3 Sulfurous acid HNO3 Nitric acid HClO4 Perchloric acid Practicing Naming All Acids Formula HCl Binary or Ternary B Name Hydrochloric acid HI B Hydroiodic acid HNO2 T Nitrous acid H2SO5 T Persulfuric acid H3PO2 T Hypophosphorous acid H4C B Hydrocarbonic acid Chemical Compound Quiz Hypochlorous acid helps get the laundry white and bright. What is the common name? Bleach Naming Bases Name the metal first Add hydroxide Ex: NaOH = KOH = Sodium hydroxide Potassium hydroxide Some Common Bases NaOH sodium hydroxide, lye KOH potassium hydroxide, liquid soap Ba(OH)2 barium hydroxide, stabilizer for plastics Mg(OH)2 magnesium hydroxide “MOM” Milk of magnesia Al(OH)3 aluminum hydroxide, Maalox (antacid) Tell you what, I’ll follow you!! Practice Naming Bases Formula Name NaOH Sodium hydroxide Fe(OH)3 Iron (III) hydroxide Mg(OH)2 Magnesium hydroxide Ni(OH)2 Nickel (II) hydroxide NH4OH Ammonium hydroxide Acids and Bases: Naming Let’s see if you can: 1. Name any acid or base 2. Determine if the acid is binary or ternary (oxy-acid) and use the appropriate naming system Get Your Clicker!!! Name HCl. 1. 2. 3. 4. 5. 6. 7. 8. Hydrogen chloride Hydrochloric acid Chloric acid Perchloric acid Chlorous acid Hypochlorus acid I have no idea!! Who cares?? Name HClO. 1. 2. 3. 4. 5. 6. 7. 8. Hydrogen chloride Hydrochloric acid Chloric acid Perchloric acid Chlorous acid Hypochlorus acid I have no idea!! Who cares?? Name HClO3. 1. 2. 3. 4. 5. 6. 7. 8. Hydrogen chloride Hydrochloric acid Chloric acid Perchloric acid Chlorous acid Hypochlorus acid I have no idea!! Who cares?? Forgetter Be Forgotten? My forgetter's getting better, But my rememberer is broke To you that may seem funny But, to me, that is no joke. For when I'm 'here' I'm wondering If I really should be 'there' And, when I try to think it through, I haven't got a prayer! Forgetter Be Forgotten? Oft times I walk into a room, Say 'what am I here for?' I wrack my brain, but all in vain! A zero, is my score. At times I put something away Where it is safe, but, Gee! The person it is safest from Is, generally, me! Forgetter Be Forgotten? When shopping I may see someone, Say 'Hi' and have a chat, Then, when the person walks away I ask myself, 'who the hell was that? Yes, my forgetter's getting better While my rememberer is broke, And it's driving me plumb crazy And that isn't any joke. Name HClO4. 1. 2. 3. 4. 5. 6. 7. 8. Hydrogen chloride Hydrochloric acid Chloric acid Perchloric acid Chlorous acid Hypochlorus acid I have no idea!! Who cares?? Name HClO2. ho W 12% ca re s? ? id ea ... 12% o av en Ih ch lo r ou s sa cid ou 12% a. .. 12% Hy po lo r Ch hl or ic ic a Pe rc lo r Ch 12% ac i.. . 12% cid 12% or ic a. .. oc hl ch lo r Hy dr og en Hydrogen chloride Hydrochloric acid Chloric acid Perchloric acid Chlorous acid Hypochlorous acid I have no idea!! Who cares?? Hy dr 1. 2. 3. 4. 5. 6. 7. 8. ... 12% Name H2SO4 12% 12% 12% 12% 12% 12% ic ac Pe id rs ul fu ric ac Su ... lfu ro us Hy ac po id su lfu ro us Ih ... av en o id ea ... W ho ca re s? ? ic ... 12% Su lfu r os ul fu r Hy dr og en Hydrogen Sulfate Hydrosulfuric acid Sulfuric acid Persulfuric acid Sulfurous acid Hyposulfurous acid I have no idea!! Who cares?? Hy dr 1. 2. 3. 4. 5. 6. 7. 8. Su lfa ... 12% Name H3PO3 ho W 12% ca re s? ? id .. ea ... 12% o or ou . av en os ph Hy po os ph Ph 12% Ih ph ou sa c.. . . 12% or sp h ho or Pe rp os ph 12% ic ac .. ci. .. 12% ic a ic ... sp h ho op 12% Ph ph Hy dr og en Hydrogen phosphite Hydrophosphic acid Phosphoric acid Perphosphic acid Phosphorous acid Hypophosphorous acid I have no idea!! Who cares?? Hy dr 1. 2. 3. 4. 5. 6. 7. 8. os p. .. 12% Name HNO. 12% ca re s? ? ea ... ho W av en o us Ih tro 12% id ac .. ac id ni us 12% . 12% Hy po ca cid 12% Ni tro itr i Ni tri c ac id 12% Pe rn . 12% itr ic ac .. on Ni tr Hy dr og en Hydrogen Nitrite Hydronitric acid Nitric acid Pernitric acid Nitrous acid Hyponitrous acid I have no idea!! Who cares?? Hy dr 1. 2. 3. 4. 5. 6. 7. 8. i.. . 12% Name Sr(OH)2 1. Strontium (II) Hydroxide 2. Strontium Oxygen 1 2 3 4 5 6 7 8 9 10 21 22 23 24 25 26 27 28 29 30 14% 14% 14% 14% 14% (I I ).. . m St O ro xy nt g. .. iu m Ox St ro yh nt ... iu m Hy St dr ro .. . nt in oi St cA ro c.. nt . iu m Di hy . .. No tl ist ed 14% 11 12 13 nt iu St ro nt iu m Hydrogen Strontium Oxyhydride Strontium Hydroxide Strontinoic Acid Strontium Dihydroxide Not listed St ro 3. 4. 5. 6. 7. 14% 14 15 16 17 18 19 20 Name Fe(OH)3 17% 17% 17% 17% (I I I) Hy d. Iro .. n Hy dr ox id e Iro ni cA cid Iro n (I ) Hy dr Iro o. n .. Ox yh yd rid .. . No tl ist ed Iron (III) Hydroxide Iron Hydroxide Ironic Acid Iron (I) Hydroxide Iron Oxyhydride Not listed 17% Iro n 1. 2. 3. 4. 5. 6. 17% 1 2 3 4 5 6 7 8 9 10 21 22 23 24 25 26 27 28 29 30 11 12 13 14 15 16 17 18 19 20 Red-Neck Innovations: