By: Shawn Sales & Cece Pridgen 6th Period Structure: CONH2 A carboxylic acid contains the -COOH group, and in an amide the -OH part of that group is replaced by an -NH2 group. Amides result from carboxylic acids. Amides are the most common non-basic functional group. The melting points of amides are high for the size of the molecules because they can form hydrogen bonds. Amides have different chemical properties from amines, and are really weak bases. Amides are named by adding the suffix ”amide” after the acid dropping the “ic, oic, or acid.” methanamide acetamide Amides (R-CO-NH2) take the suffix –amide if the carbon in the amide group cannot be included in the main chain . Acid formation of an ester from an amide to alcohol. Esters reacting with amines (ammonia) to form an amide. Heating Carboxylic Acids and amines together to form an amide Methanamide- HCONH2 Enthanamide- CH3CONH2 Propanamide- CH3CH2CONH2 Formamide-CH3NO Butanamide- C4H9NO Amides are used in industries such as paper making, crayons, ink, and the rubber industries. Amides have an unsubstituted aliphatic carboxylic acid in them that makes them suitable for making plastic because of its powerful solvent properties. Nylon is made up of long-chain-fiber-forming polyamides with reoccurring amide groups. The first polyamide was Nylon 66, produced by the reaction of adipic acid (a 6-carbon dibasic acid) and hexamethylene diamine (a 6carbon aliphatic diamine) Nylon was produced as an alternative to silk, and is used in things such as winter jackets, yarn, and zip ties. Polyamide Taslan Jacket Polyamide zip ties. Nylon fabric Amides are a result of what acid? A. Hydrochloric acid B. Carboxylic acid C. Carbonic acid What is the structure of an amide? A. CONH2 B. –NH2 C. -COOH Why is the melting point of an amide high for the size of the molecules? A. Powerful solvent properties B. It’s a weak base C. It can form hydrogen bonds How are amides named? What is the name of this amide? C4H9NO A. Methanimide B. Formamide C. Butanamide www.chem.shef.ac.uk/chm1312003/chao3cb/uses.html http://www2.chemistry.msu.edu/faculty/reu sch/VirtTxtJml/intro1.htm http://chemed.chem.purdue.edu/genchem/to picreview/bp/2organic/2org_frame.html http://masterorganicchemistry.com/category /functional-groups/ http://www.chemistry-drills.com/functionalgroups.php?q=simple