Science 10 “ Imagination should give wings to our thoughts but we always need decisive experimentive proof, and when the moment comes to draw conclusions and to interpret the gathered observations, imagination must be checked and documented by the factual results of the experiment” Louis Pasteur, 1864 1 Unit 1 Energy and Matter in Chemical Change 2 1.0 Particles Make Up the Underlying Structure of Matter Enduring Understanding: The understanding that particles make up the underlying structure of matter has led to advancements in technology. • • • Safety in the Lab Properties and Classification of Matter Developing Ideas of Matter 3 1.1 Safety in the Lab • • • • • Safety depends on awareness, knowledge and action Must be aware of hazards and alert to unforeseen hazards Must know how to use the right equipment and how to act in an emergency Must know how to behave safely and responsibly around hazardous substances Safety Rules have been developed to minimize the risk of working with hazardous substances 4 Safety Symbols • (1) (2) • • There are two systems developed for safety when working with chemicals WHMIS – Workplace Hazardous Materials Information System HHPS – Household Hazardous Product Symbols MSDS – Material Safety Data Sheet; Designed to provide written information about chemicals, such as handling, storage, disposal, reactivity, manufacturer These systems have been developed to protect you and the environment 5 HHPS SYMBOLS Explosive Flammable Poisonous Corrosive 6 1.2 Properties and Classification of Matter • (1) (2) Two types of properties that matter has: Chemical:Describes the reactivity of the substance. Ex. combustability, flammability, reactivity with water, ability to neutralize Physical: Describes the physical appearance and composition of the substance Ex. boiling/melting point, colour, density, state of matter, ductility, malleability 7 Chemical Reactions • • • • • • • • • To observe a chemical property, you must see chemical change How do you know if a chemical reaction has happened? At least one new substance is produced • Ex. Bubbles, A Precipitate A change in colour Energy is absorbed or released in the form of heat, light or sound Odour is released The reaction may be difficult to reverse The reactants of a chemical change will have different chemical and physical properties than the products If a new substance is not produced (i.e. a change in state), then only a physical change has occurred 8 Classifying Matter • • • • Matter is often grouped and sub-grouped based on chemical and physical properties All matter can be classified as a pure substance or a mixture In a pure substance, all of the particles that make up the substance are identical A mixture is a combination of two or more pure substances 9 10 Pure Substances • • • • • Pure substances can further be broken down into elements and compounds Elements cannot be broken down into smaller substances and are found on the periodic table Ex. Helium, Sodium, Lithium Compounds are chemical combinations of two or more elements in a fixed ratio Ex. Water, Baking Soda, Carbon Dioxide 11 Mixtures • • • • 1) 2) 3) Mixtures can further be broken down into Homogeneous and Heterogeneous Mixtures A Homogeneous mixture is a solution because of the consistent composition throughout the substance Ex. Air, Coffee, Hydrochloric Acid A Heterogeneous Mixture can be considered a Mechanical Mixture, a Suspension or a Colloid Mechanical Mixture: Different Substances are visible. Ex. Soil, Cereal, Concrete Suspension: The components are in different states of matter. Ex. Italian Salad Dressing, Dirt Water Colloid: Similar to the suspension, but the parts cannot be easily filtered and separated. Ex. Ranch Salad Dressing, milk 12 1.3 Developing Ideas of Matter • Early people used their knowledge about the nature of matter to meet their basic needs: • Food Chemistry • Metallurgy • Alchemy 13 Food Chemistry • • • • Heating: Raise the temperature to temporarily sterilize it Freezing: Lowering the temperature to prolong decomposition Salting: Adding salt to draw water out of meat Fermentation: Biochemical method of food preservation that maintains nutrient levels through use of bacteria called lactobacilli, which convert sugar and starch into lactic acid 14 Metallurgy • • • • • Metallurgy is the science of producing and using metals Ex. Use of gold to make jewellery, not weapons; too malleable and rare Ex. Use of copper to make weapons, such as spears, arrows and knife blades Ex. Use of copper to make handles for pots, staples and rivets Ex. Smelting of tin with copper or iron with carbon to make metal alloys 15 Alchemy • • Alchemy is the combination of science and magic Alchemists hoped to use chemical processes to try to turn cheap materials into valuable substances, such as lead into gold 16 The Development of the Atom • • • Through this work, ancient people began to wonder what made up matter Atoms were proposed by Democritus thousands of years before work of early scientists Early scientists began to develop experiments to study matter and the concept of atoms 17 Robert Boyle and Antoine Lavoisier • • • Boyle, through experimenting with the relationship between volume and pressure of gasses, concluded that gases are made of tiny particles Lavoisier, through experimenting with chemicals during chemical reactions, discovered that the mass of the reactants was always the same as the mass of the products This theory is known as the Law of Conservation of Mass 18 John Dalton (1766 – 1844) • • • • English chemist and physicist Proposed that all atoms were like small solid spheres, but they could have different properties He claimed they varied in size, colour and mass Often referred to as the Billiard Ball Model 19 Dalton’s Atomic Theory • Dalton also proposed a theory about atoms: All matter is made of small, invisible particles called atoms All atoms of an element have identical properties such as size and mass Atoms of different elements are not the same Atoms can combine together in fixed ratios to form new substances 20 J.J. Thomson (1856 – 1940) • • • • • • English physicist Discovered the electron through experimenting with beams of particles produced in a vacuum tube Experiment showed that the beam was made of negatively charged particles Showed that different elements all produced the same negatively charged beam Proposed that the negative charge was embedded throughout a positively charged atom Known as the Plum Pudding Model/Raisin Bun Model 21 Ernest Rutherford (1871 – 1937) • • • • • • • English scientist who began working with radioactive materials Discovered the nucleus of atoms through gold foil experiment Encased the radioactive material in lead with only a small opening This material released positively charged particles, which he aimed at gold foil The gold atoms would either have no effect on the beam, or would slightly deflect it 1 in 10 000 particles would bounce back or be sharply deflected Suggested that the atom was made of mostly space with a dense, positively charged core 22 23 Neils Bohr (1885 – 1962) • • • • Danish Physicist Proposed that electrons circle the nucleus in specific shells or energy levels Evidence for energy levels was based on hydrogen When hydrogen is made to glow in a tube, it releases light in a specific spectrum 24 The Quantum Mechanical Model of the Atom • • • • • Today’s model of the atom Abstract model that’s difficult to visualize Electron location is based on mathematical probability Electrons are thought of as a “cloud” of negative charge Nucleus is made of nucleons: protons (positively charged) and neutrons (neutrally charged) 25 2.0 Elements Combine to Form Compounds Enduring Understanding: Elements combine to form many substances, each with its own set of properties • • • • • The Periodic Table and Atomic Structure Naming Ionic and Molecular Compounds Properties and Classification of Ionic and Molecular Compounds Acids and Bases Our Chemical Safety 26 Metals • • • Metals share similar properties Malleable, ductile, lustrous, solid at room temperature (except for mercury), good conductors of heat and electricity Found on the left side and center of the periodic table 27 Non-Metals • • • • Non-metals are grouped based on their differences from metals, rather than similarities to other substances Brittle, can be solid, liquid and gas, dull, poor conductors of heat and electricity Gases commonly form molecular elements, or molecules of the same element, Ex. H2 Found on the right hand side of the periodic table 28 Metalloids • • • Properties that are intermediate of metals and non-metals Ex. Some conduct electricity, but not very well Metalloids are found on the staircase dividing metals from nonmetals 29 30 2.1 The Periodic Table and Atomic Structure • • • • • The periodic table organizes elements based on chemical and physical properties Periods refer to the horizontal rows of the periodic table, as the properties of chemicals seem to repeat periodically as you travel from one side of the table to the other Groups or families refer to the vertical columns of the periodic table Chemical families share similar chemical properties Different chemical families: • Alkali Metals • Alkaline-Earth Metals • Halogens • Noble/Inert Gases 31 32 Alkali Metals • • • • Group 1 Most reactive group of metals Soft, shiny and highly reactive with water Form highly soluble compounds 33 Alkaline – Earth Metals • • • • Group 2 2nd most reactive group of metals Shiny, but not as soft as alkali metals Form less soluble, often white compounds 34 Halogens • • • • • Group 17 Most highly reactive group of non-metals Highly poisonous React to form salts Form molecular elements 35 Noble/Inert Gases • • Group 18 Very unreactive gases 36 The Atom • • • • • The atom is the smallest part of an element, made of protons, neutrons and electrons Protons are located in the nucleus, are positively charged and do not leave the atom during a chemical reaction Electrons are located surrounding the nucleus, are negatively charged and are exchanged or shared during a chemical reaction Neutrons are located inside the nucleus, are neutrally charged Protons and electrons are attracted to each other because they are oppositely charged 37 Using the Table to Find Subatomic Particles • • • • Because an atom is neutrally charged in an atom, the number of protons and electrons must be equal The number of electrons and protons is equal to the atomic number of the element Because protons and neutrons make the majority of the atomic mass of an atom, the number of neutrons is equal to the atomic mass, rounded to the nearest whole number, minus the atomic number The number of neutrons may vary between atoms of the same element, thus creating isotopes 38 Energy Levels • • • • • • Electrons occupy energy levels, or a specific region of space The energy levels closest to the nucleus have the lowest amount of energy, and electrons in this level are tightly held to the nucleus The number of electrons that can occupy a region varies depending on the level The first level can hold 2 electrons, the second can hold 8, the third can hold 8 Beyond this, the pattern is far more complicated Energy levels can be empty, partially filled, or completely filled 39 Formation of Ions • • • • • • • Under some circumstances, an atom can gain or lose electrons to become an ion This occurs to create a more stable structure Stability occurs when the last energy level contains the maximum number of electrons possible Atoms lose or gain electrons to become ions which have full valence An element will gain electrons if it has over a half full last shell, thus becoming negatively charged, as non-metals do, becoming anions An element will lose electrons if it has less than half full last shell, thus becoming positively charged, as metals do, becoming cations This process is called ionization, as the new particle is called an ion 40 41 The Octet Rule • • • The Noble Gases have complete valence, thus explaining their unreactivity The octet rule is modeled on Argon and Neon, both containing valences of 8 The Octet Rule states that atoms will bond in such a way as to have 8 electrons in their valence levels 42 2.2 Naming Ionic and Molecular Compounds • (1) (2) • Compounds can be broken into two basic types: Ionic Molecular IUPAC (International Union of Pure and Applied Chemistry) is responsible for developing names for compounds to maintain consistency and set standards 43 Ionic Compounds • • • • • • Bonds between metals and non-metals Form as a result of a transfer of electrons to form ions Ions have an electrostatic attraction that holds them together in a crystal lattice The ions are in specific ratio, depending on how many electrons were transferred Ex. sodium chloride (NaCl), baking soda (NaHCO3) Ionic compound properties: • Solid at room temperature • High melting points • Tend to dissolve in water • Solutions of ionic compounds almost always conduct electricity 44 45 Naming Ionic Compounds (1) (2) (3) (4) (5) (6) Name the cation using the elements name Name the anion only using the first part of the anion name, add the ending “ide” NO PREFIXES ARE USED If the element has multivalence, need to balance the charges to determine which valence is used, and then use Roman Numerals to denounce the cation If the compound contains a polyatomic ion, use the name of the ion from the table of polyatomic ions; do not change the ending from “ide” , “ite” or “ate” Use only lower case letters; no capitals 46 Writing Formulas for Ionic Compounds (1) (2) (3) (4) (5) Identify the ions and their charges Determine the ratio of positive to negative charges needed Use subscripts to write the formula If multivalence elements are used, use Roman Numerals to indicate which element is being referred to If Polyatomic ions are used, use brackets around the ion, and write the subscript on the outside of the brackets 47 Molecular Compounds • • • • • Bonds between non-metals to form molecules Form as a result of sharing electrons; do not form ions Do not form crystal lattices, form independent particles with elements combined in fixed ratios Ex. carbon dioxide, glucose Properties of Molecular Substances: • Can be solid, liquid or gas • Tend to be poor conductors, even when in solution • Many do not dissolve in water very well 48 Molecular Elements • • • Molecules that are made up of only one type of element are called molecular elements Form to increase stability Ex. H2(g), N2(g), O2(g), F2(g), Cl2(g), Br2(g), I2(g), P4(g), S8(g) 49 Naming Molecular Compounds – No Hydrogen (1) (2) (3) (4) Name the first element using the elements name Name the second element only using the first part of the element name, add the ending “ide” USE PREFIXES TO INDICATE HOW MANY OF EACH ELEMENT HAS BEEN USED If there is only one atom of the first element, no prefix is use 50 Prefixes 1 2 3 4 5 – mono – di – tri –tetra – penta 6 – hexa 7 – hepta 8 – octa 9 – nona 10 - deca ***7 is NOT ‘septa’ *** (Southeastern Pennsylvania Transportation Authority) 51 Naming Molecular Compounds – Hydrogen Containing • • • • • • • • • • • Many compounds of hydrogen have just been given names H2O(l) – water H2O2(l) – hydrogen peroxide NH3(g) – ammonia C12H22O11(s) – sucrose C6H12O6(s) – glucose CH4(g) – methane C3H8(g) – propane CH3OH(l) – methanol C2H5OH(l) – ethanol H2S(g) – hydrogen sulfide 52 Writing Formulas for Molecular Compounds (1) (2) (3) Write the symbol for the first element, followed by the subscript which matches the prefixes Write the symbol for the second element, followed by the subscript which matches the prefix Use only lower case letters 53 2.3 Properties and Classification of Ionic and Molecular Compounds • Ionic compounds have unique properties from molecular compounds 54 Properties of Ionic Compounds • • High Melting Point • Have high melting points which make them solid at room temperature • Large amount of energy must be added to break the bonds between cations and anions Retention of Crystal Shape • Retain crystal shape regardless of size of piece resulting from the positive and negative alignment of the ions 55 Properties Continued.. • • Solubility in Water • All ionic compounds dissolve to a certain extent due to the attraction of the anions and cations to water molecules • Water molecules are polar, with slightly positive and negative regions within the molecule, thus the attraction Conductivity of Solution • When ionic compounds dissolve in water, free floating ions occur, creating an electrolyte • This electrolyte will conduct electricity 56 Determining the Solubility of an Ionic Compound • (1) (2) (3) (4) • Use a solubility chart Find the anion along the top of the chart Go down the column to find the cation Determine the solubility Use subscript (aq) to symbolize highly soluble Sometimes when ionic compounds are mixed, they will form a precipitate, a solid with low solubility 57 Properties of Molecular Compounds • • Low Melting Point • Have low melting points • The attraction between molecules is very weak and easily broken using heat energy • The compound does not separate, only the molecules Crystal Shape • When molecular compounds form crystals, they are easily crumbled due to the weak attractive forces between the bonds 58 Properties Continued.. • • Solubility in Water • Recall, polar refers to slight separation of positive and negative charges within a molecule, thus creating positive and negative areas • If the molecule is polar, it will dissolve in water, because water is polar • If the molecule is non-polar, it will not dissolve in water Poor Conductivity of Solution • Molecular compounds do not conduct electricity, even when in solution 59 2.4 Acids and Bases • Acids have unique properties from bases *Coke Classic* 60 Properties of Acids • • • • • • • • • • Solutions that have a pH less than 7 Contain H+ ion Taste Sour Feel Wet Corrosive React with metals React with litmus to turn red Turn phenolphthalein clear Turn bromthymol blue yellow Conduct electricity 61 Naming Acids • • • Hydrogen _______ide hydro _______ic acid Hydrogen _______ate _______ic acid Hydrogen _______ite _______ous acid 62 Properties of Bases • • • • • • • • • • Solutions that have a pH greater than 7 May contain (OH)- ion Taste bitter Feel Slippery Corrosive Do not attack metals React with litmus to turn blue Turn phenolphthalein pink Turn bromthymol blue blue Conduct electricity 63 Neutralization • • When acids and bases react together, the new substance becomes more neutral, moving closer to a pH of 7, thus neutralization has occurred When an acid reacts with a base, water and a salt are formed 64 Acids and Bases at Home • • Bases tend to be found in many chemical cleaners, especially to clean off grease or oil Acids tend to be found in our food, but can also be used as cleaners 65 2.5 Our Chemical Society • • • • Issues related to Chemicals • Environmental effects and toxic effects related to humans need to be considered Health Concerns • Damaging effects of alcohol and nicotine Regulated Substances • Benzene, due to its level of danger must be highly controlled and regulated Chemistry Related Careers • Food Technologists, Cosmetic Formulator, Engineers 66 3.0 Chemical Change Enduring Understanding: Chemical change is a process that involves recombining atoms and energy flows • • • • Important Examples of Chemical Change Writing Chemical Equations Five Common Chemical Reactions The Mole 67 3.1 Important Examples of Chemical Change • • • • In a chemical reaction, the chemicals reacting together are called reactants The chemicals produced are called the products The reactants are written on the left hand side of a chemical equation, and are separated by an arrow from the products, which are written on the right hand side of the arrow Recall that the products will have new and different properties than the reactants 68 Indicating State of Matter • • • • Indicate the state of matter of the chemical by using subscripts, gas (g), liquid (l), solid (s) and aqueous (aq) All ionic compounds are solid at room temperature If added to solution, they may be aqueous; need to consult chart Molecular states are hard to predict. Generally small molecular compounds tend to be gases, large tend to be solids 69 Energy Change and Chemical Reactions • • • • • • Energy flow is an essential part to chemical reactions Energy can be either released or absorbed Exothermic describes reactions which release energy, usually in the form of heat, light or electricity Ex. A Battery, Combustion Endothermic describes reactions which absorb energy Ex. A Cold Pack, Cooking 70 3.2 Writing Chemical Equations • • • Two ways to represent chemical reactions is using a chemical equation or a word equation Chemical Equation: • 6CO2(g) + 6H2O(l) C6H12O6(s) + 6O2(g) Word Equation: • carbon dioxide reacts with water to produce glucose and oxygen gas • carbon dioxide + water glucose + oxygen 71 Balancing Chemical Equations • • • • Because of the Law of Conservation of Mass, the number of atoms used in the reaction must be conserved, thus it is necessary to balance the equation using whole number coefficients The chemical formula is not changed, only a coefficient is added in front of the compound to indicate the number of compounds reacting The lowest possible combination of compounds is used When Balancing, try balancing: • Metals • Polyatomic Ions • Non-Metals • Hydrogen 72 • Oxygen 3.3 Five Common Chemical Reactions • • • • • Formation Decomposition Single Replacement Double Replacement Hydrocarbon Combustion 73 Formation, Simple Composition or Synthesis • • • A + B AB Element + element compound Na(s) + Cl2(g) NaCl(s) 74 Decomposition • • • AB A + B Compound element + element NaCl(s) Na(s) + Cl2(g) 75 Single Replacement • • • Element + compound element + compound A + BC B + AC, where the metallic element replaces the metal in the compound Na(s) + MgBr2(s) Mg(s) + NaBr(s) 76 Double Replacement • • • compound + compound compound + compound AB + CD AD + CB, where the metallic element in the first compound replaces the metallic element in the second compound NaI(s) + MgBr2(s) MgI2(s) + NaBr(s) 77 Hydrocarbon Combustion • Hydrocarbon compound + oxygen water + carbon dioxide CxHx + O2(g) H2O(l) + CO2(g) Balance the following equation: • __C3H8(g) + __O2(g) __H2O(l) + __CO2(g) 78 Check your work • C3H8(g) + 5O2(g) 4H2O(l) + 3CO2(g) 79 Predicting the Products of a Chemical Reaction (1) (2) (3) (4) Classify the reaction as one of the five reaction types Predict the products resulting based on the reactions pattern Re-write the chemical formulas for the products Balance the equation 80 3.4 The Mole • • • Atoms are too small to measure using our metric system Atoms must be grouped together when measuring their mass This group is extremely large due to the small nature of atoms 81 Avogadro’s Number and the Mole • • • The grouping that chemists use is called the mole (mol) There are 6.02 x 1023 particles in one mole This many atoms is referred to as Avogadro’s number, named after the Italian scientist Amedeo Avogadro 82 Molar Mass of Elements • • • • • • • • To find the mass of one mole of any element, look at the atomic mass This is called the Molar Mass Ex. 1 mole of hydrogen has a mass of 1.01 g, thus, 6.02 x 1023 hydrogen atoms have a mass of 1.01g If you have a fraction of one mole, or more than one mole, you can calculate the mass by using the formula: m=nxM m = mass (g) n = number of moles (mol) M = molar mass (g/mol) 83 Molar Mass of Compounds • • • To find the molar mass of compounds, simply add the molar mass of the individual elements that make up the compound In a balanced chemical equation, the number of moles of each compound is indicated by the coefficients • 6CO2(g) + 6H2O(l) C6H12O6(s) + 6O2(g) Ex. 6 moles of CO2(g) + 6 moles of H2O(l) 1 mole of C6H12O6(s) + 6 moles of O2(g) 84