Name ______________________________________ Date ____________ Class _______________________ Modern Chemistry • CHAPTER 17 HOMEWORK 17-1 (pp. 511–517) 1. Explain the difference between temperature and heat. ____________________________________________________ _________________________________________________________________________________________________ _________________________________________________________________________________________________ 2. VOCABULARY A. Choose the term from Column B that is most closely related to each term in Column A. Write the letter of the term you choose in the space at the right. Column A Column B ____1. exothermic a. ∆ H ____2. endothermic b. thermochemical ____3. enthalpy c. gives off heat ____4. heat of reaction d. absorbs heat e. amount of energy released or absorbed as heat B. Write true or false. ____________1. The molar heat of formation refers to the heat released or absorbed when a compound decomposes into its elements. ____________2. A compound has a high negative heat of formation if a large amount of energy is released when the compound is formed. ____________3. Compounds with highly positive values of heats of formation are stable compounds. ____________4. The heat of combustion is the heat released by the complete combustion of one mole of a substance. ____________5. A combustion calorimeter can be used to determine heats of combustion. 3. Graphic Organizer A. Use the words absorbed, exothermic, positive, negative, endothermic, and released to complete the chart. Type of Reaction Enthalpy of Reaction Heat is B. This chart shows standard enthalpies of formation in kcal/mol for various substances. Write whether the formation of each substance is an exothermic or endothermic reaction. Substance ∆ H (kcal/mol) Exothermic or Endothermic AlCl3(s) –167.4 HCl(g) –22.1 NO(g) 21.6 O3(g) 34.0 MgO(s) –143.8 Name ______________________________________ Date ____________ Class _______________________ Modern Chemistry • CHAPTER 17 HOMEWORK 17-1 (pp. 511–517) 4. MULTIPLE CHOICE Choose the letter of the best answer. ______1. Which should not be included in a thermochemical equation? A. number of molecules of reactants B. physical state of the products C. number of moles of reactants D. coefficients that are fractions ______2. Which statement is not true? A. A chemical equation does not tell you the heat that is involved in a reaction. B. A system must be at constant pressure in order to measure the enthalpy. C. Fractional coefficients can be used in thermochemical reactions. D. The enthalpy of a system can be measured directly. 5. Use the above chart to answer the next 3 questions. ________________________A. Which compound is most stable? Include the physical state. ________________________B. Which compound (including physical state) is least stable? C. Use the values in the chart to draw a general conclusion about the stabilities of various states of matter. __________________________________________________________________________________________________ __________________________________________________________________________________________________ 6. In each group, which is the most stable compound? __________a. NH3 Ca(OH)2 FeCl2 __________b. Na2SO4 K2SO4 MgSO4 7. In each group, which is the least stable compound? __________a. NH3 K2SO4 SO3 __________b. Ca(OH)2 N2O3 LiNO3 Name ______________________________________ Date ____________ Class _______________________ Modern Chemistry • CHAPTER 17 HOMEWORK 17-1 (pp. 511–517) 1. Temperature is a measure of the average kinetic energy of particles, while heat is the total kinetic energy of all particles in a sample of matter. VOCABULARY 1. c 2. d 3. a 4. e VOCABULARY AND SKILL BUILDER 1. false 2. true 3. false 4. true 5. true GRAPHIC ORGANIZERS Enthalpy and Heat Type of Reaction Enthalpy of Reaction Heat exothermic negative released endothermic positive absorbed Substance Δ H Exothermic or Endothermic AlCl3(s) –167.4 exothermic HCl(g) –22.1 exothermic NO(g) 21.6 endothermic O3(g) 34.0 endothermic MgO(s) –143.8 exothermic STANDARDIZED TEST PREP 1. a 2. d CHAPTER 17 • HOMEWORK 17-3 SKILL BUILDER 1. solid potassium sulfate 2. ethyne gas 3. In general, solids are more stable than liquids and gases. 4. a. Ca(OH)2 b. K2SO4 5. a. NH3 b. N2O3 STANDARDIZED TEST PREP 1. a 2. c