Writer: Timothy Fiore Chemical Formula: Covalent and Ionic- Page 3 Bonding Diagrams: Covalent and Ionic- Page 8 Naming Compounds (Dear Timothy)- Page 12 VSEPR Theory- Page 15 Polarity- Page 18 Intermolecular Forces- Page 20 Comics- Page 22 1. 2. 3. 4. 5. Determine the charge on each element/ or polyatomic ion Write the charge above the element or polyatomic ion Criss-cross the two numbers and write them as subscripts Use parentheses around polyatomic ions if there is more than one Simplify so that the formula has smallest wholenumber ratio Page 3 Al O Al3 O-2 Al2O3 Ca SO3 Ca2 SO32 Ca2 (SO3)2 Ca SO3 Page 4 To write the formula for a covalent bond, use the Greek prefixes in the name of the compound. The prefix is what determines the subscript. If there is only one atom in the first element, omit mono. Mono 1 Hexa 6 Di 2 Hepta 7 Tri 3 Octa 8 Tetra 4 Nona 9 Penta 5 Deca 10 Page 5 Sulfur Dioxide 1S SO2 2O Dibromine Heptaoxide 2Br Br2O7 7O Page 6 Dear editor, Throughout all the articles I have read, this last one was the easiest to understand. Writing chemical formulas, specifically for covalent compounds, made a lot of sense to me. This is because all I really had to do was memorize the Greek prefixes in order to write the formulas. I really appreciate the way you explained how to write the formulas. You were a great help. I look forward to reading more of your magazines and articles. Sincerely, Matt Page 7 Bonding diagrams predict the compound formed between a metal and non-metal To make a bonding diagram one must know the electron dot diagram Element with the smaller number of electron goes to the one with more http://hyperphysics.phy-astr.gsu.edu/hbase/pertab/perlewis.html Page 8 Page 9 Use covalent bonding diagrams made with Hydrogen and elements from groups 14, 15, 16, and 17 Called the Lewis Dot Formula Must get each element to have 8 electrons except Hydrogen (2) Do not have to use electron dot structures Put element that makes most bonds in middle (Like elements from group 14) Page 10 http://www.docbrown.info/page04/4_72bon d3.htm Page 11 Dear Timothy, I am in chemistry now and I am having trouble naming compounds. Can you teach me how to do that? Sincerely, Spencer Dear Spencer, Yes! I can definitely help you name compounds. The compounds you will be using are called binary compounds. This means the compound is composed of 2 elements. First you have to know what type of compound it is. If the compound is made up of a metal and a non-metal that means it is ionic. This means the metal in the formula lost an electron to form a positively charged ion (cation). The non-metal in the compound has a negative charge called anions. Ionic compounds also sometimes include a polyatomic ion and a metal. Naming a regular ionic compound (metal and non-metal) is very easy. All you have to do is write the name of the first element, and the second element's stem with “ide” added to it. If a polyatomic ion is paired with a metal, it is still very easy. You just write the name of the element first, and the polyatomic ion second. No changes are necessary. If you are dealing with transition metals (from groups 3-12) you must first determine the charge on the metal. After that is done you write the charge as a roman numeral after the metal. I know that might seem like a lot to think about just to name an ionic compound, but I promise after you see the examples on the next page it will be a lot easier. Page 12 Naming Ionic Compounds: NaCl------Sodium Chloride Al(PO3)------Aluminum Phosphite NiBr2------Nickel(II) Bromide Dear Spencer, As you can see, naming an ionic compound is not tough. If you are dealing with a two non-metals then the compound becomes covalent. The elements in covalent compounds are Hydrogen, and all the elements in groups 13-16. To name covalent compounds you must first know the greek prefixes. You can find a table with the prefixes on page 5. In the formula to find out what prefix to use you look at the subscripts of each formula. Once you know the prefixes you just write out the first element name with the prefix attached, then the second element stem name with the prefix attached and “ide’’ added to the end of it. It is pretty much the same as naming an ionic compound but greek prefixes are attached to the words. Remember mono is omitted if you are dealing with the first element in the compound Page 13 Naming Covalent Compounds: P2I5------Diphosphorous pentaoxide CS2------Carbon disulphide Cl2O7------Dichlorine heptaoxide Dear Spencer, I hope that what I have shown you helped you name compounds. There is also a metallic compound formed between metals but you won’t ever have to name those so don’t worry.I assure you, they are not too hard once you practice! Sincerely, Timothy Page 14 Valence Shell Electron Pair Repulsion theory (VSEPR) predicts the shape of a molecule or a covalent compound. It is a lot similar to the bonding diagram for covalent compounds, but it uses geometry shapes instead of straight lines. The shared and unshared pairs of electrons repel from each other, or try to get as far away as possible. This is what makes the shape of the molecule or compound. There are 6 main shapes in the VSEPR theory. Page 15 Linear: There can be 2 or 3 elements and when they bond there is zero unshared pairs of electrons. Bent: There are three elements. The central atom can have 1 or 2 unshared pairs of electrons. Trigonal Planar: There are four elements. Three of the elements bond to the central element and as a result there is zero unshared pairs of electrons. Pyramid: There are four elements. Three elements are bonded to central element and as a result there is 1 unshared pair of electrons. Tetrahedral: There are five elements in this shape. The four outer elements bond to central element and there is zero unshared pairs of electrons. Trigional Pyramid: There are six elements in this shape. This shape is made from elements in period 3. Page 16 http://www.public.asu.edu/~jpbirk/CHM113_BLB/Chpt09/sld011.htm Page 17 Polar bonds are bonds where electrons are shared unequally between atoms. In the bond, the element with the most electronegativity will pull the electrons closest to itself. On the periodic table, electronegativity increases as it goes to the right and decreases as it goes down. Each atom has a different pull on electrons. The bond is not polar if electrons are shared equally between the two atoms. If the elements are the same then they have the same pull on the shared electrons. Generally, a molecule will always be polar if the elements outside are different. Oppositely, same atoms around a central atom will be non polar. Page 18 http://www.800mainstreet.com/5/0005009-polar-molecules.htm Page 19 Hydrogen Bond: A hydrogen bond is formed between Hydrogen and a lone pair electron found in Flourine, Oxygen, or Nitrogen. Dipole-Dipole Force: This force is formed between molecules that are polar and covalent. This is because of the electronegativity between nonmetals. London Dispersion Forces: Also known as Van der Waals Force. This force is made between covalent molecules that are not polar. Comes from the fact that electrons are always moving. Dipoles occur because of uneven electron distributions. Ionic Solids: These are ionic compounds (metal and non-metal). They are formed do to electrostatic attraction. Ionic bonding is higher as atoms get smaller, and higher as charges get bigger Page 20 http://preparatorychemistry.com/bishop_at traction_strengths.htm Page 21 http://faaizajaz.wordpress.com/2010/10/05/chemistry-jokes-are-funny/ http://www.chem.uci.edu/~potma/cartoons.htm Page 22