Chemistry Mav Marks http://www.sciencespot.net/Pages/startersphy sci.html Element Challenge 1 Mav Marks http://www.sciencespot.net/Pages/startersphy sci.html Element Challenge 2 Mav Marks http://www.sciencespot.net/Pages/startersphy sci.html Element Challenge 3 Mav Marks http://www.sciencespot.net/Pages/startersphy sci.html Atomic Math 1 Mav Marks http://www.sciencespot.net/Pages/startersphy sci.html Atomic Math 2 Mav Marks http://www.sciencespot.net/Pages/startersphy sci.html Atomic Math 3 Mav Marks http://www.sciencespot.net/Pages/startersphy sci.html Atomic Math 4 Mav Marks http://www.sciencespot.net/Pages/startersphy sci.html Common Compound 1 Mav Marks http://www.sciencespot.net/Pages/startersphy sci.html Common Compounds 2 Mav Marks http://www.sciencespot.net/Pages/startersphy sci.html Compound Challenge 1 Mav Marks http://www.sciencespot.net/Pages/startersphy sci.html Compound Challenge 2 Mav Marks http://www.sciencespot.net/Pages/startersphy sci.html Compound Challenge 3 Mav Marks http://www.sciencespot.net/Pages/startersphy sci.html Compound Challenge 4 Mav Marks http://www.sciencespot.net/Pages/startersphy sci.html Compound Challenge 5 Mav Marks http://www.sciencespot.net/Pages/startersphy sci.html Periodic Table 1 Mav Mark Test Day Take out a sheet of paper and a pencil. Clear your desk. Physical Properties Properties of matter that can be observed or measured without changing the identity of the matter Ex. Color, Smell, Mass, Volume, Density Conductivity (ability to transfer energy) State {physical form (solid, liquid, gas)} Malleability (ability to be hammered into thin sheets) Ductility (ability to be drawn into a wire) Solubility (ability to dissolve in another substance) Chemical Properties Chemical Properties: describe a substance based on its ability to change into a new substance with different properties Ex. Flammability, reactivity Metal reacts with oxygen to form rust. Physical Properties Properties of matter that can be observed or measured without changing the identity of the matter Ex. Color, Smell, Mass, Volume, Density Conductivity (ability to transfer energy) State {physical form (solid, liquid, gas)} Malleability (ability to be hammered into thin sheets) Ductility (ability to be drawn into a wire) Solubility (ability to dissolve in another substance) Physical changes A change that affects one or more physical properties of a substance, but doesn’t change its chemical identity. Ex: breaking a pencil, melting, dissolving sugar in water, cutting your hair, crushing an aluminum can Physical changes An easy way to tell if something is a physical change, is to determine if it can be undone. Ex: Ice cubes that melt in a bowl can be refrozen. A broken pencil still writes. Hair doesn’t turn into something else when it’s cut. Chemical Change A change that occurs when one or more substances are changed into entirely new substances with different physical properties. Ex. Baking a cake, effervescent tablets fizzing in water, a car rusting States of Matter There are four states of matter: solid, liquid, gas, and plasma Matter is in constant motion. Pure Substance Pure substances are made of only one type of particle. Elements: A pure substance that cannot be separated into simpler substances by physical or chemical means. Ex. Carbon (C), Oxygen (O), Gold (Au) Represented by 1 or 2 letters, first letter always capital Each element has unique physical and chemical properties that can be used to identify them. For the most part…elements can be divided into three categories. Pure substances: Elements Elements Metals Nonmetals Metalloids Pure substances: Elements Metals: Shiny, good conductors of electricity, malleable, ductile Nonmetals: Dull, poor conductors of electricity, brittle and unmalleable Ex. Iron, Copper Ex. Sulfur, Neon Metalloids: Semiconductors of electricity, somewhat malleable and ductile, some shiny some dull Ex. Boron, Silicon Periodic Table Pure Substance: Compounds Compounds: A pure substance that is composed of two or more elements that are chemical combined. Have a fixed ratio of elements. When compounds form they take on new characteristics. Ex. Na + Cl → NaCl or 2H2 + O2 → 2H2O Common Compounds NaCl: Sodium Chloride (Table Salt) H2O: Dihydrogen Monoxide (Water) CO2: Carbon Dioxide CH4: Methane C6H12O6: Glucose (Sugar) Pure Substance: Compounds Since compounds are composed of elements that are chemical combined, they must undergo chemical changes to be broken down into the constituent elements. Most of the substances that we deal with everyday are compounds, because most elements are too reactive to remain as a single element. Ex: Proteins, CO2, NH4 Mixtures A mixture is a combination of two or more substances that are NOT chemically combined. Ex. Pizza, Salt water Mixtures can be separated by physical means. (filtration, centrifuge, evaporation, mechanical separation, magnetism) Do not have fixed ratios. Mixtures :Solutions Homogenous (solution): Particles are uniform throughout Solute: substance that is dissolved Examples: Salt water, alloy (metals dissolved in metals) Brass=zinc+copper Ex: Salt Solvent: substances that is doing the dissolving Ex. Water (Universal Solvent!) Mixtures :Solutions Solubility: basically how much of the solute can be completely dissolved by the solvent Increases with: Temperature (except with gases) Surface Area Stirring Atoms An atom is the smallest particle into which an element can be divided and still be the same substance. (Building block of matter) Composed of… Protons Neutrons Electrons Atoms Particle Charge Mass Location Proton (+) 1 amu Nucleus Neutron Neutral 1 amu Nucleus Electron (-) Almost zero Electron Cloud Atoms Atomic number: tells the number of protons Mass number: # protons + # neutrons Atomic mass: average of the masses of the existing isotopes in an element Isotopes: Elements that have the same # of protons, but a different # of neutrons Some isotopes are radioactive (carbon dating) Naming: Isotopes are named for the element and then the atomic mass (Carbon-14) Practice Determine the number of protons, neutrons, and electrons in the following: Potassium (K) Oxygen (O) Sodium (Na) Helium-3 (3He) Ions Atoms that have either gained or lost one or more electrons. Therefore they have either a positive or negative charge. Cation: (+) Positive charge Anion: (-) Negative charge Atoms: Electrons Electrons orbit the nucleus of the atom. For the Bohr model electrons are placed in orbitals by the formula 2n2, where n=energy level So for the first energy level: The second energy level: The third energy level: 2(1)2=2 2(2)2=8 2(3)2=18 Reactivity All elements want to achieve noble gas configuration. They will donate or accept electrons to achieve this configuration. The most reactive elements are very close to achieving noble gas configuration and they readily achieve it! Ideally they want 8 electrons in their outer shell! Valance Electrons: outer electrons The Periodic Table Why is the Periodic Table important to me? The periodic table is the most useful tool to a chemist. You get to use it on every test. It organizes lots of information about all the known elements. Pre-Periodic Table Chemistry … …was a mess!!! No organization of elements. Imagine going to a grocery store with no organization!! Difficult to find information. Chemistry didn’t make sense. Dmitri Mendeleev: Father of the Table HOW HIS WORKED… Put elements in rows by increasing atomic weight. Put elements in columns by the way they reacted. SOME PROBLEMS… He left blank spaces for what he said were undiscovered elements. (Turned out he was right!) He broke the pattern of increasing atomic weight to keep similar reacting elements together. The Current Periodic Table Mendeleev wasn’t too far off. Now the elements are put in rows by increasing ATOMIC NUMBER!! The horizontal rows are called periods and are labeled from 1 to 7. Periods tell the number of energy levels the atom has. The vertical columns are called groups are labeled from 1 to 18. Groups…Here’s Where the Periodic Table Gets Useful!! Elements in the same group have similar chemical and physical properties!! (Mendeleev did that on purpose.) Why?? • They have the same number of valence electrons. • They will form the same kinds of ions. Families on the Periodic Table Columns are also grouped into families or groups. Families may be one column, or several columns put together. Families have names rather than numbers. (Just like your family has a common last name.) Hydrogen Hydrogen belongs to a family of its own. Hydrogen is a diatomic, reactive gas. (Br, I, N, Cl, H, O, F) Hydrogen was involved in the explosion of the Hindenberg. Hydrogen is promising as an alternative fuel source for automobiles Alkali Metals 1st column on the periodic table (Group 1) not including hydrogen. Very reactive metals, always combined with something else in nature (like in salt). Soft enough to cut with a butter knife 1 electron in outer orbital Alkaline Earth Metals Second column on the periodic table. (Group 2) Reactive metals that are usually combined with nonmetals in nature. Not as reactive as alkali metals. Several of these elements are important mineral nutrients (such as Mg and Ca) 2 electrons in outer shell Transition Metals Elements in groups 312 Less reactive harder metals Includes metals used in jewelry and construction. Metals used “as metal.” Higher densities and melting points than groups 1 and 2. Lanthanides and Actinides Transition metals placed here to keep periodic table from being too wide. Named for the elements that they follow. Lanthanides: Actinides: Shiny, reactive metals, used in steel manufacturing Radioactive (unstable) Synthetic past U! Boron Family/Group Elements in group 13 Aluminum metal was once rare and expensive, not a “disposable metal.” Contains 1 metalloid and 4 metals 3 electrons in outer level Solid at room temperature Carbon Family/Group Elements in group 14 Contains elements important to life and computers. Carbon is the basis for an entire branch of chemistry. Silicon and Germanium are important semiconductors. 4 electrons in outer shell Nitrogen Family Elements in group 15 Nitrogen makes up over ¾ of the atmosphere. Nitrogen and phosphorus are both important in living things. The red stuff on the tip of matches is phosphorus. 5 electrons in outer shell Oxygen Family/Group Elements in group 16 Oxygen is necessary for respiration. Many things that stink, contain sulfur (rotten eggs, garlic, skunks,etc.) 6 outer electrons Halogens Elements in group 17 Very reactive, volatile, diatomic, nonmetals Always found combined with other element in nature . Used as disinfectants and to strengthen teeth. 7 outer electrons The Noble Gases Elements in group 18 VERY unreactive, monatomic gases Used in lighted “neon” signs Used in blimps to fix the Hindenberg problem. Have a full valence shell. Reactivity Noble Gases are at the far right of the periodic table. Reactivity increases as you go to the left and the top of the periodic table. Chemical Bonding A chemical bond is the force of attraction that holds two atoms together. The key to bonding is found in the number of valance electrons. Valance electrons: electrons that are in the outermost energy level of an atom Remember the goal is to have 8 valance electrons (exception H and He) Chemical Bonding The oxidation number of an atom is the charge that atom would have if the compound was composed of ions. Bonding: Ionic, Covalent, Metallic Ionic bond: forms between a metal and a nonmetal where the metal gives up an electron to the nonmetal and the resulting oppositely charged ions attract each other. Bonding: Ionic, Covalent, Metallic Covalent bond: involves the sharing of electrons between atoms Can exist as a single, double, or triple bond (C, O, N) Bonding: Ionic, Covalent, Metallic Metallic bond: gives metals their unique characteristics due to delocalized electrons that can flow throughout the metal Occurs in transition metals. Predicting bonding First determine how many e- are in the atoms outer shell. Next determine whether it is likely to lose or gain e- or if it is able to share e-. Ionic=nonmetal+metal Covalent = nonmetal + nonmetal Predict whether the following will form ionic, covalent, or metallic bonds. Carbon and Carbon Cadmium and Cadmium Phosphorous and Fluorine Strontium and Selenium Chemical Reactions A chemical reaction is the process by which one or more substances undergo change to produce one or more different substances. Clues a reaction has occurred: Gas formation (bubbles) Precipitate forms (solid) Color change Energy change (heat absorbed or given off) Chemical formula A chemical formula is a shorthand way of writing a compound. It represents the element by the chemical symbol. It represents the quantity of the element by the subscript. Writing Covalent Chemical Formulas Prefixes to know: MonoDiTriTetraPenta- 1 2 3 4 5 HexaHeptaOctaNonaDeca- 6 7 8 9 10 Use prefixes to tell you the number of atoms of that element! Writing Covalent Chemical Formulas Carbon dioxide Dinitrogen monoxide Dihydrogen monoxide Triphosphorous pentoxide CO2 N 2O Writing Ionic Chemical Formulas Occurs between metals and nonmetals. The compound must be neutral. Sodium chloride Beryllium oxide Magnesium chloride Calcium chloride Chemical Equations Reactants → Products C + O2 → CO2 ***All equations must be balanced!!!*** The law of conservation of mass: mass can neither be created nor destroyed! The law of conservation of energy: energy can neither be created nor destroyed! Practice balancing equations Count the atoms! H2 + O2 → H2O Place coefficients to balance the atoms. Check and finish balancing. H=2 O=1 H2 + O2 → 2H2O H=2 O=2 H=2 O=2 H=4 O=2 2H2 + O2 → 2H2O H=4 O=2 H=4 O=2 Types of Reactions Synthesis A + X → AX Na + Cl2 → NaCl Decomposition AX → A + X H2CO3 → H2O + CO2 Types of Reactions Single-replacement reaction A + BX → AX + B Zn + HCl → ZnCl2 + H2 Double-replacement reaction AX + BY → AY + BX NaCl + AgF → NaF + AgCl Types of Reactions Rusting (Slow oxidation) 4Fe + 3O2 → 2Fe2O3 Combustion (Fast oxidation) CH4 + 2O2 → CO2 + 2H20 + Heat Energy and reactions Exothermic: energy is released (energy may be in form of light, electrical, or thermal) 2Na + Cl2 → 2NaCl + energy Endothermic: energy is absorbed or goes into the reaction (ex. Photosythesis) 2H2O + energy → 2H2 + O2 How a reaction gets started Activation energy: minimum amount of energy needed for substances to react. Factors that affect reaction rates Temperature: an increase in temperature increases the rate of the reaction Concentration: an increase in the amount of reactants increases the rate of the reaction Surface area: Grinding reactants into powder can increase the rate of reaction Factors that affect reaction rates Catalysts: a substance that speeds up a reaction without permanently being changed. Enzymes: proteins in human’s that act as catalyst. Factors that affect reaction rates Inhibitors: a substance that slows down or stops a chemical reaction Preservatives act as inhibitors to prevent spoilage Star Formation Sun made mostly of Hydrogen. The H exist in an extremely high energy state called plasma. In stars the pressure is so high that the nuclei of atoms, which normally repel, are joined together. (Nuclear Fusion) Two Hydrogen atoms collide and produce helium. Two Helium atoms collide and produce one helium and two Hydrogen atoms.