Unit 1. Matter and Change Do Now: What are the State of Matter? Objectives: Define the term “chemistry” Describe the difference branches of Chemistry. Describe the difference between a physical change and a chemical change and give several examples of each. Describe different characteristics of the three states matter. Classify a mixture as homogeneous or heterogeneous. Classify a pure substance as an element or a compound. Chapter 1 Section 1 Chemistry is a Physical Science Chemistry is the study of matter and the changes that it undergoes. Biological Science Chemistry Physical Sciences Chemistry is central to all sciences. Both living and non living matter have a chemical structure. Chemistry deals with: 1. What is material made of? 2. What is the makeup and internal arrangement of the atoms? 3. How does it behave when heated, cooled or mixed with other materials? Branches of Chemistry Organic chemistry – the study of carbon containing compounds. Inorganic chemistry – the study of substances that do not contain carbon (metals and gases). Physical chemistry – the study of the properties and changes of matter and their relation to energy. Analytical chemistry –the identification of the components and composition of materials. Biochemistry – the study of the processes occurring in living systems. Types of Research Basic Research - carried out for the sake of increasing knowledge. Most basic research is carried out in universities. Research is normally published in scientific journals. Types of Research Applied Research - carried out to solve a problem. Research is carried out by companies to make a profit. Usually short term goals set by the company. Summary 1) Define the word chemistry. 2) Name the five branches of chemistry. 3) Define basic and applied research. STATE OF MATTER States of Matter There are Four state of matter A. Solid B. Liquid C. Gas D. Plasma State of matter depends on Kinetic Energy between the particles A. Kinetic Molecular Theory KMT Particles The of matter are always in motion. kinetic energy (speed) of these particles increases as temperature increases. Four States of Matter A. Solids very low KE - particles vibrate but can’t move around fixed shape fixed volume Four States of Matter B. Liquids low KE - particles can move around but are still close together variable fixed shape volume Four States of Matter C. Gases high KE - particles can separate and move throughout container variable shape variable volume Matter and its Properties It’s Classified! Objective Distinguish between: intensive and extensive properties Physical & chemical changes/properties Classify matter Properties & Changes in Matter Extensive Physical vs. Intensive vs. Chemical A. Extensive vs. Intensive Extensive Property depends on the amount of matter present ex,.- Intensive Property depends on the identity of substance, not the amount Ex.- A. Extensive vs. Intensive Extensive Property depends on the amount of matter present ex,.- Volume, mass, Energy Intensive Property depends on the identity of substance, not the amount Ex.- melting point, boiling point, conduct electricity or heat WHAT ABOUT DENSITY?? A. Extensive vs. Intensive Examples: boiling point volume mass density conductivity A. Extensive vs. Intensive Examples: boiling point…… intensive Volume …. extensive Mass ….. extensive Density ….. intensive Conductivity ….. intensive PROPERTY B. Physical vs. Chemical Physical Property can be observed without changing the identity of the substance Chemical Property describes the ability of a substance to undergo changes in identity B. Physical vs. Chemical Examples: melting point physical flammable chemical density physical magnetic physical tarnishes chemical in air B. Physical vs. Chemical Examples: melting point physical flammable chemical density physical magnetic physical tarnishes chemical in air CHANGE C. Physical vs. Chemical Physical Change changes the form of a substance without changing its identity properties remain the same Chemical Change changes the identity of a substance products have different properties B. Physical vs. Chemical Signs of a Chemical Change change in color or odor formation of a gas formation of a precipitate (solid) change in light or heat Properties and Changes in Matter In the example of burning of charcoal, carbon and oxygen are the reactants in the combustion reaction. Carbon dioxide is the product. carbon + oxygen C + O2 (reactants) carbon dioxide CO2 (product) B. Physical vs. Chemical Examples: rusting iron dissolving in water burning a log melting ice grinding spices B. Physical vs. Chemical Examples: rusting iron dissolving burning in water a log or charcoal melting ice grinding spices chemical physical chemical physical physical Four States of Matter D. Plasma very high KE - particles collide with enough energy to break into charged particles (+/-) gas-like, variable shape & volume stars, fluorescent light bulbs, CRTs SOLUTIONS AND MIXTURES Objective: Classification DO of Matter NOW: What is a solution? Describe the difference between a heterogeneous and homogenous mixture A. Pure Substances Element composed of identical atoms EX: copper wire, aluminum foil A. Pure Substances Compound composed of 2 or more elements in a fixed ratio properties differ from those of individual elements EX: table salt (NaCl) A. Pure Substances Law A given compound always contains the same, fixed ratio of elements. Law of Definite Composition of Multiple Proportions Elements can combine in different ratios to form different compounds. A. Pure Substances For example… Two different compounds, each has a definite composition. Pure Substances (constant composition) Elements Listed on the Periodic Table Cannot be broken down into unique components Na, Cl, Al, O2, S8 Compounds Made of elements that are chemically joined Can be broken down NaCl, H2O, AlCl3, H2SO4 B. Mixtures Variable combination of 2 or more pure substances. Heterogeneous Homogeneous B. Mixtures (variable composition) Homogeneous Solutions – evenly distributed Heterogeneous not evenly distributed B. Mixtures Solution homogeneous very small particles no Tyndall effect Tyndall Effect B. Mixtures Colloid heterogeneous medium-sized Tyndall particles effect particles don’t settle EX: milk B. Mixtures Suspension heterogeneous large particles Tyndall effect particles settle EX: fresh-squeezed lemonade C. Mixtures Examples: mayonnaise muddy water fog saltwater Italian salad dressing C. Mixtures Examples: mayonnaise colloid muddy suspension water fog colloid saltwater solution Italian suspension salad dressing A. Matter Flowchart MATTER yes MIXTURE yes Is the composition uniform? Homogeneous Mixture (solution) PURE SUBSTANCE no Heterogeneous Mixture Colloids no Can it be physically separated? yes Can it be chemically decomposed? Compound Suspensions no Element A. Matter Flowchart Examples: graphite pepper sugar paint soda (sucrose) A. Matter Flowchart Examples: graphite element pepper hetero. mixture sugar compound (sucrose) paint hetero. mixture soda solution Tea – Homogeneous Mixture Air – Homogeneous Mixture Alloys – Homogeneous Mixtures Cereal – Heterogeneous Mixture Sand – Heterogeneous Mixture Separating Mixtures Only a physical change- no new matter Filtration - separate solids from liquids with a barrier (filter paper) Distillation - separate liquids because of different boiling points Heat mixture Catch vapor in cooled area Chromatography - different substances are attracted to paper or gel, so move at different speeds The Periodic Table A. Mendeleev Dmitri Mendeleev (1869, Russian) Organized elements by increasing atomic mass. Elements with similar properties were grouped together. There were some discrepancies. C. Johannesson A. Mendeleev Dmitri Mendeleev (1869, Russian) Predicted properties of undiscovered elements. C. Johannesson B. Moseley Henry Moseley (1913, British) Organized elements by increasing atomic number. Resolved discrepancies in Mendeleev’s arrangement. C. Johannesson II. Organization of the Elements A. Metallic Character Metals Nonmetals Metalloids C. Johannesson B. Blocks Main Group Elements Transition Metals Inner Transition Metals C. Johannesson Do Now: Classify the following as either a METAL, NON-METAL or METALLOID: a. Au b. Si c. Br d. An element that is brittle and conducts electricity e. An element that is malleable f. An element that has tendency to become an anion Periods and Families Periods: horizontal rows on the periodic table physical and chemical properties change somewhat regularly across a row. Elements closer to each other in the same period tend to be similar than those that are farther apart. Families: groups vertical rows of elements, aka Each group contains similar chemical properties Types of Elements METALS: Shiny Conductors of heat and electricity Most metals are malleable (can be pounded into thin sheets; a sugar cube sized chunk of gold can be pounded into a thin sheet which will cover a football field), Most metals are ductile (can be drawn out into a thin wire). Metals cont….. All are solids at room temp (except Mercury, which is a liquid) Metals tend to have low ionization energies, and typically lose electrons (i.e. are oxidized) when they undergo chemical reactions Alkali metals are always 1+ (lose the electron in s subshell) Alkaline earth metals are always 2+ (lose both electrons in s subshell) Compounds of metals with non-metals tend to be ionic in nature. Types of Elements NON- METALS: Vary greatly in appearance Non-lustrous Poor conductors of heat and electricity The melting points of non-metals are generally lower than metals Seven non-metals exist under standard conditions as diatomic molecules: H2(g) N2(g) O2(g) F2(g) Cl2(g) Br2(l) I2(l) (volatile liquid - evaporates readily) Non-Metals cont…….. Nonmetals, when reacting with metals, tend to gain electrons (typically attaining noble gas electron configuration) and become anions: Nonmetal + Metal -> Salt Compounds composed entirely of nonmetals are molecular substances (not ionic) Types of Elements Metalloids: Elements may share properties of metals and non-metals. A stair-step line separates the metals from the nonmetals on the periodic table. Metalloids cont…… Properties: All metalloids are solids at room temperature. Less malleable than metals but not as brittle as nonmetals. Metalloids tend to be semiconductors of electricity. (intermediate between metals and nonmetals). Metalloids cont…… Properties: Metalloids are used in semiconducting materials found in computers, calculators, televisions and radios. Elements include: boron, silicon, germanium, antimony Noble Gases Noble Gases - the elements in Group 18 of the periodic table. They are considered nonmetals. These elements are generally unreactive. All are gases at room temperature. Examples: neon, argon, krypton, xenon (all used in lighting) and helium.