National 4 & 5 Chemistry Every day consumer products Examples Booklet NATIONAL 4 AND NATIONAL 5 CHEMISTRY Unit 2: Nature’s Chemistry EVERDAY CONSUMER PRODUCTS PRACTICE EXAMPLES BOOKLET Document1 Page 1 of 15 National 4 & 5 Chemistry N4/5 Every day consumer products Examples Booklet ALCOHOLS PROPERTIES AND USES N4/5 USES OF ALCOHOLS Alcohol Use Alcoholic drinks ethanol C2H5OH Fuel for vehicles. Solvent for varnish, perfume, deodorant. Feedstock for making chemicals. Mixed with ethanol to make methylated spirits. methanol CH3OH Fuel Feedstock for making chemicals propanol C3H7OH Medical – used in hand sanitizers and drug preparation. Fuel Feedstock for making chemicals. Q1) Describe the properties of the alcohol family that make them suitable molecules to use in the examples shown above. You may wish to use page 59-62 of the National 5 Chemistry textbook to help you. Q2) a) Using page nine of your Chemistry Data Booklet copy and complete the melting and boiling points for the following alcohols. b) A student made the hypothesis that has chain length of an alcohol increases, its boiling point also increases. Which of the above alcohols should have their boiling points compared in order to test this hypothesis? C) The student also made the hypothesis that when the (–OH) functional group of alcohols are found at the end of the molecule it will have a higher boiling point. Which of the above alcohols should have their boiling points compared in order to test this hypothesis? Document1 Page 2 of 15 National 4 & 5 Chemistry N5 Every day consumer products Examples Booklet N5 NAMING ALCOHOLS Q1) Copy and complete No. of C atoms Alkanol Name Molecular Formula Full Structural Formula / Shortened Structural formula H 1 methanol H CH3OH C O H CH3OH 2 CH3 CH2 OH 3 4 5 6 Document1 Page 3 of 15 H National 4 & 5 Chemistry N5 1. Every day consumer products Examples Booklet N5 SYSTEMATIC NAMING - ALKANOLS Draw full structural formula and shortened structural formula of each of the following molecules. (a) ethanol (b) butan-2-ol (c) 3-methylpentan-1-ol (d) 2,4-dimethylhexan-1-ol (e) 3-ethylheptan-2-ol (f) 2. 2-methylbutan-2-ol Write the systematic name of the following alkanol molecules (a) (b) H H C (c) H H H O H H H H C C C O H H H H H H H O H H H C C C C C C H H H H H H C H H H (d) (e) H H (f) H H C H H C H H H H H H H C C C C C H H H H O H H H H C C C O H H C H H Document1 H H H H H H H O H C C C C C C C C H H H H H H H H H C C H H H H H N5 H CARBOXYLIC ACIDS PROPERTIES Page 4 of 15 N5 National 4 & 5 Chemistry Every day consumer products Examples Booklet PHYSICAL PROPERTIES – BOILING POINT Q1) The following graph shows the boiling point of alkanoic acids versus number of carbon atoms. Find the boiling points of methanoic acid, ethanoic acid, propanoic acid and butanoic acid in the data booklet and plot a spike chart on the graph paper. 180 160 Boiling point / oC 0 140 120 100 80 60 40 20 0 3 4 2 No.0of carbon atoms 0 0 0 Q2) Describe the relationship between the number of carbon atoms within the carboxylic acid and the effect on the boiling point of the acid. 1 0 Q3) The full structural formulae for the first three carboxylic acids are shown below. Suggest a general formulae for this family of compounds. N5 NAMING CARBOXYLIC ACIDS Copy and complete Document1 Page 5 of 15 N5 National 4 & 5 Chemistry No. of C atoms Alkanoic Acid Name Every day consumer products Examples Booklet Molecular Formula Full Structural Formula / Shortened Structural formula O 1 methanoic HCOOH H C O H HCOOH 2 CH3COOH 3 4 5 6 N5 1. ESTERIFICATION - EXTENSION Copy and complete the table below. Document1 Page 6 of 15 N5 National 4 & 5 Chemistry Every day consumer products Examples Booklet Alcohol Carboxylic Acid methanol butanoic acid Name of Ester pentanol pentyl ethanoate butyl hexanoate ethanol 2. Copy and complete the following (condensation) esterification reactions. (a) propan-1-ol C C C + water + O H H H H octanoic acid O H + + H + + + water + H O H H H H H C O C C C C C H H H H H + + water H H O H H C C O C C H + H H + H + ESTER FORMULAE - EXTENSION Name the following ester molecules. Document1 + + + 1. H + (c) N5 H + (b) methanol O H H O H H H CH3CH2CH2OH C Page 7 of 15 N5 National 4 & 5 Chemistry (a) O H C Every day consumer products Examples Booklet (b) H O H C H H H O H C C C C C C O O H H C C C H H H H (c) H H H O H H H H H H H H C C C C C C H H H H H H H (d) H H H H O H C C C H H H H O C C H H H (e) CH3CH2CH2COOCH2CH2CH2CH2CH3 (f) (g) CH3OOCH2CH2CH2CH2CH3 (h) CH3CH2CH2CH2COOCH2CH3 2. H CH3CH2OOCCH3 Draw the full structural formula of the following esters. (a) ethyl methanoate (b) propyl ethanoate (c) octyl ethanoate (d) heptyl propanoate (e) methyl hexanoate (f) N5 hexyl butanoate RESEARCH & RESPORT [2.1 AND 2.2] N5 Assessment Activity 2 In activity 2, candidates will produce a short report, of 50–100 words or equivalent, which covers both Assessment Standards 2.2 and 2.3. The Document1 Page 8 of 15 National 4 & 5 Chemistry Every day consumer products Examples Booklet candidate should, with guidance from the assessor, select an application of chemistry from a key area of this Unit, which they will investigate. The candidate should describe the use of the application and consider the effect of this application on the environment/society. This should be done individually by the pupil and conducted under supervised conditions. Research Task Focus of Research task Success Criteria 2.2 Describing an application By using the chemistry knowledge you have learned in this sub-topic describe an application in everyday life/society. This means use your unit 2 learning intentions to explain a situation where the chemistry knowledge you have learned has been used and put into operation in a real life situation. When chemistry is used in a real life situation it can be a benefit to society but sometimes can cause unwanted problems for society and has an impact on the environment. Highlight if possible a chemical issue that comes from a particular application of chemistry learned in this topic. It can be a chemical issue related or unrelated to the environment for example health etc. Evidence must demonstrate that the candidate has a clear understanding of the chemistry related to the application and its effect on the environment/society. 2.3 Describing a chemical issue in terms of the effect on the environment/society RESEARCH & REPORT [2.2] Document1 CHEMISTRY Page 9 of 15 The candidate’s report should make statements that are relevant to the application and to the issue, which demonstrate understanding of the underlying chemistry. These should use terms and ideas that are correct and at a depth appropriate to National 5 Chemistry. [key mandatory areas] N5 National 4 & 5 Chemistry Every day consumer products Examples Booklet USES / OCCURRENCE OF CARBOXYLIC ACIDS INTRODUCTION O Many carbon-based acids contain the carboxyl group (-COOH). Carboxylic acids are present in a large number of everyday substances, in our bodies and in nature. C O H carboxyl group (-COOH) Examples of carboxylic acids are: methanoic acid , ethanoic acid, butanoic acid, lactic acid, citric acid. Carboxylic acids are used in the manufacture of other chemicals. They are important feedstock molecules. RESEARCH Select one of the carboxylic acids listed above. Using a variety of resources research: The formula of the carboxylic acid and draw the structure of its molecule. The other name (common name / systematic name) of the carboxylic acid. The occurrence of the carboxylic acid in our everyday lives. The names of chemicals made using the carboxylic acid. REPORT Produce a report on your research. This can be in the form of a: Report / information leaflet Poster Presentation / talk. RESEARCH & REPORT [2.2] Document1 CHEMISTRY Page 10 of 15 N5 National 4 & 5 Chemistry Every day consumer products Examples Booklet USES / OCCURRENCE OF ESTERS INTRODUCTION Esters are molecules found in nature (plants and animal). Many plant fragrances and flavourings are esters. Vegetable oils and animal fats are esters. A number of drugs are esters. Esters are good solvents for varnishes. A characteristic feature of many ester molecules is they have pleasant smells. RESEARCH Research the uses / occurrence of esters in the categories in bold in the introduction. Select three different esters The name and formula of the each ester. The name and formula of the alcohol and carboxylic acid from which the ester is made. Where the ester is found in nature or the use of the ester. REPORT Produce a report on your research. This can be in the form of a: Report / information leaflet Poster Presentation / talk. RESEARCH & REPORT [2.2] Document1 CHEMISTRY Page 11 of 15 N4 / 5 National 4 & 5 Chemistry Every day consumer products Examples Booklet USES OF ALCOHOLS INTRODUCTION Common alcohol (ethanol) is the best-known alcohol as it is present in alcoholic drinks. Ethanol has many different uses. There are a number of different alcohols Examples are: ethanol, methanol, propanol (isopropanol), glycerol, ethylene glycol. Alcohols are present in a number of everyday chemicals. Alcohols are used to manufacture other chemicals. They are important feedstock molecules. RESEARCH Select one of the alcohols listed above. Using a variety of resources research: The formula of the alcohol and draw the structure of its molecule. The everyday chemicals, which contain the alcohol. The names of other chemicals, which are made using the alcohol as a feedstock. REPORT Produce a report on your research. This can be in the form of a: Report / information leaflet Poster Presentation / talk. RESEARCH & REPORT [2.2 & 2.3] CHEMISTRY PALM OIL Document1 Page 12 of 15 N5 National 4 & 5 Chemistry Every day consumer products Examples Booklet INTRODUCTION Esters are molecules found in nature (plants and animal). Many plant fragrances and flavourings are esters. Vegetable oils and animal fats are esters. Palm oil is an edible vegetable oil derived from the mesocarp (reddish pulp) of the fruit of the oil palms, primarily the African oil palm Elaeis guineensis, and to a lesser extent from the American oil palm Elaeis oleifera and the maripa palm Attalea maripa. RESEARCH Research the uses / occurrence of esters that are produced from palm oil. The name and formula of the esters obtained. The name and formula of the alcohol and carboxylic acid from which the ester is made. Where the ester is found in nature or the use of the ester. Use the internet or other sources to find out and discuss the impact on the environment and society of producing products from palm oil. Discuss the underlying chemistry of palm oil and why it is used in the products you discuss. At the end of the piece, list all the websites and other sources you have looked at during your research, even if you have not quoted from them directly. REPORT Produce a report on your research. This can be in the form of a: Report / information leaflet Poster Presentation / talk. RESEARCH & REPORT [2.2 & 2.3] CHEMISTRY METHANOL USED AS A FUEL Document1 Page 13 of 15 N5 National 4 & 5 Chemistry Every day consumer products Examples Booklet INTRODUCTION Methanol belongs to the alcohol family and is being used in some countries as a fuel. RESEARCH Research the underlying chemistry as to why methanol is regarded by some as a good fuel source for society. Use the internet or other sources to find out why methanol is not more widely used as a fuel and write a short article for a popular newspaper giving the arguments for and against using methanol/ethanol as a fuel for cars. Include relevant chemistry (for example, explain what complete combustion means and represent this as a chemical & structural equation) and discuss the impact on the environment and society. At the end of the piece, list all the websites and other sources you have looked at during your research, even if you have not quoted from them directly. REPORT Produce a report on your research. This can be in the form of a: Report / information leaflet Poster Presentation / talk. RESEARCH & REPORT [2.2. & 2.3] CHEMISTRY ETHANOL - FUEL OR FOOD? INTRODUCTION Document1 Page 14 of 15 N4 / 5 National 4 & 5 Chemistry Every day consumer products Examples Booklet Ethanol made from fermenting sugars (carbohydrates) from sugar cane, potatoes and corn, is a renewable source of energy. Ethanol is currently being used as a fuel for vehicles in some countries. However if farmers are growing crops to produce fuels, they are not producing food to feed people. There are large numbers of people in the world who experience hunger, so there are important decisions to be made regarding how crops are to be used. RESEARCH Using a variety of resources research: How ethanol for fuel is made from plants – naming the plants used. The reason why burning ethanol as a fuel would not add to the level of CO2 in the atmosphere. Name countries where production of ethanol for fuel is currently taking place and find data on how much ethanol is being produced. The issue of growing crops for food, versus growing crops of fuel. Is it possible to grow crops for food and for fuel? (Hint – look at producing ethanol from cellulose.) REPORT Produce a report on your research. This can be in the form of a: Report / information leaflet Poster Presentation / talk. Document1 Page 15 of 15