Thermodynamic Cycles Carlos Silva November 18th 2009 THERMODYNAMIC PROCESSES Different Processes Isobaric Isometric Isothermal ΔT = 0 but Q ≠ 0 Adiabatic Cyclic ΔT ≠ 0 but Q = 0 If clockwise – heat engine If counterclockwise – heat pump THERMODYNAMIC CYCLES Ideal (Carnot) Cycle Carnot Theorem • No engine operating between two heat reservoirs can be more efficient than a Carnot engine operating between those same reservoirs Pressure-Volume Temperature-Entropy Real Cycles There are no ideal cycles • Irreversible systems, losses of heat Types of Cycles Heat Engine • Rankine Gas Power Systems • Brayton Internal Combustion Engines • Otto, Diesel,Stirling, Atckison Refrigeration Heat Pump Air Conditioning HEAT ENGINE Heat Engines Converts thermal energy (heat) to mechanical output (work) The working fluids are gases and liquids. Phase change cycles • The engine converts the working fluid from a gas to a liquid. • Rankine • Regenerative Gas cycles • The working fluid is always gas • Carnot • Stirling Rankine (Classical steam engine) Generation power plants • practical Carnot Cycle • heat addition and ejection are isobaric (and not isothermal) Working fluid is alternatively vaporized and condensed PV vs TS diagrams Alternative Rankine cycles Super Heat Reheat Regenerative Reheat and Regenerative Efficiencies Cycle Efficiencies Unmodified Rankine Cycle Rankine Cycle with Regeneration Carnot efficiency 52.6% 52.6% Thermal efficiency 36.2% 38.4% % Increase in Power Generation 0% 6.1% mean temperature of heat addition 226.7 C 251.5 C GAS POWER SYSTEMS Brayton Cycle (Joule Cycle) Usually used in gas turbines • Basis of jet engines Examples 1968 Howmet TX 480 MW GE unit J85 GE unit Jet Engine diagram A-37 Dragonfly Combined Cycle Combining Rankine and Brayton cycles INTERNAL COMBUSTION Special type of heat engines Combustion of fuel used to produce work directly • in heat engines is used to heat the fluid • the expansion of the high temperature and pressure gases, produced by the combustion, directly applies force to a movable component of the engine, such as the pistons or turbine blades and by moving it over a distance, generate useful mechanical energy • combustion is usually intermittent Otto engine Gasoline vehicles • External ignition • Octane rating- measure of the resistance of gasoline and other fuels to detonate at constant volume. • The higher the value, the slower the fuel burns Diesel engine Diesel cars • no external ignition • highest efficiency due to compression ration • low speed engines can exceed 50% • Diesel Cetanes • combustion quality during compression ingnition Stirling Cycle Similar to Otto cycle • replace adiabatic per isothermals Used in Micro CHP Atkison Cycle four-stroke cycle to occur in a single turn of the crankshaft designed to bypass patents covering the existing Otto cycle engines REFRIGERATION AND HEAT PUMP Vapor compression cycle Refrigerator vapor • Freon Heat Pump Can pump heat in two directions • reversing valve Absorption Heat Pump Heated by gas, solar thermal, etc.. Air Conditioning Refrigerator + resistance Heat pump