Calculations based on Compounds Objective: To calculate formulas of compounds from data Samples are analyzed to determine type & amount of each component (type of atoms) Chapter 11, pp. 322 - 324 Molar mass Practice mole conversions Check answers from methane problems Determining formulas based on data % composition Empirical formulas Molecular formulas Chemistry Essential Standard 2.2.5 To analyze quantitatively the composition of a substance (empirical formula, molecular formula, percent composition, and hydrates) Calculate empirical formula from mass or % composition from experimental data Calculate molecular formula from empirical formula using molecular weight Determine the percentage composition by mass of a given compound Perform calculations based on percent composition Determine the composition of hydrates using experimental data Molar Mass for Compounds Molar Mass for Compounds Names: Molar Mass for Compounds Names: Practice What is the molar mass of Magnesium oxide? What is the number of moles of 60 g of Mg? How many moles are in 40 g of O? CH₄ Mole Ammonia side for homework Methane 1) What is the molar mass of CH₄? 2) How many moles are present in 34 grams of CH₄? 3) How many grams are in 11.5 moles of CH₄? 4) How many moles are there in 3.4 x 10²⁴ molecules of CH₄? 5) How many molecules are in 8.5 moles of CH₄? Mole calculations- methane 6) How many molecules are in 300 grams of CH₄? 7) How many grams are in 5.2 x 10²⁴ molecules of CH₄? Moles & mass (small sheet) 25 g NaCl 2.5 moles NaCl Hydrate: Copper II Sulfate – Penta Hydrate 35 grams of CuSO₄⁃5H₂O 3.2 moles of CuSO₄⁃5H₂O See Mass and Moles Worksheet Calculations based on Compounds Percent composition of each component in a compound Empirical Formula: formula derived from experimental data Based on mass Smallest possible whole number ratio of subscripts Molecular Formula: actual number of atoms of each element (actual subscripts) Percent Composition – by mass Show the contribution of each component to the mass of the compound Applies to all compounds Nuts & Bolts/Beans Determining % composition Magnesium chloride Magnesium oxide Determining % composition Magnesium carbonate Magnesium nitrate Write the steps to determine % composition 1. First, 2. For each type of atom, the % is calculated by: 3. The answers are checked by … Video segment Molecular vs. Empirical Formulas Molecular Formula Empirical Formula H2 O CH3COOH CH2O C6H12O6 By looking at the compounds above, Predict what type of compounds are used Empirical Formula Based on analytical data from an unknown sample Steps: Percent to mass Mass to mole Divide by small Multiply ‘til whole Empirical formula: steps Example 1. A compound consists of 72.2% magnesium and 27.8% nitrogen by mass. What is the empirical formula? Percent to mass Mass to mole Divide by small Multiply ‘til whole A compound is analyzed and found to contain 68.54% carbon, 8.63% hydrogen, and 22.83% oxygen. The molecular weight of the compound is known to be approximately 140 g/mol. What is the empirical formula? Percent to mass Mass to mole Divide by small Multiply ‘til whole Video: Empirical formulas Molecular formulas To calculate molecular formulas, you must know: Empirical Formula Molecular mass of the compound Empirical formula? Molecular mass? A 1.50 g sample of hydrocarbon undergoes complete combustion to produce CO₂ and H₂O. The empirical formula of this compound is CH₃. Its molecular mass has been determined to be about 78. What is the molecular formula? Empirical formula? Molecular mass? Caffeine has the following percent composition: carbon 49.48%, hydrogen 5.19%, oxygen 16.48% and nitrogen 28.85%. Its molecular mass is 194.19 g/mol. What is its molecular formula?