Name No: Homework 3 1- Which of the following gives the molarity of a 17.0% by mass solution of sodium acetate, CH3COONa (molar mass = 82.0 g/mol) in water? The density of the solution is 1.09 g/mL. A. 2.26 10-6 M B. 0.207 M C. 2.07 M D. 2.26 M E. 2.72 M 2- What is the molarity of a solution that is 26.0% by mass phosphoric acid (H3PO4) and that has a density of 1.155 g/mL? A. 2.30 10-3 M B. 0.30 M C. 2.30 M D. 3.06 M E. 300 M 3- What is the percent CdSO4 by mass in a 1.0 molal aqueous CdSO4 solution? A. 0.001 % B. 0.10 % C. 17.2 % D. 20.8 % E. 24.4 % 4- What is the percent CsCl by mass in a 0.711 M CsCl solution that has a density of 1.091 g/mL? A. 3.87 10-4 % B. 3.87 10-1 % C. 11.0 % D. 1.1 % E. 6.5 10-2 % 5- How many grams of water are needed to dissolve 27.8 g of ammonium nitrate NH4NO3 in order to prepare a 0.452 m solution? A. 769 g B. 36.2 g C. 100. g D. 0.157 g E. 157 g 6- The solubility of gases in water usually decreases with A. B. C. increasing pressure. increasing temperature. decreasing temperature. 1 Name No: Homework 3 7- The vapor pressure of water at 20C is 17.5 mmHg. What is the vapor pressure of water over a solution prepared from 2.00 102 g of sucrose (C12H22O11) and 3.50 102 g water? A. 0.51 mmHg B. 16.0 mmHg C. 17.0 mmHg D. 18.0 mmHg E. 19.4 mmHg 8- A solution is 40.0% by volume benzene (C6H6) in carbon tetrachloride at 20C. The vapor pressure of pure benzene at this temperature is 74.61 mmHg and its density is 0.87865 g/cm3; the vapor pressure of pure carbon tetrachloride is 91.32 mmHg and its density is 1.5940 g/cm3. If this solution is ideal, its total vapor pressure at 20C is A. 84.64 mmHg. B. 84.30 mmHg. C. 82.96 mmHg. D. 81.63 mmHg. E. 165.93 mmHg. 9- Dissolving a solute such as KOH in a solvent such as water results in A. an increase in the melting point of the liquid. B. a decrease in the boiling point of the liquid. C. a decrease in the vapor pressure of the liquid. D. no change in the boiling point of the liquid. 10- What is the freezing point of a solution that contains 10.0 g of glucose (C6H12O6) in 100. g of H2O? Kf for water is 1.86C/m. A. B. C. D. E. -0.186C +0.186C -0.10C +0.10C -1.03C 11. Which of the following aqueous solutions has the highest boiling point? Kb for water is 0.52C/m. A. B. C. D. E. 0.2 m KCl 0.2 m Na2SO4 0.2 m Ca(NO3)2 0.2 m KCl AND 0.2 m Na2SO4 0.2 m Na2SO4 AND 0.2 m Ca(NO3)2 2