Unit 3 The Atom & Light Today… • Turn in: – Complete Unit 1 Goal Sheet • Write 2 things you would do differently if you did not meet your goal – When you turn in your Goal Sheet pick up a calendar & notebooklet • Our Plan: – New Calendar – Symbols Video – Review – BINGO – Symbols Quiz #1 – Build an Atom Online – due today – Begin Stop the Process Ch. 4 in your booklet – Wrap Up – Inside-Outside Circle • Homework (Write in Planner): – Build an Atom Online due Element Song http://www.youtube.com/watch?v=GFIvXVMbII0 Why can’t you remember the symbols if they can? Why can’t you remember the symbols if they can? Why can’t you remember the symbols if they can? Review • BINGO – Fill out a bingo card with the symbols of any of the elements that you were to memorize (use the handout you were given last class if you aren’t sure). – The instructor will call out an element; mark off the symbol if you have it. The first student to get a BINGO wins! Play will continue until there are 3 winners. – The prize – you can ask for 2 FREE ANSWERS on the quiz if you are one of the 3 winners! Ready for the Symbols Quiz? • • • • • • • • • • Fe Ag H He O Ar K Xe I U Iron Silver Hydrogen Helium Oxygen Argon Potassium Xenon Iodine Uranium • • • • • • • • • • Magnesium Aluminum Zinc Gold Phosphorus Carbon Francium Calcium Boron Lithium Mg Al Zn Au P C Fr Ca B Li Wrap Up • Inside-Outside Circle – Each student will get 1 or 2 element flashcards. – Find a partner. Form a circle in the classroom with one partner on the inside and one on the outside. Face each other. – Quiz your partner and they will quiz you. The instructor will tell you when and how to rotate (inside move 2 people left, outside move 1 person right, etc.) Today… • Turn in: – Build Your Own Atom Online - basket • Our Plan: – Review – Quiz, Quiz, Trade – Symbols Quiz #2 – Atoms Family Song – Finish Stop the Process – due today – Timeline Activity – Wrap Up – Group Draw • Homework (Write in Planner): – Timeline Activity due MONDAY Review • Quiz, Quiz, Trade –Every student will get 2 or 3 element flashcards. Move around the classroom finding partners. Quiz them, they will quiz you, and then trade cards. Continue finding new partners and learning the symbols. The Atoms Family Song! Activity Time • Complete the History of the Atom Timeline individually. • DUE MONDAY! Wrap Up - Group Draw • Number off 1 – 4 in your group and obtain a whiteboard or piece of construction paper. • As a group you are to draw a Sulfur atom with the correct number of protons, neutrons, and electrons in the correct location. – Person 1 – Energy Levels – Person 2 – Protons – Person 3 – Neutrons – Person 4 – Electrons Today… • Turn in: –Timeline Activity • Our Plan: –Review – Find Someone Who –Isotopes POGIL –Wrap Up – Word Wall Password • Homework (Write in Planner): –Nothing – Can finish POGIL next class Find Someone Who • Move around the classroom and find students who can answer the questions on p. 7 of your notebooklet. Be sure to get their signature or initials. POGIL Jobs • Leader – In charge of the group, reads the questions, summarizes what should be written • Task Master – Makes sure the group is on task and keeps track of time • Quality Control – Makes sure that everyone has close to the same answers recorded • Motivator – encourages the group and makes sure that everyone is participating and that all ideas are heard Wrap Up • $100,000 Pyramid Game •Wrap Up Time Ion Protons Atomic Number Nucleus Compound Chemical Symbol •Wrap Up Time Element Mass Number Electron Cloud Neutron Positive Quarks • Turn in: Today… – Nothing • Our Plan: – Review - Clicker Review – Finish POGIL – Hog Hilton – Notes – orbitals & electron configurations – Worksheet #1 – Wrap Up - Battleship • Homework (Write in Planner): – Worksheet #1 Review Activity • Atom Clicker Review Bohr • He said that electrons travel around the atom in defined orbits or energy levels • The energy levels are like rungs of a ladder Bohr’s Model Schrödinger • He developed the modern theory of the atom • Came up with mathematical equations to predict the locations of electrons • Quantum mechanical model – based on probability Analogy – p.130 • Similar to the motion of a rotating propeller blade. –Cannot tell its precise location at any instant –The cloud is more dense where the probability of finding an electron is high Atomic Orbitals • Electrons are found in energy sublevels (atomic orbitals) • The sublevel corresponds to an orbital of a different shape Atomic Orbitals • Orbitals are located inside energy levels just like subdivisions are located inside cities. Orbitals •Region of space in which there is a high probability of finding an electron Sublevels Energy Level Names of sublevels that exist in the energy level 1st Energy Level s 2nd Energy Level s and p 3rd Energy Level s, p, and d 4th & 5th Energy Level s, p, d, and f Label Your PT Sublevel # of Types of Orbitals Possible s 1 p 3 d 5 f 7 Types Orbitals • Only 2 electrons can fit in each orbital. • That means that any s orbital can only hold 2 electrons, and any d orbital can only hold 2 electrons • Since there are 5 d orbitals, it can hold 10 electrons total Electrons Sublevel # of Electrons s 2 p 6 d 10 f 14 Label Your PT Quantum Number •Indicates the probable location of an electron in an atom •LIKE AN ADDRESS! Principle Quantum Number • Symbol = n • Indicates – energy level • Possible Values – 1-7 (K-Q) • STATE Angular/Orbital Quantum # • Symbol = l • Indicates – sublevel • Possible Values – s, p, d, f • CITY Magnetic Quantum Number • Symbol = ml • Indicates – orbital orientation • Possible Values – x, y, or z • STREET Spin Quantum Number • Symbol = ms • Indicates – 2 possible spin states • Possible Values – +1/2 (CW) or -1/2 (CCW) • HOUSE NUMBER EXAMPLE • •n= 4 • p orbital •l = p • z axis •ml = z • Counterclockwise •ms = -1/2 spin th 4 energy level Break Time! • Do the front of WS#1. Challenge • This is the electron configuration for potassium. What do you think each number and letter means? 2 2 6 2 6 1 1s 2s 2p 3s 3p 4s The Blocks of the PT The Blocks of the PT • Whichever block an element is in corresponds to the orbital that it’s valence electrons are located. • Valence electrons are the outermost electrons in an atom Electron Configuration •Shows how many electrons an atom has in each of its sublevels. Remember • s holds 2 electrons • p holds 6 electrons • d holds 10 electrons • f holds 14 electrons Aufbau Principle • An electron occupies the lowest energy level that is available • Additional electrons keep “building up” to new levels Hund’s Rule • Every orbital in a subshell is singly occupied with one electron before any one orbital is doubly occupied, and all electrons in singly occupied orbitals have the same spin. • http://www.strw.leide nuniv.nl/~thi/lecture3/ aufbau4.gif Hund’s Rule • library.tedankara.k12.tr/ carey/ch1-1depth.html Visual representation of electrons • http://www.learner.org/interactives/periodi c/elementary_interactive.html Electron Configurations • All of these principles allow us to write an electron configuration for each element • Electron configurations show the location of each of an atoms’ electrons. Examples •Oxygen Examples •Potassium Examples •Bromine Try it Out! • Lithium –1s22s1 • Sulfur –1s22s22p63s23p4 • Cobalt –1s22s22p63s23p64s23d7 Want to try the f orbital? • The first f orbital is the 4f, the second is the 5f (one number behind the d orbital) • You say the f before you say the d orbital (just like it fits in on the periodic table). Example • Bismuth • Uranium •Do you feel smart yet? Noble Gas Notation • Instead of writing the whole electron configuration, you can just write the ones since the nearest noble gas. Examples 1. Magnesium 2. Iodine Try it Out! 1.Carbon 2 2 • [He]2s 2p 2.Iron 2 6 • [Ar] 4s 3d STOP! • Complete Worksheet #1 by next class • Worksheets are… – A completion grade (i.e. You do not get a grade until it is 100% finished) – 10 points on time – -2.5 points each day it’s late Wrap Up – Battleship • Obtain a Battleship board and a dry erase marker. On the bottom section, mark where you want to put your ships by blocking out boxes on the Periodic Table. – – – – – Destroyer – 4 Blocks Carrier – 5 Blocks Submarine – 3 Blocks Patrol Boat - 2 Blocks Battleship - 3 Blocks • Try to guess where your partner has placed their boats by asking them energy level, orbital, and how many electrons. For example, you might say 5s2. Your partner will say hit or miss. Play alternates and you continue until all ships are sunk. • Turn in: Today… – Get out WS#1 to Check – Get your Battleship Board Ready • Our Plan: – Battleship – Review/Quiz WS#1 – Notes – Light – Worksheet #2 – Wrap Up – Light Activities • Homework (Write in Planner): – Worksheet #2 – due next class Review – Which element? 1. 1s22s22p63s2 2. 1s22s22p63s23p64s23d8 5. Write Lead (noble gas notation) 3. 1s22s22p63s23p64s23d9 4. [Ar]4s23d4 6. Write Krypton (long form) Daily Challenge • What are the 6 types of radiation that make up the electromagnetic spectrum? Properties of Light •Light behaves as both a PARTICLE and a WAVE. Parts of a Wave Amplitude – height of a wave Parts of a Wave Wavelength – distance between waves from peak to peak or trough to trough Parts of a Wave Frequency – number of waves in a given unit of time Formula • The wavelength and frequency of light are inversely proportional to each other (oppositives). • c = λν • c = 2.998 x 108 m/s Important Note • All wavelengths must be in m to use the constant, so you may have to convert. • Hz and s-1 are the SAME THING Practice Problem • Calculate the wavelength of the yellow light emitted by a sodium lamp if the frequency of the radiation is 5.10 x 1014Hz. 5.88 x 10-7 m Try It Out! • What is the frequency of radiation with a -8 wavelength of 5.00 x 10 m? • (6.00 x 1015 s-1) Properties of Light • Electromagnetic Spectrum - made up of all the forms of electromagnetic radiation Electromagnetic Spectrum • 1. 2. 3. 4. 5. 6. 7. 7 types of Electromagnetic Radiation Gamma Rays X-Rays Ultraviolet Light Visible Light Infrared Radiation Microwaves Radio Waves Electromagnetic Spectrum Visible Light Frequency vs. Wavelength geography.uoregon.edu/.../geog101/ lectures/lec01/lec01.htm Visible Light • Visible light is the part of Ultraviolet Radiation that we can SEE! • To remember the colors in order of increasing frequency, remember ROYGBIV! E = hν E=Energy ν= frequency h= Planck’s Constant = 6.626 x 10 -34 J·s Energy and Frequency E = hν High ν = High E Low ν = Low E High E = dangerous! Challenge Which waves are most dangerous? Sample Problem • Find the amount of energy given off by a wave whose frequency is 1.6 x 1012 Hz. (Remember h = Planck’s constant = 6.626 x 10-34 J·s) • 1.1 x 10-21 J Try It Out! • Find the amount of energy given off by a wave whose frequency is 3.9 x 1018 Hz. • 2.6 x 10-15 J Light as Particles • Quantum – minimum amount of energy that can be lost or gained by an atom • Each particle of light carries a quantum of energy. The particles are called PHOTONS. Light Emission • Ground State – Lowest energy state of an electron • Excited State – When an electron has more energy than in it’s ground state Light Emission • When an excited electron moves to its ground state it GIVES OFF ENERGY (IN THE FORM OF ELECTROMAGNETIC RADIATION). • When an electron moves from its ground state to an excited state it REQUIRES ENERGY. Think of it like this.. • The energy levels are like rungs of a ladder • When you climb up or down a ladder, you must step on a rung (you can’t be between rungs) • It requires energy to go up the ladder and gives off energy when you go down Light Emission • The more energy levels the electron moves, the more energy it emits (quantum leap) • The amount of energy is consistent with the frequency (color) of light that is given off. • That’s why different elements give off different colors of light. Bohr’s Model of the Atom www.astrosociety.org/.../publicatio ns/ tnl/35/light3.html Continuous Spectrum • Continuous Spectrum – emission of a continuous range of frequencies of electromagnetic radiation Example: Rainbows and White Light Continuous Spectrum Did you know? • White light is a mixture of all colors of visible light • When sunlight passes through raindrops, it is broken into the colors of the rainbow Line Emission Spectra • Line-emission Spectrum – bands of light emitted by an atom Each element has its own distinct spectrum Emission spectrum can be used to identify unknown samples Line Emission Spectrum Absorption Spectrum • Bands of light absorbed by an atom Each element has its own distinct spectrum Absorption spectrum can be used to identify unknown samples Absorption Spectrum STOP! • Complete Worksheet #2 – due next class Wrap Up • Light Activities – Obtain a lifesaver individually, and as a group of 4 get a roll of tape and 2 sugar cubes. – The lights will be off and the room will be made completely dark. Allow your eyes to adjust to the darkness for several minutes. When your instructor tells you, go ahead and try the activities. – Bite on the lifesaver, pull the tape quickly, and rub the sugar cubes together. You should see light emitted! Wrap Up • Light Activities Rules – No moving throughout the room, no rude or inappropriate noises, do not touch anyone, etc. – BE MATURE AND USE COMMON SENSE OR THIS FUN ACTIVITY WILL BE STOPPED AND YOU WILL RUIN IT FOR EVERYONE! Today… • Turn in: – Get out WS#2 to Check • Our Plan: – Clicker Review – Review Problems/Quiz WS#2 – Flame Test Lab – Wrap Up – Problems with Flame Test Lab • Homework (Write in Planner): – Lab Due Next Class Review • Clicker Review Review Formulas & Constants E = hν h= Planck’s Constant = 6.626 x 10-34 J·s c = λν c = 2.998 x 108 m/s Review 1. Find the amount of energy given off by a wave whose frequency is 3.4 x 1016 s-1. (Remember h = Planck’s constant = 6.626 x 10-34 J·s) 2.3 x 10-17 J 2. Calculate the wavelength of the yellow light emitted by a sodium lamp if the frequency of the radiation is 8.10 x 1012s-1 3.70 x 10-5 m Wrap Up What are some problems with using a flame test as your only method for identifying a substance? Today… • Turn in: – Flame Test Lab • Our Plan: – Review – Find Someone Who – Spectroscopy Activity – Test Review – Wrap Up – Scavenger Hunt • Homework (Write in Planner): – Test Review due next class – TEST NEXT CLASS PERIOD Find Someone Who • Move around the classroom and find students who can answer the questions on p. 18 of your notebooklet. Be sure to get their signature or initials. Wrap Up • Scavenger Hunt Today… • Turn in: – Get out Test Review to Check • Our Plan: – Board Game Review – Test Review Questions – Test – You Choose Article • Homework (Write in Planner): – Article Due next class