Chapter 2 The nature of molecules. Elemental and molecular composition of living matter: 1. Elemental composition 2. Structure of an atom 3. Chemical bonds. Elements Common in Living Things Elemental composition of earth’s crust. Chemical composition of living material: 1. Major elements (95%) O, H, C, N 2. Minor elements (5 %) Na, K, P, Ca, Mg, Cl, S, 3. Trace elements EARTH’S CRUST HUMAN PUMPKIN Oxygen 47 Oxygen 65 Oxygen 85 Silicon 28 Carbon 18 Hydrogen 11 Carbon 3 Aluminum 8 Hydrogen 10 Iron 5 Nitrogen 3 Potassium 0 Calcium 4 Calcium 2 Nitrogen 0 Sodium 3 Phosphorus 1 Phosphorus 0 Potassium 3 Potassium 0 Calcium 0 Magnesium 2 Sulfur 0 Magnesium 0 Sodium 0 Iron 0 Chlorine 0 Sodium 0 Structure of an ATOM: Atom Structure Structure of the noble gas NEON Both the K (2 e-) and L (8 e-) are completely filled: the atom is unreactive. nucleus electron neutron proton Atom number = # electrons = # protons Atom mass = # protons + # neutrons Atom Structure The ‘octet’ rule: atoms tend to establish completely full (8 electrons) outer energy levels. Atoms bond together to form molecules: Covalent Bonds: Ionic (bond) Interaction: Chapter 2 The nature of molecules. Water is a dipole. pH and buffers. Water: Chemical Bonds: Single covalent bond A pair of electrons is shared equally in a covalent bond. Double covalent bond Water Molecule: Polar covalent bond Water is a dipole: Water is a DIPOLE Water forms Hydrogen bonds: Carbonyl-group Hydrogen bond Hydroxyl-group Water molecules Butanol and water Water is COHESIVE: Water is COHESIVE Water vapor Liquid water Ice High specific heat. Ice is less dense than water. Consequence for life on earth? Water has high specific heat: Water has high heat of vaporization: Water has a high heat of vaporization. Cooling of a surface by transition from liquid to gas. Water is ADHESIVE: Capillary Action Water dissolves polar molecules: Spheres of Hydration Around Two Charged Ions Salt (NaCl) dissolves in water and separates into Na+ and Cl- Hydration shell or water mantle Water ionizes: Acids and bases: pH is a measure of (free) [proton]: Acids and Bases: Buffers maintain free H+ (pH) though protons are added or removed: Buffers maintain free H+ (pH) though protons are added or removed: The End.