UNIT 2 S PECIFIC L EARNING O UTCOMES Relate an element’s position on the periodic table to its combining capacity (valence). Include: alkali metals, alkaline earths, chalcogens, halogens, noble gases. Explain, using the periodic table, how and why elements combine in specific ratios to form compounds. Include: ionic bonds, covalent bonds. Write formulas and names of binary ionic compounds. Include: IUPAC guidelines and rationale for their use. Write formulas and names for covalent compounds using prefixes. Include: mono, di, tri, tetra. Investigate the Law of Conservation of Mass, and recognize that mass is conserved in chemical reactions. Balance chemical equations. Investigate and classify chemical reactions as synthesis, decomposition, single displacement, double displacement, or combustion. Perform an experiment to classify acids and bases using their characteristic properties. Include: pH, indicators, reactivity with metals. Explain how acids and bases interact to form a salt and water in the process of neutralization. R EVIEW OF THE ATOM Atoms can be broken down into subatomic particles. The three main subatomic particles are protons, neutrons, and electrons. Charge Location Mass Protons +1 Nucleus 1 amu Electrons - Outer shells Negligible Neutrons 0 Nucleus 1 amu amu = atomic mass unit D ETERMINING THE N UMBER OF S UBATOMIC PARTICLES Number of protons The number of protons is equal to the atomic number. Number of electrons In any atom, the number of electrons is equal to the atomic number. Number of neutrons The number of neutrons is equal to the mass number (rounded to a whole number) minus the atomic number. Atomic number Atomic mass Protons = 6 Electrons = 6 Neutrons = 12 – 6 =6 Mass number = atomic number (number of protons) + number of neutrons Atomic number = mass number – number neutrons B OHR ’ S ATOMIC M ODEL Bohr's model of the atom proposed that electrons occupy orbits or energy levels or shells. Bohr discovered that the location of each shell was a certain distance from the nucleus. He also discovered that only a specific number of electrons populated each shell. When electrons occupy the shells, they begin at the closest shell to the nucleus. The first shell can contain a maximum of two electrons, and the second and third shells allow a maximum of eight electrons. Nucleus Protons 1 p+ Electrons 1 e- Nucleus First orbit (max 2e- ) Second orbit (max 8e- ) Third orbit (max 8e- ) L ITHIUM Nucleus The third electron in Li occupies the second energy level (shell) F LUORINE The first 2 electrons are located in the first shell. The next 7 electrons occupy the second shell. When an element has more than four electrons in its shell, you arrange the dots in twos. These electrons are important in helping to determine how an element will react with other materials. These electrons in the outermost energy level are called valence electrons. T HE P ERIODIC TABLE Dmitri Mendeleev, a Russian scientist and professor, placed characteristic properties of elements on pieces of paper and arranged them in many different ways. He discovered a certain pattern or repetition of properties. This repetition of properties or periodicity was an important outcome of Mendeleev's work. Mendeleev used the periodicity of properties to create a periodic table. This table summarized the structure and properties of the elements. Today's periodic law states that the properties of elements are a periodic function of their atomic numbers. The periodic table is an important tool for chemists. It quickly determines some key facts about an element. The basic information with regard to the structure of an atom is quickly established with the periodic table. 13 +3 Al 26.98 Chemistry : Periodic Table & Elements C OLUMNS IN THE P ERIODIC TABLE The periodic table arranges the elements in columns. A single column is called a group or family. A family contains elements that have similar but not identical properties. A LKALI M ETALS (H, L I , N A , K, R B , C S , F R ) Occupies the first column in the periodic table. Has one valence electron in its outer energy level. Most reactive metals In their natural state, alkali metals are always found combined with other substances because of their reactivity. A LKALINE E ARTH M ETALS (B E , MG, CA, S R, B A, R A) Located in the second column of the periodic table. Less reactive than the alkaline metal family. Has two valence electrons in the outer energy level. C HALCOGENS (O, S, S E , T E , P O ) Located in the 16th column. Slightly less reactive than the halogen family. Have six valence electrons in their outer energy level H ALOGENS (F, C L , B R , I, AT ) The halogen family is the 17th family Halogens such as fluorine and chlorine react with one atom of hydrogen to form HF and HCI respectively. Have seven valence electrons Most reactive non-metals. In their natural state, the highly reactive halogens are found combined with another element. N OBLE G ASES (H E , N E , A R , K R , X E , R N ) The noble gas family is the 18th family Called noble gases because they do not generally form compounds with other elements. Inert, unreactive because their outer energy levels are completely filled with electrons. No natural compounds formed from these gases exist. H YDROGEN Sometimes hydrogen behaves as a metal and sometimes as a non-metal. Hydrogen has one electron in its outermost energy level, so it is reactive. Almost all the hydrogen on Earth is combined with other materials or with itself. You should be able to predict with some accuracy the properties of elements that are in the same families. Look at your periodic table and note the number of valence electrons in each family. State the number of valence electrons for the families in the table shown below. Family Number of Valence Electrons alkali metals 1 alkaline earth metals 2 chalcogens 6 halogens 7 noble gases 8 R OWS IN THE P ERIODIC TABLE Rows in the periodic table are called periods. Elements in periods do not demonstrate similar properties as they do in families. Periods, however, show trends. Video: How to Use the Periodic Table Video: “The Elements” E LECTRON D OT D IAGRAM An electron dot diagram or Lewis diagram represent an atom and its valence electrons. The electrons in the valence shell are shown as dots placed around the symbol. Electron dot diagrams are a valuable tool for describing, predicting, and explaining compound formation. Example: Draw an electron dot diagram for calcium. Ca Example: Draw an electron dot diagram for sulphur. S Example: Draw an electron dot diagram for nitrogen. N Video: Valence Electrons & Lewis Diagrams Video: How to draw Lewis Diagrams I ONIC B ONDS Ionic bonds result when electrons are transferred from metal atoms to non-metal atoms. The metal atoms lose electrons to become positive ions, while the non-metal atoms gain electrons to become negative ions. The ions are then held together by the action of opposite charges in an ionic bond. Atoms are considered neutral because the number of protons in the nucleus and the number of electrons in the shells around the nucleus are equal, resulting in a zero net charge for the atom. C ATIONS (P OSITIVE I ONS ) What happens if an electron is removed from an atom? Sodium atom Sodium ion How many positive charges in the atom? How many positive charges in the ion? 11 11 How many negative charges in the atom? How many negative charges in the ion? What is the residual (net) charge in the atom? 0 What is the residual (net) charge in the ion? 11 – 10 = +1 11 10 When an atom from the alkali family reacts with an atom from another element, it will give off its valence electron to the other atom. In giving away its electron, the alkali metal atom has a filled outer shell. Also, in giving away its electron, the atom becomes positively charged with a 1+ charge. Na loses this electron Na You do not have to write the 1 Na Atoms from the alkaline earth family have two valence electrons. These atoms will give off the two valence electrons when combining with an atom from another element. After giving away the two valence electrons, the alkaline earth metal atom has a 2+ charge. Mg loses these electrons 2+ Mg Mg To get charge: 0 – (-2) = +2 Electrons lost Alkali and alkaline earth metals form positive ions when forming an ionic bond with another element. Always write the charge with the number first, followed by the sign ie.) 1+ A NIONS (N EGATIVE I ONS ) The oxygen family and the halogen family behave differently. These two families readily accept electrons to fill their valence shells so that their electron configuration also resembles a noble gas. The halogens need only one electron to fill their valence shells, so they accept only one electron. Once the extra electron is accepted, a 1- ion is formed. O XYGEN To get charge: 0 + (-2) = -2 As 2 electrons are placed into the valence shell, the oxygen atom becomes a 2- ion. 8p 8n Oxygen has a combining capacity of two. The chalcogen family all have the same combining capacity. F LUORINE To get charge: 0 + (-1) = -1 As the electron is placed into the valence shell, the fluorine atom becomes a 1- ion. 9p 10 n Fluorine has a combining capacity of one. The halogen family all have the same combining capacity. When a positively charged ion comes near a negatively charged ion, they attract each other and form a bond called an ionic bond. An ionic bond will hold the two ions together to form a compound. The formation of compounds often takes place vigorously when metals and non-metals are placed together. If a sample of sodium metal is placed in a container of chlorine gas, an explosive reaction takes place and the sodium combines with the chlorine to form sodium chloride. The Bohr model below provides an explanation for this reaction. Electron from Na has been transferred to Cl Sodium Chlorine 11 p 12 n 17 p 18 n An electrostatic attraction holds the ions together. The cation and anion are attracted to each other. This is what forms an ionic bond. + 11 p 12 n 17 p 18 n - Notice that atoms when combine to form ionic compounds, they always gain or lose enough electrons to have a valence shell like its closest noble gas neighbour. Ionic Bonds S TRUCTURE OF N AC L M ETALS AND N ON - METALS Metals o Generally have three or fewer valence electrons o Alkali family of elements has the strongest metallic properties o The next strongest metallic properties are found in the alkaline Earth family. o Metallic properties exist but in decreasing amounts through the boron family. M ETALS AND N ON - METALS Non-metals o Have five or more electrons in the valence shell. o Begin at the chalcogen family and end at the noble gas family. There are exceptions to this general classification and some families have members that behave as both metals and non-metals (e.g., silicon). These elements are called metalloids. Many periodic tables have stair steps across families at the right side. These steps show the dividing line between metals and non-metals. The elements on the dividing line are metalloids. State Metals Appearance o solids at room temp., o shiny lustre except for Hg (liquid) Non-metals o some gases at room temp. o some solids o one liquid (bromine) o not very shiny Metalloids o solids at room temperature o can be shiny or dull Conductivity Metals o good conductors of heat and electricity Malleability and ductility o malleable o ductile Non-metals o poor conductors of heat and electricity o brittle o not ductile Metalloids o may conduct electricity o poor conductors of heat o brittle o not ductile R EVIEW OF VALENCE E LECTRONS Family Valence Electrons Electrons Lost/Gained Charge of Ions Alkaline metals 1 Lose 1 1+ 2 Lose 2 2+ 3 Lose 3 3+ Carbon 4 Lose or gain 4 4+/- Nitrogen 5 Gain 3 3- Chalcogen 6 Gain 2 2- Halogen 7 Gain 1 1- Noble gas 8 ----------- 0 Alkaline earth metals Boron When ionic compounds are formed, elements with a positive valence number will combine with elements having a negative valence number. In general terms, metals (families 1 and 2) combine with non-metals (families 16 and 17). C OVALENT B ONDS Many compounds do not form ionic bonds. These compounds contain two or more non-metallic atoms. For example, C02 is made of two different non-metals, carbon and oxygen. These compounds are formed through the sharing of valence electrons. A covalent bond is formed when two or more non-metallic atoms share valence electrons. Two hydrogen atoms form a covalent bond by sharing electrons to produce a hydrogen molecule. A molecule is the smallest unit of a covalent compound. A molecule has different characteristic properties from the atoms that form it. The Bohr model for hydrogen shown below illustrates a covalent bond. H H Each line is a bond which shares 2e- Covalent bond The electrons are shared in the outer shells of both atoms. This covalent bond forms a molecule of hydrogen (H2). The two hydrogen atoms form a diatomic molecule. Covalent Bonds See white board for example A basic rule in chemistry is that an atom with eight electrons in its outer shell is particularly stable. This need for eight electrons in a covalent bond is called the octet rule. Isn’t it Ionic Song Chemical Bonds Song Covalent vs Ionic How to Determine Ionic & Covalent Bonds D IATOMIC M OLECULES Name of Element Symbol for One Atom of the Element Formula for One Molecule Hydrogen H H2 Nitrogen N N2 Oxygen O O2 Fluorine F F2 Chlorine Cl Cl2 Bromine Br Br2 I I2 Iodine The elements forming diatomic gases are unstable as single atoms and combine almost instantaneously to form stable molecules. Diatomic molecules are still classified as elements even though they are molecules. Remember that diatomic molecules are made of only one kind of atom. C HEMICAL F ORMULAS Chemistry has its own language. Chemists communicate in this language to describe the millions of known compounds. This communication depends on a standard system of naming and writing the formulas for compounds. Chemists formed a group to standardize the system of naming and called themselves the International Union of Physical and Applied Chemists, or IUPAC. A chemical formula is a shorthand method to represent compounds that uses the elements' symbols and subscripts. The chemical formula gives the following information: The different elements in the compound. The number of atoms of each element in the compound. element symbols H2O subscript •Subscript tells you amount of each element. •Water contains: •2 Hydrogens •1 Oxygen * No subscript indicates only 1 atom is present* Na2SO4 •Contains: •2 sodium atoms •1 sulphur atom •4 oxygen atoms Types of Chemical Formulas N AMING I ONIC C OMPOUNDS When naming an ionic compound from its formula follow the rules below: 1. The cation (positive ion) is named first, followed by the anion (negative ion). 2. Write the full name of the metallic element (positive ion). 3. Write the name of the non-metallic element (negative ion) and change the ending to "-ide". Example: Write the name of NaCl. Step 1: Name the first element. Na = sodium Step 2: Name the second element and change the ending to "-ide". Cl = chlorine chloride sodium chloride The name of the compound is ______________________. Example: Write the name of Mg3P2. Step 1: Name the first element. Mg = magnesium Step 2: Name the root of the second element and add "-ide". P = phosphorus phosphide magnesium phosphide The name of the compound is _____________________. W RITING I ONIC F ORMULAS The following must occur, when writing the formula for ionic compounds. 1. The formula must have the cation first, followed by the anion. 2. The sum of the charges of the ions must be zero. That is, the number of positive charges must equal the number of negative charges. 3. You may not change the charge of the ions to make the ion charges equal zero. T HE “C ROSS -O VER ” M ETHOD 1. Write the ions and their charges side by side. 2. Make the number of the charge of one ion the subscript of the other ion (omitting the + or – sign). Remember we do not write the number one as a subscript. 3. Reduce all subscripts to their simplest form, if necessary. Example: Write the formula for aluminum oxide. Step 1: Write the ions and their charges. Al3+ and O2Step 2: Make the number of the charge of one ion the subscript of the other ion. Al3+ O2Al2O3 Example: Write the formula for barium fluoride. 2+ Ba 1F BaF2 The charge on the fluoride ion is 1-. Since IUPAC rules do not write the number one as a subscript, we leave the barium without a subscript. Example: Write the formula for magnesium chloride. See white board Example: Write the formula for calcium oxide. See white board Naming Ionic Compounds P OLYATOMIC I ONS Some ions are composed of several atoms joined covalently. These are called polyatomic ions (poly = many). The charge for polyatomic ions is for the whole group of atoms not just for the atom written last. DO NOT change the subscripts of polyatomic ions; if you change the subscripts you change the identity of these ions. When indicating the presence of more than one polyatomic ion in a compound, we use parenthesis around the polyatomic ion, followed by its subscript. For example, the compound Al(CH3COO)3 has an aluminum ion and 3 acetate ions. Placing the acetate ion in parenthesis and following it with the subscript 3 indicates there are 3 acetate ions. Example: Write the name for KNO3. Step 1: Identify the cation. K+ potassium ion Step 2: Identify the anion. NO3- nitrate ion Step 3: Write the name of the cation first, followed by the anion. potassium nitrate Example: Write the name of Na3PO4. Step 1: Identify the cation. Na+ sodium ion Step 2: Identify the anion. PO43- phosphate ion Step 3: Write the name of the cation first, followed by the anion. sodium phosphate Writing the formula for polyatomic ions is the same as writing the formula for ionic compounds. You will use the cross-over method and your polyatomic table. Example: Write the name of sodium sulfate. Step 1: Identify the cation. sodium Na+ Step 2: Identify the anion. sulfate SO42Step 3: Cross-over the charges to write the formula. + Na 2SO4 Na2SO4 Example: Write the name of ammonium thiocyanate. See white board S TOCK N AMING S YSTEM Most of the transition metals have more than one possible ion charge. They are often referred to as being multivalent. For example, Ion Possible Ion Charges Copper Iron Cobalt Chromium 1+, 2+ 2+, 3+ 2+, 3+ 2+, 3+ Lead Tin 2+, 4+ 2+, 4+ In 1919, Alfred Stock (1876 – 1946), a German chemist, suggested using numbers to indicate the charge of the ions. Prior to this the ions were given different names based upon their charge. The Cu+ ion was called cuprous and the Cu2+ ion was called cupric. However, the Fe2+ ion was ferrous and the Fe3+ ion was ferric. Since the charges were not always the same, the "–ic" and "–ous" suffixes caused some confusion. Today, the Stock naming system uses Roman numerals following the metal ion's name to indicate the ion's charge. Example: Copper (I) = Cu+ Copper (II) = Cu2+ cuprous cupric Iron (II) = Fe2+ ferrous Iron (III) = Fe3+ ferric As a general rule, all metals are multivalent (have more than one ion charge) except group one and two metals, silver, cadmium, zinc, and aluminum. Unless the metal is one of these use the Roman numeral. Example: Write the formula for iron (III) chloride Step 1: Write out the ions. Fe3+ and ClStep 2: Cross-over the charges. FeCl3 Example: Write the formula for lead (IV) sulfide. Step 1: Write the ions. Pb4+ and S2Step 2: Cross-over the charges. Pb2S4 Step 3: Reduce the subscripts. Pb2S4 ÷ 2 PbS2 *divide by GCF* N AMING M ULTIVALENT C OMPOUNDS We name in a very similar manner as those ions with a single ion charge, except we must determine the charge on the metal ion. See overhead for examples N AMING C OVALENT C OMPOUNDS Non-metals tend to combine chemically by sharing electron pairs. These bonds are known as covalent bonds. Neutral compounds made of atoms joined covalently are called molecular or covalent compounds. We name covalent compounds differently than ionic compounds. We must indicate the number of each element by adding a prefix in front of the element's name. Subscript Prefix one two three four five six seven eight nine ten mono di tri tetra penta hexa hepta octa nona deca There are three exceptions to the naming rules. Here the common names for the compounds are used: H2O = water NH3 = ammonia CH4 = methane Example: Write the name for CO2. Step 1: Name the first atom with prefixes. There is only 1 carbon. We omit “mono” for the first element. carbon Step 2: Name the second element using prefixes and end in "-ide". There are 2 oxygens, so we use the di prefix dioxide Step 3: Write the name of the compound writing the substance found more to the left on the periodic table first. carbon dioxide Example: Write the name for N2O4. dinitrogen tetraoxide Example: Write the name for SF6. sulfur hexafluoride W RITING C OVALENT F ORMULAS Writing formulas for covalent compounds involves the following rules: 1. Write the symbol for the first element followed by the subscript indicated by the prefix. 2. Write the symbol of the second element followed by the subscript indicated by its prefix. DO NOT REDUCE THE SUBSCRIPTS!!! Example: Write the formula for dinitrogen monoxide. Step 1: Write the symbol and subscript for the first element. dinitrogen N2 Step 2: Write the symbol and subscript for the second element. 1 as a subscript is monoxide O not needed Step 3: Combine N2O Example: Write the formula for sulphur hexachloride. SCl6 Example: Write the formula for carbon tetrachloride. CCl4 Naming Covalent Compounds 1 How to Name Ionic & Covalent Compounds Naming Covalent Compounds 2 B ALANCING E QUATIONS The Law of Conservation of Mass tells us that every chemical equation must have equal numbers of atoms of each element on each side of the equation. This means atoms cannot be created or destroyed in a chemical reaction. Four atoms of hydrogen Two atoms of oxygen Four atoms of hydrogen and two atoms of oxygen. As you balance equations, there are several rules to remember 1. You cannot change the formula of any reactant or product to change the numbers of atoms. 2. You can only change the coefficients in front of the reactants and products. a. Coefficients can be placed only in front of the formula, not somewhere inside it b. Coefficients apply to the whole molecule. If no coefficient is shown in front of a molecule, it means the molecule has a coefficient of 1. c. Note the difference between a coefficient and a subscript. i. A coefficient tells us the number of molecules in an equation and can be changed to balance an equation. ii. A subscript tells us the number of atoms in a molecule and cannot be changed. There are some rules that you can use when you are given an unbalanced H2(g) + O2(g) H2O(l) 1. Determine the number of atoms for each element in the molecules for reactants and products. The number of atoms on each side of the equation are not the same. 2. If the numbers of atoms on both sides of the equation are equal at this point, the equation is already balanced and you are finished. In this example, they are not the same and you go to the next step. 3. Choose the substance that has the most influence on the equation and insert coefficients in the formulas as needed. 4. Inspect the equation and recalculate the numbers of atoms on both sides of the equation. If they are equal, the equation is balanced. If they are not equal, change the coefficients until the equation is balanced. A Beginner’s Guide to Balancing Equations How to Balance Equations How to Write, Balance & Classify a Chemical Reaction How to Write Chemical Equations C HEMICAL R EACTIONS In chemistry, a reaction happens when two or more molecules interact and the molecules change. S INGLE D ISPLACEMENT R EACTIONS In single displacement reactions, one element replaces another element in a compound. There are two possible reactions: a) One positive ion replaces another Zn + HCI ZnCl2 + H2 b) One negative ion replaces another Cl2 + 2NaBr 2NaCl + Br2 A + BC B + AC S YNTHESIS R EACTIONS Synthesis reactions involve joining atoms to make a molecule, or joining elements to form a compound. Two or more simple elements or compounds combine to form a more complex compound. 2Mg + O2 2MgO A + B AB D ECOMPOSITION R EACTIONS During decomposition, one compound splits apart into two (or more) pieces. sodium chloride sodium + chlorine 2HgO 2Hg + 02 AB A + B D OUBLE D ISPLACEMENT R EACTIONS In double displacement, elements in different compounds replace each other (split up and exchange partners). AC + BD AD + BC C OMBUSTION R EACTIONS Combustion reactions involve the burning of a chemical substance in oxygen. Metals burn in oxygen to produce a metal oxide. Magnesium + oxygen magnesium oxide Nonmetals burn in oxygen to produce a dioxide. Carbon + oxygen carbon dioxide Hydrocarbon + O2 CO2 + H20 Bill Nye Chemical Reactions Chemical Reactions Exothermic and Endothermic Reactions 7 Chemical Reactions that will Facinate C OMMON A CIDS AND B ASES Acids are used in many industrial processes. Production of paper, steel, and many other products requires the use of acids. Sulphuric and hydrochloric acids are commonly used in such industrial processes. Bases are important household chemicals used for cleaning and disinfecting. Bases are also used in hairdressing when a "permanent" change is needed to change straight hair to curly hair. The names and formulas of some common acids and bases are shown below. Acids Bases hydrochloric acid HCl sodium hydroxide NaOH sulphuric acid H2SO4 Ca(OH)2 nitric acid HNO3 calcium hydroxide ammonium hydroxide NH4OH Notice that acids tend to have H in their formula and bases often have OH (hydroxide) as the second component in their formula. C HARACTERISTICS OF A CIDS AND B ASES Taste Feel Reaction to Litmus Paper Other Properties Acids Bases sour burns turns litmus paper red bitter slippery turns litmus paper blue •neutralizes basic •neutralizes acidic solutions solutions •corrosive to metal •conduct electricity •conduct electricity Acid + bases water + salt Reactions Acid + metals H2 gas Acid + carbonates CO2 + H2O + salt Bases + acids water + salt •HCl – gastric juice •citric acid –lemons & oranges •acetic acid – vinegar •ascorbic - vitamin C Examples acid •acetylsalicylic - Aspirin acid •NaOH – sodium hydroxide •Ca(OH)2 – limewater •Mg(OH)2 – milk of magnesia •bleaches •soaps •toothpaste A substance that changes colour when added to an acid or base is called an indicator. Indicator Acid Base Litmus red blue Phenolphthalein colourless pink Methyl Orange orange Bromothymol Blue blue N EUTRALIZATION An acid and a base, when combined, will neutralize each other. Acids will lose their acid properties and bases will lose their base properties. When an acid reacts with a base, a salt and water are produced. acid + base salt + water A salt is a compound composed of the negative ion of an acid and the positive ion of the base. The water is formed when the hydrogen ion (H+) of the acid combines with the hydroxide ion (OH-) of the base. acid base salt water HCl(aq) + NaOH(aq) NaCl(aq) + H2O(l) M EASURING THE S TRENGTH OF ACIDS AND B ASES The strength of an acid or a base is measured using a scale called pH. pH 0-6.9 acidic pH 7 (water) neutral pH 7.1-14 basic (alkaline) Measures the strength of acid where a smaller number equals stronger acid and a larger number equals weaker acid Neutral - neither acid nor base Measures the strength of base where smaller number equals weaker base and larger number equals stronger base strong weak weak strong Question: Use the pH values described below to determine whether the substance is neutral, a weak or strong acid, or a weak or strong base. pH = 12 strong base pH = 7 neutral pH = 6 weak acid pH = 9 weak base pH = 2 strong acid Acids, Bases and pH