CHEM SKETCH ASSIGNMENT: Save your CHEMSKETCH page and e-mail it to me before you leave class today: byoung@livingston.org PART I: Using CHEMSKETCH – 1. Open CHEMSKETCH from the program menu. 2. In the top left corner, highlight the tab. 3. Click on . Then go to the page and click to build a carbon chain. Play with the program until you feel comfortable building molecules. Try adding multiple bonds to the molecules by clicking on the bond. 4. To replace a carbon with a halogen: first put a carbon in the position that the halogen will occupy. Then click on the halogen on the far left, and click again on the carbon being replaced. 5. To name molecules: select the molecule being named with the button on the top left. (under structure). Then click on the “volcano” to the right on the tool bar: PART II: Creating and naming molecules. Build each of the molecules listed below. Then name the molecules listed below to determine whether you built them correctly. Copy and paste into a word document, using Ctrl C and Ctrl V, before moving to the next section. a. 2,3,4-trimethyl nonane b. 3-chloro-5-ethyl-octane d. ethyl cyclopentene (use the column to the right of the screen) c. 2-methyl-3-pentyne e. 3-bromo-cyclohexene PART III: Create the molecules below on CHEMSKETCH. Predict whether each molecule will be the E or Z isomer. Try naming, but remember that CHEMSKETCH uses a slightly different system. The placement of the double bond will be inserted into the chain name. If there is an –OH present, it will be written as –ol at the end of the name. CH3 H3C H3C CH3 CH3 CH3 CH3 H3C Cl H3C CH3 OH CH3 PART IV: Use CHEMSKETCH to create each of the molecules listed below. Use the naming function to make sure you have created it correctly: a. b. 4,5,6-trimethyl-2-octyne 6-isopropyl-3-decyne* f. (3Z)-4-ethyl-3,6-dimethyl-3-heptene g. (3E)- 3,6-dimethyl-4-propyl-3-heptene c. 2-methyl-1-butene h. (2E)-2-chloro-2-hexene d. (3E)- 3-methyl-3-heptene **i. (2Z,4E)-3-chloro-2,4-hexadiene **j. (2E,4Z)-4-ethyl-6-methyl-2,4-heptadiene *- chem sketch has a different name for isopropyl. Can you see where it came from?