Models of the Atom Ms Fedor Arts and College Preparatory Academy ChemCatalyst The model shown here is a tiny cube of gold. 1. What do you think a scientific model is? 2. The spheres in this model represent atoms. What do you think atoms are? Agenda Objectives: describe the structure of an atom, understand how atomic theory developed over time Collect Assignments 2. Notes: Atomic Structure 3. Activity: Atomic Pudding HW: Students who have completed quiz 2: study and schedule Quiz 3 Students who have completed Quiz 3: work on organizing your notebook, finishing your preplanning for your element project 1. What I Need From You Supplements for Quiz 2 ◦ Mole practice problems ◦ Chemical formulas/reactions Activities: ◦ A New Language ◦ Copper Cycle Lab ◦ What Goes Around Comes Around Earliest Ideas About Atoms Democritus – 460 BCE Philosopher All matter is made up of indivisible particles Atoms means “indivisible” No experimental evidence to support idea Democritus Greek banknote with Democritus and drawing of atom Where did Democritus get his ideas for small, indestructible, indivisible atoms? Atoms are small… new wedding rings old wedding ring EVIDENCE: Old wedding rings get worn away slowly, and get thinner and thinner, but you never see the gold atoms on your finger, so gold atoms must be very small! Atoms are indestructible… EVIDENCE: The Earth has been around a long time. Even though mountains get washed away, the rocks continue to exist. New plants grow where old plants die. Atoms are indivisible… EVIDENCE: None. This was a HYPOTHESIS made by Democritus to explain nature as he saw it. Aristotle had other ideas Greek banknote and coin picturing Aristotle ARISTOTLE: Famous Greek philosopher, born 384 BCE. He was a student of Plato (another famous philosopher) and the teacher of Alexander the Great, who later conquered the world. Aristotle’s idea of matter Aristotle did not believe that Democritus’s idea of atoms was correct. He believed all matter was made from four elements: Earth Air Fire Water Aristotle’s idea of matter Aristotle was more famous than Democritus, so people believed him, even though he was wrong. So Democritus’s idea of atomos (atoms) was lost for nearly 2000 years until John Dalton brought it back in 1803. Then in 1803… John Dalton, an English chemistry teacher, made several conclusions about atoms from his experiments: 1. All elements are composed of tiny particles called atoms, and the atoms of different elements are different from one another. 2. Atoms of different elements combine to form new substances in whole number ratios. 3. Chemical reactions occur when atoms are rearranged so that they attach to different atoms. Dalton’s Chemical Symbols We use different symbols today. Overarching Question These ideas formed the basis of atomic theory. Dalton was wrong about atoms being indivisible. So if atoms aren’t indivisible, then where does our modern idea of the atom come from? Activity: Atomic Pudding Objectives: • I can interpret the results of each major experiment in the development of atomic theory • I understand and can describe the structure of an atom, and am able to explain the differences between atoms of different elements 1. 2. 3. Examine and compare the different models Use new evidence to determine the correct sequence of the models Identify the parts of the atom Atoms are the smallest units of an element Sulfur (S) Average Atomic Mass and Reactivity : a simplified representation of something more complex, that facilitates understanding certain aspects of a real object or process the smallest unit of an element that retains the chemical properties of that element. ChemCatalyst Which model represents Dalton’s idea that atoms are indivisible? Which model suggests that there are negative particles in an atom? Atomic Theory All matter is made of atoms first proposal of the atom, 442 BC Solid sphere model, 1803 Plum pudding model, 1897 nuclear model, 1911 Solar system model, 1913 cloud model, quantum model, 1927-1932 How did Thomson know to run an electrical current through matter? Michael Faraday, English chemist, born 1791. In 1834 he learned that matter would interact with electricity. He realized that electricity had to me made up of particles that could be counted, but he did not know what they were. (They were electrons.) ChemCatalyst What are the three particles that make up an atom? What is the charge of each particle? J.J. Thomson 1856-1940 Discovered electron 1897 ◦ Cathode Ray Experiment: electric charges make materials lose negatively charged particles. ◦ Atoms contain negatively charged particles Plum Pudding model 1904 ◦ Electrons in a soup of positive charges More About Charge… Opposite charges attract, alike charges repel (push away). Cathode Ray Experiment Thomson’s “Plum pudding” atom – electron ENGLISH PLUM PUDDING – raisin RULE: Matter is NEUTRAL, so for every electron (one negative charge) they must also have a proton (one positive charge) to balance the math to zero charge (“neutral”). Ernest Rutherford 1871-1937 Gold foil experiment: ◦ Shot alpha particles (positively charged particles) at gold atoms ◦ Most went through, but some bounced back Nuclear model 1911 ◦ An atom’s mass is mostly in the nucleus ◦ The nucleus has a positive charge ◦ Electrons in fixed orbit Rutherford’s Gold Foil Experiment Rutherford gold foil experiment Rutherford expected the a particles to pass straight through, like this… But what he got was most a particles went straight through, but a few were deflected, like this… Problem with Rutherford’s Model But there also was a problem with Rutherford’s nuclear atom! To prevent the negative (-) electrons from being attracted to the positive (+) nucleus, the electrons would have to orbit the nucleus like the Earth orbits the sun. Why don’t the electrons crash into the nucleus? Niels Bohr 1885-1962 Each element emits specific set of wavelengths of light (colors) ◦ Wavelength = amount of energy ◦ Electrons of those elements have different energy levels Solar system Model 1913 ◦ Nucleus surrounded by orbiting electrons at different energy levels ◦ Electrons have definite orbits Bohr’s Quantized Energy Levels Bohr’s new atomic model had quantized energy levels, meaning the electrons could only move by jumping between levels (numbered n = 1, n = 2, n = 3, etc.). They absorb energy when they jump out, and emit (send out) energy when they jump in. Ernest Rutherford 1871-1937 Alpha particles can knock positively charged particles out of the nucleus. ◦ Nucleus contains positively charged particles called protons Proton model 1918 ◦ Central nucleus made of protons ◦ Tiny orbiting electrons (negatively charged) ◦ Most atom is empty space ChemCatalyst Who discovered the electron? What did Bohr’s research change about the atom? Ernst Schrödinger 1887-1961 Werner Heisenberg 1901-1976 Quantum Mechanical Model 1926 ◦ Electrons are in probability zones called “orbitals”, not orbits and the location cannot be pinpointed (Heisenberg uncertainty principle) Cloud/Quantum mechanical model James Chadwick 1891-1974 Discovered Neutron 1932 Neutrons hold positively charged nucleus together Atomic Theory JJ Thomson Democratus 400 BC 1803 John Dalton 1904 Niels Bohr 1910 Ernest Rutherford 1913 1926 Schroedinger / Heisenberg The Complete Modern Atom An atom is mostly empty space with a nucleus containing protons and neutrons which contain most of the mass of an atom. Electrons are in energy levels around the nucleus, and are very tiny. Electrons jump between levels, emitting and absorbing energy as they jump. We often refer to these energy levels as “orbitals”, but real orbitals are much more complicated… Simple atomic model Includes: 1. Rutherford’s discovery of the proton 2. Chadwick’s discovery of the neutron 3. Bohr’s discovery of electrons in orbits Regions of an atom Electron cloud: Nucleus: •center of the atom •Makes up most of its mass •Mostly empty space •Take up most of the radius of the atom Subatomic Particles Nucleus Electron Cloud Protons (+) electrons (-) Neutrons (Neutral) Atomic Particles * amu = atomic mass units Particle Charge mass Relative mass proton +1 1 amu neutron 0 1.67 x 10-24 g 1.67 x 10-24 g electron -1 9.11 x 10-28 g 1/1840 amu 1 amu A neutral atom has no net charge: number of protons is equal to the number of electrons. #P + #e = 0 Images of atoms Scanning tunneling electron microscope 1981 Bombards surface with electrical current (electrons) Read changes in current, translate into image