Unit 8 Plan: Kinetics and Equilibrium Stage One: Desired Results Key Points The laws of equilibrium dictate the rate of reactions. Energy is conserved in every chemical reaction. Energy is commonly released or absorbed by a chemical system as heat. The energy changes of a chemical reaction can be traced via potential energy diagram. Skills and Knowledge Students will be able to… S K I L L S Explain collision theory Determine the factors that affect reaction rates Define equilibrium Explain LeChateliers Principle Determine the effect of LeChateliers Principle on chemical reactions Identify a potential energy diagram Distinguish between an exothermic reaction versus an endothermic reaction by looking at a potential energy diagram Identify the heat of reaction and activation energy on a potential energy diagram Define catalyst Essential Questions What factors affect the rate of reaction? How do chemical reactions react to changes in a chemical system? How do we track changes in energy during a reaction? Vocabulary Collision theory Rate Equilibrium Concentration Surface area Pressure LeChateliers Principle Kinetics Potential energy diagram Heat of Reaction Exothermic Endothermic Activation energy Activated complex Catalyst Students will know… K N O W L E D G E Formative: In order for reactions to occur, the reactants must collide with the proper orientation and right amount of energy to create the desired product There are factors that affect the rate of reaction: identity of the compound (ionic vs. covalent), concentration, surface area, temperature, pressure, and the presence of a catalyst Forward and reverse reaction rates are equal in reversible systems and concentration stays constant at equilibrium Types of equilibrium: phase equilibrium, solution equilibrium, chemical equilibrium LeChateliers Principle states that the equilibrium will shift to the left or right depending on what is added or taken away from the system (stress) A potential energy diagram can represent exothermic and endothermic reactions Exothermic reaction produce heat and have a negative heat of reaction Endothermic reactions absorb heat and have a positive heat of reaction The heat of reaction is the difference between the PE of the reactants and the PE of the products Activation energy is the amount of energy needed to form the activated complex A catalyst speeds up a reaction by lowering the activation energy Stage Two: Assessment and Evidence Assessments Mastery of individual objectives will be measured by: Accuracy of individual work produced in class and as homework Summary Questions Exit Slips Written exam with multiple opportunities/formats for testing mastery of each learning objective Summative: Performance-based exam asking students to demonstrate competence in conducting and analyzing the results of a simple experiment Grading/Feedback Comments/grades based on homework and class-work rubrics Individual conferences during work time: I try to meet with each student individually at least once per work period (work time in lesson) Peer-editing: students switch work and check their partner’s accuracy. Students use peer editing form to provide specific feedback for their classmate. Informed Changes Based on Student Data Me: Daily assessment of student mastery of objectives will help pace instruction (i.e. spend another day revisiting the learning objective) and change the mode of instruction (i.e. reteach the concept in a different way to incorporate varying learning modalities, etc.) Also, if it is evident that a certain topic is still challenging students, I will provide more opportunities to practice the skill/concept during homework assignments, do-now’s, or in-class activities. Students: Students will track their own mastery of objectives on their personal mastery charts and know which topics they still have to work on. During our individual conferences, we can address these specific challenges and collaborate on an individualized learning plan. Stage Three: Instruction Learning Activities and Approaches Resources Kinesthetic: Weekly labs Visual: Digital Presenter/overhead Video clips/internet simulations Digital Projector, computer Reading Materials Poster paper, markers Internet connection Hand-outs and guided notes Miscellaneous lab supplies Auditory: Video/simulations group-discussion Interpersonal: cooperative learning labs Mathematical-logical: Inquiry based do nows Artistic: Making posters, process charts Drawing particle diagrams Day 1 Daily Lesson Objectives and Aims AIM: What is collision theory and what factors affect the rate of reaction? Objective 1: SWBAT explain collision theory. Standards PS 3.4d Collision theory states that a reaction is most likely to occur if reactant particles collide with the proper energy and orientation. PS 3.4f The rate of a Potential Misunderstandings Increase in surface area as a factor for reaction rate is a little tricky for students to understand so it will be helpful to bring in a demonstration or even find animation of it online. Lesson Plan Notes Online animations of collision theory are extremely helpful for students. 2 Objective 2: SWBAT determine the factors that affect reaction rates. chemical reaction depends on several factors: temperature, concentration, nature of reactants, surface area, and the presence of a catalyst. AIM: What is equilibrium? PS 3.4i At equilibrium the rate of the forward reaction equals the rate of the reverse reaction. The measurable quantities of reactants and products remain constant at equilibrium. Students don’t understand the difference between constant and equal. Remember to emphasize that equal means the same and constant means not changing. Remember to show graphs that represent equilibrium. Common on Part B-2 and Part C of the Regents. PS 3.3j LeChatelier’s principle can be used to predict the effect of stress (change in pressure, volume, concentration, and temperature) on a system at equilibrium. Remember to tell students that all responses regarding LeChatelier’s principle should be phrased, “The equilibrium shifts to the ….” Students need to understand that if you increase the concentration of the reactant, all reactant concentration will decrease. An introduction activity where students break an alka seltzer tablet in half and they make predictions about what will happen when the other half of the alka seltzer is put into water. Objective 1: SWBAT define equilibrium. 3 AIM: What is LeChatelier’s Principle? Objective 1: SWBAT explain LeChateliers Principle. Objective 2: SWBAT determine the effect of stress on a chemical system in equilibrium. 4 5 AIM: How do you identify an exothermic versus endothermic reaction based on a potential energy diagram? Objective 1: SWBAT identify a potential energy diagram? Objective 2: SWBAT distinguish between an exothermic reaction versus an endothermic reaction by looking at a potential energy diagram. AIM: What is heat of reaction and activation energy? Objective 1: SWBAT identify the heat of reaction and activation energy on a potential energy diagram. PS 4.1b Chemical and physical changes can be exothermic or endothermic Table H is really daunting for students. Explain why heat of reaction is negative for exothermic and is positive for endothermic reactions. Check for understanding game in which students have an exothermic and endothermic card and you show different potential energy diagrams. Heat of reaction is the potential energy of the PRODUCTS minus the potential energy of the REACTANTS. Scaffolded station work where students have to identify values and parts of the PE diagram is effective for this lesson. Remember to emphasize that catalysts DECREASE the activation energy, but Start with a demo in which a slice of PS 4.1c Energy released or absorbed during a chemical reaction can be represented by a potential energy diagram. PS 4.1b Chemical and physical changes can be exothermic or endothermic PS 4.1c Energy released or absorbed during a chemical reaction can be represented by a potential energy diagram. PS 3.4g A catalyst provides an alternate reaction pathway, which has a lower activation energy than an uncatalyzed reaction. 6 AIM: What are catalysts? PS 3.4g A catalyst provides an alternate reaction pathway, which has a lower SWBAT define catalysts. activation energy than an uncatalyzed reaction. 7 REVIEW 8 UNIT 8 TEST INCREASE the reaction rate. potato is put into hydrogen peroxide and explain how the potato is a catalyst for the break down of the hydrogen peroxide.