Name: __________________________________________ Date: _________________ Class/Period: _____________________________________ Chemistry Matter 1. Calculate the density of an object with a volume of 25 cm3 and a mass of 50. g. 2.0 g/cm3 D = m/V = 50. g/25 cm3 = 2.0 g/cm3 2. Find the mass of an object with a density of 5.0 g/cm3 and a volume of 20. cm3. 100 g m = DV = 5.0 g/cm3 x 20. cm3 = 1.0 x 102 g 3. Find the volume of an object with a mass of 200 g and a density of 100 g/mL. 2 mL V = m/D = 200 g/100 g/mL = 2 mL 4. How many significant figures are in the following numbers: a. 5370 b. 200. 3 3 c. 2410.10 d. 2001 6 4 5. A mixture that is uniform throughout is classified as a is not uniform in appearance is known as a Homogeneous mixture whereas a mixture that Heterogeneous mixture. 6. A type of homogeneous mixture made of two or more metals is known as a(n) Alloy. 7. Identify the following as a chemical or physical property or chemical or physical change. a. copper reacts with oxygen to form a green patina chemical b. milk spoils chemical c. copper compounds are blue physical d. ice melts physical e. pancakes burn on a griddle chemical f. fermentation chemical g. an iron nail rusts chemical h. combustion chemical 8. What is the difference between an element and compound? An element is a pure substance that appears on the periodic table and consists of one type of atom. A compound is a pure substance that is composed of 2 or more elements combined chemically and in definite proportions. 9. Identify the following as elements, compounds or mixtures – if a mixture identify as homogeneous or hetergeneous Exampe Element Compound Homogeneous Air Nitrogen Mixture (tell type Element Compound Potassium Chloride Gasoline Homogeneous Gravel (with rocks and Heterogeneous sand) Bromide Copper (II) sulfate Element Compound Atomic Structure 10. Define the term atom in your own words (do not copy the definition from the book)! Class consensus _______________________________________________________________________ 11. C2H6 is an example of what? a. ion b. element c. atom 12. Fill in the chart below concerning subatomic particles. Subatomic Particle Location Proton Nucleus d. compound Charge Positive e. mixture Job of Particle Identifies the element Adds to Nucleus 0 atomic mass Balances electron Outside Negative charge of nucleus nucleus What is an isotope? An isotope is an atom of the same element Neutron 13. with the same number of protons but a different number of neutrons. 14. Calculate the number of protons, neutrons, and electrons of Magnesium-25. # protons: # neutrons: 12 13 # electrons :12 15. Find the average atomic mass of Element X if 51.83% of Element X occurring in nature has a mass of 106.905 amu and 48.17% of the atoms have mass of 108.905 amu. 107.868 amu Identity of Element X: Isotope X-107 X-109 Abundance (%) 51.83 48.17 Atomic Mass (amu) Decimal Product 106.905 .5183 55.4088615 108.905 .4817 + 52.4595385 107.8684 16. Circle the most abundant isotope of hydrogen: know? Ag hydrogen-1, hydrogen-2, or hydrogen 3. How do you It is the closest to the atomic mass of hydrogen appearing on the periodic table. Which has only 1 proton? They all have one proton. 17. What is the atomic number of Uranium-238? 92 18. Write the full electron configuration for the following elements AND circle the valence electrons. a. titanium b. bromine 1s2 2s2 2p6 3s2 3p6 4s2 3d2 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p5 19. Write the noble-gas configurations for the following elements AND circle the valence electrons: a. Calcium [Ar] 4s2 b. Francium [Rn] 7s1 20. Draw the Lewis/Electron Dot structure for the following elements: a. Sodium b. Iodine 21. Fill in the following chart. Sublevel s See whiteboard c. Aluminum d. Oxygen # of Orbitals # of electrons in sublevel 1 3 5 7 2 6 10 14 p d f 22. Explain the octet rule and the role of valence electrons in bonding. The octet rule says that atoms tend to gain, lose or share electrons so as to achieve eight electrons in their outer or valence electron shell. 23. The fact that electrons occupy the lowest energy levels possible is known as the Aufbau Principle whereas the idea that only two electrons of opposite spin can occupy a single orbital is known as the exclusion Principle. Finally, Pauli Hund's Rule states that single electrons with the same spin must occupy each orbital before additional electrons with opposite spins can occupy the same orbitals. Nuclear Chemistry 24. What type of radiation is emitted when Uranium-238 decays to Thorium-234? Show the nuclear reaction below. 238 92U --> 234 90Th + 4 2He Beta radiation 25. Fill in the chart below. Type of Decay Particle Emitted What Can Stop It? Rank from Least (1) to Most Penetrating (3) Alpha Decay (α) Helium nucleus (42He) Beta Decay () Gamma Decay () 0-1e Skin Metal foil Thick concrete, steel, lead 1 2 3 0 0 26. Use the chart below to answer questions a, b, and c. Isotope 1 Mass Number 50 Percent Abundance/Occurrence 4.35 % Isotope 2 52 83.79 % Isotope 3 53 9.50 % Isotope Mass Number(amu) Abundance (%) Decimal 1 50 4.35 0.0435 Isotope 4 54 2.36 % Product 2.175 2 52 83.79 0.8379 43.5708 3 53 9.50 0.0950 5.035 4 54 2.36 0.0236 Totals 52.0552 a. What is the average atomic mass of this element? b. What is the name of this element? c. Isotope 4 has how many protons? + 1.2744 52.1 amu Chromium 24 neutrons? 30 electrons? 24 27. The half life of DDT, a pesticide is 15 years. If 60 grams of DDT is released into the environment, how much will remain after 60 years? O years 15 years 30 years 45 years 60 years 60 grams 30 grams 15 grams 7.5 grams 3.75 grams AR = IA(1/2)n AR= 60 (1/2)60/15 AR = 60 (1/2)4 AR = 3.75 grams Periodic Table 28. Fill in the following chart. Group Name Number Valence Electrons Number of Electrons Lost/Gained Oxidation Number 1 2 1 2 +1 +2 3 4 5 3 4 3 +3 +/- 4 -3 6A 6 2 -2 7A 7 8* 1 0 -1 0 Group Number Alkali Metals Alkaline Earth Metals Boron Group Carbon Group Nitrogen Group (Pnictogens) Chalcogens Group Halogens Noble Gases 1A 2A 3A 4A 5A 8A * Helium has 2 valence electrons and is happy 29. All elements except Hydrogen and Helium want to achieve valence shell. This is known as the Octet rule. 8 electrons in the outermost or 30. Name any element with properties similar to calcium. Magnesium 31. Alkali metals are most likely to react with what group to produce a compound with a 2:1 ratio? Explain. They would most likely react with any member of the oxygen group because the oxygen group requires two electrons to make a complete octet. 33. Mendeleev arranged the periodic table by arranged by Atomic Mass whereas the modern periodic table is Atomic Number. 34. Rows on the periodic table are called Periods 35. Which group of metals is the most reactive group? and columns are called Groups or Families. Alkali Metals Why? They have only one valence electron to lose 36. Which group of nonmetals is the most reactive group? Halogens Why? They have seven valence electrons and only require one more for a complete octet. 37. Which group of elements is the least reactive? complete octets Noble gases Why? They have 38. Fill in the chart below by placing a check mark by the properties that match each type of element. Physical/Chemical Property Lustrous Metal Nonmetal x X Brittle Malleable Conductive X X X Dull Reacts with Acid and CuCl2 X X Gaseous Solid x 39. Which of the following elements is not in the same family? a. calcium b. strontium 40. List all the metalloids. c. beryllium d. potassium Boron, Silicon, Germanium, Arsenic, Antimony, Tellurium, Polonium, Astatine 41. What is: a. atomic radius: The size of an atom b. electronegativity: The ability of an atom to attract an electron when it makes a chemical bond c. ionization energy: The amount of energy required to remove an electron from an atom's outermost shell. What does: a. atomic radius do across a period? It gets smaller down a group? It gets bigger b. electronegativity do across a period? It gets larger c. ionization energy do across a period? It gets larger down a group? It gets smaller down a group? It gets smaller Cations form when neutral atoms lose 42. How do cations form from neutral atoms? electrons 43. How do anions form from neutral atoms? Anions form when neutral atoms gain electrons Bonding 44. Explain the difference between Mg and Mg+2. Mg is a neutral atom while Mg+2 is a cation that results from Mg losing 2 electrons. 45. Explain the difference between Cl and Cl-1. Cl is a neutral atom while Cl-1 is an anion that results from Cl gaining an electron 46. Name the following compounds. a. CaOH Calcium Hydroxide b. C3H8 Propane d. SO3 c. CuSO4 Copper(II) Sulfate Sulfur Trioxide 47. Complete an atom inventory for 5 (NH4)3PO4. Also indicate the number of formula units for each. 15 N, 60H, 5P, 20O There are 5 Formula Units of Ammonium Phosphate 48. When Pb+4 and SO4-2 combine, what is the formula of the compound formed? covalent? Pb(SO4)2 Is it ionic or Ionic How do you know? The compound is made from a metal and a polyatomic anion. 49. Which of the following IS a polyatomic ion? a. Cl b. O-2 d. PO4-2 c. Ca+2 The # of electrons an atom loses or gains when it forms an ion is the oxidation number for an element! 51. What is the oxidation number for the cation in FeCl ? +3 50. What is an oxidation number? 3 52. Circle the set of formulas and names that IS CORRECT. There can be more than one answer! a. Al2O3 (dialuminum trioxide) c. FeSO4 (Iron (II) sulfate) b. CS2 (carbon disulfide) d. PbO2 (lead (IV) oxide) 53. Label the above compounds (in number 60) as ionic or covalent. a. Ionic c. Ionic b. Covalent d. Ionic Organic Chemistry 54. What element does an organic compound contain? Carbon 55. List the prefixes for alkanes containing from 1 to 10 carbon atoms in order. Meth, Eth, Prop, But, Pent, Hex, Hept, Oct, Non, Dec 56. (a) What is a hydrocarbon? A hydrocarbon is an organic compound made of only hydrogen and carbon. (b) List three compounds in the body that contain hydrocarbons. and Proteins Fats and Carbohydrates 57. Name the organic compounds below. Ethene a. C2H4 c. C8H14 Methane b. CH4 d. C10H22 Octyne Decane Chemical Equations 58. Balance the following equations AND identify the type of reaction as single replacement, double replacement, synthesis, decomposition, or combustion in the blank space to the far right. a. 1 b. 2 Al c. 2 KIO d. 2C e. 2H Li2SO4 + 12H26 + 1 Pb(NO ) 3 2 3 CuSO 2 3 2 + 4 1 KI + 3O 37 O + 2 1O 2 2 LiNO 3 Al2(SO4)3 + + 1 PbSO 3 Cu 4 Double Replacement Single Replacement Decomposition 2 24 CO + 26 H O 2 2 2H O 2 Combustion Synthesis 60. Write a balanced equation from the sentence below and identify the type of reaction in the blank. a. Hydrogen gas reacts with oxygen gas to produce dihydrogen monoxide. See 67 e 61. Explain the Law of Conservation of Matter. Matter can be neither created nor destroyed only rearranged. ___________________________________________________________________________________