Name (IN INK!)____________________________________________ Date ___________ Class ___________ HONORS CHEM 1st SEMESTER EXAM STUDY GUIDE FALL 2010 STRATEGY: Start by reading through your notes to refresh your memory on these topics. Then, use this review sheet as a starting point to identify the areas on which you need to spend more study time. For those areas, go back to homework assignments, quizzes, and reviews to practice more problems. I would also recommend going through all of your tests since these questions are only samples and do not include specific examples of how vocabulary and other conceptual information might appear in a multiple-choice or other format. Remember you can access notes and reviews on my website. IMPORTANT INFORMATION: This must be handed in BEFORE taking your final exam If entirely complete, 5 points will be added to your exam grade All work must be shown in DETAIL on lined paper Introduction to Chemistry – Chapter 1 1. Identify safe/unsafe lab practices. 2. List pieces and uses of lab equipment. 3. List the requirements for tables and graphs. 4. What is plotted on the x-axis and on the y-axis? 5. Make a density graph. 6. What is water displacement? Matter and Change – Chapter 2 7. Classify the following substances as solid, liquid, gas, or plasma based on their properties. a. flexible volume, high KE, particles can disperse freely. b. flexible volume, very high KE, particles are charged. c. fixed volume, very low KE, orderly particles. d. fixed volume, low KE, particles can move past each other. 8. Classify the following as element, compound, heterogeneous mixture, or solution. a. graphite (carbon) b. grape juice c. table salt (NaCl) d. pepper 9. Classify the following as chemical or physical changes. a. cutting wire b. ripening tomato c. apple slices turning brown d. compressing a gas 10. Classify the following properties as physical or chemical. a. melts at 68.0C b. corrosive c. reacts violently with water d. decomposes in air e. magnetic 11. Classify the following properties as intensive or extensive. a. melting point b. volume c. mass d. reactivity e. density VOCAB:kinetic molecular theory Honors Chemistry -1- Scientific Measurement – Chapter 3 12. In a lab, the average measured density for Pre-1982 pennies was 7.98 g/cm3. Given that the accepted value for the density is 8.92 g/cm3, calculate the percent error. 13. How many sig figs are in the following numbers? a. 2.35 _______ c. 89.70 _______ b. 34,000 _______ d. 0.0052 _______ 14. Convert the following numbers into or out of scientific notation. a. 548,000 __________________ c. 1.200 × 10-3 __________________ b. 0.0000770 __________________ d. 9.25 × 107 __________________ 3 15. Osmium is the densest element with a density of 22.57 g/cm . Find the mass of a 56.2 cm3 sample of osmium. 16. Perform the following SI prefix conversions. a. 65.2 mm = _____ dm c. 65,000 mL = _____ L b. 2.3 kg = _____g d. 0.502 km = _____ cm 17. Perform the following temperature conversions. a. 25oC = _____ K c. 29.8oC = _____ oF o b. 398 K = _____ C d. 75.5oF = _____ K 18. How many milliliters are in a 2.0 quart jug of milk? 19. I will spend next weekend grading lab reports. If each lab report averages 4.12 pages and it takes me an average of 2.50 min per page, how many hours will it take me to grade all 39 papers? 20. Record the appropriate # of SigFigs when measuring with equipment. (look back at test) VOCAB: accuracy vs. precision Periodic Table, Bonding & Chemical Formulas and Names– Chapters 7, 8 & 9 21. What are the names of Groups 1, 2, 17 and 18 on the periodic table? 22. Which of the following is a representative/main group element? Fe, Be, Ce, Re 23. Are the bonds in the following substances IONIC or COVALENT? a. MgO c. LiCl b. H2O d. Br2 24. Are the following properties characteristics of ionic or covalent bonding? a. These bonds involve a transfer of electrons. b. Substances containing these bonds do not conduct electricity and have low melting points. c. Compounds containing these bonds have a crystal lattice structure. d. These bonds are formed by sharing electrons. 25. Which metalloid is in the 4th period and the same group as phosphorus? 26. Write formulas for the following compounds (HINT: First determine ionic/acid/covalent). a. hydrosulfuric acid e. sulfur trioxide b. calcium chloride f. ammonium dichromate c. iron(III) nitrate g. dinitrogen pentoxide d. hydrobromic acid h. sulfurous acid 27. Write names for the following compounds (HINT: First determine ionic/acid/covalent). a. CrCl2 e. CaSO4 b. H3PO3 f. P5O8 c. As2Cl3 g. Fe2CO3 d. Na2C2O4 h. HClO4 VOCAB: octet rule Chemical Quantities – Chapter 10 28. How many magnesium sulfate molecules are in 25.0 g? Honors Chemistry -2- 29. Find the number of moles in 346 g of potassium nitrate. 30. Calculate the number of grams in of 6.12 moles of NaOH. 31. Find the % composition of copper (II) chloride. 32. The percent composition of a compound is 40.91% C, 4.58% H, and 54.51% O. The molar mass of the compound is 176.12 g/mol. Find its empirical and molecular formulas. 33. Find the percent composition of a sample of amoxicillin which has the formula C16H19N3O5S• 3H2O. 34. List these in order of decreasing hydrogen, by mass: water, methane, glucose, and hydrochloric acid. 35. How many grams of lead are in a 41.2-gram sample of lead (II) oxide? 36. What is the percent of H2O in magesium sulfate pentahydrate? VOCAB: Avogadro’s number empirical formula percent composition molecular formula Chemical Reactions – Chapter 11 37. Write a word equation for the following reaction (incl. how many? of what? what state?). Ba(ClO3)2(s) BaCl2(s) + 3O2(g) 38. Rewrite and balance the following word equation using chemical formulas, physical states, and energy. – When solid sodium chlorate absorbs energy, it produces solid sodium chloride and oxygen gas. 39. Balance this equation: Fe2(SO4)3 + KSCN K3Fe(SCN)6 + K2SO4 40. Predict the products and balance (48 – 51). Write N.R. if no reaction will occur. Include physical states. For each of the reactions, specify whether it is combustion, synthesis, decomposition, single replacement, or double replacement. 41. Cu(s) + MgSO4(aq) 42. C5H12(l) + O2(g) 43. NH4Cl(aq) + Pb(NO3)2(aq) 44. Fe2O3(s) VOCAB: Aqueous Combustion Synthesis Decomposition Precipitate Complete ionic equation Net ionic equation Spectator ion Stoichiometry – Chapter 12 45. How many grams of copper would be produced from 49.48 g of chromium? Cr + CuSO4 Cu + Cr2(SO4)3 46. How many grams of chromium are required to react with 125 g CuSO4. (same reaction as above) 47. How many grams of ZnS are required to react with 12.6 g of oxygen gas? ZnS + O2 ZnO + SO2 48. 6.45 g of lithium reacts with 9.20 g of oxygen gas to produce lithium oxide. How many grams of Li2O are formed? 49. What are the limiting and excess reactants in #38? 50. The actual yield of the reaction in #39 is 12.5 g. What is the percent yield of this reaction? 51. Dimethlylhydrazine has a molar mass of 60.10g/mol. It is made up of carbon, hydrogen, nitrogen atoms. The combustion of 2.859g of Dimethyhydrazine in excess oxygen yields nitrogen, 4.190 g of CO2 and 3.428 g water, what are its empirical and molecular formulas? Honors Chemistry -3- VOCAB: theoretical yield percent yield limiting reactant excess reactant Extra Practice with Ionic Names & Formulas and Predicting Products For the following compounds, give the names: Name 52. Na2CO3 _______________________________________ 53. KCl _______________________________________ 54. FeCl2 _______________________________________ 55. FeCl3 _______________________________________ 56. Zn(OH)2 _______________________________________ 57. Be2SO4 _______________________________________ 58. Li3PO4 _______________________________________ 59. TiI4 _______________________________________ For the following compounds, give the formulas: Formula 60. sodium phosphide ____________________________ 61. lead (II) sulfite ____________________________ 62. gallium nitride ____________________________ 63. iron (II) bromide ____________________________ 64. vanadium (V) phosphate ____________________________ 65. silver bromide ____________________________ 66. lead (IV) nitrite ____________________________ Predict the products of the following reactions, if applicable, write complete and net ionic equations: 67. ____ Na + ____ FeBr3 68. ____ NaOH + ____ H2SO4 69. ____ Cl2 + ____ Al 70. ____ Na2SO4 + ____ AgNO3 71. ____ PBr3 72. ____ HBr + ____ Fe 73. ____ K2CO3 + ____ ZnCl2 74. ____ Na + ____ H2O 75. ____ Na2SO4 + ____ Ca(OH)2 Honors Chemistry -4- HONORS CHEMISTRY – 1st SEMESTER EXAM REVIEW – FALL 2010 ANSWER KEY common sense – safe: wear goggles, tie back hair, no horseplay, Bunsen burner safety; unsafe: running, eating, drinking, pouring down the drain, cleaning spills 2. volume – graduated cylinder, mass – triple-beam balance, all metric measurements 3. make sure they have a title, both axes are labeled, both have correct units; line graph for change over time, bar graph for comparing counts, pie chart for percentages 4. x-axis = independent variable, y-axis = dependent variable 5. mass versus volume 6. using water to find the volume of irregularly shaped objects 7. a. gas, b. plasma, c. solid , d. liquid 8. a. element, b. solution, c. compound, d. heterogeneous mixture 9. a. physical, b. chemical, c. chemical, d. physical 10. a. physical, b. chemical, c. chemical, d. chemical, e. physical 11. a. intentensive, b. extensive, c. extensive, d. intensive, e. intensive 12. 10.5% 13. a. 3, b. 2, c. 4, d. 2 14. a. 5.48 × 105, b. 7.70 × 10-5, c. 0.001200, d. 92,500,000 15. 1270 g 16. a. 0.652 dm, b. 2,300 kg, c. 65 mL, d. 50,200 cm 17. a. 298K, b. 125oC, c. 85.6oF, d. 297K 18. 1900 mL 19. 6.70 hours 20. look back at your tests!! 21. Group 1 – Alkali Metals, Group – Alkaline Earth Metals, Group 17 – Halogens, Group 18 – Noble Gases 22. Be 32. EF = C3H4O3, MF = C6H8O6 23. a. ionic, b. covalent, c. ionic, d. covalent 33. 45.81% C, 4.57% H, 10.02% N, 19.07% O, 7.64% S, 24. a. ionic, b. covalent, c. ionic, d. covalent 11.00% H2O 25. arsenic 34. CH4, H2O, C6H12O6, HCl 26. a. H2S, b. CaCl2, c. Fe(NO3)3, d. HBr, e. SO3, f. 35. 38.2 g Pb (NH4)2Cr2O7, g. N2O5, h. H2SO3 36. 42.81% H2O 27. a. chromium(II) chloride, b. phosphorous acid, c. 37. One unit of solid barium chlorate when heated produces diarsenic trichloride, d. sodium oxalate, e. calcium one unit of solid barium chloride and three molecules of sulfate, e. pentaphosphorous octoxide, g. iron (I) oxygen gas. carbonate h. perchloric acid. 38. 2NaClO3(s) 2NaCl(s) + 3O2(g) 28. 1.25 x 1023 molec MgSO4 39. Fe 2(SO4)3 + 12KSCN 2K3Fe(SCN)6 + 3K2SO4 29. 3.42 mol KNO3 40. single replacement, combustion, double replacement, 30. 245 g NaOH decomposition 31. 47.27%Cu, 5.73% Cl _______________ 64. V3(PO4)5 41. Cu(s) + MgSO4(aq) N.R. 65. AgBr 42. C5H12(l) + 8O2(g) 5CO2(g) + 6H2O(g) 66. Pb(NO2)4 43. 2NH4Cl(aq) + Pb(NO3)2(aq) 2NH4NO3(aq) + PbCl2(s) 67. 3 Na + 1 FeBr3 3 NaBr + 1 Fe 44. 2Fe2O3(s) 4Fe(s) + 3O2(g) 68. 2 NaOH + 1 H2SO4 2 H2O (l) + 1 Na2SO4 (aq) 45. 90.71 g Cu 69. 3 Cl2 + 2 Al 2 AlCl3 46. 27.1 g Cr 70. 1 Na2SO4 + 2 AgNO3 2 NaNO3 (aq) + 1 Ag2SO4 (s) 47. 25.6 g ZnS 71. 2 PBr3 2 P (s) + 3 Br2 (l) 48. 13.9 g Li2O 72. 2 HBr + 1 Fe 1 FeBr2 (s) +1 H2 (g) 49. LR: Li, XS: O2 73. K2CO3 + ZnCl2 2 KCl (aq) + ZnCO3 (s) 50. 89.9% yield 74. 2 Na + 2 H2O 2NaOH + H2 51. EF = CH4N, MF = C2H8N2 75. ____ Na2SO4 + ____ Ca(OH)2 CaSO4 + NaOH NR 52. sodium carbonate 53. potassium chloride 54. iron (II) chloride 55. iron (III) chloride 56. zinc hydroxide 57. beryllium sulfate 58. lithium phosphate 59. titanium (IV) iodide 60. Na3P 61. PbSO3 62. GaN 63. FeBr2 1. Honors Chemistry -5-