CHEMISTRY Periodic Table of the Elements 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 Elements of the Periodic Table You Need to Know atomic # symbol element name atomic symbol # 1 19 2 20 3 24 4 25 5 26 6 27 7 28 8 29 9 30 10 35 11 46 12 47 13 50 14 51 15 53 16 79 17 80 18 82 element name Chemistry Terminology Place the following terms next to the appropriate definition. anion atom atomic number cation electron isotope mass number metal metalloid molecule neutral neutron non-metal period proton group The negative particle in an atom Having no charge Two or more atoms bonded together A negatively charged ion The neutral particle in an atom Tells the number of protons A positively charged ion The positive particle in an atom Is made of protons, electrons and neutrons together An element located near the “staircase” of the periodic table with some metallic and some non-metallic properties An element that is generally a non-conductor of electricity and is brittle An element that is a good conductor of electricity, malleable and ductile Atoms of an element that have the same number of protons and electrons, but differ in the number of neutrons A column of elements in the periodic table A row of elements in the periodic table Bohr diagrams Complete the following Bohr diagrams. 1. 28 Al 35 2. Cl p= n= 4. 55Fe 5. 48Ti 79 51 V+2 32 -2 S 11. 9. 29 Si 31 +3 P p= n= 12. 80 p= n= 14. p= n= p= n= p= n= p= n= 13. p= n= p= n= p= n= 10. Mn 6. 84Kr 8. 52Cr Se 55 p= n= p= n= 7. 3. 56 Fe+3 p= n= Br-1 p= n= 15. 57 Ni+2 p= n= Electron Configurations Fill in the following chart using and symbols for electrons for the given elements. 1s 1. Li 2. N 3. Ne 4. Zn 5. Ti 6. Ca 7. Mn 8. V 9. Si 10. Mg 11. Ar 12. C 13. Ni 14. Sc 15. O 16. K 17. F 2s 2p 3s 3p 4s 3d Electron Configurations atomic # 1 2 3 4 5 6 7 8 9 10 name symbol total e- valence e- closest noble gas full electron configuration abbreviated electron configuration Lewis dot diagram atomic # 15 17 19 20 22 25 26 29 30 35 36 name symbol total e- valence e- closest noble gas full electron configuration abbreviated electron configuration Lewis dot diagram Properties of Elements Lab Use careful observations and research to complete the following table. Make sure you record your sources on the last page. Atomic # 1 2 3 6 7 8 10 11 12 13 14 Symbol Element Name Mass of 1 a.m.u. (2 decimals) Properties (colour, clarity, state and 1 other property) Two Common Uses 15 16 17 18 19 20 24 25 26 27 28 29 30 32 33 34 35 36 47 48 50 51 52 53 78 79 80 82 83 References: Classification of Elements Metals, Non-metals, Metalloids 1 2 H He 3 4 5 6 Li Be B C 11 12 13 14 Na Mg Al Si 19 20 21 22 23 24 25 26 27 28 29 30 31 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn 37 38 39 40 41 42 43 44 45 46 47 48 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag 55 56 57 72 73 74 75 76 77 78 Cs Ba La Hf Ta W Re Os Ir 87 88 89 104 105 106 107 108 109 Fr Ra Ac 58 59 60 61 62 63 Ce Pr Nd Pm Sm Eu 90 91 92 93 94 Th Pa U Np Pu 7 8 9 10 O F Ne 15 16 17 18 P S Cl Ar 32 33 34 35 36 Ga Ge As Se Br Kr 49 50 51 52 53 54 Cd In Sn Sb Te I Xe 79 80 81 82 83 84 85 86 Pt Au Hg Tl Pb Bi Po At Rn 110 111 112 113 114 115 116 117 118 64 65 66 67 68 69 70 71 Gd Tb Dy Ho Er Tm Yb Lu 95 96 97 98 99 100 101 101 103 Am Cm Bk Cf Es Fm Md No Lr N metals non-metals semi-metals transition metals Chemical Groups (Families) 1 2 H He 3 4 5 6 7 8 9 10 Li Be B C 11 12 13 14 15 O F Ne 16 17 Na Mg Al Si 18 P S Cl Ar 19 20 21 22 23 24 25 26 27 28 29 30 31 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga 32 33 34 35 36 Ge As Se Br 37 38 39 40 41 42 43 44 45 46 47 48 Kr 49 50 51 52 53 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag 54 Cd In Sn Sb Te I 55 56 57 72 73 74 75 76 77 78 Xe 79 80 81 82 83 84 85 Cs Ba La Hf Ta W Re Os Ir 86 Pt Au Hg Tl Pb Bi Po At Rn 87 88 89 104 105 106 107 108 109 Fr Ra Ac 110 111 112 113 114 115 116 117 118 N alkali metals alkaline earth metals halogens noble gases 58 59 60 61 62 63 64 65 66 67 68 69 70 71 Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu 90 91 92 93 94 95 96 97 98 99 100 101 101 103 Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr Common Charges 1 2 H He 3 4 5 6 7 8 9 10 Li Be B C 11 12 13 14 15 O F Ne 16 17 18 Na Mg Al Si 19 20 21 22 23 24 25 26 27 28 29 30 31 32 P S Cl Ar 33 34 35 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga 36 Ge As Se Br Kr 37 38 39 40 41 42 43 44 45 46 47 48 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd 49 50 51 52 53 54 In Sn Sb Te I 55 56 57 72 73 74 75 76 77 78 79 Xe 80 81 82 83 84 85 86 Cs Ba La Hf Ta W Re Os Ir Pt 87 88 89 104 105 106 107 108 109 110 Au Hg Tl Pb Bi Po At Rn 111 112 113 114 115 116 117 118 Fr Ra Ac 58 59 60 61 62 63 64 65 66 67 68 69 70 71 Ce Pr Nd Pm Sm Eu 90 91 92 93 94 95 Gd Tb Dy Ho Er Tm Yb Lu 96 97 98 99 100 101 101 103 Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr N +1 +2 +3 -1 -2 -3 -4 Ionic Charges and Chemical Families Alkali Metals element name symbol valence electrons electron dot diagram of atom electron dot diagram of stable ion ionic charge Alkaline Earth Metals element name symbol valence electrons electron dot diagram of atom electron dot diagram of stable ion ionic charge Halogens element name symbol valence electrons electron dot diagram of atom electron dot diagram of stable ion ionic charge electron dot diagram of stable ion ionic charge Noble Gases element name symbol valence electrons electron dot diagram of atom Metallic Elements element name symbol valence electrons electron dot diagram of atom electron dot diagram of stable ion ionic charge aluminum tin lead Non-Metallic Elements element name symbol valence electrons electron dot diagram of atom electron dot diagram of stable ion ionic charge nitrogen oxygen phosphorous Conclusions: 1. The alkali metals always develop a charge of . 2. The alkaline earth metals always develop a charge of . 3. The halogens always develop a charge of . 4. The noble gases always develop a charge of . 5. Metals develop positive charges and become . 6. Non-metals will develop a negative charge and become . Australian – atoms and their electrons 1. How are atoms grouped on the periodic table? 2. All matter is made up of 3. All atoms are made up of 4. Protons have a 5. Most of the atoms is 6. Atoma means 7. Dalton said that molecules are made of 8. JJ Thompson discovered the . 9. Thompson’s model was called . . , and . charge . . . 10. Rutherford shot the nuclei of helium atoms at a thin sheet of 11. Rutherford thought the positive spinning around it. . was in the centre of the atom with electrons 12. Bohr said the electrons circled in . 13. Atoms are positioned in the periodic table according to the arrangement of 14. The smallest atom is . . 15. Deuterium is called . 16. has a low density. 17. Beryllium is in on the periodic table. 18. Fluorine has outer electrons. 19. is very corrosive and the only element to attack glass. 20. is satisfied because it has a full outer shell of electrons. 21. The elements on the right side of the periodic table are called 22. Write the symbols for 3 noble gases. 23. Chlorine has layers of electrons. 24. Which halogen is the most attractive? 25. is below carbon on the periodic table. 26. Who are the bouncers at the under 18 disco? 27. Who is an undesirable element? 28. Who’s always trying to get into under 18 parties? . 29. Which elements are police? 30. How many electrons does oxygen want? 31. Sharing electrons is called a . 32. The hardest substance in the world is . 33. CH4 is called . 34. NH3 is called . 35. H2O is called . 36. CO2 is called . 37. Who is the element of sodium’s dream? 38. Sodium and chlorine form an bond. 39. How can sodium and chlorine split? Atom bond: the atom with the golden electrons 1. Who is the atom with the blonde bomb shell? 2. What is the only atom that can attack silica – SiO2 (glass)? 3. How many bonds can halogens form? 4. How many bonds can carbon form? 5. Atoms all want 6. The smaller an atom is, the it holds its electrons. 7. Lop-sided charges are called ? 8. The strongest of the dipole-dipole bonds is the covalent bond. 9. KCl is called 10. Water is a electrons? , but it is only 1/10th the strength of a . solvent. 11. Which element is the police officer? 12. What is O3 called? 13. CCl4 is called . 14. What is project D? 15. This molecule may be unzipped by breaking . Elements and the Periodic Table – Simple Ions Complete the following table. Note that the name of the NON-METALLIC ion ends in “ide” while the name for METALLIC ions uses the normal name of the element. ion name symbol number of protons number of electrons number of electrons transferred fluoride F-1 9 10 0 1 2 3 4 lost gained 53 54 0 1 2 3 4 lost gained 0 1 2 3 4 lost gained 0 1 2 3 4 lost gained 0 1 2 3 4 lost gained 0 1 2 3 4 lost gained Sr+2 0 1 2 3 4 lost gained H+1 0 1 2 3 4 lost gained 8 0 1 2 3 4 lost gained 12 0 1 2 3 4 lost gained 10 0 1 2 3 4 lost gained 36 0 1 2 3 4 lost gained 0 1 2 3 4 lost gained 0 1 2 3 4 lost gained 0 1 2 3 4 lost gained 0 1 2 3 4 lost gained 0 1 2 3 4 lost gained 0 1 2 3 4 lost gained 0 1 2 3 4 lost gained 0 1 2 3 4 lost gained 0 1 2 3 4 lost gained 16 potassium Ca+2 35 aluminum 34 H-1 lithium Rb+1 17 beryllium 7 C-4 P-3 18 are electrons lost or gained? same number of e- as this noble gas neon neon Flame Colours Lab name: Introduction: When atoms are “excited”, electrons can jump up one or more energy levels. Energy is needed for this to happen. When these electrons fall back down towards their original energy level, they release energy, some of which we see as visible light. The colours of light emitted when the electrons fall back down can be used to identify the atom. Purpose: To use the flame test to distinguish between different cation salts. Materials: evaporating dishes cation salts (in methanol) lighter safety glasses Procedure: 1. Make qualitative observations of the original salts and solutions. 2. Light a control of pure methanol. 3. Light each of the solutions and observe the flame colour. 4. Allow the flames to burn out. The dishes will be very hot at this point. 5. If required, allow the dishes to cool, then relight the solutions using more methanol. 6. Test the unknowns and decide which cations they contain. Observations: cation none sodium barium calcium strontium cobalt lithium potassium copper symbol qualitative observations of salt and solutions qualitative observations of flame qualitative observations of salt and solutions qualitative observations of flame cation unknown #1 unknown #2 unknown #3 unknown #4 Questions: 1. What is a cation? 2. Which cations were easiest to distinguish? Why? 3. Which cations were difficult to distinguish? Why? 4. Some of these cations are used in fireworks. Which ones would you choose to make a fireworks display? Bonus: The control sample that was burned contained only alcohol. Why would methanol create a flame that had more than one colour? Bill Nye – Chemical Reactions 1. Everything is made up of ___________________________. 2. Metal rusting, candles burning and food being digested are examples of: 3. What gas makes iron rust? 4. When electrons recombine with other electrons, _________________ is given off. 5. CH2H4O2 (vinegar)+ NaHCO3 (baking soda) react to give off____________ gas. 6. Two poisons that we can’t live without are _________________________ and ____________________________. 7. Another name for NaCl is ________________________. 8. Pyrotechnics is another name for the manufacture of: 9. How many elements make up everything we know and love? 10. What prize is awarded to people who have done great works for humanity? 11. Alfred Nobel became very rich because he invented _______________________. 12. Vinegar is an ________________________, while baking soda is a _______________________________. 13. All of the elements are listed on the ___________________________________. 14. Ca is found in____________________, salt contains________________________, and K is found in _________________________. 15. Why are sodium and potassium grouped together? Reactions of Metals with Water Part A: Review positive tests for OXYGEN, HYDROGEN, CARBON DIOXIDE, ACIDS and BASES. Draw a series of labeled diagrams with brief descriptions. Part B: Calcium and Magnesium For each metal, add a small piece carefully to a test tube approximately ¼ full of water along with 3 drops of phenolphthalein indicator. Record at least 4 qualitative observations for calcium with water. Record at least 2 qualitative observations for magnesium with water. Questions: 1. 2. 3. 4. What gas is produced when calcium is added to water? How do you know? Is the remaining liquid acidic or basic? How do you know? Which of the metals is more active in its reaction with water? Write full electron configurations for calcium and magnesium. How many electrons do each of them have in their outer shell? 5. Which of these 2 metals has their outer shell electrons closer to the nucleus? Part C: LITHIUM, SODIUM and POTASSIUM For each metal, add a small piece carefully to a test tube approximately ¼ full of water along with 3 drops of phenolphthalein indicator. Make qualitative observations for each of the metals. Be sure to include: a) the shape of the metal b) movement of the metal c) relationship between the metal and the surface of the water d) any materials produced in the reaction Questions: 1. 2. 3. 4. What does the phenolphthalein indicate? What does this mean? Based on part B, what other substance do you think was produced? Why? Rate these 3 metals in order of their reactivity with the water. Write full electron configurations for Li, Na and K. How many electrons do each of them have in their outer shell? 5. Which of these 3 metals has their electrons closest to the nucleus? How do you think this is related to your answer in question 3? 6. Make some predictions about the behaviour of: a) cesium (ie more or less reactive than Li, Na and K. Why?) b) barium (ie more or less reactive than Ca and Mg. Why?) Conclusions 1. What happens to the reactivity of the alkali metals as you move down the periodic table? What does this have to do with outer shell electrons? 2. What happens to the reactivity of the alkaline earth metals as you move down the periodic table? What does this have to do with outer shell electrons? Periodic Trends 1. Select the element which has the: a) highest electronegativity b) smallest atomic radius c) smallest electronegativity of the alkali metals d) largest first ionization energy of period 3 e) smallest first ionization energy of the noble gases f) largest atomic radius of period 5 g) greatest electronegativity of the halogens 2. Which of the following has the lowest ionization energy? chromium iron calcium arsenic copper 3. Which of the following has the largest electronegativity? neon xenon silver antimony tin phosphorous aluminum 4. Which of the following is the largest? lithium neon potassium 5. Which of the following has the smallest electronegativity? lead platinum bromine germanium nickel 6. Which of the following has the smallest ionic radius? K+ Ca2+ Ar Cl- S2- 7. Which of the following has the largest first ionization energy? Ba Hg Au P Si Chemical Bonding Between Atoms Molecular Substance Molecular formula trichloromethane CHCl3 ammonia NH3 water H2O bromine Br2 hydrogen H2 chlorine Cl2 hydrogen chloride HCl Lewis dot diagram of the atoms Lewis dot diagram of the molecule Structural diagram Molecular Substance Molecular formula methane CH4 arsenious chloride AsCl3 phosphorous bromide PBr2 ethane C2H6 dinitrogen tetrahydride N2H4 hydrogen peroxide H2O2 silicon tetrahydride SiH4 Lewis dot diagram of the atoms Lewis dot diagram of the molecule Structural diagram Molecular Substance Molecular formula methanal H2CO ethyne C2H2 nitrogen N2 carbon dioxide CO2 hydrogen cyanide HCN bromoiodomethane CH2BrI tetrafluoroethene C2F4 Lewis dot diagram of the atoms Lewis dot diagram of the molecule Structural diagram Legal Grade 10 Nomenclature Cheat Sheet Compound Ions nitrate NO3-1 carbonate CO3-2 fluorate FO3-1 sulphate SO4-2 chlorate ClO3-1 phosphate PO4-3 bromate BrO3-1 hydrogen carbonate HCO3-1 iodate IO3-1 hydrogen sulphate HSO4-1 hydroxide OH-1 monohydrogen phosphate HPO4-2 ammonium NH4+1 dihydrogen phosphate H2PO4-1 Latin “ous / ic” Cations element higher charge lower charge iron +3 ferric +2 ferrous copper +2 cupric +1 cuprous tin +4 stannic +2 stannous antimony +5 stibbic stibbous +3 antimonic antimonous gold +3 auric +1 aurous mercury +2 mercuric +1 mercurous lead +4 plumbic +2 plumbous phosphorous +5 phosphoric +3 phosphorous Prefixes mono di tri tetra penta hexa hepta octa nona deca Naming Binary Compounds Rules: 1. Determine which element is the cation. The cations are usually found toward the left of the periodic table and are written first in the name and formula of a molecule. 2. Determine which element is the anion. The anions are non-metals (or hydrogen), located on the right side of the periodic table, and are written second in the name and formula of a molecule. 3. Write the cation first using the name of the element. 4. Write the anion second, dropping the usual ending and replacing it with “ide”. element fluorine chlorine bromine iodine hydrogen anion fluoride chloride bromide iodide hydride element oxygen sulphur nitrogen phosphorous carbon eg. KCl = potassium chloride Write the correct chemical name for each of the following: 1. MgO 11. K2S 2. LiF 12. Na2O 3. NaBr 13. K2O 4. CaO 14. Ca3P2 5. AlN 15. H2O 6. NaI 16. CaBr2 7. Al2S3 17. MgS 8. Ag3P 18. ZnBr2 9. BaCl2 19. B2O3 10. AlCl3 20. Ba2C anion oxide sulphide nitride phosphide carbide Writing Chemical Formulae Rules: 1. Write the chemical symbol for the cation first, followed by the symbol of the anion. 2. Write the charge of each ion above each symbol. 3. Cross the charges, ignoring the signs. 4. Reduce the numbers if there is a common factor. 5. If the number beside an element is 1, do not write it. (The total positive charge will now equal the total negative charge in the molecule.) Example: silicon oxide Rule 1 Si O Rule 2 Si+4 O-2 Rule 3 Si2O4 Rule 4 SiO2 Write the correct chemical formula for each of the following: 1. sodium nitride 11. calcium phosphide 2. sodium oxide 12. sodium fluoride 3. calcium chloride 13. boron nitride 4. magnesium sulphide 14. calcium hydride 5. silicon oxide 15. hydrogen oxide 6. aluminum carbide 16. aluminum nitride 7. boron fluoride 17. potassium carbide 8. potassium nitride 18. zinc iodide 9. cesium oxide 19. barium bromide 10. aluminum bromide 20. silver selenide Multiple Valences Latin method – “ous/ic” Many cations have more than one possible charge. The latin method is the oldest method used to deal with this program, and while it can’t be used for many molecules, it is still used in industry. Rules: 1. Determine the charge on the cation. 2. Select the proper name for the cation. a) The “ous” ending refers to the lower cation charge. b) The “ic” ending refers to the higher cation charge. 3. Write the name of the anion as before, using the “ide” ending element iron copper tin antimony higher charge +3 ferric +2 cupric +4 stannic stibbic +5 antimonic lower charge ferrous cuprous stannous stibbous +3 antimonous +2 +1 +2 element gold mercury lead phosphorous higher charge +3 auric +2 mercuric +4 plumbic +5 phosphoric Write the correct “ous/ic” name for each of the following: 1. FeCl2 6. Au2S3 2. Cu2O 7. Sb2O5 3. Hg3N 8. SnBr5 4. PbO2 9. AuCl 5. CuF2 10. SbF5 Write the correct formula for each of the following: 1. ferrous chloride 6. stannous phosphide 2. plumbic oxide 7. aurous fluoride 3. ferric nitride 8. mercuric nitride 4. cuprous sulphide 9. stibbic bromide 5. stibbous oxide 10. stannic carbide +1 +1 +2 +3 lower charge aurous mercurous plumbous phosphorous Multiple Valences Prefix Method This method is commonly used only for naming binary compounds composed of two non-metals. Rules: 1. A prefix is used to indicate the number of atoms in the molecule. number of atoms 1 2 3 4 5 prefix mono di tri tetra penta number of atoms 6 7 8 9 10 prefix hexa hepta octa nona deca 2. Place the appropriate prefix in front of the cation (mono is dropped in the first element). 3. Place the appropriate prefix in front of the anion, using the “ide” suffix as before. Exceptions: 1. Peroxides – contain O2-2 ion Peroxides have an extra oxygen atom. Write the formula for the ordinary oxide and add one additional oxygen atom. Peroxides are NOT reduced. barium oxide – BaO barium peroxide – BaO2 hydrogen oxide – H2O hydrogen peroxide – H2O2 2. Diatomic Elements The following gaseous elements consist of two atoms joined together. They do not occur naturally as a single atom. (mnemonic – HOFBrINCl or Hey NO halogens) H2 N2 O2 F2 Cl2 Br2 I2 1. sulphur dioxide 2. carbon disulphide 3. nitrogen trichloride 4. phosphorous pentabromide 5. diiodine pentasulphide 6. selenium tetrachloride 7. bromine heptafluoride 8. nitrogen monoxide 9. selenium trioxide 10. dinitrogen trisulphide Multiple Valences IUPAC (Roman Numeral) Method The IUPAC (International Union of Pure and Applied Chemists) method is a standardized nomenclature system that always works. The Roman Numerals are NOT used when there is only one possible positive valence (ie Columns I, II, III, Ag, Zn and Cd). Rules: 1. Determine the charge on the anion (there is only one possibility). 2. Determine the total negative charge by multiplying the anion charge by the number of anions present. 3. The total positive charge equals the total negative charge in a neutral molecule. 4. Divide the total negative charge by the number of cations present to determine the charge on each cation. 5. Write down the name of the cation. 6. Write the charge on the cation using Roman Numerals in brackets after the cation. 7. Write down the name of the anion using the “ide” ending. eg. Fe2O3 1. 2. 3. 4. charge on O = -2 total negative charge = –2 x 3 = -6 total positive charge = +6 charge on iron = +6 2 = +3 5. name of molecule = iron (III) oxide Write the correct IUPAC name for each of the following. 1. FeCl2 6. Au2S3 2. Cu2O 7. Sb2O5 3. Hg3N 8. SnBr4 4. PbO2 9. AuCl3 5. CuF2 10. CrBr3 Write the correct formula for each of the following. 1. mercury (I) oxide 6. tin (II) phosphide 2. lead (IV) chloride 7. gold (I) fluoride 3. iron (III) nitride 8. mercury (II) nitride 4. copper (I) sulphide 9. antimony (V) bromide 5. antimony (III) oxide 10. tin (IV) carbide Compound Ions Many ions consist of more than one element. These ions all have special names which you will not need to memorize. A chart of the compound ions will be provided to you for all tests and quizzes. The charge given in the chart is the charge on the compound ion as a unit. Compound molecules are named using the IUPAC system, the only difference being that if more than one of the compound ions is needed to form a neutral molecule, brackets are placed around the ion. nitrate NO3-1 carbonate CO3-2 fluorate FO3-1 sulphate SO4-2 chlorate ClO3-1 phosphate PO4-3 bromate BrO3-1 hydrogen carbonate HCO3-1 iodate IO3-1 hydrogen sulphate HSO4-1 hydroxide OH-1 monohydrogen phosphate HPO4-2 ammonium NH4+1 dihydrogen phosphate H2PO4-1 eg. iron (III) sulphate = Fe+3 SO4-2 Fe2(SO4)3 Complete the following table. 1. silver carbonate 11. Fe(NO3)3 2. calcium nitrate 12. AuClO3 3. lead (II) bromate 13. Mn(HCO3)2 4. ammonium chloride 14. Sr(FO3)2 5. manganese (IV) iodate 15. Ti(BrO3)4 6. potassium phosphate 16. Co3(PO4)4 7. lithium hydrogen carbonate 17. (NH4)2SO4 8. copper (II) sulphate 18. Ni(OH)3 9. zinc dihydrogen phosphate 19. Sb(IO3)5 10. aluminum hydroxide 20. Sn(CO3)2 Simple Nomenclature ions molecule molecular name 1. silicon oxide 21. MgCl2 2. boron fluoride 22. SiC 3. aluminum carbide 23. Al2S3 4. potassium nitride 24. SiH4 5. cesium oxide 25. H2S 6. aluminum bromide 26. Ag3P 7. calcium phosphide 27. H2O 8. sodium fluoride 28. MgO 9. boron nitride 29. CaH2 10. nitrogen hydride 30. NaBr 11. hydrogen oxide 31. KF 12. calcium nitride 32. C3N4 13. aluminum nitride 33. H2S 14. calcium oxide 34. B2S3 15. potassium sulphide 35. BaO 16. zinc oxide 36. ZnO 17. silver nitride 37. SrS 18. lithium fluoride 38. BeS 19. magnesium iodide 39. SiCl4 20. hydrogen arsenide 40. AlF3 Binary Nomenclature 1. ferric sulphide 21. MgCl2 2. calcium chloride 22. SiC 3. tin (IV) carbide 23. Al2S3 4. carbon dioxide 24. SiH4 5. aluminum bromide 25. H2S 6. rubidium nitride 26. Ag3P 7. cuprous phosphide 27. H2O 8. stibbic fluoride 28. MgO 9. antimony (V) fluoride 29. CaH2 10. cesium oxide 30. NaBr 11. mercury (II) iodide 31. KF 12. plumbic chloride 32. C3N4 13. gold (I) nitride 33. H2S 14. zinc sulphide 34. B2S3 15. silver bromide 35. BaO 16. stannous oxide 36. ZnO 17. copper (II) phosphide 37. SrS 18. beryllium iodide 38. BeS 19. mercuric carbide 39. SiCl4 20. table salt 40. AlF3 Compound Ion Nomenclature 1. copper (II) nitrate 21. K2CO3 2. ferrous sulphate 22. Na2SO4 3. potassium chlorate 23. Zn3(PO4)2 4. zinc carbonate 24. Hg2SO4 5. silver phosphate 25. Ba(NO3)2 6. sodium sulphate 26. Fe(HSO4)3 7. barium hydroxide 27. Pb3(PO4)4 8. ammonium phosphate 28. Hg(NO3)2 9. 29. FeSO4 plumbous hydrogen carbonate 10. cuprous nitrate 30. Sb(HCO3)5 11. mercury (II) hydrogen sulphate 31. MgSO4 12. zinc sulphate 32. Ag3PO4 13. auric phosphate 33. NH4NO3 14. aluminum nitrate 34. Sn(OH)4 15. ammonium hydroxide 35. BPO4 16. boron carbonate 36. Be(OH)2 17. lead (IV) hydrogen carbonate 37. AuHSO4 18. ammonium sulphide 38. Cu3(PO4)2 19. mercuric phosphate 39. AgHCO3 20. stibbous carbonate 40. Li2SO4 Nomenclature: A Little Bit of Everything 1. oxygen gas 21. NaClO3 2. magnesium chloride 22. Sb2O5 3. tin (IV) carbonate 23. Sn(NO3)4 4. carbon monoxide 24. Na2O2 5. aluminum hydrogen sulphate 25. HgBr 6. copper (II) phosphate 26. Zn2C 7. cupric phosphide 27. H2 8. stibbous nitrate 28. Al2O3 9. argon gas 29. ZnCO3 10. ammonium hydroxide 30. Mg(HSO4)2 11. mercury (II) sulphate 31. Pb3N4 12. diantimony trioxide 32. AlF3 13. gold (I) hydrogen carbonate 33. He 14. beryllium sulphide 34. SO3 15. silver bromide 35. NaCl 16. boron oxide 36. N2 17. plumbous bromide 37. Pb(CO3)2 18. barium carbonate 38. CO2 19. mercuric carbide 39. (NH4)2O 20. chlorine gas 40. AuBr3 Nomenclature Rummy Rules Group size: 3-5 players (6 if absolutely necessary) Periodic Tables or “Official Cheat Sheets” are permitted during the game. 1. Dealer deals 7 cards to each player. 2. Place the remaining cards face down in a stack with the top card turned face up beside it as the start of the discard pile. 3. Each turn begins with picking up a card from either the stack or the discard pile. 4. The person to the left of the dealer starts the game by picking up the face down card from the stack or the face up card on the discard pile. 5. If this player can lay down any COMPLETE MOLECULES, they can do so at this time. They must correctly name each molecule as they lay it down (Jokers may be used for any ion.) eg. CaCl2 = 1 card of Ca+2 and 2 cards of Cl-1 Ne = 1 card of Ne0 O2 = 2 cards of O-2 6. This player ends their turn by placing a card from their hand onto the discard pile. 7. The play then passes to the next person on the left. 8. The round is completed when a player gets rid of all of their cards. They do NOT have to have a discard. 9. Once the round is scored (see below), the next person to the left becomes the new dealer. DECOMPOSITION! If a player lays down an incorrect molecule (ex they call out calcium chloride and place down 1 Ca+2 card and 1 Cl-1 card) or if they name the molecule incorrectly (don’t forget about multiple valences), another player may yell DECOMPOSITION as the mistake is made. If there was indeed a mistake, the player who made the mistake must pick up all of the molecules they put down during that turn. Their turn is now over and they do NOT get to discard. If the molecule was correct, then the player who yelled incorrectly yelled decomposition loses 10 points. SCORING winner of the round: 10 bonus points incorrect decomposition: –10 points cards in your hand: joker –10, noble gas –5, all other cards are worth the negative of their valence, ions with more than one charge are counted as the highest value against you cards on the table: all cards count as the positive of the valence used Keep running total of all rounds played during the class. Make a grand total of all the rounds when the time is up. Rank players 1st, 2nd, etc. and hand in your results. name: Nomenclature Rummy Practice Cl-1 O-2 Ca+2 Hg+1 +2 H+1 Fe+2 +3 O-2 H+1 PO4-3 CO3-2 HSO4-1 Sb+3 +5 H+1 Al+3 Cl-1 Zn+2 NO3-1 Sn+2 +4 H+1 Cl-1 Cl-1 Build as many molecules as you can from the above nomenclature rummy cards. You can use every card as many times as you like. You must write the formula and name for each molecule. Fill in the top 8 rows first. Any molecules you make after this are BONUS . Comparing the Masses of Reactants and Products Purpose: To test the law of conservation of mass. Materials: electronic balance 250 mL beaker small test tube copper (II) sulphate solution sodium hydroxide solution Procedure: 1. Pour 20 mL of sodium hydroxide solution into the beaker. 2. Pour copper (II) sulphate solution into the small test tube until the test tube is about half full. 3. Place the test tube in the beaker, being careful not to mix the solutions. 4. Determine the mass of the beaker and its contents. 5. Record observations and measurements. 6. Carefully pour the copper (II) sulphate solution into the beaker, leaving the empty test tube in the beaker. 7. Predict the mass of the beaker and its contents. 8. Record observations about the appearance of the contents and the measurement. 9. Flush contents of the beaker down the sink with water. 10. Clean the beaker and the test tube and return them to your teacher. Discussion Questions: 1. When the solutions were mixed, did a chemical change occur? What is your evidence for this? 2. How did the mass of the reactants and glassware before the reaction compare with the mass after the reaction? 3. If you noted a change in mass, offer an explanation to account for it. 4. Do your results support the law of conservation of mass? If not, what sources of error might have affected your observations and measurements? 5. The products of the reaction are copper (II) hydroxide and sodium sulphate. Write a word equation to describe the reaction. Counting Atoms Worksheet Na2CO3 Type of atom # of atoms Total K2CrO4 Type of atom # of atoms # of atoms Total # of atoms 4 Al2(CO3)3 Type of atom # of atoms Total # of atoms Total 10 (NH4)2S Type of atom 3 BaCl2 Type of atom Total Total Pb(NO3)2 Type of atom # of atoms Total Total NH4C2H3O2 Type of atom Ca3(PO4)2 Type of atom 2 (NH4)2Cr2O7 Type of atom # of atoms Total # of atoms 25 CH3COOH Type of atom Total # of atoms Balancing Equations Chemical equations are used to show a chemical process or reaction. They are often written first as a word equation and then translated to chemical formulae using your nomenclature skills. One of the key concepts of a chemical reaction is the fact that both sides of the equation MUST balance. This means that not only must both sides have the same total number of atoms, but that the amount of a single type of atom on both sides must also balance. Example: If you started with only two oxygen atoms, you must still have two oxygen atoms when you finish. You cannot have less or more. So, the total number of oxygen atoms on the left side of the equation (reactants - before the arrow) and the total number of oxygen atoms on the right side of the equation (products - after the arrow) must be the same. To make the number of atoms the same, the coefficient (number in front of each molecule) can be changed, adding entire molecules to either side until the overall equation is balanced. You cannot change the chemical formula – only leading numbers. For this simulation, we will be using M&M’s to represent the different atoms. Do NOT start eating the “atoms” until after you have completed the work. Once you are finished all the questions, you will be permitted to eat your molecules. Legend (you may substitute colours if necessary) Hydrogen – yellow Oxygen – red Nitrogen – green Chlorine – blue Carbon – brown Calcium – orange Example: word equation: oxygen + hydrogen water translates to chemical equation: O2 + H2 H2O To model this, we place an oxygen molecule (2 reds) in the place of the first reactant and a hydrogen molecule (2 yellows) in the place of the second reactant. In the space for the first product, place a water molecule (2 yellows and a red). Since there isn’t a second product, leave that space blank. a) Are there equal numbers of reds on both sides? NO Add an extra molecule that includes a red to the side that is missing some. b) (Add one more water on the product side – two yellows and a red together.) c) Are there equal numbers of yellows on both sides? NO Add an extra molecule that includes a yellow to the side that is missing some. (Add one more hydrogen molecule – 2 yellows – to the reactant side) d) Are there equal numbers of all colours on both sides? YES e) Count the number of each molecule and place it in front of the molecules in the equation. O2 + 2 H2 2 H2O Balancing Equations Reactant 1 + Reactant 2 Product 1 + Product 2 Practice In each of the questions below, you are given the word equation, an unbalanced chemical equation and a chemical equation with blanks. Use the M&M’s to help determine the number that belongs in each of the blanks. Remember, the number represents the number of MOLECULES, not the number of atoms (M&M’s). 1. methane + oxygen carbon dioxide + water CH4 + O2 CO2 + H2O O2 CH4 + CO2 + H2O 2. calcium + water calcium hydroxide + hydrogen Ca + H2O Ca(OH)2 + H2 H2O Ca + Ca(OH)2 + H2 3. nitrogen + hydrogen ammonia N2 + H2 NH3 H2 N2 + NH3 4. calcium chloride + water calcium hydroxide + hydrochloric acid CaCl2 + H2O Ca(OH)2 + HCl CaCl2 + H2O Ca(OH)2 + HCl 5. nitric acid hydrogen + nitrogen dioxide + oxygen HNO3 H2 + NO2 + O2 HNO3 H2 + NO2 + O2 Bonus: 6. oxygen + glucose carbon dioxide + water O2 + C6H12O6 CO2 + H2O O2 + C6H12O6 CO2 + H2O Balancing Chemical Equations H2 1. N2 + NH3 2. KClO3 3. NaCl + 4. H2 + 5. Pb(OH)2 + 6. AlBr3 + 7. CH4 + 8. C3H8 + O2 9. FeCl3 + NaOH 10. P + 11. Na + 12. Ag2O 13. S8 + 14. CO2 + 15. K + 16. HCl + 17. HNO3 + 18. H2O + 19. NaBr + 20. H2SO4 + KCl + O2 F2 NaF + O2 Cl2 H2O HCl H2O + PbCl2 K2SO4 KBr + Al2(SO4)3 O2 O2 CO2 + H2O CO2 + H2O Fe(OH)3 + NaCl P2O5 H2 O NaOH + Ag + O2 O2 SO3 H2O C6H12O6 + MgBr2 KBr + CaCO3 O2 Mg CaCl2 + NaHCO3 O2 H2 H2O + NaNO3 + H2O + H2O2 CaF2 NaNO2 NaF + HNO2 + CaBr2 Na2SO4 CO2 CO2 More Balancing Equations HCl 1. Ca(OH)2 + 2. SO2 + 3. Al + 4. P4O10 + 5. AgNO3 + 6. Pb(NO3)2 7. Ag2O 8. Br2 + 9. C5H12O + 10. N2 + 11. AsCl3 + H2S 12. FeCl3 + (NH4)2S 13. Na2SO4 + 14. Cl2 + 15. PCl3 + 16. Mg3N2 + 17. SiCl4 + H2O HCl + 18. SbCl5 + H2O Sb2O5 + 19. Al4C3 + H2O Al(OH)3 + 20. KOH + SO2 21. C10H16 + 22. Al + 23. Al2(CO3)3 + 24. K2SO4 + 25. Cl2 + 26. Pb(NO3)2 + O2 CaCl2 + H2O SO3 H2SO4 Al2(SO4)3 + H2O H2 H3PO4 CaCl2 AgCl + Ca(NO3)2 PbO + NO2 + O2 Ag + O2 KI I2 + O2 O2 KBr CO2 + H2O N2O3 As2S3 + Fe2S3 + C H2O Na2S + HCl + H2O NH4Cl CO2 HOCl H3PO3 + H2O HCl Mg(OH)2 + HCl CH4 H2O HCl + H2SO4 NH3 SiO2 K2SO3 + Cl2 C Al2(SO4)3 + H2O BaCl2 NaBr HCl Al(OH)3 + BaSO4 + Br2 + NaBr H2O + CO2 KCl NaCl PbBr2 + NaNO3 SO2 Types of Chemical Reactions Purpose: To study four different types of chemical reactions Introduction: It is not easy to classify all chemical reactions precisely. Nevertheless, most reactions can be classified into one of four major categories. Synthesis Reactions – are reactions in which atoms and molecules join together directly to produce larger molecules. An example of a synthesis reaction is the combustion of sulphur to form sulphur dioxide: S(s) + O2 (g) SO2 (g) Decomposition Reactions – are reactions that are just the opposite of synthesis reactions. One larger molecule is broken up into several smaller elements or molecules. An example is the decomposition of carbonic acid: H2CO3 (aq) H2O (g) + CO2 (g) Single Displacement Reactions – are reactions that involve a change of partners between an element and a molecule. An example is the liberation of bromine from calcium bromide by reacting it with chlorine: CaBr2 (aq) + Cl2 (g) CaCl2 (aq) + Br2 (g) Double Displacement Reactions – are reactions that involve the joint exchange of partners between two molecules. An example of this is the precipitation of silver chloride when solutions of silver nitrate and sodium chloride are mixed. AgNO3 (aq) + NaCl (aq) AgCl (s) + NaNO3 (aq) In this experiment, you will study six different chemical reactions. You will identify some of the products, and then classify each reaction as one of the four types. Assign each member in your group the task of preparing a particular reaction and then take the time to observe each reaction within the group. Materials: Bunsen burner, crucible tongs, 5 test tubes, medicine dropper, spatula, retort stand, test tube clamp, 10 mL graduated cylinder, test tube rack, wood splints, sodium sulphate solution, strontium chloride solution, mossy zinc pieces, hydrochloric acid, manganese dioxide, aluminum pieces, copper (II) chloride solution, copper wire, hydrogen peroxide, copper (II) sulphate pentahydrate Procedure: Lab A Place a piece of aluminum in a test tube and cover it with a solution of copper (II) chloride. After about 30 minutes, remove the aluminum and examine it. 1. Do you observe any change in the appearance of the aluminum? 2. If so, what is the charge? 3. Do you observe any change in the appearance of the copper (II) chloride solution? 4. If so, what is the change? Lab B Place 5 mL of sodium sulphate solution in a test tube. Add a medicine dropper full of strontium chloride. Make observations and then leave the test tube aside for 20-30 minutes? 5. What do you observe right away? after 20-30 minutes? 6. If one of the products is sodium chloride (which is soluble in water), what is the other product? Lab C Using crucible tongs, hold a 5 cm piece of copper wire in a burner flame. Remove the wire and examine it. Dip it in strong hydrochloric acid that your teacher has to clean the wire and then return it to the place you got it. 7. What do you observe? 8. With what did the copper combine? Lab D Place a small piece of mossy zinc in a test tube. Add 5 mL of dilute hydrochloric acid. Hold your thumb over the mouth of the test tube. 9. What do you observe? Insert a BURNING splint into the mouth of the test tube. 10. What do you observe? Lab E Place 3 mL of hydrogen peroxide in a test tube. Add a pinch of manganese dioxide using a spatula. Hold your thumb over the mouth of the test tube. 11. What do you observe? Insert a GLOWING splint into the mouth of the test tube. 12. What do you observe? Water is one of the products of this reaction. 13. What is the other product of this reaction. 14. The manganese dioxide used in this experiment is a CATALYST. What is a catalyst? Is the catalyst a reactant in the reaction? Lab F Place about 5-6 crystals of copper (II) sulphate pentahydrate in a clean, dry, heatable test tube. Clamp the test tube to a retort stand and heat until no further changes occur. 15. What do you observe in the upper part of the test tube? 16. What do you observe in the lower part of the test tube? 17. What is the substance remaining in the test tube after heating? Allow the test tube to cool and add 3 drops of water. 18. What do you observe? Concluding Questions 1. Write word equations to describe the chemical reactions in each of the labs. 2. What TYPE of chemical reaction is illustrated in each of these reactions? 3. Write balanced chemical equations for each of the six reactions. Balancing Equations Again? Balance each skeletal equation provided. Identify each reaction as synthesis or decomposition. H2O (l) 1. CaO(s) + Ca(OH)2 (aq) 2. FeCl3 (s) 3. P2O5 (s) + 4. NH4NO3 (s) H2O (l) + N2O(g) 5. NaHCO3 (s) H2O (l) + CO2 (g) + 6. NO(g) + 7. Ag2CO3 (s) Ag2O (s) + CO2 (g) 8. Ca(OH)2 (s) H2O (l) + Ca (s) + 9. CaCO3 (s) CaO (s) + CO2 (g) synthesis or decomposition? 10. PbCO3 (s) PbO (s) + CO2 (g) synthesis or decomposition? 11. Be Cl2 (s) + O2 (g) Be(ClO3)2 (s) synthesis or decomposition? 12. CuO (s) O2 (g) + Cu (s) synthesis or decomposition? 13. Mg (s) + Cl2 (g) MgCl2 (s) synthesis or decomposition? Fe (s) + H2O (l) O2 (g) synthesis or decomposition? Cl2 (g) synthesis or decomposition? H3PO4 (aq) synthesis or decomposition? synthesis or decomposition? Na2CO3 (s) synthesis or decomposition? NO2 (g) synthesis or decomposition? synthesis or decomposition? O2 (g) synthesis or decomposition? Writing Displacement Reactions Complete each equation by writing the correct products. State whether the reaction is a single or double displacement reaction. 1. CaO (s) + Mg (s) single or double displacement 2. NaOH (aq) + HCl (aq) single or double displacement 3. LiCl (aq) + Na (s) single or double displacement 4. H2O (l) + Mg (s) single or double displacement 5. KOH (aq) + HBr (aq) single or double displacement 6. LiOH (aq) + HF (aq) single or double displacement 7. Ag2SO4 (s) + Cu (s) single or double displacement? Writing and Balancing Chemical Equations 1. solid aluminum + oxygen gas solid aluminum oxide 2. solid iron + solid sulphur solid iron (III) sulphide 3. solid calcium oxide + water aqueous calcium hydroxide 4. liquid hydrogen nitrate water vapour + nitrogen dioxide gas + oxygen gas 5. aqueous copper (II) nitrate + aqueous potassium hydroxide aqueous copper (II) hydroxide + aqueous potassium nitrate 6. aqueous hydrogen chloride + aqueous sodium sulphate aqueous sodium chloride + water + sulphur trioxide gas 7. aqueous sodium hydroxide + aqueous ammonium sulphate aqueous ammonium hydroxide + aqueous sodium sulphate 8. solid cobalt + aqueous lead (IV) chlorate aqueous cobalt (II) chlorate + solid lead 9. aqueous iron (III) bromide + aqueous magnesium carbonate aqueous magnesium bromide + aqueous iron (III) carbonate 10. solid tin (IV) hydroxide solid tin (IV) oxide + water vapour 11. solid sodium + water hydrogen gas + aqueous sodium hydroxide 12. aqueous aluminum phosphate + aqueous ammonium carbonate aqueous aluminum carbonate + aqueous ammonium phosphate