Regulation for Classification of Water The Official Gazette of the Republic of Macedonia No. 18-99 Based on Article 85 paragraph 4 of the Law on waters / " Official Gazette of Republic of Macedonia " No 4/98 / and Article 46 paragraph 3 of the “ Low on the Government of the Republic of Macedonia” / " Official Gazette of Socialistic Republic of Macedonia " No 38/90 and " Official Gazette of Republic of Macedonia " No 63/94 and 63/98 / the Government of the Republic of Macedonia on the session held 23.03.199 brought REGULATION FOR CLASSIFICATION OF WATER Article 1 With this Regulation the classification is made of the surface waters / water courses, natural and artificial lakes / and of groundwater. This Regulation shall not apply to mineral and thermal waters. Article 2 According to the use and the water purity the Water referred to in Article 1, paragraph 1 of this Regulation are delineated in 5 classes, namely: Class1 This is very clean, oligotrophic water, which in its natural state which can, with possible disinfecting, can be used for drinking and production and processing of food product and is suitable for mating and cultivation of noble types of fish – salmonides. The buffering capacity of the water is very good. It is constantly saturated with oxygen, with low content of nutrients and bacteria, contains very slight, occasional antropogenic pollution with organic matters / but not with inorganic matters /; Class 2 This is a very clean, mesotrophic water, which in its natural state can be used for bathing and recreation, water sports, production of other types of fish / ciprinides /, or which can be used – after usual methods of purification / coagulation, filtration, disinfection etc./–for drinking and production and processing of food products. The buffering capacity and oxygen saturation is present throughout the yea., are good.The loadings may lead to slightly increased primary productivity; Class 3 That is moderately euthrophic water, which in its natural state can be used for irrigation, and after usual purification methods (conditioning) for industries which do not need drinking water quality. Buffering capacity of the water is low, bat it maintains the / pH value / acidity at a level still suitable for most fish. In hypolimnion occasionally oxygen deficit occurs. The level of primary production is considerable, and some changes in community structure, including fish species can be observed. The load of harmful substances is evident as well as microbial pollution. The concentration of the harmful substances varies from natural levels to levels of chronic toxicity for aquatic life; Class 4 This is strongly euthrophic, polluted water, which in its natural state can be used for other purposes only after certain processing. The buffering capacity is exceeded, which leads to higher levels of acidity, and which affects the development of the offspring. In the epilimnion there is oxygen saturation, and in hypolimnion there is oxygen deficit. Algal blooms are common. Increased decomposition of organic matter at the same time with the stratification of the water can cause anaerobic conditions and fish death. Mass occurrences of more tolerant species, fish population and benthic organisms can be affected. Microbiologic pollution does not allow the water to be used for recreation, at Harmful substances emitted or released from the sediment / deposits /, can affect the quality of the aquatic life. The concentration of harmful substances can very from level of chronic to acute toxicity to aquatic life; Class 5 This is a very polluted, hiperthrophic water. , which in its natural state can be used for other purposes . The water has no buffer capacity and its acidity / pH value / is harmful for many fish species.Large problems occur with the oxygen regime, namely saturation in hipolimnion absence of oxygen, leading to anaerobic conditions in hipolimnion. Decomposers dominate over producers. Fish and bentosic species are constantly not present. Concentration of harmful substances exceeds acutetoxicity levels for aquatic life. Article 3 Page 1 of 9 Regulation for Classification of Water The Official Gazette of the Republic of Macedonia No. 18-99 The indicators for the classification of water into classes according to article 2 of this Regulation are: A. B. C. Organoleptic Indicators: Indicator of Acidity: Oxygen Regime indicators : D. E. Mineralization Indicators: Eutrofication indicators: F. G. Microbiological Indicators: Radioactivity : H. Harmful and Dangerous Matters: visible waste, visible color and color, notable smell, turbidity and transparency pH value and alcality dissolved oxygen, oxygen saturation, biochemical oxygen demand for 5 days at 20 oC / BOD5 /, chemical oxygen demand from potassium permanganate, total organic carbon suspended matters, total dry residue after filtration / total dissolved solids / total phosphorus, total nitrogen, chlorophyll “a“ , primary production, saprobic index,level of biological productivity most probable number thermo-tolerant coliforms bacteria total activity of heavy radioactive waste materials which can be released into the surface water - water course during one year, shall be calculated by a separate formula metals and their compounds, other inorganic parameters, phenols , hydrocarbons, halogenated hydrocarbons , nitrated hydrocarbons , pesticides, other organic compounds Article 4 Upper values of indicators from Article 3 of this Regulation are set as follows: Table I: Upper values / maximum permited values or concentrations / of Organoleptic Indicators: Indicators: Upper values and concentrations per class Class I Class II Class III Class IV Class V A. Organoleptic Indicators: 1. Visible waste 2. Visible color None None None None None turbidity - 3. Notable smell None None 4. Color 5. Turbidity NTU 6. Transparency Secci 1 m < 15 < 0.5 >7 15-25 0.5-1.0 7.0-4.0 None Little turbidity Hardly notable 26-40 1.1-3.0 3.9-2.0 notable >40 > 3.0 < 2.0 > 40 > 3.0 < 2.0 Table II: Upper values / maximum permited values or concentrations / of Indicators of Acidity: Indicators: Upper values and concentrations per class Class I Class II Class III Class IV Class V 6,5-8,5 > 200 6,5-6,3 200-100 6,3-6,0 100-20 6,0-5,3 20-10 < 5,3 < 10 B Indicators of Acidity: 1. pH value 2. Alcality mg/l CaCO3 Table III: Upper values / maximum permited values or concentrations / of Oxygen Regime Indicators: Indicators: C. Oxygen Regime Indicators : 1. Dissolved oxygen mg/l O2 2. Oxygen saturation epilimnion % O2 2 Upper values and concentrations per class Class I Class II Class III Class IV Class V > 8,00 7,99 – 6,00 5,99 – 4,00 3,99 – 2,00 < 3,00 90 - 105 75 – 90 105 - 115 50 – 75 115 - 125 30 – 50 125 – 150 < 30 > 150 1 Given values refer only on lakes and reservoirs 2 Given values refer only on lakes and reservoirs Page 2 of 9 Regulation for Classification of Water The Official Gazette of the Republic of Macedonia No. 18-99 hipolimnion % O2 2 Total % O2 3. Biochemical oxygen demand for 5 days at 20 oC / BOD5 / mg/l O2 4. Chemical oxygen demand – permanganate mg/l O2 5. Total organic carbon mg/l C 75 - 90 75 - 90 50 - 75 50 – 75 105 - 115 30 - 50 50 – 30 115 - 125 30 - 10 30 – 10 125 – 150 < 10 < 10 > 150 < 2,00 2,01 – 4,00 4,01 – 7,00 7,01 – 15,0 > 15,0 < 2,50 < 2,50 2,51 – 5,00 2,51 – 4,20 5,01 – 10,0 4.21 – 6.70 10,0 – 20,0 6.71-10.0 > 20,0 > 10,0 Table IV: Upper values / maximum permited values or concentrations / of Mineralization Indicators : Indicators: D. Mineralization Indicators : 1. Suspended matter mg/l 2. Total dry residue after filtration / total dissolved solids –TDS / mg/l: Surface water Groundwater – karstic Groundwater – not karstic Upper values and concentrations per class Class I Class II Class III Class IV Class V < 10 10 - 30 30 - 60 60 - 100 > 100 350 350 800 500 500 1000 1000 1000 1500 1500 1500 1500 > 1500 > 1500 > 1500 Table V: Upper values / maximum permited values or concentrations / of Eutrofication Indicators : Indicators: E. Eutrofication Indicators : 1. Total phosphorus P mg/l 2. Total nitrogen N g/l 3. chlorophyll “a“ g/l 4.Primary production 4gC/m2/a 5. Saprobic 6. Saprobic Index – Puntel Buck 5. Level of biological productivity Upper values and concentrations per class Class I Class II Class III Class IV Class V <10 / < 15 / 3 < 200 / < 200 / 10 – 25 / 15 – 40 / 200 - 325 / 200–325 / 25 – 50 / 40 – 70 / 326 - 450 / 326-450 / 50 – 125 / 75 – 190 / > 450 / > 450 / > 125 / > 190 / > 450 / > 450 / < 2,0 / < 2,0 / 2,01–3.79 / 2.01-3.79/ 3.79–7.50 /3.79-7.50/ 7.51-10.0 / 7.51-10.0/ > 10.0 / > 10.0 / < 25 Oligosaprobic 51-90 Meso saprobic 2.51-3.50 > 90 -Meso saprobicpolisabrobic 3.51-4.50 > 90 Polisaprobic < 1,50 26-50 Meso saprobic 1.50-2.50 Oligotrophic Mesotrophic Moderate eutrophic Eutrophic Hypertrophic > 4.51 Table VI: Upper values / maximum permited values or concentrations / of Microbiological Pollution Indicators : Indicators: F. Eutrofication Indicators : 1.Most probable number of termotolerant coliform bacteria No/100 ml Upper values and concentrations per class Class I Class II Class III Class IV Class V 5 5 – 50 50 – 500 > 500 > 500 Table VII: Upper values / maximum permited values or concentrations / of Radiological Indicators : Indicators: G. Radiological Indicators : 1. Level of radioactivity Upper values and concentrations per class Class I Class II Class III Class IV Class V Total activity of heavy radioactive waste materials which can be released into the surface water - water course during one year, shall be calculated by a following formula: F/O ( Ai/MDKi ) 3 Given values on brackets refer only on lakes and reservoirs Given values refer only on lakes and reservoirs a/ Mean value of investigation in summer period 4 Page 3 of 9 Regulation for Classification of Water The Official Gazette of the Republic of Macedonia No. 18-99 where: Ai - total activity of i-th nucleid releised into water course during one year in Bq. MDKi – maximum allowed concentration of i-th radio nucleid in drinking water for ion radiation Bq/m3 O – average yearly discharge of the river in m3/s F – safety factor and reserve, a number depending on radioecological and hydrodynamical conditions of the river, of the river water use, the number and position of the inflow of radfioation within the catchment and other information, calculated in a way to provide protection of ionic radiation. Table VIII:Upper values / maximum permited values or concentrations / of Harmful and Dangerous Matters : HARMFUL AND DANGEROUS MATTER - NAME I. Metals and its Compounds 01. Aluminium 02. Antimony 03. Arsenic 04. Copper 05. Barium 06. Beryllium 07. Bismuth 08. Zink 09. Cadmium 10. Cobalt 11. Selenium - inorganic 12. Chromium – total Chromium – six-valent 13. Manganese 14. Molybdenum 15. Nickel 16. Lead 17. Palladium 18. Silver 19. Thallium 20. Titanium 21. Vanadium 22. Iron 23. Mercury – total Total organic-Mercury compounds. II. Other Inorganic Parameters: 24. Ammonia Num 25. Asbestos 26. Boron 27. Cyanides 28. Fluoride 29. Phosphorus - elementary 30. Chlorine 31. Nitrate 32. Nitrite 33. Selenium 34. Sulfides –total III. Phenols 35. Phenol Upper values and concentrations Unit Class I-II Class III-IV Class IV g/l Al g/l Sb g/l As g/l Cu g/l Ba g/l Be g/l Bi g/l Zn g/l Cd g/l Co g/l Sn g/l Cr g/l Cr6+ g/l Mn g/l Mo g/l Ni g/l Pb g/l Pd g/l Ag g/l Ta g/l Ti g/l V g/l Fe g/l Hg g/l Hg 1500 30 30 10 1000 0.2 50 100 0.1 100 100 50 10 50 500 50 10 2 2 3 100 100 300 0.2 0.02 1500 50 50 50 4000 1 50 200 10 2000 500 100 50 1000 500 100 30 20 20 30 100 200 1000 1 0.1 > 1500 > 50 > 50 > 50 > 4000 >1 > 50 > 200 > 10 > 2000 > 500 > 100 > 50 > 1000 > 500 > 100 > 30 > 20 > 20 > 30 > 100 > 200 > 1000 >1 >0.1 g/l NH3 g/l NH4 g/l g/l B g/l CNg/l Fg/l P g/l Cl2 g/l N g/l N g/l Se g/l S-2 20 1000 200 1 300 0.01 2 10000 10 10 2 g/l 1 Page 4 of 9 500 > 500 10000 >10000 May not be present 750 > 750 100 > 100 1500 > 1500 0.1 > 0.1 10 > 10 15000 > 15000 500 > 500 10 > 10 50 > 50 50 > 50 Regulation for Classification of Water The Official Gazette of the Republic of Macedonia No. 18-99 36. Cresol / o-, m-, p- / 37. Nonylphenol 38. 2-chlorophenol 39. 2, 4-dichlorophenol 40. 2, 4, 5-trichlorophenol 41. Pentachlorophenol 42. o-nitrophenol 43. m-nitrophenol 44. p-nitrophenol 45. 2, 4-dinitrophenol 46. Picric acid 47. 4, 6-dinitro-o-cresol 48. Aminophenol / o-, m-, p- / IV. Hydrocarbons: 49. Oil 50. Benzene 51. Toluene 52. Xylene / o-, m-, p- / 53. Ethylbenzene 54. Styrene 55. Mesitylene 56. Diisopropyl benzene 57. Naphthalene , methyl naphthalene 58. Fluorene 59. Phenanthrene 60. Anthracene 61. Acenaphthene 62. Fluoranthene 63. Polynuclear aromatic hydrocarbons /higher homologous/-cancerogenous 64. Ethylene 65. Propilene 66. Isobutylene 67. 1-butene 68. Isoprene 69. Cyclohexane 70. Cyclohexene 71. Biphenyl propane V. Halogenated Hydrocarbons : 72. Methylchloride 73. Methylbromide 74. Dichloromethane 75. Bromodichlormethane 76. Bromoform 77. Chloroform 78. Tetrachlorcarbon 79. 1,2-dichloroethane 80. 1,1.2-trichloroethane 81. 1,1,1-trichloroethane 82. 1,1,2,2-tetrachloroethane 83. Hexachloroethane 84. Vinyl chloride 85. Dichloroethylene 86. Trichloroethylene 87. Tetrachloroethylene 88. Monochlorobenzene 89. Dichlorobenzene 90. Trichlorobenzene 5 Values given in brackets refer to water Class IV Page 5 of 9 g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l 2 1 0.1 0.3 1 1 1 10 10 30 10 10 10 20 10 10 5 10 10 50 50 50 50 50 50 50 > 20 > 10 > 10 >5 > 10 > 10 > 50 > 50 > 50 > 50 > 50 > 50 > 50 g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l 10 1,5 50 50 50 20 5 50 1 5 5 5 5 5 50 / 100 / 5 10 / 50 / 100 / 500 / 100 / 500 / 100 / 500 / 100 / 500 / 100 / 500 / 100 / 500 / 10 / 100 / 50 50 50 50 50 > 100 > 50 > 500 > 500 > 500 > 500 > 500 > 500 > 100 > 50 > 50 > 50 > 50 > 50 g/l 0.01 0.04 > 0.04 g/l g/l g/l g/l g/l g/l g/l g/l 50 50 50 20 5 20 20 10 100 / 500 / 100 / 500 / 100 / 500 / 100 / 500 / 100 / 500 / 100 / 500 / 100 / 500 / 100 / 500 / > 500 > 500 > 500 > 500 > 500 > 500 > 500 > 500 g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l 2 2 2 2 2 2 2 7 3 25 2 6 5 1,5 20 2 20 2 10 20 20 20 20 20 20 20 100 50 100 15 10 50 25 75 4 100 20 20 > 20 > 20 > 20 > 20 > 20 > 20 > 20 > 100 > 50 > 100 > 15 > 10 > 50 > 25 > 75 >4 > 100 > 20 > 20 Regulation for Classification of Water The Official Gazette of the Republic of Macedonia No. 18-99 Pentachlorobenzene Hexachlorobenzene Trichloronaphthalene Tetrachloronaphthalene Pentachloronaphthalene Hexachloronaphthalene Dekachloronaphthalene Dichloropropane Dichloropropene 1.3-dichlorobutane Dichlorocyclohexane Tetrachloropropane Tetrachloropenthane Tetrachloroheptanee Tetrachlorononane Tetrachlorodekane Pentachloroheptane Hexsachlorobutadiene Heksachlorociklobutadiene Heksachlorobutane 2, 3, 7, 8-tetrachlorodibenzo-pdioksin / TKDD / VI. Nitrated Hydrocarbons : 112. Nitrobenzene 113. Dinitrobenzene 114. 2, 4-dinitrochlorobenzene 115. Nitrotoluen / o-, m-, p- / 116. Nitrochlorobenzene 117. Dinitrotoluene 118. 2, 4, 6-trinitrotoluene 119. Dinitronaphthalene 120. Nitromethane 121. Nitropropane 122. Nitroethane 123. Nitrobutane 124. Nitroform 125. Tetranitrometane 126. Nitrocyclohexsane 127. N-nitrosodimethylamine 128. N-nitrosodiethylamine 129. N-nitrosodibutilamine g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l 0.5 1 4 1,5 0,4 0,15 0,1 50 1 20 20 10 5 3 3 7 20 1 1 10 5 1 4 1,5 0,4 0,15 0,1 200 20 50 50 50 50 30 30 50 100 10 10 100 >5 >1 >4 > 1,5 > 0,4 > 0,15 > 0,1 > 200 > 20 > 50 > 50 > 50 > 50 > 30 > 30 > 50 > 100 > 10 > 10 > 100 g/l 4,5 10-7 4,5 10-7 4,5 10-7 g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l 20 10 10 10 20 1 20 1 5 5 5 5 10 20 20 0.03 0.01 0.015 50 50 50 50 50 10 50 10 50 50 50 50 50 50 50 0.034 0.01 0.015 > 50 > 50 > 50 > 50 > 50 > 10 > 50 > 10 > 50 > 50 > 50 > 50 > 50 > 50 > 50 0.03 0.01 0.015 130. 131. 132. g/l g/l g/l 0.1 2,0 10-3 2,0 10-2 0.1 1 10-2 2,0 10-2 0.1 1 10-2 2,0 10-2 g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l 0,003 0,003 0.001 0,004 0,01 0,03 0.001 0.005 0.001 0,01 0,2 0,003 0.001 0.04 0,1 0,3 0.01 0.05 0.001 0,1 > 0,2 0,003 0.001 > 0.04 > 0,1 > 0,3 0.01 0.05 0.001 0,1 g/l g/l g/l g/l 0,01 0,1 0,1 0,04 0,1 1 1 0,4 0,1 1 1 0,4 91. 92. 93. 94. 95. 96. 97. 98. 99. 100. 101. 102. 103. 104. 105. 106. 107. 108. 109. 110. 111. N-nitrosopirolidine Benzidine 3,3-dihlorbenzidine VII. Pesticides 133. Aldrin 134. Dieldrin and metabolites 135. DDT 136. Endrin 137. Lindane 138. Methoxychlor-DDT 139. Polihlorinated biphenyl PCBs 140. Toxsaphene / kamphechlor / 141. Heptachlor 142. Chlordane 143. Common kriterium for otherOrganic chlornated pesticides 144. Karbophos / Malathion / 145. Merkaptophos / Demeton / 146. Tiophos / Parathion / Page 6 of 9 Regulation for Classification of Water The Official Gazette of the Republic of Macedonia No. 18-99 147. VIII. 148. 149. 150. 151. 152. 153. 154. 155. 156. 157. 158. 159. 160. 161. 162. 163. 164. 165. 166. 167. 168. 169. 170. 171. 172. 173. 174. 175. 176. 177. 178. 179. 180. 181. 182. 183. 184. 185. 186. 187. 188. 189. 190. 191. 192. 193. 194. 195. 196. 197. 198. 199. 6 Common kriterium for otherOrganic Phosphorus and carbamic pesticides Other Organic Compounds : Acetone Acetone cyanohydrin Acrolein Acrylonitril Anion detergents Kation detergents Non-ionic detergents Surface active materials Amini / C7 – C9 / Amini / C10 – C16 / Amini / C17 – C20 / Benzoic acid Buten-1 Butanol Butyl acrilat Butyric acid / BOD5 / Butyl xantate n-Butylmercaptan Hydrogen sulphide Dimethyl sulphide Diisopropyl amine Cyclohexanol Cyclohexanone Cyclohexanonoksim Diphenylhidrazine Ethylacrilat Ethylamine Ehylenglicol Formaldehyde Phtalic ester Heptanol Isophorone Isobutanol Ethyl-merkuric chlorid Kaprolactam Potassiumdiethylditio-phosphate Potassiumisopropyl-ditio-phosphate Maleic anhydride Mercaptoethyldiethyl-amin Methyldithiocarbamat Na-sol Methanol Methylacrilat Methylbenzoat Maslena acid Milk acid Mravja acid Nonil alcohol Oktil alcohol Sintetic masni acid C5-C20 Tannin Terpentin Tetraethylselenium Tetraethyllead Tributilphosphate g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l mg/l g/l g/l g/l mg/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l g/l the value in the brackets refers to class II Page 7 of 9 0,1 1 1 100 2000 2000 1 1 1 2 10 10 0,1 200 200 100 500 > 500 50 100 > 100 100 500 > 500 1000 /30006/ 5000 > 5000 100 100 > 100 40 500 500 30 50 50 BOD5 not more than allowed concentration for certain water class 100 10000 10000 1000 5000 5000 15 1000 1000 5 10 10 1 6 3 3 3 3 300 300 500 50 500 500 500 500 20 20 20 1000 1000 1000 0,4 20 20 5 50 > 50 300 500 500 1000 1000 1000 300 500 500 3 30 30 5 5 5 6 60 60 1000 5000 5000 0,1 0,1 0,1 500 1000 1000 200 2000 2000 20 1000 1000 1000 1000 1000 100 1000 1000 20 500 500 100 500 500 20 200 200 1 100 100 500 1000 1000 500 2000 2000 1000 4000 > 4000 10 10 > 10 50 500 500 1000 5000 5000 500 10000 > 10000 200 5000 > 5000 0,2 20 20 0,1 0,1 10 100 100 Regulation for Classification of Water The Official Gazette of the Republic of Macedonia No. 18-99 200. 201. Carbondisulfide Dimethylformamide 202. Methyllethyl ceton g/l mg/l mg/l 203. Propilen glicol mg/l 204. Triethylen glicol mg/l 3 3 >3 BOD5 not more than allowed concentration for certain water class BOD5 not more than allowed concentration for certain water class BOD5 not more than allowed concentration for certain water class BOD5 not more than allowed concentration for certain water class Article 5 The values of indicators from Article 4 of this Regulation shall be applied upon: 1. 2. 3. 4. For water courses without regulated flow: for all discharges equal or larger than the monthlly loe flow with 95 % probability; For water courses with regulated flow: for all discharges larger than the guaranteed low flow; groundwateri: for all discharges and water levels; lakes: for unfavourable cases of mixing of waters / during periods of ice and during critical summer months /. Article 6 As exemptions from Arcicle 4 of this Regulation, certai indicators shall not be used for classification of: 1. 2. 3. water courses -indicators under number 16 / level of biological productivity /; groundwater flows in karst - indicators under number 16 / level of biological productivity /, and for other types of groundwater indicators under number 6 / dissolves oxygen /, under number 15 / level of saprobity/ and indicators under number 16 / level of biological productivity /; natural lakes - indicators under number 6 / dissolves oxygen /, under number 15 / level of saprobity / and for second class of natural lakes the indicators under number 2 / visible color /. In the classification of carstic springs, if the turbidity ids from natural cause, the indicators from Article 4 of theis Regulation under number 10 / suspended matter/ may be exceeded, but the turbidity should not be present in more than 30 days in one year. Article 7 In the calculation of the toxicity of larger number of dangerous and harmful matter the allowed concentrations has to comply with the following formula: Ca La Cb Lb ....... Cn Ln 1 Where: Ca, Cb, ….. Cn are the measured concentrations of harmful and dangerous substances in the water, , La, Lb, ….. Ln are the maximum allowed concentrations / MAC / , for each of those substances individually. Article 8 Concentrations of harmful and dangerous substances are determined: Page 8 of 9 Regulation for Classification of Water The Official Gazette of the Republic of Macedonia No. 18-99 for concentrated use of water – at the boundary of the first zone of sanitary protection, or nat the place of water intake; for other concentrated use of water, in the zone of 95 % mixing. Article 9 With the day of coming into force of this Regulation the use of "Regulation for the maximum allowed concentrations of radio-nucleids and dangerous substances in the international water courses, inter-republical waters and coast sea waters of Yugoslavia" / Official gazette of SFRJ number 8/78 /. Article 10 This Regulation shall come into force eight days from the day it it published in the "Official Gazette of Republic of Macedonia". Number 23-1665/1 23.03.1999 Skopje PRESIDENT OF THE GOVERNMENT OF REPUBLIC OF MACEDONIA Ljubcho Georgievski, s.r. Page 9 of 9