Sample Questions – Chapter 7 CP Chemistry 1. Calculate the percent composition of iron (II) nitrate. Fe(NO3)2 Fe: 1 x 55.85 = 55.85 g N: 2 x 14.01 = 28.02 g O: 6 x 16.00 = 96.00 g % Fe = 55.85/179.87 *100 = 31.05% % N = 28.02/179.87*100 = 15.58% % O = 96/179.87*100 = 53.37% Molar mass = 179.87 g/mol 2. A compound’s empirical formula is NO2. If the formula mass is 138 g/mol, what is the molecular formula? NO2 – molar mass = (14.01) + (2*16.00) = 46.01 g/mol 138 g/mol ÷ 46.01 g/mol = 3, so molecular formula is N3O6 3. You have 9.45 g of the compound dinitrogen pentoxide. How many molecules are contained in this mass? 9.45 g ÷ 108.02 g/mol = 0.0874837 mol * 6.02E23 = 5.27 * 1022 molecules N2O5 4. If you have 3.5 x 1024 formula units of CaI2, how many moles of the compound do you have? 3.5 * 1024 formula units ÷ 6.02E23 = 5.8 moles 5. Find the empirical formula of a compound that is 41.67% magnesium, 54.87% oxygen, and 3.46% hydrogen? 41.67/24.31 = 1.714 mol Mg 54.87/16.00 = 3.429 mol O 3.46/1.01 = 3.425 mol H 1.714/1.714 = 1 3.429/1.714 = 2 3.425/1.714 = 2 MgO2H2 6. What is the molar mass (in grams) of Li3PO4? Li: 3 * 6.94 = 20.82 P: 1 * 30.97 = 30.97 O: 4 * 16.00 = 64.00 Molar mass = 115.79 g/mol 7. Phosgene, a gas used in World War I, consists of 12.41% C, 16.17% O, and 71.69% Cl. a. What is the empirical formula for phosgene? 12.41/12.01 = 1.033 mol C 16.17/16.00 = 1.01 mol O 71.69/35.45 = 2.022 mol Cl 1.033/1.01 = 1 1.01/1.01 = 1 2.022/1.01 = 2 COCl2 b. If the molar mass is 99 g/mol, then what is the molecular formula? Molar mass of COCl2 = (12.01) + (16.00) + (2*35.45) = 98.91 g/mol 99 g/mol ÷ 98.91 g/mol = 1 Molecular formula = COCl2 8. Calculate the percent composition of each element in AgNO3. Ag: 1 * 107.87 = 107.87 N: 1 * 14.01 = 14.01 O: 3 * 16.00 = 48.00 % Ag = 107.87/169.88 * 100 = 63.49 % % N = 14.01/169.88 * 100 = 8.25 % % O = 48.00/169.88 * 100 = 28.25 % Molar mass = 169.88 g/mol 9. Based on your answer in # 8, how many grams of silver are in a sample of AgNO3 that has a mass of 34.75 g? 34.75 g * 0.6349 = 22.06 g 10. How many moles are in 364 g of thallium? How many atoms? 364 g Tl/204.4 = 1.78 mol Tl 1.78 mol Tl * 6.02E23 = 1.07 x 1024 atoms Tl