Thermodynamics I Gas Power Cycles Dr.-Eng. Zayed Al-Hamamre 1 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Content Internal Combustion Engines o Otto Cycle o Diesel Cycle o Dual Cycle Gas Turbine Cycles o Brayton Cycle o Regenerative Gas Turbines o Regenerative Gas Turbines with Reheat and Intercooling o Gas Turbines for Aircraft Propulsion o Ericsson and Stirling Cycles Compressible flow through Nozzles and Diffusers Combined Gas-Vapor Cycles 2 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Introduction Many work-producing devices (engines) utilize a working fluid that is always a gas. The spark-ignition automotive engine is a familiar example, as are the diesel engine and the conventional gas turbine. In all these engines there is a change in the composition of the working fluid, because during combustion it changes from air and fuel to combustion products. These engines are called internal combustion engines Because the working fluid does not go through a complete thermodynamic cycle in the engine (even though the engine operates in a mechanical cycle), the internal combustion engine operates on the so-called open cycle. For analyzing internal-combustion engines, the air-standard cycle approach is assumed. 3 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Air Standard Assumption 1. A fixed mass of air is the working fluid throughout the entire cycle, and the air is always an ideal gas. The combustion process is replaced by a process transferring heat (heat-addition process) from an external source. 2. All the processes that make up the cycle are internally reversible. 3. The exhaust process is replaced by a heat-rejection process that restores the working fluid to its initial state, i.e. the cycle is completed by heat transfer to the surroundings (in contrast to the exhaust and intake process of an actual engine). 4. An additional assumption is often made that air has a constant specific heat, recognizing that this is not the most accurate model. 4 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Reciprocating Engines The piston reciprocates in the cylinder between two fixed positions called the top dead center (TDC)—the position of the piston when it forms the smallest volume in the cylinder—and the bottom dead center (BDC)— the position of the piston when it forms the largest volume in the cylinder. Intake valve Exhaust valve The distance between the TDC and the BDC is the largest distance that the piston can travel in one direction, and it is called the stroke of the engine. The diameter of the piston is called the bore. The air or air–fuel mixture is drawn into the cylinder through the intake valve, and the combustion products are expelled from the cylinder through the exhaust valve. 5 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Reciprocating Engines The minimum volume formed in the cylinder when the piston is at TDC is called the clearance volume. The volume displaced by the piston as it moves between TDC and BDC is called the displacement volume The ratio of the maximum volume formed in the cylinder to the minimum (clearance) volume is called the compression ratio r of the engine Another term frequently used in conjunction with reciprocating engines is the mean effective pressure (MEP). It is a fictitious pressure that, if it acted on the piston during the entire power stroke, would produce the same amount of net work as that produced during the actual cycle 6 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Reciprocating Engines Reciprocating engines are classified , depending on how the combustion process in the cylinder is initiated, as i. Spark-ignition (SI) engines: the combustion of the air–fuel mixture is initiated by a spark plug The air–fuel mixture is compressed to a temperature that is below the autoignition temperature of the fuel, and the combustion process is initiated by firing a spark plug The Otto cycle is the ideal cycle for spark-ignition reciprocating engines. ii. Compression-ignition (CI) engines: the air–fuel mixture is self-ignited as a result of compressing the mixture above its self ignition temperature. The air is compressed to a temperature that is above the autoignition temperature of the fuel, and combustion starts on contact as the fuel is injected into this hot air The Diesel cycle is the ideal cycle for CI reciprocating Chemical Engineering Department | University of Jordan | Amman 11942, Jordan engines Tel. +962 6 535 5000 | 22888 7 Reciprocating Engines With the intake valve open, the piston makes an intake stroke to draw a fresh charge into the cylinder. With both valves closed, the piston undergoes a compression stroke, raising the temperature and pressure of the charge. A combustion process is then initiated, resulting in a high-pressure, high-temperature gas mixture. Intake valve Exhaust valve In compression-ignition engines, combustion is initiated by injecting fuel into the hot compressed air, beginning near the end of the compression stroke and continuing through the first part of the expansion. A power stroke follows the compression stroke, during which the gas mixture expands and work is done on the piston as it returns to bottom dead center. The piston then executes an exhaust stroke in which the burned gases are purged fromDepartment the cylinder through the | Amman 11942, Jordan Chemical Engineering | University of Jordan open exhaust Tel.valve. +962 6 535 5000 | 22888 8 Otto Engine 1. Initially, both the intake and the exhaust valves are closed, and the piston is at its lowest position (BDC). 2. During the compression stroke, the piston moves upward, compressing the air–fuel mixture. Shortly before the piston reaches its highest position (TDC), the spark plug fires and the mixture ignites, increasing the pressure and temperature of the system. 3. The high-pressure gases force the piston down, which in turn forces the crankshaft to rotate, producing a useful work output during the expansion or power stroke. At the end of this stroke, the piston is at its lowest position (the completion of the first mechanical cycle), and the cylinder is filled with combustion products. Now the piston moves upward one more time, purging the exhaust gases through the exhaust valve (the exhaust stroke), and down a second time, drawing in fresh air–fuel mixture through Chemical Engineering Department | University of Jordan | Amman 11942, Jordan intake the intake valve (the6 535 Tel. +962 5000stroke | 22888). 9 Otto Engine 10 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Otto Engine i. Process 1–2 is an isentropic compression of the air as the piston moves from bottom dead center to top dead center. ii. Process 2–3 is a constant-volume heat transfer to the air from an external source while the piston is at top dead center. This process is intended to represent the ignition of the fuel–air mixture and the subsequent rapid burning. iii. Process 3–4 is an isentropic expansion (power stroke). iv. Process 4–1 completes the cycle by a constant-volume process in which heat is rejected from the air while the piston is at bottom dead center. 11 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Otto Engine 12 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Otto Engine Substituting these equations into the thermal efficiency relation and simplifying, where 13 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Otto Engine Remember that for an adiabatic process For a given compression ratio, an ideal Otto cycle using a monatomic gas (such as argon or helium, k 1.667) as the working fluid will have the highest thermal efficiency. The specific heat ratio k, and thus the thermal efficiency of the ideal Otto cycle, decreases as the molecules of the working fluid get larger In gasoline engines, a mixture of air and fuel is compressed during the compression stroke, and the compression ratios are limited by the onset of autoignition or engine knock 14 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Example An ideal Otto cycle has a compression ratio of 8. At the beginning of the compression process, air is at 100 kPa and 17°C, and 800 kJ/kg of heat is transferred to air during the constant-volume heat-addition process. Accounting for the variation of specific heats of air with temperature, determine (a) the maximum temperature and pressure that occur during the cycle, (b) the net work output, (c) the thermal efficiency, and (d ) the mean effective pressure for the cycle. 15 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Example Cont. 16 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Example Cont. 17 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Example Cont. 18 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Diesel Cycle In diesel engines, only air is compressed during the compression stroke, eliminating the possibility of autoignition. Therefore, diesel engines can be designed to operate at much higher compression ratios, typically between 12 and 24. The fuel injection process in diesel engines starts when the piston approaches TDC and continues during the first part of the power stroke. Therefore, the combustion process in these engines takes place over a longer interval. Because of this longer duration, the combustion process in the ideal Diesel cycle is approximated as a constant-pressure heat-addition process. 19 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Diesel Cycle 2-3 constant-pressure heat-addition (includes work and heat) The Diesel cycle is executed in a piston–cylinder device, which forms a closed system, The amount of heat transferred to the working fluid at constant pressure and rejected from it at constant volume 20 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Diesel Cycle 2-3 constant-pressure heat-addition (involves work and heat) And Where cutoff ratio rc, is the ratio of the cylinder volumes after and before the combustion21 process: Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Diesel Cycle 22 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Diesel Cycle 23 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Diesel Cycle Utilizing this definition and the isentropic ideal-gas relations Comparing with Otto engine, As rc is the ratio approaching 1 = 24 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Diesel and Otto Cycle 25 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Example An ideal Diesel cycle with air as the working fluid has a compression ratio of 18 and a cutoff ratio of 2. At the beginning of the compression process, the working fluid is at 14.7 psia, 80°F, and 117 in3. Utilizing the cold-airstandard assumptions, determine (a) the temperature and pressure of air at the end of each process, (b) the net work output and the thermal efficiency, and (c) the mean effective pressure 26 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Example Cont. 27 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Example Cont. 28 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Example Cont. 29 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Example Cont. 30 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Dual Cycle 31 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Dual Cycle During the isentropic compression process 1–2 there is no heat transfer, and the work is 32 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Dual Cycle the constant-volume heat rejection process 5–1 that completes the cycle involves heat transfer but no work 33 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Striling and Ericsson Cycles Stirling cycle • 1-2 T = constant expansion (heat addition from the external source) • 2-3 v = constant regeneration (internal heat transfer from the working fluid to the regenerator) • 3-4 T = constant compression (heat rejection to the external sink) • 4-1 v = constant regeneration (internal heat transfer from the regenerator back to the working fluid) Both cycles are totally reversible, 34 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Striling and Ericsson Cycles The Stirling and Ericsson cycles give a message: Regeneration can increase efficiency. The Ericsson cycle is very much like the Stirling cycle, except that the two constant-volume processes are replaced by two constant-pressure processes. A steady-flow Ericsson engine. The execution of the Stirling cycle. 35 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan 35 Tel. +962 6 535 5000 | 22888 Example Using an ideal gas as the working fluid, show that the thermal efficiency of an Ericsson cycle is identical to the efficiency of a Carnot cycle operating between the same temperature limits. For a reversible isothermal process, heat transfer is The entropy change of an ideal gas during an isothermal process 36 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Brayton Cycle for Modeling Gas Turbine Power Plants Brayton Cycle is the ideal cycle for modeling gas turbine power plants. It is used for gas turbines only where both the compression and expansion processes take place in rotating machinery Constant-pressure heat-addition Constant-pressure heat-removal 37 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Brayton Cycle for Modeling Gas Turbine Power Plants 38 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Brayton Cycle for Modeling Gas Turbine Power Plants Assuming the turbine operates adiabatically and with negligible effects of kinetic and potential energy, the work developed per unit of mass is compressor work per unit of mass is The heat added to the cycle per unit of mass is 39 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Brayton Cycle for Modeling Gas Turbine Power Plants 40 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Brayton Cycle for Modeling Gas Turbine Power Plants For the same pressure rise, a gas turbine compressor would require a much greater work input per unit of mass flow than the pump of a vapor power plant because the average specific volume of the gas flowing through the compressor would be many times greater than that of the liquid passing through the pump 41 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Brayton Cycle for Modeling Gas Turbine Power Plants For fixed values of Tmin and Tmax, the net work of the Brayton cycle first increases with the pressure ratio, then reaches a maximum at rp = (Tmax/Tmin)k/[2(k - 1)], and finally decreases. 42 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Brayton Cycle for Modeling Gas Turbine Power Plants The highest temperature in the cycle is limited by the maximum temperature that the turbine blades can withstand. This also limits the pressure ratios that can be used in the cycle. The air in gas turbines supplies the necessary oxidant for the combustion of the fuel, and it serves as a coolant to keep the temperature of various components within safe limits. An air– fuel ratio of 50 or above is not uncommon. 43 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Example Gas-turbine power plant operating on an ideal Brayton cycle has a pressure ratio of 8. The gas temperature is 300 K at the compressor inlet and 1300 K at the turbine inlet. Utilizing the airstandard assumptions, determine (a) the gas temperature at the exits of the compressor and the turbine, (b) the back work ratio, and (c) the thermal efficiency. 44 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Example Cont. 45 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Example Cont. OR 46 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Example Cont. 47 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Development of Gas Turbines Increasing the turbine inlet (or firing) temperatures Increasing the efficiencies of turbomachinery components (turbines, compressors): Adding modifications to the basic cycle (intercooling, regeneration or recuperation, and reheating). Deviation of Actual Gas-Turbine Cycles from Idealized Ones Reasons: Irreversibilities in turbine and compressors, pressure drops, heat losses Isentropic efficiencies of the compressor and turbine The deviation of an actual gasturbine cycle from the ideal Brayton cycle as a result of irreversibilities. Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 48 THE BRAYTON CYCLE WITH REGENERATION In gas-turbine engines, the temperature of the exhaust gas leaving the turbine is often considerably higher than the temperature of the air leaving the compressor. Therefore, the high-pressure air leaving the compressor can be heated by the hot exhaust gases in a counter-flow heat exchanger (a regenerator or a recuperator). The thermal efficiency of the Brayton cycle increases as a result of regeneration since less fuel is used for the same work output. A gas-turbine engine with regenerator. T-s diagram of a Brayton cycle with regeneration. In the limiting (ideal) case, the air exits the regenerator at the inlet temperature of the exhaust gases 49 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 THE BRAYTON CYCLE WITH REGENERATION Effectiveness of regenerator Effectiveness under cold-air standard assumptions Under cold-air standard assumptions T-s diagram of a Brayton cycle with regeneration. The thermal efficiency depends on the ratio of the minimum to maximum temperatures as well as the pressure ratio. Regeneration is most effective at lower pressure ratios and low minimum-tomaximum temperature ratios. Thermal efficiency of the ideal Brayton cycle with and without regeneration. Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 50 THE BRAYTON CYCLE WITH INTERCOOLING, REHEATING, AND REGENERATION For minimizing work input to compressor and maximizing work output from turbine: A gas-turbine engine with two-stage compression with intercooling, two-stage expansion with reheating, and regeneration and its T-s diagram. 51 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 THE BRAYTON CYCLE WITH INTERCOOLING, REHEATING, AND REGENERATION Multistage compression with intercooling: The work required to compress a gas between two specified pressures can be decreased by carrying out the compression process in stages and cooling the gas in between. This keeps the specific volume as low as possible. Multistage expansion with reheating keeps the specific volume of the working fluid as high as possible during an expansion process, thus maximizing work output. Intercooling and reheating always decreases the thermal efficiency unless they are accompanied by regeneration. Why? Comparison of work inputs to a single-stage compressor (1AC) and a two-stage compressor with intercooling (1ABD). As the number of compression and expansion stages increases, the gas-turbine cycle with 52 intercooling, reheating, and regeneration Chemical Engineering Department | University of Jordan | Amman 11942, Jordanthe Ericsson cycle. approaches Tel. +962 6 535 5000 | 22888 IDEAL JET-PROPULSION CYCLES Gas-turbine engines are widely used to power aircraft because they are light and compact and have a high power-to-weight ratio. Aircraft gas turbines operate on an open cycle called a jet-propulsion cycle. The ideal jet-propulsion cycle differs from the simple ideal Brayton cycle in that the gases are not expanded to the ambient pressure in the turbine. Instead, they are expanded to a pressure such that the power produced by the turbine is just sufficient to drive the compressor and the auxiliary equipment. The net work output of a jet-propulsion cycle is zero. The gases that exit the turbine at a relatively high pressure are subsequently accelerated in a nozzle to provide the thrust to propel the aircraft. Aircraft are propelled by accelerating a fluid in the opposite direction to motion. This is accomplished by either slightly accelerating a large mass of fluid (propeller-driven engine) or greatly accelerating a small mass of fluid (jet or turbojet engine) or both (turboprop engine). In jet engines, the high-temperature and highpressure gases leaving the turbine are accelerated in a nozzle to provide thrust. 53 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 IDEAL JET-PROPULSION CYCLES Thrust (propulsive force) Propulsive power Propulsive efficiency Propulsive power is the thrust acting on the aircraft through a distance per unit time. Basic components of a turbojet engine and the T-s diagram for the ideal turbojet cycle. Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 54 Combined Gas-Vapor Cycles A gas power cycle topping a vapor power cycle, which is called the combined gas–vapor cycle, or just the combined cycle The combined cycle of greatest interest is the gas-turbine (Brayton) cycle topping a steam turbine (Rankine) cycle. The modified cycle has a higher thermal efficiency than either of the cycles executed individually Gas-turbine cycles typically operate at considerably higher temperatures than steam cycles. The maximum fluid temperature at the turbine inlet is about 620°C for modern steam power plants, but over 1425°C for gas-turbine power plants. Gas-turbine cycles have a greater potential for higher thermal efficiencies. However, the gas-turbine cycles have one inherent disadvantage: The gas leaves the gas turbine at very high temperatures (usually above 500°C), which erases any potential gains in the thermal efficiency. 55 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Combined Gas-Vapor Cycles The efficiency can be modified by using the high temperature exhaust gases as the energy source for the bottoming cycle such as a steam power cycle. 56 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Example Consider the combined gas–steam power cycle shown. The topping cycle is a gas-turbine cycle that has a pressure ratio of 8. Air enters the compressor at 300 K and the turbine at 1300 K. The isentropic efficiency of the compressor is 80 percent, and that of the gas turbine is 85 percent. The bottoming cycle is a simple ideal Rankine cycle operating between the pressure limits of 7 MPa and 5 kPa. Steam is heated in a heat exchanger by the exhaust gases to a temperature of 500°C. The exhaust gases leave the heat exchanger at 450 K. Determine (a) the ratio of the mass flow rates of the steam and the combustion gases and (b) the thermal efficiency of the combined cycle. 57 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Example Cont. Energy balance on the heat exchanger: 58 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888 Example Cont. 59 Chemical Engineering Department | University of Jordan | Amman 11942, Jordan Tel. +962 6 535 5000 | 22888