Click Here JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 111, D17312, doi:10.1029/2005JD006580, 2006 for Full Article Ultraviolet climatology over Argentina Eduardo Luccini,1 Alexander Cede,2 Rubén Piacentini,1,3 Carlos Villanueva,4 and Pablo Canziani5 Received 10 August 2005; revised 17 March 2006; accepted 26 May 2006; published 14 September 2006. [1] Satellite-derived climatologies of UV index (UVI) and erythemal daily dose were determined for Argentina at a geographical resolution of 0.5 latitude by 0.5 longitude. Total Ozone Mapping Spectrometer climatology of key input parameters was used to calculate the clear-sky ground-level solar UV irradiance. NASA Surface meteorology and Solar Energy cloud cover data were used to determine the UV attenuation by clouds. Two cases were tested: (1) monthly averages of total cloud cover and (2) monthly averages for three ranges of cloud cover percentage (0–10%, 10–70%, and 70–100%). Case 2, with smaller biases, was selected. Measured erythemal irradiance at seven stations of the Argentine Ultraviolet Monitoring Network was used to validate the satellite-derived climatologies, as well as to estimate aerosol parameters, surface albedo corrections, and UV cloud transmittance for the calculations. Annual average biases of the monthly mean satellite-derived UVI and erythemal daily dose with respect to the ground measurements are mostly within ±10%. The strong longitudinal gradient of UV levels toward the Andes Mountains is emphasized. Very high UVI and erythemal daily dose values are registered in the northwestern tropical high-elevation Andean plateau, with extreme monthly means above 18 and 10 kJ/m2 respectively, in December–January. Even northern low-elevation regions show averages over 12 and 7 kJ/m2, respectively. On average, clouds attenuate the clear-sky erythemal irradiance by less than 20% for most of the continental region during all months. UV levels are considerably higher than those for equivalent regions in the Northern Hemisphere. Citation: Luccini, E., A. Cede, R. Piacentini, C. Villanueva, and P. Canziani (2006), Ultraviolet climatology over Argentina, J. Geophys. Res., 111, D17312, doi:10.1029/2005JD006580. 1. Introduction [2] Solar UV radiation, especially the UVB range (280 – 320 nm), which is strongly influenced by the ozone content in the atmosphere, has large impact on the life and materials on Earth [United Nations Environment Programme (UNEP), 2003]. In appropriate doses, it is beneficial for several biological reactions [Wharton and Cockerell, 1998; Grant, 2002], but many negative effects on humans, plants, animals and materials can be caused by excessive UV exposure [UNEP, 2003]. The progressive depletion of the stratospheric ozone layer in the last decades caused concern by an eventual increase in the UV radiation levels reaching 1 Instituto de Fı́sica de Rosario, Consejo Nacional de Investigaciones Cientı́ficas y Técnicas – Universidad Nacional de Rosario, Rosario, Argentina. 2 Science Systems & Applications Inc., Lanham, Maryland, USA. 3 Facultad de Ciencias Exactas, Ingenierı́a y Agrimensura, Universidad Nacional de Rosario, Rosario, Argentina. 4 Servicio Meteorológico Nacional, Buenos Aires, Argentina. 5 Programa de Estudios de Procesos Atmosféricos en el Cambio Global, Pontificia Universidad Católica – Consejo Nacional de Investigaciones Cientı́ficas y Técnicas, Buenos Aires, Argentina. Copyright 2006 by the American Geophysical Union. 0148-0227/06/2005JD006580$09.00 the Earth’s surface [UNEP, 2003]. Particularly, Argentina is placed very near the Antarctic Continent and is frequently affected by the ‘‘ozone hole’’ which develops every year in springtime [e.g., World Meteorological Organization, 2003]. The typical UV radiation levels at surface must be known to correlate with possible biological and chemical effects. [3] The effective UV irradiance acting on a specific biological system is obtained by weighting the incoming spectral UV irradiance with its corresponding ‘‘action spectrum’’. In particular, the erythemal irradiance is the wavelength-integrated spectral irradiance weighted by the action spectrum of the human skin defined by McKinlay and Diffey [1987]. The UV index (UVI) is defined as the erythemal irradiance at horizontal plane multiplied by a factor of 40 m2/W [World Health Organization (WHO), 2002] (available at http://www.who.int/uv/publications/ globalindex/en/) and indicates the risk of producing damage on typical human skin exposed to the sun. UVI is currently informed to the people from the daily maximum erythemal irradiance [WHO, 2002], and its analysis is based on local solar noon values. UVI information is intended to prevent sudden damaging effects. Information on typical UV daily dose is also important as other effects, like photoaging and carcinogenesis, are associated to cumulative long-term UV exposure [e.g., Amer and Metwalli, 1998]. D17312 1 of 15 D17312 LUCCINI ET AL.: ULTRAVIOLET CLIMATOLOGY OVER ARGENTINA [4] Even though there are many sites in the world where solar UV radiation at the surface is measured, these data are usually representative only for a local area. If a long enough database is available, the UV radiation climatology of averages and trends for this single place can be determined [Weatherhead et al., 1998; Intergovernmental Panel on Climate Change, 2001]. To establish UV climatology over an extended region on ground-based measurements, it is necessary to strategically arrange a large number of instruments in representative zones and then making an appropriate geographical interpolation of their long-term data. However, for logistic and economic reasons, the number of distributed instruments is usually small. Another frequently used approach to establish UV climatology consists in using a reliable radiative transfer model to calculate the clear-sky ground-level UV irradiance and applying attenuation factors due to cloudiness. The input parameters for the radiative transfer calculations in the UV range include the elevation of the place, total ozone column, aerosol parameters, surface UV albedo and cloud optical parameters. These input data are often obtained from satellite databases, which cover the whole Planet at variable geographical resolution. The calculations are then validated by comparison with the measured UV irradiance at sites in the region. [5] Several UV radiation global climatologies have been established in this way: Lubin et al. [1998] (at a geographical resolution of 2.5 latitude by 2.5 longitude), Mayer and Madronich [1998] (1 1.25), Sabziparvar et al. [1999] (5 5), Madronich et al. [1999] (1 1.25), Herman et al. [1999] (approximately 1 1), Pubu and Li [2003] (1 1.25). Verdebout [2000] uses a similar approach to generate high-resolution maps over Europe (0.05 0.05). Fioletov et al. [2003] determined UV maps for Canada by applying an interpolation method to the calculated values at specific sites through correlations between the UV and the total solar radiation (300 – 3000 nm). Fioletov et al. [2004] used an improved version of this algorithm, together with the Total Ozone Mapping Spectrometer (TOMS) satellite method, to generate the UV index climatology over the United States and Canada (1 1.25). Meloni et al. [2000] interpolate the calculated values at 69 sites to determine UV maps in Italy at a resolution of 0.5 0.5. [6] The Argentine Ultraviolet Monitoring Network (UV Net) consists currently of 9 stations, where the erythemal irradiance is measured. The analysis of their measurements after an extensive calibration campaign [Cede et al., 2002a] gave important results on characterization of the UV irradiance [Cede et al., 2002b], effects of clouds on the UV irradiance [Cede et al., 2002c], comparison with UV TOMS satellite method and corrections to the surface UV albedo in zones with high variability [Cede et al., 2004], and estimation of aerosol parameters [Cede, 2001] at the stations. The small number of stations in such an extended area prevents the application of rigorous interpolation methods such as kriging, inverse square distance, etc. [e.g., Shepard, 1968; Caruso and Quarta, 1998]. Instead, the information retrieved from these sites is used in this work to construct climatological UV maps from model calculations of the clear-sky erythemal irradiance, corrected for mean attenuation by cloudiness. Even though the time span of available data is not extensive enough, the term ‘‘UV climatology’’ D17312 will be used as a characterization of long-term average UV values in the region under study. [7] In this paper we present the climatologies of solar erythemal UV irradiance at noon and erythemal daily dose on a horizontal plane for Argentina, both calculated at a geographical resolution of 0.5 0.5. We noted that working at a geographical resolution of 0.5 0.5 supplies important local-scale details in regions with large gradients in the UV irradiance levels, with respect to lowerresolution calculations. The base of this paper was developed by Luccini [2003] (available at http://www.ifir.edu.ar/ ~solar/luccini/tesis/) using TOMS Version 7 ozone data and Surface meteorology and Solar Energy (SSE) release 4 cloud data. Recently, TOMS Version 8 (available at http:// toms.gsfc.nasa.gov/) and SSE release 5.1 (available at http://eosweb.larc.nasa.gov/sse/) data sets were published in August and December 2004 respectively. Nevertheless, new versions imply changes that are not substantial to the present work [Wellemeyer et al., 2004; P. W. Stackhouse, NASA Langley Atmospheric Sciences Data Center, personal communication, 2005]. Given that a new method was applied to determine the UV climatologies, Luccini [2003] explored some additional steps like the fitting of several parameters in search of improving the approach, which were not applied in this version. [8] The erythemal UV measurements used to validate and estimate the uncertainty of the present climatologies comprise the period 1996– 2000 and correspond to the following UV Net stations: 1, La Quiaca (22.11S, 65.57W, 3459 m a.s.l.); 2, Pilar (31.66S, 63.88W, 338 m a.s.l.); 3, Rosario (32.96S, 60.62W, 25 m a.s.l.); 4, Buenos Aires (34.61S, 58.41W, 25 m a.s.l.); 5, Comodoro Rivadavia (45.78S, 67.50W, 46 m a.s.l.); 6, San Julián (49.32S, 67.75W, 62 m a.s.l.); and 7, Ushuaia (54.80S, 68.27W, 14 m a.s.l.). Station Mendoza (32.88S, 68.87W, 704 m a.s.l.) started its measurements during the calibration campaign and was not included, and station Marambio is placed in Antarctica being then out of the area studied in this work. Details on the stations, measurements, calibration and characterization of erythemal irradiance at the UV Net are given by Cede et al. [2002a, 2002b]. [9] Maps of the average UV attenuation by clouds in the whole region are also determined, and the hourly course of average cloud attenuation is studied by comparison of the modeled attenuation with that resulting from the measurements at the UV Net stations. The climatological maps for January, April, July and October are presented in this paper. Climatological data and maps for all months of both UV index and erythemal daily dose are available online at http://www.ifir.edu.ar/~luccini/uvclimatology/. 2. Data [10] Both calculations of the clear-sky UV irradiance and cloudiness attenuation use monthly mean values of the input parameters. UV index was determined from noon irradiance calculations for each day, while hourly calculations within each day were made to determine the erythemal daily dose. [11] Calculations of the clear-sky irradiance were made with the one-dimensional discrete ordinates radiative transfer model described in Table 1, at each grid point with a 2 of 15 Surface albedo Rayleigh scattering Ozone absorption Total ozone column Ozone vertical profile Aerosol parameters Continental AOD340 Marine AOD340 Single-scattering albedo Asymmetry factor Wavelength dependence of AOD Continental a Marine a Aerosol vertical profile Temperature and pressure vertical profiles Number of streams Wavelength grid Extraterrestrial flux Layers Description/Value DISORT algorithm [Stamnes et al., 1988], pseudospherical version based on the Tropospheric Ultraviolet and Visible (TUV) radiation model (available at http://cprm.acd.ucar.edu/Models/TUV/) 16 121 wavelengths from 280 to 400 nm, step 1 nm SUSIM-Atlas 3 spectrum (available at ftp://susim.nrl.navy.mil/pub/atlas3) 58 layers: 0.5 km width from 0 to 2 km, 1 km width from 2 to 50 km, and 5 km width from 50 to 80 km; 0 km means the elevation of the station above sea level formula from Bodhaine et al. [1999] cross sections by Bass and Paur [1985] TOMS Version 7 Level 3 pixel-by-pixel climatology 1978 – 2000 with trend TOMS Version 7 climatology of ozone profiles for corresponding latitude and total ozone column [McPeters et al., 1998] Model type Table 1. Radiative Transfer Model Used for the Clear-Sky Calculations latitudinal interpolation with altitudinal correction from the estimated monthly mean values at the UV Net stations [Cede, 2001] 0.2 (mean value from the measurements of the AVHRR satellite instrument) 0.95 [Hess et al., 1998] 0.73 [Hess et al., 1998] Angström formula AOD(l) = bla 1.11 [Hess et al., 1998] 0.75 (mean value from AVHRR) rural type from Shettle and Fenn [1979], combined with the ‘‘Warneck’’ vertical profile [Erlick and Frederick, 1998] COSPAR International Reference Atmosphere (1986) (0 km to 120 km) for corresponding latitude and time (available at http://nssdc.gsfc.nasa.gov/ space/model/atmos/cospar1.html) climatology from Herman and Celarier [1997], corrected for ‘‘mean’’ albedo toward the southernmost region as suggested by Cede et al. [2004] LUCCINI ET AL.: ULTRAVIOLET CLIMATOLOGY OVER ARGENTINA D17312 D17312 geographical resolution of 0.5 0.5 (approximately 55 km by 55 km) between latitudes 21.25S and 55.25S and longitudes 53.25W and 73.75W, thus covering the whole continental region of Argentina, part of its neighboring countries and of the South Atlantic Ocean. Input parameters for the clear-sky calculations are the surface mean elevation, total ozone column, surface UV albedo and aerosol parameters. Finally, satellite cloud cover data were used to determine the average attenuation of the UV irradiance by cloudiness in the same grid. 2.1. Elevation [12] The altitude increase effect on the UV erythemal irradiance may be over 20%/km under certain conditions [Pfeifer et al., 2006]. Then the surface elevation grid, representing the average height of the surface for a given geographical resolution, is a key parameter in the calculations. For this work, the elevation grid was obtained from the terrain digital model of the region [see, e.g., Cancoro, 2005] (available at http://www.teses.usp.br/teses/ disponiveis/3/3138/tde-10102005-104155/) at a geographical resolution of 0.5 0.5. It is shown in Figure 1 (upper left panel). Note that at this resolution, many pixels corresponding to the northwestern tropical high-elevation Andean plateau (NAP) have elevations above 4000 m, and some ones even above 5000 m (the highest-elevation pixel is 5610 m a.s.l.). Taking into account that the highest peak of the region is Mount Aconcagua (32.65S, 69.98W) with 6960 m a.s.l., the selected grid is very appropriate for the calculations. 2.2. Ozone [13] A monthly pixel-by-pixel climatology of total ozone vertical column was built by analyzing TOMS Version 7/ Level 3 data from the whole period of Nimbus 7 satellite (1978 – 1993) and the first years of EarthProbe satellite (1996– 2000). Data from EarthProbe were merged to the Nimbus 7 data by using their differences to the groundbased Dobson network. This climatology comprises monthly averages, standard deviations and tendencies of the total ozone over the studied region. To derive the tendencies, the monthly means for each pixel of 1 latitude by 1.25 longitude were first corrected for the seasonal and solar cycles, El Niño effect and the quasi-biennial oscillation, and then a linear regression was applied on the residues. In order to change from the original resolution of 1 1.25 to the new resolution of 0.5 0.5, the ozone amount below the pixel’s elevation was estimated using the TOMS Version 7 ozone vertical profiles and added to the monthly means to get the mean total ozone at sea level. After this, data were bilinearly interpolated to the 0.5 by 0.5 grid and finally the ozone amount below the elevation of these new pixels was resubtracted. UV calculations were made for year 2000. As an example, the ozone map for January 15, 2000 is also shown in Figure 1 (upper right panel). 2.3. Albedo [14] The surface UV albedo from the TOMS monthly climatology [Herman and Celarier, 1997] was used as a base. Given that it was determined from an average of the smallest albedo values at each point, this climatology is appropriate for zones and seasons without large variations 3 of 15 D17312 LUCCINI ET AL.: ULTRAVIOLET CLIMATOLOGY OVER ARGENTINA D17312 Figure 1. Maps of the surface elevation, monthly mean total ozone column, surface UV albedo, and aerosol optical depth at 340 nm, used as input parameters in the daily calculations of the clear-sky erythemal irradiance in Argentina. Maps for each month were built at a geographical resolution of 0.5 0.5 of the calculations. Maps for January are shown as an example. in the albedo. However, in regions with large variability, e.g., due to frequent snowfall, it is more appropriate to replace it by a climatology of ‘‘mean’’ albedo [Cede et al., 2004]. Fioletov et al. [2004] use a snow flag method to estimate the presence of snow in daily UV TOMS estimates. The work by Cede et al. [2004] showed that the TOMS climatology represents rather well the surface UV albedo for stations 1 (La Quiaca) to 6 (San Julián), providing also the 4 of 15 D17312 LUCCINI ET AL.: ULTRAVIOLET CLIMATOLOGY OVER ARGENTINA monthly average corrections to the albedo at station 7 (Ushuaia), where snowfall is frequent. On the basis of those results, in the present work the albedo from the latitude of San Julián station (49.32S) was increased linearly over the continental region toward the corrected albedo of Ushuaia station (54.80S) for each month. Maximum correction increased the albedo at Ushuaia from the climatological TOMS value of 0.07 up to 0.25 in July. As an example, the UV albedo map for January is also shown in Figure 1 (lower left panel). 2.4. Aerosols [15] The aerosol parameters used for the calculations are the total vertical aerosol optical depth at 340 nm (AOD340), the Angström exponent a, the single-scattering albedo and the asymmetry factor. The Angström formula AOD(l) = bla for the spectral dependence of the aerosol optical depth was used, where b is the Angström turbidity coefficient. The monthly means of AOD340 in the continental region were obtained by geographical interpolation of the average values estimated at the stations from UV measurements under clear-sky conditions [Cede, 2001]. Initially, a linear interpolation in latitudinal direction was made for AOD340. In addition we applied a correction for elevations above 400 m, reducing the AOD340 linearly down to the AOD340 value of station 1 at 3459 m (average AOD340 0.17 at station 1 [Cede, 2001]). Then, other linear interpolation above 3459 m was made between the AOD340 value of station 1 and an estimated very clean atmosphere AOD340 of 0.01 at 5700 m. The elevation of 400 m was selected, as it is just above all the low-elevation stations of the UV Net (stations 2 – 7, see section 1). [16] Of course, the AOD340 maps are just rough estimates within the limited available data. For example, the AOD340 at the latitude of the urban station 4 (Buenos Aires) is extrapolated to every site below 400 m at the same latitude in the continent, including many rural sites on that latitude. However, this is only a conceptual observation as the estimated AOD340 has rather similar values for all the central stations: Pilar (rural), Rosario (river coastal-urban) and Buenos Aires (big city) [Cede, 2001]. As pointed out by Cede et al. [2004], the aerosol correction is important as it reduces significantly the systematic differences between calculations and measurements. The future incorporation of data sets from the NASA Aerosol Robotic Network sites in the region (AERONET, http://aeronet.gsfc.nasa.gov/) and NASA Moderate Resolution Imaging Spectroradiometer (MODIS, http://modis-atmos.gsfc.nasa.gov/) satellite data will give new insights on this subject. Continental a was taken constant at the value 1.11 [Hess et al., 1998]. In the marine region, the mean values of AOD340 and a were determined from the measurements of the Advanced Very High Resolution Radiometer (AVHRR) satellite instrument [Mishchenko et al., 1999]. As both parameters exhibited no important seasonal variation, constant values of AOD340 = 0.2 and a = 0.75 were used throughout the year in the marine region. Also, given the small differences, a constant single-scattering albedo of 0.95 and asymmetry factor of 0.73 were used in both continental and marine regions [from Hess et al., 1998]. With these parameters, maximum reduction of erythemal irradiance throughout the region due to aerosols, with respect to the aerosol-free case, amounts D17312 12% for AOD340 0.5 in the central continental region [Cede et al., 2004]. As an example, the AOD340 map for January is also shown in Figure 1 (lower right panel). 2.5. Clouds [17] Cloud data were taken from the 10-year (1983 – 1993) global climatology given by the SSE release 4 data set [see Whitlock et al., 2000], at a geographical resolution of 1 1 obtained from the original (280 km equal-area grid) International Satellite Cloud Climatology Project (ISCCP) D1 database. For comparison, SSE Release 5.1 consists of true 1 1 resolution cloud data obtained from the raw ISCCP DX database, implying improvements in grid boxes bordering topographic features like the Andes Mountains (P. W. Stackhouse, NASA Langley Atmospheric Sciences Data Center, personal communication, 2005). Nevertheless, given that the major cause of the large UV gradient in these zones, i.e., the surface elevation grid, is taken at true 0.5 0.5 resolution, cloudiness play a modulating role that reduces the influence of such differences. Two cases using SSE data were tested. Case 1 consists in monthly average total cloud cover percentage every 3 hours for each month (at 0000, 0300, 0600, 0900, 1200, 1500, 1800 and 2100 UT). Case 2 supplies the percentage of time within the month that the sky is in each of the following conditions: clear skies from 0% to 10% cloud cover, broken-cloud skies from 10% to 70%, and nearovercast skies from 70% to 100%, every 3 hours (at 0000, 0300, 0600, 0900, 1200, 1500, 1800 and 2100 UT). No distinction in the type of clouds or in the frequency distribution within each case of cloud cover is given. A bilinear geographical interpolation and a linear time interpolation were made to obtain grids of 0.5 0.5 every 1 hour in each case. [18] As will be seen in section 3.3, case 2 produced the smaller biases between the calculations and ground measurements, and all the following analysis is centered on SSE case 2 data. As an example, the maps for each range of SSE case 2 cloud cover at 1600 UT (around local solar noon) in January are shown in Figure 2. 3. Methods and Results 3.1. UV Index Climatology [19] With the input data introduced in section 2, calculations of the clear-sky erythemal irradiance at noon for every day in the year were made for each point of the 0.5 0.5 grid. Monthly means were determined, obtaining in this way the ‘‘clear-sky climatology’’ of noon erythemal irradiance. Then, the average attenuation by clouds was incorporated. For this purpose, the measured average erythemal effective transmittance factors for each case of SSE cloud cover data were obtained from a previous work on UV measurements and cloud cover observations at the stations of the Argentine UV Net [Cede et al., 2002c]. In that work, major differences were noted for large cloud cover percentage between the high-elevation station (1, La Quiaca) and the low-elevation ones. In the NAP, high clouds with smaller optical depth are more frequent, yielding a larger transmittance of erythemal irradiance [Cede et al., 2002c]. On the basis of the results of that paper, the average erythemal transmittance curve as a function of the cloud cover percentage was used for SSE case 1. In turn, the 5 of 15 D17312 LUCCINI ET AL.: ULTRAVIOLET CLIMATOLOGY OVER ARGENTINA D17312 Figure 2. Maps of the percentage of time within the month with cloud cover between 0 and 10%, 10 and 70%, and 70 and 100% in Argentina, from NASA SSE release 4. Data are used to apply the cloud attenuation to the calculated clear-sky UV irradiance. Maps for January at 1600 UT (around local noon) are shown as an example. erythemal transmittance curve was averaged within each range of SSE cloud cover for case 2: the mean erythemal transmittance factors for the cloud cover ranges 0 – 10% (T0 – 10) and 10– 70% (T10 – 70) were set at the values 1 and 0.96 respectively, for the complete region. While, the mean erythemal transmittance in the cloud cover range 70– 100% (T70 – 100) was set to 0.78 for the high-elevation station and 0.67 for all the other (low-elevation) stations. Finally, a map was constructed for T70 – 100 making 0.67 the transmittance for every continental or marine region, except toward the NAP were a linear altitudinal interpolation was made for elevations between 1 km (T70 – 100 = 0.67) and 3 km (T70 – 100 = 0.78), setting T70 – 100 = 0.78 for elevations above 3 km. A small systematic difference appears here. As several works showed [Malberg, 1973; Schreiner et al., 1993; McKenzie et al., 1998], satelliteestimated cloud cover fraction is generally smaller than that determined from ground observations. This is to be expected, as the first one is representative of the area covered while the latter is the fraction of the sky hemisphere covered. From the effective cloud transmittance curve, determined as a function of the ground observations of cloud cover [Cede et al., 2002c], this implies that the effective transmittance of corresponding SSE cloud cover interval is slightly overestimated (SSE cloud cover range 70 – 100% implies ground-observed >70 – 100%). The higher satellite-derived UV cloud transmittance with respect to that measured from the ground, particularly for large cloud cover, was stated by Matthijsen et al. [2000] and Williams et al. [2004] on ISCCP D1 cloud data. The difference is more notorious when observed on daily averages than on monthly averages, given that large cloud cover percentages are more frequent for shorter time periods. Then, differences by this fact are negligible for the present work. d,noon is the modeled clear-sky erythemal irradi[20] If Ics,mod ance at noon at each grid point on day d of month M having N days, then the satellite-derived monthly mean erythemal irradiance including the attenuation by cloudiness for SSE case 2 is given by ISM;noon ¼ N 1 X M ;noon M ;noon I d;noon ðT010 F010 þ T1070 F1070 N d¼1 cs;S M ;noon þ T70100 F70100 Þ M ;noon M ;noon M ;noon T010 F010 þ T1070 F1070 þ T70100 F70100 ¼ N N X d;noon Ics;S ð1Þ d¼1 M,noon M,noon where FM,noon 0 – 10 , F10 – 70 and F70 – 100 are the fractions of time of month M around noon with the sky in the three ranges of cloud cover (0 – 10%, 10– 70% and 70– 100%) respectively, provided by the SSE database (see Figure 2). The small time offset between the noon calculations at each grid point and the cloud cover data at 1600 UT (ranging from 27 min on the east to +55 min on the west of the region under study) is completely concealed by the monthly average of cloud data. Of course, the condition M,h M,h FM,h 0 – 10 + F10 – 70 + F70 – 100 = 1 is satisfied for every hour h within month M. [21] Thus climatological maps of monthly mean erythemal irradiance at noon, converted to UVI units, were obtained for each month in the year. Figure 3 shows, particularly, the monthly mean UVI for January, April, July and October. [22] UVI for the low-elevation zones (see Figure 1) shows the characteristic latitudinal dependence, responding to the behavior of the stratospheric ozone and the increasing 6 of 15 D17312 LUCCINI ET AL.: ULTRAVIOLET CLIMATOLOGY OVER ARGENTINA Figure 3. Maps of the satellite-derived monthly mean UV index for January, April, July, and October in Argentina, calculated at a geographical resolution of 0.5 0.5. 7 of 15 D17312 D17312 LUCCINI ET AL.: ULTRAVIOLET CLIMATOLOGY OVER ARGENTINA D17312 Figure 4. Maps of the satellite-derived monthly mean erythemal daily dose for January, April, July, and October in Argentina, calculated at a geographical resolution of 0.5 0.5. noon solar zenith angle (SZA) toward the south. Monthly mean values for the low-elevation regions range between about 12 in the north and 6 in the south in summer, and 4 and less than 1 respectively in winter. Simultaneously, a strong longitudinal gradient of the UVI at fixed latitudes is observed toward the Andean mountains in the west of the country, with extreme averages above 18 around January in the NAP. The high elevation, the small noon SZA and the relatively thin and stable total ozone column at low-latitude regions [e.g., Herman et al., 1991, 1993] cause the charac- 8 of 15 D17312 LUCCINI ET AL.: ULTRAVIOLET CLIMATOLOGY OVER ARGENTINA teristically high UVI values observed throughout the year over this tropical and subtropical area, which are within the highest UVI levels for densely populated regions in the world. Values are even higher than those registered at Lhasa (29.7N, 91.1E, 3648 m a.s.l.) on the Tibetan plateau, with monthly mean UVI over 16 in July [Pubu et al., 1999]. It is important to remark that the mean UVI values observed in the southernmost region during springtime may be strongly exceeded in cases when the Antarctic ‘‘ozone hole’’ passes over the continent [Dı́az et al., 2001; Cede et al., 2002b]. [23] The geographical resolution of the calculations, strongly dominated by the resolution of the elevation grid, is critical to represent local-scale details of the UV irradiance levels within a given region. A comparison of the present 0.5 0.5 UVI climatology with the global UV radiation climatology (GUVRC) by Lubin et al. [1998], which has a geographical resolution of 2.5 2.5 and is valid for the period 1985 – 1989, shows minimum differences in the low-elevation zones for every month. Those differences are within the uncertainty of the calculations for the different epochs they represent. On the contrary, in regions with large altitudinal gradient like the Andes Mountains, GUVRC strongly underestimates the irradiance values with respect to the present climatology (over 30% in the NAP), mainly because of the smaller resolution of its elevation grid. [24] Comparison of the climatology in this area of the Southern Hemisphere (SH) with equivalent ones in the Northern Hemisphere (NH) will be restricted to lowelevation zones, so as to avoid differences that may be attributable only to the geographical resolution of the calculations. For example, mean noon erythemal irradiance for coastal zones in January from Figure 3 is systematically higher by about 20– 25% from latitudes 30 to 50S than the equivalent TOMS climatology in North America from 30 to 50N in July [Fioletov et al., 2004]. A similar result is observed from the global TOMS climatology by Herman et al. [1999], where NH and SH are analyzed with the same TOMS algorithm. About 7% of this difference is inherent to the smaller Earth-Sun distance in the SH summer solstice with respect to the NH summer solstice [e.g., Liou, 2002]. To study the contribution of ozone to that difference, we determined the time average of latitudinal ozone bands from the TOMS climatology (complete years 1979 – 1992 for Nimbus 7 and 1997 – 2005 EarthProbe satellites). Summer average total ozone column for band 30 –50S is about 9% smaller than for band 30– 50N. Taking into account that the radiation amplification factor for erythemal UV irradiance, relating the percentage change of erythemal irradiance to a given percentage change of ozone, is approximately 1.1 [Madronich et al., 1998], then about 10% of the north-south difference is explained by the ozone layer. On the other hand, a test was made to analyze the NH-SH differences in cloud attenuation using the SSE database from the low-elevation regions 30 – 50S/50– 70W of the present work and 30 – 50N/70– 90W of North America, under the assumption that the same cloud transmittance factors T detailed previously are valid for both regions. Average differences between the total cloud attenuation in both NH and SH regions are smaller than 2% in summer and 5% in winter. In summary, of the total 20 –25% higher summer UVI along the 30 – 50S D17312 low-elevation band in Argentina with respect to the summer UVI along the 30– 50N low-elevation band in North America, about 10% is attributable to the ozone layer, 7% to the Earth-Sun distance, and less than 8% to the sum of clouds, aerosols and surface albedo. 3.2. Erythemal Daily Dose Climatology [25] To determine the climatology of erythemal daily dose, hourly calculations of the clear-sky erythemal irradiance were made in the same geographic grid of 0.5 0.5 within each day in the month. Then the hourly clear-sky maps were corrected for clouds attenuation using the hourly interpolated data for both cases of SSE cloud cover mentioned in section 2.5. The obtained hourly erythemal irradiance including cloud attenuation was integrated in each grid point within the corresponding day to obtain the erythemal daily dose. Finally, the daily dose maps were averaged for each month. [26] The satellite-derived monthly mean erythemal daily dose using SSE case 2 data for month M is given by DM S ¼ N 1 X Dd;M N d¼1 S ð2Þ where Dd;M ¼ S 24 X d;h M ;h M ;h M;h Ics;S T010 F010 þ T1070 F1070 þ T70100 F70100 h¼1 ð3Þ is the calculated daily dose including the attenuation by cloudiness for SSE case 2 on day d (the time interval factor and integration only for daylight time are implicit). The same transmittance factors T than for the case at noon were applied (section 3.1), supported by the fact that null or very small dependence with the SZA was found in the effective UV transmittance as a function of the cloud cover percentage for all sky conditions [Kuchinke and Nunez, 1999; Josefsson and Landelius, 2000; Cede et al., 2002c; Alados-Arboledas et al., 2003; Foyo-Moreno et al., 2003]. [27] Figure 4 shows the climatological maps of monthly mean erythemal daily dose for January, April, July and October. A behavior similar to that of the noon erythemal irradiance is noted: a pronounced latitudinal dependence with a strong longitudinal gradient toward the high-elevation Andes Mountains at fixed latitude. Low-elevation regions present typical daily dose values between about 7 kJ/m2 in the north and 4 kJ/m2 in the south in summer, and 2 kJ/m2 and 0.2 kJ/m2 respectively in winter. The NAP presents extreme monthly mean values of erythemal daily dose over 10 kJ/m2 in December – January. For comparable latitude and elevation, values are considerably higher than those registered at Lhasa on the Tibetan plateau with monthly mean daily dose of about 7.5 kJ/m2 in July [Pubu et al., 1999]. [28] A comparison between climatologies for the SH and NH is made again for low-elevation zones only. Mean erythemal daily dose at 50S in January from Figure 4 is about 4.1 kJ/m2, i.e., approximately 30% higher than the equivalent for 50N over Canada in July [Fioletov et al., 9 of 15 LUCCINI ET AL.: ULTRAVIOLET CLIMATOLOGY OVER ARGENTINA D17312 D17312 [30] A small systematic difference appears at this point given that the measurements correspond to the average over 30 min, while calculations are for the instantaneous local solar noon giving systematically higher values. This difference, verified for the clear-sky case, is of less than 1% and therefore negligible within the involved uncertainties. [31] Similarly, the percentage difference of the satelliteM derived (DM S ) with respect to the ground-measured (DG ) monthly mean erythemal daily dose at a given station for month M is M DS DM G DSGM ¼ 100x D DM G Figure 5. (top) Percentage difference of the satellitederived monthly mean UV index for SSE case 2, with respect to that measured from the ground at the stations, numbered as in section 1, throughout the year. (bottom) Annual mean percentage difference for SSE case 1 (gray symbols) and for SSE case 2 (black symbols) at the stations as a function of latitude and variability at the level of 2 standard deviations. 2003]. As mentioned, part of this difference is due to the smaller Earth-Sun distance around the SH summer solstice. Also in the daily dose the geographical resolution of calculations yields significant differences to climatologies with lower resolution. As an example, the global climatology by Pubu and Li [2003], at a resolution of 1 1.25, underestimates the monthly mean values of erythemal daily dose by above 20% in the NAP. 3.3. Validation and Uncertainty Analysis [29] Monthly means of the UV measurements at the stations were taken as a reference to validate the satellitederived climatologies and estimate its uncertainty. Comparison was made with the calculated values at the closest grid point to each station. The percentage difference of the ) with respect to the groundsatellite-derived (IM,noon S ) monthly mean UVI at a given station measured (IM,noon G for month M is given by DSGM I ¼ 100x ISM ;noon IGM ;noon IGM ;noon ! ð4Þ ð5Þ [32] Tests of uncertainty were made for the two cases of SSE cloud cover data. SSE case 2 showed the smaller uncertainties and is emphasized. In Figure 5 the uncertainty in the calculation of UVI is analyzed. Figure 5 (top) shows DSGM I for SSE case 2 at the stations during the year. A slight tendency is noted in the calculated values to underestimate the measured monthly means, with the largest difference of 23% in April at station 6 (San Julián). This is more evident in Figure 5 (bottom), where the annual average of DSGM I at the stations for SSE cases 1 and 2 is shown as a function of latitude and SSE case 2 is highlighted. Variability is shown at the level of 2 standard deviations (2s). The largest annual mean biases for SSE case 2 are noted at station 1 (6 ± 6%), station 5 (11 ± 8%) and station 6 (12 ± 12%). In turn, the largest variability is observed at station 7 (1 ± 14%). It must be noted that Patagonian stations 5 and 6 show an important negative bias with respect to central stations 2, 3 and 4 and southern station 7. As pointed out by Cede et al. [2002a], a possible underestimation of the TOMS albedo climatology may also be considered for this region, which could reduce this difference by about 3 to 6%. Biases are just a little larger than those found by Cede et al. [2004] for the same stations from daily TOMS Level 2 – derived erythemal irradiance at overpass time. This is expected given that Level 2 ozone and reflectivity overpass data have higher precision for TOMS calculations, and the retrieved information represents accurately the instant of measurement. Biases for summer months are of similar magnitude but generally of opposite sign than those found from comparison between daily TOMS Version 8 – derived and Brewermeasured UVI for summer months over the United States and Canada [Fioletov et al., 2004]. [33] In Figure 6 the uncertainty in the calculation of the erythemal daily dose is analyzed. Upper panel presents DSGM D for SSE case 2 at the stations during the year, and bottom panel the annual average of DSGM D as a function of latitude, where SSE case 2 is highlighted over SSE case 1 which showed a systematic overestimation of the satellitederived daily dose and also a larger dispersion. The highelevation tropical station 1 (La Quiaca) presents a very small annual mean bias and variability of +1 ± 5%. On the other hand, annual mean bias and variability are largest at the southernmost station 7 (Ushuaia), reaching +10 ± 20%. The DSGM D obtained by the present method are in close agreement with those found by Cede et al. [2004] from daily TOMS Level 2 – derived erythemal daily dose for 10 of 15 D17312 LUCCINI ET AL.: ULTRAVIOLET CLIMATOLOGY OVER ARGENTINA D17312 3.4. Effect of Clouds on the Erythemal Irradiance [36] The calculation given by 100x M ;noon Ics;S ISM ;noon M ;noon Ics;S ! M ;noon ¼ 100x 1 T010 F010 M ;noon M;noon þ T1070 F1070 þ T70100 F70100 ð6Þ Figure 6. (top) Percentage difference of the satellitederived monthly mean erythemal daily dose for SSE case 2, with respect to that measured from the ground at the stations, numbered as in section 1, throughout the year. (bottom) Annual mean percentage difference for SSE case 1 (gray symbols) and for SSE case 2 (black symbols) at the stations as a function of latitude and variability at the level of 2 standard deviations. stations 1 to 6, and it is noticeable that the systematic negative differences observed by Cede et al. [2004] at station 7 due to the underestimation of surface UV albedo by the TOMS albedo climatology were solved here through the ‘‘mean’’ albedo correction detailed in section 2.3. Biases for station 7 are now similar to those for the central lowalbedo stations. [34] Calibrated ground measurements from other stations like Mendoza (32.88S, 68.87W, 704 m a.s.l.) [see Cede et al., 2002a] and from the neighboring countries are currently being collected to extend the validation of the determined climatologies. [35] It is important to emphasize that this method applies directly to the determination of monthly mean UVI and erythemal daily doses. Therefore the deviations found between calculated and measured monthly mean values at the stations are related to those from other satellite methods based on daily retrievals (like TOMS UV reflectivity method) in a direct form, if simplifying conditions like normal distributions are assumed [e.g., Baird, 1995]. where IM,noon is the monthly mean clear-sky erythemal cs,S irradiance at noon, represents the monthly mean percentage attenuation of noon erythemal irradiance by clouds. Figure 7 shows the maps of the percentage of the clear-sky noon erythemal irradiance that is attenuated by the cloudiness throughout the region in January, April, July and October. [37] Maps of cloud attenuation of the erythemal daily dose are in close qualitative and quantitative agreement with those for noon erythemal irradiance. This is expected given that most of contribution to the daily dose is given in hours around the local solar noon. It is interesting to note that the attenuation by clouds of the clear-sky noon erythemal irradiance and erythemal daily dose is always below 30% throughout the whole region. Even more, for most of the continental and densely populated region the attenuation is generally of less than 20%. In terms of the UV index, this implies that cloudiness attenuates, on an average, less than 3 UVI units in the whole region during the year. The maximum attenuation (over 25%) occurs in the Andean Southwest, Patagonia and Atlantic Southeast regions, where predominant southwesterly winds generate a larger cloudiness percentage (see Figure 2). On the other extreme, the smallest attenuation (below 15%) occurs on the NAP, where the partial cloud cover predominates [Cede et al., 2002c] (see Figure 2). These results are in very close agreement with the monthly mean cloud attenuation of UVB daily doses from the global UV climatology by Sabziparvar et al. [1999] for this region. From that work, it can be observed that the attenuation of less than 15% over the NAP is within the smaller cloud effect in the SH, similar to the values over Australia. [38] In order to study the cloud effect behavior through daylight hours, the average effective cloud transmittance M,h M,h given by T0 – 10FM,h 0 – 10 + T10 – 70F10 – 70 + T70 – 100F70 – 100 for every hour h within each month M was calculated for day 1 of each month from the SSE database and compared with that resulting from the statistics of all 30 min of irradiance measurements at the stations. For this purpose, the ratio of measured (under all-sky conditions) to clear-sky erythemal irradiance was established for each data. Measurements for SZA < 70 were selected, as uncertainty increases substantially for larger SZA [Cede et al., 2002a]. The reference clear-sky erythemal irradiance was calculated using the TOMS EarthProbe daily total ozone column, and the monthly mean albedo and aerosol parameters at the stations detailed in sections 2.3 and 2.4, respectively. Results are shown in Figure 8, where time around 1300 local time (LT) corresponds to local solar noon. It is interesting to note that in every station the SSE-derived average cloud transmittance does not vary more than about 10% throughout the year at all daylight hours. The SSE-derived and the mea- 11 of 15 D17312 LUCCINI ET AL.: ULTRAVIOLET CLIMATOLOGY OVER ARGENTINA D17312 Figure 7. Maps of the monthly mean percentage attenuation of the noon erythemal irradiance by clouds for January, April, July, and October in Argentina, from the satellite-derived calculations at a geographical resolution of 0.5 0.5. sured average cloud transmittance at the stations show a significant agreement. Average cloud transmittance is rather homogeneous throughout the year for every hour, confirming the fact that similar cloud attenuation was found for noon irradiance and for daily dose. Even though quantita- tive SSE-derived and measured values agree for all the stations, some major qualitative difference in the hourly course of average transmittance is observed at station 1 (La Quiaca). As mentioned in section 3.1, in the NAP high clouds with smaller optical depth predominate and then the 12 of 15 LUCCINI ET AL.: ULTRAVIOLET CLIMATOLOGY OVER ARGENTINA D17312 D17312 Figure 8. Average cloud UV transmittance as a function of local time during daylight for all months from SSE cloud data at the stations (gray lines), compared with the measured average cloud transmittance from 30-min measurements for SZA < 70 throughout the year (black lines). The maximum and minimum numbers of measurements averaged at their corresponding hours for each station are given in parentheses. Local solar noon is around 1300 LT. measured transmittance overestimates that of SSE. On the other hand, most of medium-altitude clouds in the NAP are broken cumulus, which may have a major influence in the UV attenuation for large SZA, effect that is evident in the measurements on firsts and lasts daylight hours at La Quiaca, but is not observed from the satellite. 4. Conclusions [39] The climatologies of UV index and erythemal daily dose were established for Argentina on the base of clear-sky UV calculations with monthly average input parameters on a radiative transfer model and correction for the mean attenuation by cloudiness. The studied region includes also part of Uruguay, south of Brazil, Paraguay, Bolivia, Chile and the South Atlantic Ocean. TOMS and SSE climatologies provided key parameters for the calculations. Two cases of SSE cloud cover data were tested. Case 1 consists of monthly averages of total cloud cover, while case 2 consists of monthly averages for three ranges of cloud cover percentage (0 – 10%, 10 – 70% and 70 – 100%), every 3 hours (at 0000, 0300, 0600, 0900, 1200, 1500, 1800 and 2100 UT). Case 2 was selected as it showed the smaller biases with respect to the ground measurements, making evident that counting with more cloud information improves 13 of 15 D17312 LUCCINI ET AL.: ULTRAVIOLET CLIMATOLOGY OVER ARGENTINA substantially the precision of calculations. Maps of monthly mean UVI and erythemal daily dose were obtained at a 0.5 0.5 high geographical resolution, which allows observation of important local-scale details in areas with large gradients in the radiation values, as is the case for the Andes Mountains. Monthly mean levels as high as UVI over 18 and erythemal daily dose over 10 kJ/m2 were determined around January in the NAP, highlighting the need to take rigorous protective measures against the excessive sun exposure for the dense population in this region. Even low-elevation northern areas have monthly mean UVI and erythemal daily doses above 12 and 7 kJ/m2, respectively. Satellite-derived climatologies were validated against the erythemal irradiance measured at seven stations of the Argentine UV Net. Annual mean biases between satellite-derived and ground-measured UVI and erythemal daily dose were mostly within ±10%. Average attenuation of both the clear-sky erythemal irradiance at noon and daily dose by clouds is below 20% for most of the continental and densely populated zones throughout the year. Hourly course of the SSE-derived average cloud attenuation during daylight is very homogeneous, with variations of less than 10% throughout the year. It agrees rather well with the average cloud attenuation derived from all-sky measurements at the stations of the UV Net. [40] It is interesting to underline that unlike other satellite methods based on daily UV retrievals to calculate the monthly averages (see, e.g., Arola et al. [2002] and satellite algorithms cited in section 1), this new method determines directly the monthly mean UV irradiance and daily dose, using only long-term monthly averaged input parameters in both the clear-sky (ozone, aerosols and albedo) and cloud attenuation calculations. The geographical resolution of calculations is defined by the surface elevation grid. We have demonstrated in this study that working with a surface elevation grid of 0.5 0.5, calculations based on interpolated TOMS and SSE input data produced reliable results over an extended area of South America. The only additional parameter necessary to apply this method is the average effective cloud transmittance for all-sky case as a function of the cloud coverage. There are large networks in the world where the average effective cloud transmittance has already been determined, for example, by Long et al. [1996] at 21 sites in the United States, and also in other smaller networks and individual sites [see Calbó et al., 2005]. At these sites the applicability of this method is immediate. In turn, given that complementary maps of input parameters are currently available (e.g., ozone and albedo from TOMS, aerosols from MODIS, and clouds from SSE), accurate maps for large regions may be established if a surface elevation grid of high geographical resolution is available. [41] This work provides a detailed reference on the typical UV irradiance and doses in the region, to be used in multidisciplinary studies on the effects of solar UV radiation on public health, biological systems, environment and materials. [42] Acknowledgments. This work was supported by the Argentine Consejo Nacional de Investigaciones Cientı́ficas y Técnicas (CONICET), Ministerio de Educación Proyecto FOMEC 142, Servicio Meteorológico Nacional and Fundación del Cáncer de Piel, and by the World Meteorological Organization. Special thanks are given to Dan Lubin for providing D17312 the data files of the ‘‘global surface ultraviolet radiation climatology from TOMS and ERBE data,’’ to Fran McLemore and Kathleen Morris of the NASA Langley Research Center Atmospheric Sciences Data Center for their advice in the use of the SSE database, to Cristina Pacino of the Facultad de Ciencias Exactas, Ingenierı́a y Agrimensura, Universidad Nacional de Rosario (in agreement with the Instituto Geográfico Militar de Argentina), for providing the elevation grid data, and to Pablo Garcı́a of the Observatorio Astronómico de Rosario and Miguel Parodi of IFIR-UN Rosario for their collaboration in this work. References Alados-Arboledas, L., I. Alados, I. 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