CP CHEMISTRY Periodic Table Review 1. Answer Key Development of the Periodic Table Scientist Contribution to Periodic Table John Newland Arranged elements by increasing atomic mass, found repeating pattern every 8 elements, law of octaves Dmitri Mendeleev Arranged elements by increasing atomic mass, made accurate predictions about properties of missing elements, published work first – so gets credit for developing the first periodic table Henry Moseley Arranged elements by increasing atomic number which corrected problems with Mendeleev’s table (elements out of order based on properties), his revisions lead to periodic law 2. What is the periodic law? A periodic repetition of chemical and physical properties of the elements is observed when they are arranged by increasing atomic number. 3. What are the columns in the periodic table called? 4. What are the horizontal rows called? periods 5. What are the representative elements? Groups 1A to 8A 6. What are the transition elements? all Group B elements 7. What are the properties of the metals? shiny, good conductors, solid at room temperature, ductile and malleable most elements are metals 8. What are the metalloids? found on stair step line (except Al), have chemical and physical properties of both metals and nonmetals groups/families CP CHEMISTRY, Periodic Table Review, page 2 9. What are the properties of the nonmetals? generally gases or brittle, dull solids, poor conductors of heat and electricity 10. What are most elements classified as? metals 11. What are the differences between valence electrons and core electrons? core electrons – found in the lower orbitals of an atom close to the nucleus, are NOT involved in chemical reactions valence electrons – found in highest principal energy level orbitals, are the outer electrons of the atom, involved in chemical reactions and contribute to the element’s chemical properties, electrons in s and p orbitals 12. Why do elements found in the same group have similar chemical properties? they have the same number of valence electrons and similar end electron configurations 13. What does the period tell about an atom’s valence electrons? period = energy level of the valence electrons 14. What does the group number tell about an atom’s valence electrons? group # = # of valence electrons 15. Identify which elements are found in the following blocks on the table. Block s p Elements found in block Group 1A (alkali metals) and Group 2A (alkaline earth metals), last electrons go in s orbitals Groups 3A – 8A, last electrons going into p orbitals d B Groups – Transition metals – last electrons going into d orbitals, have valence electrons in s orbitals f Inner Transition metals at bottom of table – last electrons going into f orbitals, have valence electrons in s orbitals CP CHEMISTRY, Periodic Table Review, page 3 16. What is the trend for atomic radii as you move across a period? Why? Atomic Radius Decreases – each electron added going into same energy level so added protons in nucleus pull them in more tightly 17. What is the trend for atomic radii as you move down a group? Why? Atomic Radius Increases – electrons going into higher energy levels so size of atoms are increasing and core electrons shield the valence electrons from the pull of the protons in the nucleus 18. What happens to the size of the radius when an element’s atoms lose electrons? Why? when atom loses electrons – pulls remaining electrons in closer, so positive ions are smaller than original atoms 19. What happens to the size of the radius when an element’s atoms gain electrons? Why? when atom gains electrons – more negative charges repulse each other, so negative ions are larger than original atoms 20. What is the octet rule? Atoms tend to gain, lose, or share electrons in order to acquire a full set of 8 valence electrons. (Fill s and p orbitals) 21. What kind of ions do metals form? lose electrons, positive ions 22. What kind of ions do nonmetals form? gain electrons, negative ions 23. Give the charge on the ions formed by Groups 1A through 8A. Group 1A – 1+, Group 2A – 2+, Group 3A – 3+, Group 4A – shares, Group 5A – 3-, Group 6A – 2-, Group 7A – 1-, Group 8A - nothing CP CHEMISTRY, Periodic Table Review, page 4 24. What is ionization energy? What is first ionization energy? Energy needed to remove an electron from a gaseous atom. First ionization energy is the energy needed to remove the first electron from an atom. 25. What is the trend for first ionization energy as you move across a period? Why? Ionization Energy Increases – Atoms are smaller in size and hold onto electrons more tightly as well as having fuller valences so harder to remove valence electrons 26. What is the trend for first ionization energy as you move down a group? Why? Ionization Energy Decreases – Atoms become larger as move down group so valence electrons are in higher energy levels and with more core electrons around nucleus are shielded from the pull of protons so it becomes easier to pull off electrons 27. What is electronegativity? It indicates the relative ability of the atom to attract electrons in a chemical bond. (Note – Noble gases do not react and do not form bonds, so they are not considered to have electronegativities.) 28. What is the trend for electronegativity as you move across a period? Why? Electronegativity Increases – atoms have fuller and fuller valences as you move across a period so they pull on electrons more tightly to achieve an octet 29. What is the trend for electronegativity as you move down a group? Why? Electronegativity Decreases – atoms become much larger and have higher energy level valences, so due to shielding they do not hold onto the electrons in a bond as tightly as smaller atoms do