Countertop Chemistry from The Science House Experiment #11 Double Replacement Reactions This experiment demonstrates reactions that occur between two aqueous solutions. The driving force for the reaction is the formation of an insoluble product. Substitutions Materials 0.1 M NaCl C 0.1 M CuSO4 C 0.1 M AgNO3 C 0.1 M Na3PO4 C 0.1 M NaOH C Spot plate C Droppers (5) C watch glasses (6) I II NaCl (aq) CuSO4 (aq) NaOH (aq) CuSO4 (aq) IV NaCl (aq) AgNO3 (aq) V NaOH (aq) AgNO 3 (aq) III Na 3PO4 (aq) CuSO 4 (aq) VI Na 3PO4 (aq) AgNO 3 (aq) Procedure 1. Number wells 1-6. Place 10 drops of NaCl solution in wells I and IV, 10 drops of NaOH in wells II and V, and 10 drops of Na3PO4 in wells III and VI. 2. Using the diagram above, add 10 drops of CuSO4 to wells I, II, and III and 10 drops of AgNO3 to wells IV, V, and VI. 3. Note any color changes or precipitate formation in the Data section. This work by The Science House is licensed under a Creative Commons AttributionNonCommercial-ShareAlike 3.0 Unported License. http://creativecommons.org/licenses/by-nc-sa/3.0/ Countertop Chemistry from The Science House Experiment #11 4. Write a balanced equation for the reactions that occur. Include physical state symbols for the reactants and products. If no precipitate occurred, NO REACTION occurred. Data and Observations Well I. Well II. Well III. Well IV. Well V. Well VI. This work by The Science House is licensed under a Creative Commons AttributionNonCommercial-ShareAlike 3.0 Unported License. http://creativecommons.org/licenses/by-nc-sa/3.0/ Countertop Chemistry from The Science House Experiment #11 Teacher's Notes I. NaCl (aq) + CuSO4 (aq) -------> No Reaction. II. 2NaOH (aq) + CuSO4 (aq) -------> Na2SO4 (aq) + Cu(OH)2 (s) III. Na3PO4 (aq) + CuSO4 (aq) -------> No Reaction IV. NaCl (aq) + AgNO3 (aq) -------> NaNO3 (aq) + AgCl (s) V. NaOH (aq) + AgNO3 (aq) -------> NaNO3 (aq) + AgOH (s) VI. Na3PO4 (aq) + AgNO3 (aq) -------> 2NaNO3 (aq) + Ag3PO4 (s) Disposal All solids should be collected into a labeled waste solid container. Aqueous solutions can be flushed down the drain in the quantities suggested here. This work by The Science House is licensed under a Creative Commons AttributionNonCommercial-ShareAlike 3.0 Unported License. http://creativecommons.org/licenses/by-nc-sa/3.0/