Earth’s Building Blocks 1: Igneous Rocks Atoms/ elements As stated in the last couple lectures, atoms of elements bond together to form minerals. minerals Solid aggregates of minerals (and some other things) are what we call ROCKS.” rocks Just as minerals are the “building blocks of rocks” of the geosphere, rocks are the basic “building blocks” of the geosphere. rocks geosphere 1 Basic Classification of Rocks Rocks are classified into three main categories (igneous, sedimentary and metamorphic) based on the mode of their origin (i.e. in terms of the geological processes that form them). In addition there are rock types which combine features of two of the three main types (pyroclastic and diagenetic rocks and migmatites). For the most part, we will focus on the three main categories in this course. Igneous Pyroclastic (I-S) Sedimentary Diagenetic (S-M) Metamorphic Migmatites (M-I) Igneous Rocks 2 How Are Igneous Rocks Formed ? The term “igneous” is derived from the Latin ignis = “fire” As indicated by their name, igneous rocks are formed from hot material. The hot, molten, parent material of igneous rocks is called magma. Magma generally is comprised by the following components: 1) Liquid (“melt”) which corresponds to molten, non-volatile mineral matter. 2) Gases (“volatiles”) of various sorts including water vapour and carbon dioxide (these stay in the magma at depth due to high confining pressures). 3) As magma cools it will also begin to contain small mineral crystals. Lava is magma that has erupted onto the Earth’s surface. Where Does Magma Come From ? Magma is generated by the partial melting of pre-existing rock in Earth’s crust and mantle. The source of the heat energy required to melt the rock is derived largely from the decay of radioactive materials in the core. Consequently, as a general rule, temperature increases with increasing depth in Earth’s lithosphere. Pressure also increase with increasing depth (more material on top, pushing down). Increased temperature acts to melt rock but increased pressure, counteracts the melting effect of higher temperatures (atoms in the magma are pushed closer together, tending to forms solids). The melting point of a rock will consequently tend to increase with increasing depth. So how can rocks be melted ? 3 One way: Decompression Melting (allowing atoms to move more freely) In places where hot, near-liquid, material of the asthenosphere is allowed to rise toward Earth’s surface, the pressure acting on this material is lowered (lower pressure closer to surface). Lithosphere This material, still very hot (thermally buoyant), but is under less pressure. Reduction of pressure allows the material to be completely molten. Asthenosphere This magma-forming mechanism typically occurs where lithospheric plates are moving apart (e.g. at mid ocean ridges or rifts). Another way: Hydration-Related Melting (wet rocks melt easier than dry rocks) In some places on Earth, one lithospheric plate is pushed under another. This process is known as subduction. Note that the crust underlying the oceans (oceanic crust) contains lots of water. As the plate descends, it is heated, and releases the water in the form of vapour (dehydrates). The vapour then hydrates the rock in the asthenosphere. Dehydration and metamorphic changes in the rock at depth lower its melting point, allowing it to melt into magma. 4 What Happens to the Magma ? volcanoes volcanic fissures Lithosphere magma chambers Asthenosphere Magma, now a mixture of liquid melt and gas, is less dense (therefore more buoyant) than the rock from which is was derived and possibly also from the predominant rock of its surroundings (“country rock”). As a result, the magma will rise to a point at which its buoyancy is neutralized (density equalized) or where it can not proceed farther due to an obstruction. Unless it comes to the surface, magma will collect in large subterranean pockets known as “magma chambers” or “plutons”. When magma reaches the Earth’s surface, the development of volcanoes is the usual result. Crystallization Below the Surface Now closer to the surface than before, the magma starts to cool, allowing minerals to crystallize from chemical components of the melt. If magma remains trapped in a magma chamber, it cools very slowly (the magma is completely surrounded by rock and dissipation of heat from the magma occurs at a very low rate), allowing the crystals to grow to large sizes. 5 Intrusive Igneous Rocks Rocks that form from the cooling of magma below the surface are commonly called plutonic igneous rocks (named after Pluto, Roman god of the underworld). Because they are formed from magma intruded into preexisting rocks of the crust, they are also called intrusive igneous rocks. Depending on the characteristics of the rocks into which magma is intruded, intrusive bodies can assume different shapes and sizes Batholith Magma can be intruded as big blobs (batholiths, laccoliths) or sheet-like bodies (vertical dykes and horizontal sills) into pre-existing layered rocks. The resulting intrusive rock bodies can be exposed at the surface if erosion removes the overlying “country rock” (the rock into which the bodies were intruded). 6 Batholith: Very large mass of igneous rock (usually formed at depth) formed from cooling of one or more large intrusions. Dyke: A tabular-shaped igneous body oriented at a significant angle to layers of pre-existing rocks. Sill: A tabular-shaped igneous body intruded parallel to layers of pre-existing rocks. Laccolith: A blister-like igneous body (usually shallow) that has produced some upwarping of overlying layers. Batholith Volcanic neck: The remnant of igneous material that once occupied the vent of a volcano. The Aesthetic Beauty of Igneous Intrusions The awesome landforms in Yosemite Valley, California were naturally carved by erosion from igneous intrusions that comprise the enormous Sierra Nevada Batholith. Intrusions were emplaced between 120 and 90 million years ago. Yosemite Valley These landforms were featured prominently in the photographs of Ansel Adams (1902-1984). 7 Photographs of Ansel Adams “Monolith – The Face of Half Dome, Yosemite National Park, California, 1927” “El Capitan, Winter Sunrise Yosemite National Park, 1968” Igneous Intrusions and the Group of Seven The smooth, glacially scoured and weatherworn exposures of much older igneous intrusions (well over 1.5 billion years old) north of Georgian Bay deeply inspired the Group of Seven particularly A.Y. Jackson and Tom Thomson. This type of landscape occurs throughout Canadian Shield A.Y. Jackson “Night, Pine Island” 1924 8 Texture of Plutonic/Intrusive Igneous Rocks Because intrusive igneous rocks cool below Earth’s surface, mineral crystals have ample time to grow. As a result, the mineral crystals of intrusive igneous rocks are large enough to be observed with the unaided eye. The result is what is termed a phaneritic texture. (Greek; phaner = visible, apparent) Example of phaneritic texture Plutonic/Intrusive Igneous Rocks: Uses Phaneritic igneous rocks, particularly granites and granitoids are commonly used in facing stones of buildings, headstones, expensive countertops, and stone carvings due to their attractive “salt and pepper” appearance. 9 Extrusive Igneous Rocks Rocks that form from the cooling of magma above the surface are commonly called volcanic igneous rocks (named after Vulcan, Roman god of Fire, Blacksmiths (the forge) and Craftsmanship (particularly of the weapons of war)– equivalent to Greek god Hephaestus). As volcanic rocks are formed from magma that has come out of the ground (i.e. that has extruded from the ground), they are also called extrusive igneous rocks. Depending on the characteristics of the magma, and conditions at the surface, a number of features may result. Lava Lava is extruded from a volcanic vent due to the expansion of volatiles as the magma approaches the surface. This expansion is due to the relatively rapid decrease in confining pressure close to the surface (similar to what happens when you open a pop bottle that has been shaken). 10 Types and Nature of Eruptions Several types of volcanic eruptions are recognized. The nature of a lava eruption will depend upon its temperature, the composition and resultant physical properties of the melt and volatile content of the magma (we will discuss this in greater detail later in the term). Lava can be extruded quietly… …or violently Volcanic/Extrusive Igneous Textures: Aphanitic Extrusive igneous rocks cool above Earth’s surface and consequently, mineral crystals have little time to grow (due to lack of insulation at the surface, dissipation of heat occurs rapidly). As a result, the mineral crystals of extrusive igneous rocks are generally too small to be observed with the unaided eye. The result in most extrusive igneous rocks is what is termed a aphanitic texture. (Greek; a= not, phaner = visible, apparent) andesite Magnified about 30 x under crosspolarized light 11 Volcanic/Extrusive Igneous Textures: Porphyritic In some cases, a magma will cool slowly at depth and then travel rapidly toward the surface where it will cool at a higher rate. This two-stage cooling can result in a rock that has aphanitic matrix, but contains some large crystals called phenocrysts (apparent crystals). The resulting texture is called a porphyritic texture. Igneous rock showing porphyritic texture Volcanic/Extrusive Igneous Textures: Glassy In some instances, lava solidifies too quickly for any significant crystallization to occur. Unordered ions remain essentially “frozen” before they can unite to form crystals. The result is a glassy texture. 30 x magnification, cross-polarized light Obsidian is a common rock exhibiting such a texture. 12 Volcanic/Extrusive Igneous Textures: Glassy Obsidian was a valuable material for making arrow and spear points and cutting tools due to the sharp edges produced when knapped (intersecting conchoidal fractures). Volcanic/Extrusive Igneous Textures: Vesicular glassy Pumice is another volcanic glass (the result of nearly instant cooling). The macroscopic texture of pumice differs considerably from obsidian, being highly porous. The pores, known as vesicles represent areas where volatiles (gas bubbles) were trapped in the original magma. Pumice is highly frothy (mostly air) due to the speed with which it was erupted and cooled. Most varieties float on water as a result. Pumice is commonly used as an exfoliant. When broken, the glassy vesicular walls of pumice are very sharp – ideal for removing loose flakes of skin. Natural pumice “Pumice stone” Pumice floating in water 13 Volcanic/Extrusive Igneous Textures: Vesicular Vesicular igneous rocks have been used to make various implements in many cultures due to the good grinding surface provided by the holes. For example the familiar mortar (molcajete) and pestle (tejolote) used in traditional Latin American cooking-formerly used for grinding corn, but now used mostly for the grinding of spices and preparation of moles (sauces/stews) and salsas are made from the extrusive rock basalt. Volcanic/Extrusive Igneous Textures: Pyroclastic Lava is not the only material produced by volcanoes. Eruptions that are exceptionally violent can eject dust-sized particles (ash) to fist- or even carsized bodies (volcanic bombs). These particles include blobs of molten material (consolidate in flight) and pulverized bits of rock. Rocks composed of this fragmented material are said to have a pyroclastic texture (Greek; pyro= fire, klastos= broken) A rock showing pyroclastic texture (note large angular fragments of rock surrounded by fine-grained ash) 14 Volcanic/Extrusive Igneous Textures: Pyroclastic An item of cultural significance: The fine-grained pyroclastic debris (ash) generated by the eruption of Mount Vesuvius buried the residents of Pompeii,Italy in 79 AD, preserving an unparalleled record of the culture of that time. The ability of pyroclastic rocks to preserve “organic remains” in this manner and the layered nature of their deposits are among the most significant similarites between pyroclastic and sedimentary rocks. Back to Minerals (for a minute) Most igneous rocks are principally made of silicate minerals (although other types of minerals do occur in smaller quantities). As their name implies, silicate minerals all contain the elements silicon (Si) and Oxygen (O). Silicates other than the quartz group also contain one or more metals in their chemical makeup. Most silicates are based on the silica tetrahedron (central silicon, surrounded by 4 oxygen atoms as shown). Typical Silicate ion. (small blue ball: silicon; “charge”= +4) (large balls: oxygen; “charge”= -2X4= -8) Note:only one bond of each oxygen atom are connected to the silicon, so silicate molecule (ion) has a net –4 charge. 15 Ferromagnesian Minerals Among the most important silicate minerals used in the identification of igneous rocks are the ferromagnesian minerals. Ferromagnesian minerals are those silicate minerals containing iron (indicated by the “ferro” part of the name) and magnesium (indicated by the “magnesian” part of the name). Due to their iron/magnesium content, they are dark in colour (green, brown or black). The main ones are: Olivine Pyroxene (Mg,Fe)2SiO4 (Mg,Fe)SiO3 Amphibole Biotite Mica Ca2(Mg,Fe)5Si8022(OH)2 K(Mg,Fe)3AlSi3O10(OH)2 Note: you need not remember chemical formulae- but do remember the names Ferromagnesian Minerals These minerals can have isolated silica tetrahedra or have silica tetrahedra linked into chains or sheets, forming “structural units” of silica. These “units” are ionically bonded with metal ions (mainly iron and magnesium-silicate ion has strong negative charge, metals have positive charges) to form the ferromagnesian minerals. Strong silicate chains may be formed due to covalent bonding of the silica tetrahedra. Planes of weakness in the mineral structure relate to regions across which relatively weak ionic bonding occurs, between silicate structural units (e.g. in micas). Due to variation in the the geometry of ionic bonds as well as the stacking arrangement of silica units, varieties of ferromagnesian mineral vary in such characteristics as cleavage. 16 Ionically Structural units of silica bonded with positive (SiO4)4 metal ions Mg2+, Fe 2+ Mg2+, Fe 2+ Ca2+, Mg2+, Fe 2+ Make the ferromagnesian mineral… Olivine (no cleavage) Pyroxene (2 cleavages at 90o) Amphibole (2 cleavages at 120oand 60o) K+, Mg2+, Fe 2+, Al3+ Biotite Mica (1 cleavage) Weak ionic bonding between structural units is responsible for cleavage. Quartz Quartz, the second most common mineral type in igneous rocks, is the only common igneous silicate mineral consisting entirely of silicon and oxygen. Because of the complete sharing of electrons by oxygen by adjacent silicon atoms, all of the bonds (covalent) in quartz are equally strong. As a consequence, quartz is structurally quite homogeneous and does not exhibit cleavage. It fractures conchoidally. Pure quartz is clear and colourless. 17 Feldspar Minerals Feldspar is the most common mineral group, forming under a very wide range of temperatures and pressures. Like quartz, the structure of feldspar minerals is basically a three dimensional framework of silica units with aluminum atoms substituting for some of the silicon atoms. To offset the net negative charge of the silica-dominant framework, ions of sodium (+1), calcium (+2) or potassium (+1) are incorporated into the structure. Bonds are less uniform in strength than in quartz similar to condition in amphiboles and pyroxenes. Cleavage planes (2 at right angles) mark planes along which bonding is weakest. Feldspar Minerals The two most common types of feldspar are plagioclase and potassium feldspar: 1. Plagioclase contains ions of sodium and/or calcium. Colour ranges from white to bluish grey. 2. Potassium feldspar, contain ions of potassium. Colour ranges from creamy white to salmon pink. Plagioclase Both mineral groups have two sets of cleavage meeting at 90o, reflecting the same pattern of bonding weakness within the crystal structure of the feldspar mineral group. Potassium feldspar 18 Why Aren’t All Igneous Rocks Just Made of One Mineral ? Different minerals crystallize at different temperatures. Thus, as a magma cools, minerals crystallize in a distinct sequence (expressed as Bowen’s Reaction Series). High temperature The ferromagnesium minerals remain distinct in terms of their composition at different temperatures. Thus they crystallize in a discontinuous sequence. Plagioclase changes gradually in composition with changing temperature (six different minerals within the series). Thus, plagioclase crystallizes in a continuous sequence. Low temperature Why Aren’t All Igneous Rocks Just Made of One Mineral ? Note that during each stage in cooling, the resulting rock will preserve a different suite of minerals. 19 Igneous Rock Types: Composition On a very basic level, the composition of igneous rocks can be estimated on the basis of colour. Mafic rocks: Igneous rocks containing a high concentrations of dark minerals (especially ferromagnesian minerals) are called mafic rocks (“ma” referring to magnesium and “f” referring to ferrum or iron). These rocks are generally very dark in colour. Felsic rocks: Igneous rocks that contain small amounts of dark minerals (especially ferromagnesian minerals) are called felsic rocks (“fel” referring to the abundance of light-coloured feldspar, and the “si” referring to silica (quartz)). These rocks are generally light in colour. Intermediate rocks: These are rocks that have a colour in-between mafic and felsic. Mafic igneous rock Felsic igneous rock Intermediate igneous rock Why Igneous Rock Names are Important Note that the terms “felsic,” “intermediate,” and “mafic” only reflect the composition of an igneous rock. They do not indicate anything about texture. Specific names are applied to rocks to make communication easier among geologists (but it does take a bit of getting used to). A rock name is extremely informative as it tells something about a rock’s composition and texture (without the user having to spell out the details every time he/she refers to that specific rock). 20 Naming igneous rocks Here is a very basic scheme on how 6 common igneous rock names relate to their composition and texture. composition Mafic Intermediate Felsic (dark coloured) (“medium”-coloured) (light coloured) Name: Gabbro Name: Diorite Name: Granite Name: Basalt Name: Andesite Name: Rhyolite texture Phaneritic (large crystals) Aphanitic (very small crystals) Igneous Rocks and Plate Tectonics Not all magmas have the same composition. This is partly because of differences in their environment of formation. Magmas produced by hydration tend to be formed at lower temperatures than those produced by decompression melting. Under relatively low temperatures, low-temperature felsic minerals are preferentially melted, enriching the magma in silica. As a result, magmas produced at subduction zones tend to be felsic to intermediate in composition. volcanoes magma chambers Extrusive igneous rocks: rhyolite and andesite Intrusive igneous rocks: granite and diorite 21 Igneous Rocks and Plate Tectonics In contrast, magmas generated by decompression melting of the mantle (in places where plates are spreading apart) are produced by the melting of both low and high temperature minerals, and therefore have a more mafic composition (i.e. the magma contains silica, but also a large amount of iron and magnesium). volcanic fissures Extrusive igneous rock: basalt Lithosphere Intrusive igneous rock: gabbro Asthenosphere END OF LECTURE 22 Next on the agenda: sedimentary and metamorphic rocks 23