Note Taking Guide: Episode 1001 Name______________ Solutions • • • • • formed when substances ______________ in other ______________ _______________ mixtures _______________ phase remain _______________; particles do not _______________ out cannot be separated by _______________ • solvent: present in _______________ amount ____________ the ____________ to make the solution • solute: present in _______________ amount _______________ in the _______________ Examples of Types of Solutions LIQUID SOLUTIONS: _______________ solvent in which a __________ , _______________ , or _______________ is _______________ • _______________ dissolved in _______________: ex. ______________________________ • _______________ in _______________ ex. _______________ in water _______________: the two liquids mix _______________: the two liquids _______________ mix • _______________ dissolved in a _______________: ex. _______________ water SOLID SOLUTIONS: • _______________: solid mixtures of _______________ (_______________ is a mixture of _______________ and _______________) GAS SOLUTIONS: • gases dissolved in _______________ other (__________ is most common example) CHEMISTRY: A Study of Matter © 2004, GPB 10.1 Aqueous: _______________ is the _______________ Tincture: _______________ is the _______________ Suspension • • • • • a _______________ mixture Particles in the _______________ are thousands of times _______________ than _______________ and _______________ Particles will _______________ out upon _______________ can be separated by _______________ exhibit the _______________ _______________ --the _______________ of _______________ in all directions Colloid • • • • particles are _______________ in size between those of _______________ and true _______________ particles do not _______________ out upon _______________ can not be separated by _______________ exhibit the _______________ _______________ Emulsion • • _______________ dispersion of _______________ in _______________ _______________ agent is necessary for maintaining _______________ (________ is an example.) CHEMISTRY: A Study of Matter © 2004, GPB 10.2 Electrolyte: dissolves in water to form a _______________ that _______________ _______________ Nonelectrolyte: dissolves in water to form a _______________ that does _______________ conduct _______________ Factors Affecting the Rate of Solution 1) _______________ _______________ : increasing the surface area of the ___________ by ____________ speeds up _______________ by increasing the number of _______________ between the _______________ and the _______________ surface. 2) _______________: _______________ or _______________ helps to disperse solute particles, _______________ the number of _______________ between the _______________ and the _______________ surface. 3) _______________: increases the average _______________ _______________ of the solvent molecules so that _______________ between the solvent molecules and the _______________ are more _______________ The Chemistry Quiz CR1. _____ CR2. _____ 1. _____ 2. _____ 3. _____ 4. _____ CHEMISTRY: A Study of Matter © 2004, GPB 10.3 5. _____ Worksheet: Solutions Introduction Name______________ 1. Explain why solutions are classified as mixtures instead of compounds. 2. Solutions are ________________ mixtures made up of very small particles that are actually molecules, __________, or ________. 3. Solutions are said to be in a ______________ phase even though the components may have been in different phases before the solution was formed. 4. Pure gold is 24 carat. 14-carat gold contains 14 parts gold and 10 parts other metals. 14-carat gold is said to be a(n) ___________, which is a type of _______________ solution. An example of a gaseous solution is ________________, which is made up mostly of ______________ and nitrogen when dry. The most common solutions are ______________ solutions. 5. Define miscible: 6. Define immiscible: 7. Because of the _______________ _______________, you can see the light beams from car headlights in a fog. 8. Multiple choice: To increase the rate of solution of a solid in water, a. increase the pressure over the water. b. decrease the pressure over the water. c. crush the particles of the solid. d. chill the water. 9. If 15 grams of iodine are dissolved in 1000 mL of alcohol, the alcohol is the (solute, solvent) and the solution is said to be a(n) _______________. 10. A substance that dissolves other materials is a (solute, solvent). The substance being dissolved is a (solute, solvent). CHEMISTRY: A Study of Matter © 2004, GPB 10.6 11. In (solutions, suspensions) the substances separate after standing a while. The substances (can also, can not) be separated by filtration. 12. Smoke is an example of a _____________ of solid dirt and dust particles in air. After a while, the solid particles will fall to the ground. 13. A(n) ________________’s particles are between those of a solution and a suspension. 14. ________________ are actually colloids comprised of one liquid in another liquid. A(n) ______________ agent keeps the particles mixed. 15. What is an aqueous solution? 16. What is the solute in a brass alloy containing 75% copper and 25% zinc? 17. How does a solution behave differently from a suspension when a beam of light is shined through it? 18. Substances that conduct electricity when dissolved are said to be ______________, while substances that do NOT conduct electricity when dissolved are said to be __________________. CHEMISTRY: A Study of Matter © 2004, GPB 10.7 Note Taking Guide: Episode 1002 Name______________ Saturated: solution containing all the _______________ _______________ possible at given conditions of _______________ and _______________. Unsaturated: solution containing _______________ dissolved _______________ than the _______________ amount that can be _______________ at given conditions of _______________ and _______________. Supersaturated: unusual solution containing _______________ dissolved _______________ than is normally _______________ at given conditions of _______________ and _______________. Solubility A _______________ of how much _______________ can _______________ in a given amount of _______________ at a specific _______________. Dilute Solution: The amount of _______________ dissolved is _______________ in relation to the amount of _______________ present. Concentrated Solution: The amount of _______________ dissolved is _______________ in relation to the amount of _______________ present. CHEMISTRY: A Study of Matter © 2004, GPB 10.8 Factors Affecting Solubility 1) _______________ of _______________ and _______________: “_______________ dissolves _______________”. 2) _______________ generally, increasing the _______________ of the solution _______________ the solubility of a _______________ solute increasing the _______________ of the solution _______________ the solubility of a _______________ solute 3) _______________ only affects the _______________ of a _______________ _______________ _______________ pressure _______________ solubility _______________ pressure _______________ solubility Henry’s Law: The _______________ of a _______________ dissolved in a given _______________ of _______________ is _______________ proportional to the _______________ of the _______________. The Chemistry Quiz CR1. _____ CR2. _____ 1. _____ 2. _____ 3. _____ 4. _____ CHEMISTRY: A Study of Matter © 2004, GPB 10.9 5. _____ Worksheet: Solubility Graphs Name______________ Use the provided solubility graph to answer the following questions: For questions 1 – 4 an amount of solute is given, and a temperature is stated. If all of the solute could be dissolved in 100 g of water at the given temperature, would the resulting solution be unsaturated, saturated, or supersaturated? 1. 60 g KCl at 70 °C _________ 2. 10 g KClO3 at 60 °C _________ 3. 80 g NaNO3 at 10 °C _________ 4. 70 g CaCl2 at 20 °C _________ For questions 5 – 8 a solute and temperature are given. Tell how many grams of each solute must be added to 100 g of water to form a saturated solution at the given temperature. 5. Pb(NO3)2 at 10 °C _________ 7. NaCl at 20 °C _________ 6. Ce2(SO4)3 at 50 °C _________ 8. K2Cr2O7 at 50 °C _________ For questions 9 and 10 underline the solution that is more concentrated. 9. At 10 °C: a saturated solution of KNO3 or a saturated solution of CaCl2. 10. At 50 °C: a saturated solution of KNO3 or an unsaturated solution of NaNO3 consisting of 90 g of the solute dissolved in 100 g of water. For questions 11 – 12, show your work and circle your final answer. 11. If 115 g KNO3 are added to 100 g of water at 35 °C, how many grams do not dissolve? 12. What mass of KCl would be needed to form a saturated solution if the KCl was dissolved in 200 g of water at 80 °C? CHEMISTRY: A Study of Matter © 2004, GPB 10.12 Worksheet: More on Solubility Name______________ 1. Explain what is meant by the expression “like dissolves like”. 2. An unknown compound is observed to mix with benzene (a nonpolar solvent) but not with water. Is the unknown compound ionic or covalent? If the unknown compound is a liquid, will it be able to dissolve table salt?____________ Explain: 3. What are the chemical characteristics of a good dry-cleaning solvent? 4. Explain why you are more likely to overdose on vitamin A than on vitamin C. 5. Some industrial plants use water from nearby rivers and streams as a coolant. When the water is returned to the river or stream, the water is warmer than it was originally. This is referred to as “thermal pollution”. Using your knowledge of solubility, why might this thermal pollution be harmful to fish? CHEMISTRY: A Study of Matter © 2004, GPB 10.13 6. After a bottle of carbonated drink has been open for a while, it tastes “flat”. Explain why. 7. For most solid solutes, the degree of solubility in a liquid solvent (increases, decreases) with an increase in the temperature of the solvent. 8. Describe what happens to the degree of solubility of a gaseous solute in a liquid: a) with a decrease in the temperature of the solvent. b) with an increase in pressure ( ____________ Law). 9. The following statement is false: It is not possible to make a saturated solution from a substance that is described as only slightly soluble. Explain why this statement is false. CHEMISTRY: A Study of Matter © 2004, GPB 10.14 Note Taking Guide: Episode 1003 Name______________ Molarity (M) • expresses _______________ _______________ • M= • _______________, _______________, ______, and _______________ all represent the same ratio. Ex #1. _______________ A saline solution contains ________ g of NaCl per ________ mL of solution. What is its molarity? M= Ex. #2 ______________________ How many moles of solute are contained in _______ L of __________ M CaCl2? CHEMISTRY: A Study of Matter © 2004, GPB 10.15 Colligative Properties • Any of the _______________ of a _______________ that change when the _______________ of the _______________ changes. • • Depend on the _______________ of _______________ dissolved in a given _______________ of _______________ Examples of Colligative Properties: a. Vapor _______________ Depression -- the _______________ of the _______________ _______________ of a liquid that occurs when substances are _______________ in the _______________. -- Vapor Pressure: the _______________ of a _______________ in _______________ with its _______________ b. Freezing _______________ Depression -- the _______________ of the _______________ _______________ of a liquid that occurs when substances are _______________ in the _______________. (ex. using _____________ in car radiators and ________ on icy roads) c. Boiling _______________ Elevation -- the _______________ of the _______________ _______________ of a liquid that occurs when substances are _______________ in the _______________. -- boiling occurs when _______________ _______________ equals _______________ _______________. (ex. ______________ in a car acts as a coolant in the summer.) • More Examples of Colligative Properties: _______________ ,_______________, _______________ The Chemistry Quiz CR1. _____ CR2. _____ 1. _____ 2. _____ 3. _____ 4. _____ CHEMISTRY: A Study of Matter © 2004, GPB 10.16 5. _____