C101 FINAL EXAM REVIEW QUESTIONS revised 12/2011 Questions 1 – 71 are more or less in the order the material was covered in the course. These questions come from Chapters 1 – 7 of your textbook. At the end of this document you will find a group of 29 questions that are over the “new material” from Chapters 8 and 9. Don’t “study” the review questions, but rather use the review questions to gauge how prepared you are for the final exam and to get a feel for the kinds of questions you will be asked on the final exam. The answer key and a sample cover sheet are the last two pages of this document. 1. Which of the following are halogens? a. b. c. 2. have identical electron configurations. have the same charge. have identical mass numbers, A. have the same number of protons, but different numbers of neutrons. reside in the same period in the periodic table. 1 electron. 2 electrons. 6 electrons. d. e. 10 electrons. 18 electrons. calcium. zirconium. silicon. d. e. magnesium. carbon. arsenic germanium boron d. e. technetium antimony The atomic weight listed for an element on the periodic table is a. b. c. d. e. 8. thalium nickel Which of the following is not a metalloid? a. b. c. 7. d. e. The element from group 2 and period 4 is a. b. c. 6. vanadium fluorine rhodium A single orbital may, at most, contain a. b. c. 5. Na, Li, K, Cs Co, Mn, Fe, Pd Isoelectronic refers to species that a. b. c. d. e. 4. d. e. Which of the following elements is misspelled? a. b. c. 3. O, S, P He, Ar, Ne, Rn Cl, Br, I, F the same as its mass number the sum of the protons and neutrons the mass in amu of the most stable isotope the mass in grams of the most abundant isotope an average of the weights of naturally-occurring isotopes. If a 250. g gold bar (specific heat: 0.031 cal/g·°C) absorbs 300. cal, how much will its temperature increase? a. b. c. 110°C 1.0°C 270°C d. e. 39°C 27°C 9. Suppose 500. cal is absorbed by each of the following metals. Which has the greatest temperature increase? gold: brass: copper: stainless steel: a. b. c. 10. 131 b. 122 d. e. 20 g/cm3 24 g/cm3 131 I Sn d. 179 Hf e. 177 Hf Xe an odd number of electrons. an even number of electrons. the largest possible charge on an ion. d. e. equal numbers of electrons and protons. noble gas configurations. d. e. Al2+ Al3+ The most stable aluminum ion is Al2– Al1– Al1+ Which of the following denotes an excited state of an uncharged carbon atom? a. b. c. 15. stainless steel all have the same temperature change The electron configurations that permit maximum stability are those with a. b. c. 14. 8 g/cm3 12 g/cm3 16 g/cm3 a. a. b. c. 13. d. e. Which of the following contains 78 neutrons? c. 12. gold brass copper A student measured the mass of 5 mL of a liquid to be 120.0 g. What is the density of the liquid (with proper attention to the number of significant figures)? a. b. c. 11. 100 g, with specific heat = 0.031 cal/g·°C 100 g, with specific heat = 0.089 cal/g·°C 200 g, with specific heat = 0.091 cal/g·°C 300 g, with specific heat = 0.122 cal/g·°C 1s22s22p4 1s22s22p6 1s22s22p23s2 d. e. 1s22s22p63s1 1s22s23s2 Which neutral element has the following electron configuration: [Ne]3s23p4 a. b. c. 16. d. e. O P Arrange the following electromagnetic radiation in order of increasing energy. a. b. c. 17. S Al B blue light microwaves infrared yellow light I II III IV I < II < III < IV III < IV < I < II II < III < IV < I d. e. III < I < IV < II IV < I < III < II d. e. krypton radon Ba2+ is isoelectronic with: a. b. c. radium argon xenon 18. Phosphorus forms the stable monatomic ion: a. b. c. 19. MgCN Mg2CN Mg(CN)2 d. e. Mg(CN)3 Mg3(CN)2 Cr2NO3 Cr2(NO3)2 Cr(NO3)2 d. e. CrNO3 Cr3(NO3)2 CaPO4 Ca(PO4)2 Ca2(PO4)2 d. e. Ca2(PO4)3 Ca3(PO4)2 AlNO2 Al3(NO2)2 Al2(NO2)2 d. e. € Al2(NO2)3 Al(NO2)3 € 3 5 6 d. e. 7 8 3 5 10 d. e. 18 24 Carbon dioxide contains two double bonds, each from carbon to an oxygen atom. The shape of carbon dioxide is best described by the term a. b. c. 28. Cs O The total number of valence electrons involved in the bonding and structure of BCl3 is a. b. c. 27. d. e. The total number of valence electrons involved in the bonding and structure of NH3 is a. b. c. 26. S C F The ionic compound formed from Al 3+ and NO1– 2 has the formula: a. b. c. 25. Sr2– Sr1+ The ionic compound formed from calcium ion and the phosphate ion has the formula: a. b. c. 24. d. e. Chromium (II) nitrate has the formula: a. b. c. 23. Sr3+ Sr3– Sr2+ Magnesium cyanide has the formula: a. b. c. 22. P2– P1+ Which of the following is the most electronegative element? a. b. c. 21. d. e. Strontium forms the stable monatomic ion: a. b. c. 20. P3+ P3– P2+ bent. linear. T-shaped. d. e. tetrahedral. trigonal planar. d. e. Br2 none of the above Which of the following contains a single bond? a. b. c. P2 N2 CO 29. Which of the following molecules has exactly one lone pair of electrons? a. b. c. 30. F–F N–O NO4 NO3 NO5 d. e. N 2O 3 N 2O 4 tetrahedral trigonal planar trigonal bipyramidal d. e. triangular pyramidal square planar NH5 exists and uses nitrogen 2s and 2p orbitals for bonding. NH5 exists and uses nitrogen 2s, 2p, and 3s orbitals for bonding. NH5 exists and uses nitrogen 2s, 2p, and 3d orbitals for bonding. NH5 does not exist since there are no 2d orbitals. NH5 does not exist since there are no 3d orbitals. 90° 105° 109° d. e. 120° 180° Al2SO4 Al2(SO4)3 Al(SO3)3 d. e. Al3(SO4)2 AlSO3 What is the oxidation number of bromine in the perbromate ion, BrO1– 4 ? a. b. c. 38. d. e. What is the formula of the salt formed when aluminum hydroxide is neutralized with sulfuric acid? a. b. c. 37. C–O N≡N O–Cl What is the H-C-H angle in methane, CH4? a. b. c. 36. Cs2O CS2 Comment on the existence and structure of NH5. a. b. c. d. e. 35. d. e. What term best describes the shape of CH2O (formaldehyde)? Hint: Carbon is the central atom. a. b. c. 34. CaCl2 NaCl NaF What is the formula of dinitrogen tetraoxide? a. b. c. 33. BF3 PH3 Which of the following bonds is most polar? a. b. c. 32. d. e. Which of the following is best described as a covalently bonded molecule? a. b. c. 31. CS2 Cl2 CO2 +1 +3 +4 d. e. +5 +7 € What is the oxidation number of carbon in sodium carbonate? a. b. c. +1 +3 +4 d. e. +5 +8 39. Which of the following describes an endothermic reaction? a. b. c. 40. d. e. ΔH = +200 kcal and ΔS = 0 both b and d above ΔS > 0 ΔS < 0 ΔH > 0 d. e. ΔH < 0 ΔG < 0 alters the heat of a chemical reaction. increases the free energy of a reaction. increases the entropy change in a chemical reaction. reduces the activation energy of a chemical reaction. does all of the above. Le Châtelier’s Principle states a. b. c. d. e. 44. ΔH = –100 kcal ΔH = +100 kcal ΔH = 0 A catalyst a. b. c. d. e. 43. ΔH < 0 and heat is absorbed ΔH = 0 and heat is released The “spontaneity criterion” for chemical reactions is given by: a. b. c. 42. d. e. Which of the following is an example of an exothermic reaction? a. b. c. 41. ΔH > 0 and heat is released ΔH < 0 and heat is released ΔH > 0 and heat is absorbed when stress is applied to a system in equilibrium, the equilibrium shifts to relieve the stress. that the forward reaction is the same as the reverse reaction in a chemical equilibrium. that the entropy of the universe is increasing. that the entropy of the universe is decreasing. that, when an exothermic reaction is heated, the forward reaction rate will increase. In the compound magnesium permanganate, Mg(MnO4)2, what is the oxidation number of manganese? a. b. c. +8 +7 +5 d. e. +3 +1 Use the balanced reaction below for the next two problems. 2AuCl 3 + 3Sn → 3SnCl 2 + 2Au 45. If 10 mol of gold (III) chloride are used with excess tin, how many mol of tin (II) chloride are produced? a. b. c. 46. d. e. 15 30 If 30 mol of tin metal are used, how many moles of gold are produced? a. b. c. 47. 3 6 12 2 15 20 d. e. 25 60 In the reaction, 2 N2(g) + 5 O2(g) → 2 N2O5(g) if 3.0 moles of nitrogen gas are reacted with excess oxygen, what mass of dinitrogen pentoxide is produced? a. b. c. 108 g 216 g 320 g d. e. 810 g 1.3 kg 48. How many molecules are there in 3.00 moles of C6H6? a. b. c. 49. 1.0 3.0 1.20 × 1024 d. e. 1.81 × 1024 6.02 × 1023 What is the equilibrium expression for the following reaction? 2 NO (g) + 2 CO (g) N2 (g) + 2 CO2 (g) + heat a. K= [NO]2 [CO]2 [N2 ]2 [CO2 ]2 d. K= [ N2 ][CO2 ]2 [NO]2 [CO]2 b. K= [2N2 ][2CO2 ]2 [2NO]2 [CO]2 e. K= 2[NO]2[CO]2 [N2 ] + [CO2 ]2 € c. K= € € Find the activation energy for reactants forming products. ∆G, kcal 50. [N2 ]2 [CO2 ]2 [NO]2 [CO]2 € 16 € 15 14 13 12 11 10 9 8 7 6 5 4 3 2 1 reaction progress → a. b. c. 51. 54. 5.5 kcal 16 kcal 4 kcal –6.5 kcal +6.5 kcal d. e. 10.5 kcal 12 kcal d. e. 4 moles 5 moles How many moles are 72 g of water? a. b. c. 53. d. e. Use the diagram in the previous question to determine ΔG for the backward reaction. a. b. c. 52. 10.5 kcal 4.0 kcal 12. kcal 1 mole 2 moles 3 moles Iron corrodes to iron (III) oxide in the presence of excess oxygen gas. Which of the following is the correct balanced equation for this oxidation? a. Fe + O 2 → Fe2 O 3 d. 4Fe + 2O 2 → 2Fe 2 O 3 b. 2Fe + 3O 2 → Fe2 O 3 e. 4Fe + 3O 2 → 2Fe 2 O 3 c. 2Fe + O 2 → Fe2 O 3 If all the gases below are in a flask together, which gas has the highest average speed? a. b. c. Xe C 2H 2 CCl4 d. e. NH3 H 2S 55. A balloon occupying 12 L at 1 atm occupies what volume in the upper atmosphere at a pressure of 0.50 atm? Assume the temperature remains constant. a. b. c. 56. its surprisingly high boiling point. all of the above water CH3CH2CH2CH2CH2OH CH3CH2CH2CH2CH2CH2CH2CH2Br d. e. both a and b both b and c methane carbon dioxide hydrogen chloride d. e. carbon disulfide propane, C3H8 100 torr 200 torr 273 torr d. e. 760 torr 1000 torr boiling point will be lowered freezing point will be lowered freezing point will be elevated d. e. both a and b both a and c H2··· HCl H2··· CS2 HCl··· CS2 d. e. CS2··· CS2 HCl··· HCl If you wanted to form 10 L of the product, N2O4(g), exactly how many liters of nitrogen and oxygen would be required in the following reaction? N2(g) + 2O2(g) → N2O4(g) a. b. c. d. e. 64. d. e. A flask contains the gases H2, HCl, and CS2. Between which molecules is the dipole-dipole force greatest? a. b. c. 63. temperature independence of vapor pressure. its surprisingly low specific heat. its low heat of vaporization. Adding a non-volatile solute to a solvent will likely result in which of the following? a. b. c. 62. 2L 1L How many torr are equivalent to 1 atm of pressure? a. b. c. 61. d. e. Which of the following gases likely has significant dipole-dipole intermolecular forces? a. b. c. 60. 12 L 6L 3L Which of the following would be a good solvent for CCl4? a. b. c. 59. 12 L 24 L The existence of hydrogen bonding between water molecules is responsible for a. b. c. 58. d. e. A balloon occupies 3 L at 1 atm at 300 K. What is its volume at 2 atm and 600 K? a. b. c. 57. 0.75 L 1.5 L 6.0 L 2.5 L nitrogen and 5 L oxygen 5 L nitrogen and 5 L oxygen 5 L nitrogen and 10 L oxygen 3.3 L nitrogen and 6.7 L oxygen 10 L nitrogen and 20 L oxygen If 1.0 L of 0.33 M NaF solution were evaporated to dryness, how many g of NaF salt would we have? a. b. c. 3g 14 g 51 g d. e. 39 g 42 g 65. If a 2 L flask contains a gas at a pressure of 4 atm at 100 K, about how much gas must be in the flask? a. b. c. 66. d. e. 4 moles 5 moles A flask contains 0.75 L of helium and 0.25 L of neon at 2.0 atm. What is the partial pressure of helium? a. b. c. 67. 1 mole 2 moles 3 moles 0.5 atm 0.75 atm 1.0 atm d. e. The enthalpy change is 43.2 kcal for the reaction: 1.5 atm 2.0 atm N2 + O2 → 2 NO Formation of 90.0 g of NO gas will result in ______ being ______ . 68. 69. a. 21.6 kcal; released b. 64.8 kcal; released c. 43.2 kcal; absorbed d. 64.8 kcal; absorbed e. 130. kcal; absorbed What is the concentration if a 50.0 L sample of river water contains 250 microliters of dioxin? a. 5.0 % b. 0.05 % c. 0.50 ppm d. 5.0 ppm e. 500 ppm Suppose 200 mL of a solution contains 50. g of sucrose. What is its w/v %? a. b. c. 70. d. e. 50% (w/v) 75% (w/v) The addition of a soluble, non-volatile solute, such as KI, to water a. b. c. 71. 10% (w/v) 20% (w/v) 25% (w/v) lowers its boiling point. raises its freezing point. decreases its conductivity. d. e. increases its vapor pressure. decreases its vapor pressure. The melting point of acetone is –95°C. How much heat is needed to melt 12.2 g of acetone at –95°C? Heat of fusion is 23.4 cal/g Heat of vaporization is 124.7 cal/g q = mCΔT a. 285 cal d. 0.888 kcal b. 603 cal e. 27.1 kcal c. 1520 cal Cacetone = 0.52 cal/g°C The following problems cover concepts from Chapter 8 (N1 - N15) and Chapter 9 (N16 – N29). N1. Which of the following are strong acids? a. b. c. N2. d. e. NH3 CH3COOH a buffer strong acid strong base d. e. water all of the above water CH3COO–the hydronium ion d. e. OH– H+ d. e. 10 none of the above d. e. > 14 10–10 Which of the following corresponds to the pH of an acid? a. b. c. N6. HCl NH4+ H2SO4 What is the conjugate base of CH3COOH? a. b. c. N5. nitric acid all of the above Which of the following is always a consequence of a neutralization reaction? a. b. c. N4. d. e. Which is an example of a Brønsted-Lowry base? a. b. c. N3. sulfuric acid hydrochloric acid hydrobromic acid 12 7 2 If [H+] = 10–2 M, what is the pH? a. b. c. <1 2 4 N7. If [H+] = 2.5 × 10–5 M, what is its pH? You will need a calculator. ________________ N8. The sum of the pH and the pOH is: a. b. c. N9. 0 14 10–7 d. e. 10–14 7 The following weak acids are in order of decreasing strength: HNO2 > CH3COOH > HCN weak weakest Arrange their conjugate bases in order of increasing basicity. a. b. c. N10. NO2– < CN– < CH3COO– NO2– < CH3COO– < CN– CN– < NO2– < CH3COO– d. e. CN– < CH3COO– < NO2– CH3COO– < CN– < NO2– Buffers have which of the following properties? a. b. c. d. e. Combinations of a weak acid and its conjugate base that resists changes in pH Show, with color changes, the relative pH of two solutions Solutions formed from combination of a strong acid and a strong base Solutions with such high pH that they are unaffected by addition of acids Solutions where the Ka is very sensitive to small changes in H+ or OH– concentrations N11. What is [H+] in a 0.5 M H2SO4 solution? a. b. c. N12. ozone emission both a and b d. e. 100 mL 125 mL salt formed from mixing a strong acid and a weak base salt formed from mixing a weak acid and a strong base salt formed from mixing a strong acid and a strong base both a and b both b and c HCl HCN NaOH 7 9 10 19 d. e. H2PO4– NH3 d. e. 19 none of the above d. e. 24 none of the above d. e. 78 8 F? € 2+ How many protons are in 42 ? 20 Ca a. b. c. N18. 25 mL 50 mL 75 mL How many neutrons are in a. b. c. N17. d. e. Which can behave both as a Brønsted-Lowry acid and as a Brønsted-Lowry base? a. b. c. N16. sulfur dioxide emission NOx emission CO emission Which of the following salts yields a basic solution when added to water? a. b. c. d. e. N15. 1M 2M About how many mL of 0.30 M NaOH are required to completely neutralize 50 mL of 0.75 M HCl? a. b. c. N14. d. e. Acid rain is formed from a. b. c. N13. 0.1 M 0.2 M 0.5 M 18 20 22 How many neutrons are in a. b. c. 133 54 79 133 Xe ? € What is the product of each of the following decay paths? Nuclide Nuclear emission N19. 131 53 I β– N20. 18 F β+ N21. 222 Rn α N22. 131I a. b. c. Product has a half-life of 8 days. If you start with a 120 g sample of 131I, how much remains after 32 days? 240 g 60 g 30 g d. e. 15 g 7.5 g N23. What is X in this reaction? 2 1 N24. a. 4 2 b. 0 +1 β c. 0 –1 β b. c. b. c. b. c. 2 neutrons e. 2 protons d. e. 214 85 At 218 85 As 214 81 Tl 214 82 Pb 218 84 Po d. e. 214 81 Rn 214 82 Tl microwaves < red light < yellow light < gamma rays microwaves < gamma rays < red light < yellow light microwaves < yellow light < red light < gamma rays yellow light < red light < microwaves < gamma rays gamma rays < microwaves < red light < yellow light 235 92 U ? 238 90 U 238 92 U 235 94 U d. both a and b e. both b and c d. e. anti-proton anti-neutron A proton is converted into a neutron. What is emitted? a. b. c. N29. 214 81 Tl 210 81 Tl 214 81 Bi Which of the following is an isotope of a. N28. d. Arrange the following in order of increasing energy: gamma rays, microwaves, red light, yellow light a. b. c. d. e. N27. α Rn (222) decays with the following emissions: α, α, and then β+. What nuclide do you now have? a. N26. 3 If 214Bi decays with emission of an alpha particle, what results? a. N25. 3 H+ 1H→ 2 He + X electron positron α particle Transmutation refers to the a. b. c. d. e. conversion of one element to another. effect of ionizing radiation on body tissues. fragmentation of heavy nuclei. separation of different isotopes of the same element. conversion of matter into energy. C101 Final Exam Review Answers 1c 31a 61b New Material 2d 32e 62e N1e 3a 33b 63e N2d 4b 34d 64b N3d 5a 35c 65a N4b 6d 36b 66d N5c 7e 37e 67d N6b 8d 38c 68d N7 9a 39c 69c N8b 10d 40a 70e N9b 11a 41e 71a N10a 12e 42d N11d 13e 43a N12e 14e 44b N13e 15a 45d N14b 16c 46c N15d 17c 47c N16c 18b 48d N17b 19c 49d N18c 20c 50d N19 131 54 21c 51c N20 18 8 22c 52d N21 218 84 23e 53e N22e 24e 54d N23d 25e 55e N24b 26e 56c N25a 27b 57d N26a 28d 58e N27b 29e 59c N28b 30e 60d N29a pH = 4.6 Xe O Po Typical Cover Sheet Name ____________________ C101 FINAL EXAM 1. Print and code your name (last name, space, first name) on your answer sheet in the “last name” block. Print and code the form of your exam in the first box under “course.” Print and code the last 5 digits of your ID number in the first 5 spots in the “ID number” block. Please code carefully and check your coding. 2. Print your name in the space provided on the exam booklet. 3. Choose the best answer for each question. Using a #2 pencil, fill in the corresponding balloon on the scoring sheet. 4. Return the answer sheet AND Final Examination Booklet to your instructor when finished. ΔG = ΔH – TΔS PV = nRT P1V1/T1 = P2V2/T2 [H+][OH–] = 10–14 pH = –log[H+] pH + pOH = 14 K = °C + 273 q = mCΔT R = 0.0821 L· atm/mol· K NA = 6.023 × 1023 1 mile = 5280 ft 1 amu = 1.6606 × 10–24 g 1 inch = 2.54 cm mass of proton: 1.6726 × 10–24 g 1 atm = 760 mm Hg = 760 torr mass of electron: 9.1094 × 10–28 g 1 mL = 1 cm3 mass of neutron: 1.6749 × 10–24 g 1 cal = 4.184 J 1 mole of an ideal gas at STP occupies 22.4 liters H C N O F 2.1 2.5 3.0 3.5 4.0 Electronegativities K 0.8 Ca 1.0 Cl 3.0 Br 2.8 I 2.5 Periodic Table of the Elements s-block 1 1A 1 2 H 1.008 2A 3 4 d-block transition metals p-block 18 8A 2 He 13 3A 5 14 4A 6 15 5A 7 16 6A 8 17 7A 9 4.003 10 Li Be B C N O F Ne 6.941 9.012 10.811 12.011 14.007 15.999 18.998 20.180 11 12 13 14 15 16 17 18 Na Mg 22.990 24.305 19 20 3 3B 21 4 4B 22 5 5B 23 6 6B 24 7 7B 25 K Ca Sc Ti V Cr 39.098 40.078 44.956 47.867 50.942 37 38 39 40 41 Rb Sr Y Zr 85.468 87.62 88.906 55 56 57 Cs Ba La 132.905 137.328 138.905 10 26 9 8B 27 12 2B 30 Al Si P S Cl Ar 26.981 28.086 30.974 32.065 35.453 39.948 28 11 1B 29 31 32 33 34 35 Mn Fe 36 Co Ni Cu Zn Ga Ge As Se Br Kr 51.996 54.938 42 43 55.845 58.933 58.693 63.546 65.409 69.723 72.61 74.922 78.96 79.904 83.798 44 45 46 47 48 49 50 51 52 53 Nb Mo 54 Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe 91.224 92.906 72 73 95.94 [98] 101.07 102.906 106.42 74 75 76 77 78 79 80 81 82 83 84 Hf 85 86 Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn 178.49 180.948 183.84 186.207 190.23 200.59 204.383 207.2 208.980 [209] [210] [222] 104 105 106 107 108 87 88 89 Fr Ra Ac Rf Db Sg Bh [223] [226] [227] [261] [262] [266] [264] 58 59 60 61 62 Ce Pr Nd Lanthanide series Actinide series 140.116 140.908 144.242 Pm Sm 8 192.217 195.084 196.967 109 110 111 Hs Mt Ds Rg [277] [268] [271] [272] f-block transition metals 63 64 65 66 Eu Gd [145] 150.36 151.964 157.25 90 91 92 93 94 95 96 Th Pa U Np Pu [237] [244] 232.038 231.036 238.029 107.868 112.411 114.818 118.710 121.760 Am Cm [243] [247] 127.60 126.904 131.293 Copyright © 2007 by Keith S. Anliker www.chem.iupui.edu/~anliker 67 68 69 70 71 Tb Dy Ho Er Tm Yb Lu 173.04 174.967 97 98 99 100 101 102 103 Bk Cf Es Fm Md No Lr [247] [251] [252] [257] [258] [259] [262] 158.925 162.500 164.930 167.259 168.934