Unit 10 Notes Gases I. Pressure – force a gas exerts on its surroundings due to collisions of gas molecules with the surroundings. A. A barometer is – B. Units of pressure 1. mm Hg or torr 2. atmospheres (atm) 3. pascals (Pa) 1 atm = 760 mm Hg = 760 torr = 101,325 Pa C. Example Conversions II. Pressure and Volume: Boyle’s Law A. When pressure increases, volume will ____________if the temperature and amount of gas remain constant. Due to this fact we say that pressure and volume are _____________ proportional. B. If a change in the pressure of volume of a gas occurs, that gasses new pressure or volume can be determined using: *Boyle’s Law: P1V1 = P2V2 *Practice III. Volume and Temperature: Charles’s Law A. Temperature is a measure of kinetic energy. For a gas this means – B. At a temperature of 0 K, all motion stops. This temperature is known as __________________. C. As the temperature of a gas increases, the volume of the gas will _____________ if the pressure and amount of the gas are held constant. Due to this fact we say that temperature and pressure are _____________proportional. D. Charles’s Law: V1 V2 T1 T2 Example Practice IV. Volume and Moles: Avagadro’s Law A. As the number of moles of gas increases, the volume of the gas _____________ assuming that the temperature and pressure of the gas remain constant. Due to this fact we say that that the number of moles of gas and the volume of a gas are _________________ proportional. This relationship between moles and volume of gas is known as __________________. B. Avagadro’s Law: V1 V2 where n is the number of moles of gas. n1 n2 Example Practice V. Ideal Gas Law A. PV = nRT , where R is the universal gas constant *(R = 0.08206 L atm/K mol) Note: the units of pressure, volume, and Temperature that you plug into the above equation must match the corresponding units in the R value) B. The ideal gas law has limitations, It assumes the following: C. It is important to note that the ideal gas law is an approximation. Real gases may deviate from the way this model says that they should behave, but the model gets better at extremely low pressures and/or high temperatures. Practice VI. Dalton’s Law of Partial Pressures This law applies when there is a mixture of gasses. A. The ____________________ of a gas is the pressure that the gas would exert if it were alone in the container. B. Dalton’s law says that the total pressure of gas in a container is equal to the sum of the partial pressures of the gasses in the container: Ptotal = P1 + P2 + P3 + ….. however, many gasses there are. Example Practice VII. Laws and Models: A review A. It is important to note that the ideal gas law is an approximation. Real gases may deviate from the way this model says that they should behave, but the model gets better at extremely low pressures and/or high temperatures. VIII. Kinetic Molecular Theory of Gasses *What does the word kinetic mean? A. This theory is based on speculations about the behavior of individual gas molecules and attempts to explain the behavior of an ideal gas. B. Kinetic Molecular Theory – IX. Implications of Kinetic Molecular Theory A. The meaning of temperature – B. The relationship between pressure and temperature – C. The relationship between volume and temperature – X. Gas Stoichiometry A. Remember…Stoichiometry is all about using a mole ratio. Well…how can you get moles of gas from other information given about the gas? Answer: often you can use PV = nRT to find moles of the gas given before doing a mole ratio. Example Example Practice