Fellow name: Kim Cross Title of Lesson: What is so special about water? School: University High School Grade Level: 10th-11th Subject(s): Chemistry Summary Students will be exposed to the importance of surface tension, and its effect on life. For example, water striders are able to walk on water because of water’s surface tension. Plants rely on the surface tension to transport water inside them. Although a water molecule has an overall neutral charge, the actual structure of a water molecule makes it a polar molecule. The polarity of the water molecule causes it to be attracted to other water molecules as well as molecules of other substances. The attraction between water molecules is called cohesion. The attraction of water molecules to other substances, like soil or glass, is called adhesion. The cohesive force that occurs between water molecules is so strong that when comes in contact with another medium, such as air, the water creates a "sticky skin", which is known as surface tension. These bonds are so strong that they can support insects, In what way is your lesson/activity inquiry-based? -When the class period starts there will be a beaker of boiling water in front of the room and the students will be asked “what are the bubbles coming off the beaker?” -Then I will ask questions based on previously known information such as -What is an atom? -What is a molecule & provide and example -How are atoms held together? -What is a covalent bond & provide an example of a molecule with a covalent bond - What is an ionic bond & provide an example of a molecule with an ionic bond -What is the chemical formula for table salt? -What happens when you put salt in water & is this a chemical or physical change This is a good time to recap of physical and chemical changes, specifically in relation to bonding. When physical changes occur the molecule remains the same, for example with water you have ice at OC, liquid water at room temperature, and water vapor above boiling temperature, yet they all have the same compositing H2O. However, when chemical changes occur the molecular formula differs, chemical bonds are broken and reformed. Time Required 1 class period 90 minutes Group Size 4 Students per group Estimated cost Cost of the detergent, wax paper and needles ($15-$20) Introduction / Motivation Each student will get a picture of water molecule and on the bottom of the page that says “You depend on me. I help you exist.” “You depend on me. I help you exist” The students will be told, “Last night some one slipped this note under the door of the office at my research lab. I was very curious why someone mysteriously left this for me. So I brought it here to get some assistance from all of you. What do you guys think this is or what it means?” -Note if someone responds that its water. I will ask how they know. -Then further ask which atom is oxygen and which is hydrogen? - What are the positive and negative signs for? -If positive and negative charges attract each other, what causes something to be more positive or negative? -Covalent bonds share electrons, and it has been explained that water is covalently bonded, so how could there be a charge? Water is covalent bonded; however there is more than meets the eye with this molecule. Yes, oxygen and hydrogen share electrons; however the electrons are not shared equally. There is a slight inequality involved. Here is an example to imagine what’s occurring. A husband and wife are sleeping in the same bed right now during the winter. The husband is a tall husky guy and the wife is a short petite woman. They have a nice electric blanket to keep them warm however it just barely covers both of them. The husband, since he is bigger, needs more of the blanket, so he takes more of the blanket than the smaller wife. This is like the relationship between oxygen and hydrogen in the water molecule. The oxygen “tugs” at the electrons more than the hydrogen. Question: What is occurring when the oxygen pulls/ attracts the electron a little bit more? Think in terms of overall charge. The oxygen becomes slightly negative while the hydrogen becomes slightly positive Electronegativity is the tendency for one atom to pull the electrons of another atom. -Which atom in water is more electronegative? -What do you think this means in terms of a bunch of water molecules together? -What will happen in terms of attraction? The hydrogen atoms in one water molecule are attracted to the oxygen atom of another molecule. So the result is water molecules are attracted to other water molecules. Water molecules form weak bonds with one another. These are called Hydrogen bonds. We are going to look at an important property of water called surface tension in a lab today. When we’re done, we’ll come back and talk about what you discovered, and what that means in terms of how water helps sustain life on earth. The tendency of molecules to stick together is called cohesion, which is stronger for water than for most other liquids. Cohesion is very important in plants. Trees depend on cohesion to help transport water from their roots to their leaves. Cohesion helps water rise against the force of gravity. Surface tension is a measure of how difficult it is to stretch or break the surface of a liquid. Hydrogen bonds give water an unusually high surface tension, making it behave as though it were coated with an invisible film. Today’s ActivityWalter the Water Strider has a dilemma. Water Striders are insects that live on the surface of water in slow moving streams. They are very sensitive to the motion around them, and can move at a rate of about a meter per second. Approximately three weeks ago, someone reported that the river was changing a few miles upstream. Something was causing the striders to fall in the water, instead of being able to walk like they usually do. In the past week, several of Walter’s family members strode upstream to investigate, but, according to witnesses, they fell through the water. The new and dangerous river water seems to be getting closer to Walter’s home, and he’s concerned for his life. Walter never thought about what enables him to walk on water. He always took it for granted. But now as his life seems in danger, he wonders what helps him walk on water. Perhaps if he can figure that out, then he can learn how to save himself. What might be causing the Water Striders to fall in the water? Materials List: -dropper -water -detergent - Pepper -50 pennies -Sheet of wax paper -2 needles -Clear plastic cup - Alcohol -Petri Dish Part 1 (Needle in a Petri Dish): Water, Alcohol, Needle, Petri Dish, and Detergent Part 2 (Penny Drop): Water, Dropper, Pennies Part 3 (Over the Top): Water, Dropper, Pennies, Cup Part 4 (Pepper Time): Water, Petri Dish, Pepper, and Detergent Part 5 (Wax Paper): Water, Wax Paper, and Dropper Procedure Part 1: Needle in a Petri Dish Fill a Petri dish with water. Put the needle on a fork and slowly lower the fork over the water, then into the water, then down so the needle floats. Were you able to make it float? Then fill a Petri dish with alcohol. Try floating the needle in it by dipping it in with the fork. Were you able to make it float? Put the needle in water again. Make it float. Then dip a second needle in detergent. Try to make it float. What happened? Part 2: Penny Drop Guess how many drops of water you can place on the surface of a penny without it spilling over:___________ With a penny, conduct two separate trials to see how many drops the penny can hold. Use heads or tails and use two different pennies. Draw what the water on the penny looks like before the water spills over: Penny Drawing Trial 1 ________ Trial 2 _________ Calculate the average:________ Part 3: Over the Top Fill a small cup with water to the top without spilling over. How many pennies do you think you could add before the water spills over?________ Slowly add pennies to the lass of water one at a time. What does the side of the glass look like as you add more pennies? Draw the side view below: How many pennies did you add before it spilled over?_______ Part 4: Pepper Time Fill a Petri dish with water. Sprinkle pepper over the top of the water. What do you observe? How many pepper pieces are immersed in the water? Place one drop of detergent in the dish. What did you observe? Are there more or less pepper pieces immersed in the water? Part 5: Wax Paper Take a piece of wax paper and place some drops of water on the wax paper. Try to push the water drops together. What do you observe? Draw how the water looks on the wax paper. Lesson Closure 1. What enables Walter to walk on water? 2. What is surface tension? 3. What caused the water molecules to stick together and create surface tension? 4. Why did the needle float easier on the water than on the alcohol? 5. How did the addition of detergent affect the surface tension of water? 6. Why does detergent have this effect on water? 7. What shape did water take while on top of the glass or on top of the penny? 8. Why did water take on a dome shape, and not a flat one when on the wax paper? 9. Based on the evidence you collected in this activity, what do you think might be causing all the Water striders to fall into the water? 10. What are hydrogen bonds? 11. Draw four water molecules, and show how they are attracted to one another (show the charges). Is this lesson based upon or modified from existing materials? If yes, please specify source(s) and explain how related: - Floating Paperclip and other Surface Tension Experiments: www.exo.net/~jillj/activities/surfacetension.pdf -Surface Tension - an introduction to surface tension: physics.about.com/od/physicsexperiments/.../surfacetension.htm -Walking On Water: Water Striders and Surface Tension: http://www.woodrow.org/teachers/bi/1998/waterstrider/student_lab.html References Smith, Robert W. Hands On Science, Copyright, 1989, Instructional Fair Publisher Walpole, Brenda, 175 Experiments to Amuse and Amaze Your Friends Copyright 1988, Random House Publisher John W. M. Bush (May 2004). "MIT Lecture Notes on Surface Tension, lecture 5" (PDF). Massachusetts Institute of Technology. http://web.mit.edu/1.63/www/Lecnotes/Surfacetension/Lecture5.pdf. Retrieved April 1 2007. John W. M. Bush (April 2004). "MIT Lecture Notes on Surface Tension, lecture 1" (PDF). Massachusetts Institute of Technology. http://web.mit.edu/1.63/www/Lecnotes/Surfacetension/Lecture1.pdf. Retrieved April 1 2007. John W. M. Bush (May 2004). "MIT Lecture Notes on Surface Tension, lecture 3" (PDF). Massachusetts Institute of Technology. http://web.mit.edu/1.63/www/Lecnotes/Surfacetension/Lecture3.pdf. Retrieved April 1 2007. "Surface and Interfacial Tension". Langmuir-Blodgett Instruments. http://www.ksvinc.com/surface_tension1.htm. Retrieved 2007-09-08. ^ Calvert, James B.. "Surface Tension (physics lecture notes)". University of Denver. http://mysite.du.edu/~jcalvert/phys/surftens.htm. Retrieved 2007-09-08. List CA Science Standards addressed -Atomic and Molecular Structure a. Students know how to relate the position of an element in the periodic table to its atomic number and atomic mass. b. Students know how to use the periodic table to identify metals, semimetals, nonmetals, and halogens. c. Students know how to use the periodic table to identify alkali metals, alkaline earth metals and transition metals, trends in ionization energy, electronegativity, and the relative sizes of ions and atoms. -Chemical Bonding a. Students know atoms combine to form molecules by sharing electrons to form covalent or metallic bonds or by exchanging electrons to form ionic bonds. b. Students know chemical bonds between atoms in molecules