ADVANCED PLACEMENT CHEMISTRY SYLLABUS Course Description and Overview: This Advanced Placement (AP) Chemistry course has been designed to follow the guidelines set forth by the College Board and covers the topics listed in the AP CHEMISTRY COURSE DESCRIPTION handbook. The course is designed to give 11th and 12th grade students the most comprehensive coverage possible of a university-level general chemistry course. The course relies heavily upon the conceptual, laboratory, and problemsolving foundations laid in first-year chemistry. Great emphasis is placed on linking topics/chapters/units together as material is covered in order to provide students with a ‘big picture’ idea of the fundamental principles of chemistry. Great emphasis is also placed on problem-solving and graphical analysis. All students who enroll in this course must have successfully completed a first-year college preparatory chemistry class. Our school offers the students two options for that first-year course: Honors Chemistry or College-Preparatory Chemistry. Students who meet that requirement, along with our school district’s mandated mathematical prerequisite of successful completion of second-year algebra. All AP Chemistry students are enrolled in either trigonometry-math analysis or calculus. All units in AP Chemistry are covered by means of lecture, class discussion, small group problem-solving, and laboratory experiences. Students are provided with teacherprepared notes for each chapter studied. Lectures in AP Chemistry involve frequent question-and-answer dialogue between the teacher and students. Frequent references to what the students were introduced to in first-year chemistry are made. After the students are taught a particular type of problem-solving, they will be given a ‘warm up’ problem the following class session. Course Goals: Over 75% of our school’s seniors advance to college or university-level work following graduation; many of them pursue pre-medical, pre-engineering, or other sciencerelated majors. There is therefore a strong emphasis in AP Chemistry to prepare those students as thoroughly as possible for the work that lies ahead of them. In short, the goals of this course include the development in students of: a comprehensive foundation and conceptual framework in the science of chemistry an advanced level of critical thinking, data analysis, and problem solving an advanced skill level in using various laboratory techniques and equipment an appreciation for the impact of chemistry in their everyday lives, and an awareness of selected ethical and environmental issues associated with chemistry 1 Course Schedule: Our school operates on a traditional school day, with 55-minute periods. AP Chemistry officially meets five days a week. The academic calendar is based on a fourquarter system from early September until mid June. Extra time is allotted and provided before school, at lunch, and after school as needed for the completion of the laboratory portion of the course (that is not completed during the normal school day). A minimum of an average two days per week is assigned to laboratory work. A two-hour review session before major exams is scheduled outside of the school day. During the three weeks leading up to the AP exam itself, twenty hours of extra teacher-led review time is scheduled for students. Course Materials: PRIMARY TEXT (up until June 2007): Kotz, John C., Paul M. Treichel, Gabriela C. Weaver. Chemistry & Chemical Reactivity. Pacific Grove, CA: Brooks/Cole Thomson Learning PRIMARY TEXT (beginning September 2007): Zumdahl, Steven, and Susan Zumdahl. Chemistry. Boston: Houghton Mifflin PRIMARY LABORATORY MANUAL: Beran: Laboratory Manual for Principles of General Chemistry, 7th Edition SUPPLMENTAL PROBLEM SOLVER: AP Chemistry Practice Problem Book SUPPLEMENTAL DATA TABLES: AP Chemistry Data Tables (I wrote and assembled this five years back and have the school district Print Shop produce these for each student each year. It is a sixty-four page manual that tracks our textbook and offers the students practice problems for all primary and supplemental equations covered in the course. It is fashioned after a similar problem-solver that a former student of mine brought back from a summer chemistry course at Harvard University. The practice problems are used both for lecture examples and for supplemental homework assignments) (I assembled this also five years ago as a handy resource for students to use throughout the year. Again, it is provided to each student at the start of the year. It is a twenty-six page compilation of 2 necessary charts and tables, including such things as density data, thermodynamic data, ionization constants for acids and bases, vapor pressure tables, VSEPR molecular geometry and shapes, equation prediction guidelines as used on the AP Chemistry exam, and so on.) AUDIOVISUAL MATERIALS: The Mechanical Universe (video series) COMMONLY ACCESSED/ASSIGNED WEB SITES: Unitedstreaming by Discovery Education www.unitedstreaming.com Web-Based High School Chemistry Simulations cse.edc.org/products/simulations/catalo g.asp#periodictablereactions Chemistry Experiment Simulations and Conceptual Computer Animations http://www.chem.iastate.edu/group/Gr eenbowe/sections/projectfolder/animati onsindex.htm Course Requirements: Students who enroll in AP Chemistry expect and are assigned homework each evening. They spend an average of one to hours per night on homework assignments. Homework comprises: daily reading from the textbook daily problem sets taken from the primary text biweekly essays (which allow them to practice AP-type essay questions related to each chapter or unit) biweekly laboratory reports (which, when graded, are placed by students into a portfolio and kept for the duration of the school year) weekly special problems (which are challenging applications of what we have been learning in class; often these are problems taken from old AP exams) one final investigative project (completed after the AP exam) which is written in the style of a traditional chemistry abstract Students are given quizzes (a short selection of multiple choice questions) almost every week. At the end of each unit (or sometimes at the end of two combined chapters or units), comprehensive exams are given. The tests are modeled very much after AP exams in that the students are required to complete (1) multiple choice questions, (2) 3 answer equation prediction problems, (3) solve problems, and (4) respond to essay questions. At the end of each grading period, the student’s grade is determined by a weight percentage: 75% test scores, 10% homework, and 15% laboratory reports. To better delineate how the various assignments work in conjunction with each other, please refer to the sample calendar which is included below. Calendars such as these are distributed to the students on a monthly basis. CHEMISTRY II – February 2007 Calendar January 29 - Welcome to the 2nd semester! - Begin ch. 15 – CHEMICAL KINETICS January 30 - Determine factors that affect reaction rates - Discuss rate laws and rate orders February 5 - Continue lab work, as needed - Work on group problem February 6 - Complete lab work - Discuss experiment results and calculations ESSAY 1 February 12 PS 1 February 13 - Begin ch. 16 – EQUILIBRIUM - Review dynamic aspects of equilibrium systems LAB REPORT February 20 - Discuss Kc lab and begin solution making Abraham Lincoln’s Birthday February 19 George Washington’s Birthday PS PS PS PS PS PS 1: 2: 3: 4: 5: 6: ch. ch. ch. ch. ch. ch. ESSAY 2 15 15 15 15 16 16 January 31 - Work on problems - Discuss integrated rate laws February 1 - Discuss temperature and the Arrhenius equation February 2 - Discuss rate law experiment and begin lab work SP 1a February 7 - Work on problems - Discuss mechanisms and rate- determining steps PS 2 February 14 - Define K expressions – K, Kc, Kp and G - Work on problems SP 1b February 8 - Review PE diagrams - Discuss reversibility of reactions PS 3 February 15 - Work on sample problems - Discuss special cases of equilibrium SP 1c February 9 - QUIZ – Kinetics PS 4 February 21 - Continue lab work PS 5 February 22 - Complete lab work - Discuss write-up computations SP 3 February 23 - Work on thermodynamics equilibrium problems PS 6 SP 4 SP 2 February 16 - Discuss Le Chatelier’s Principle (#5,6,8,11,12,19,22,23,24,25,27,28,31-34) (#40,42,43,46,47,61,65,79) (#13,35,36,48-51,54,56,58,60,63) (#66,68,70,73,81-86) (#10,12,14,18,19,21,23-25) (#28,30,32-34,36,38,40,42,44,45,50,59,62,63) 4 Course Laboratory Experiments: Laboratory experiments and classroom demonstrations are a vital and integral part of the AP Chemistry course. Often to introduce a new chapter or unit, I will perform a demonstration or two. We are fortunate indeed to have a spacious and safe laboratory facility; our science department was modernized just four years ago. Our school district supports the purchase of a wide variety of equipment. Our science building has a computer lab associated with it that is frequently used by students for internet work or plotting and analyzing of data. During their first-year college-preparatory chemistry course, students will have completed the following experiments that are either a part of the recommended list of lab experiences in the AP CHEMISTRY COURSE DESCRIPTION handbook or which are fundamental to the ability of the students to better perform the labs that will be required of them at the second-year, Advanced Placement level: 1. Determination of the mass and mole relationship in a chemical reaction - A single displacement reaction occurs between copper wire and silver nitrate 2. Demonstration of the conservation of mass in a chemical reaction - Honors Chemistry students perform the classic “copper recovery cycle” laboratory, involving an overview of single displacement, precipitation, decomposition, and oxidation-reduction reactions 3. Determination of the molar volume of a gas - Hydrogen gas is generated in a gas-collecting buret over water when magnesium ribbon reacts with hydrochloric acid 4. Determination of the waters of hydration in a chemical compound - Done as a class demonstration, followed by student computations, copper sulfate pentahydrate is slowly heated and dehydrated, then rehydrated 5. Establishment of a cooling and heating curve - Paradichlorobenzene is heated and then cooled in a water bath; time and temperature are tabulated. Then a solidified pdB sample is warmed in a water bath; again, time and temperature data are gathered. 6. Determination of the enthalpy change associated with a reaction - Three separate reactions involving the dissolving and subsequent neutralizing of sodium hydroxide and hydrochloric acid allow the students to use Hess’ Law to compute the enthalpy of reaction 7. Separation and qualitative analysis of cations and anions - Solubility data is gathered as students prepare a 10 x 10 grid of ionic combinations; the data is subsequently used to separate an unknown sample 8. Synthesis of an organic compound - Again completed as a classroom demonstration, methyl alcohol and salicylic acid are combined to form methyl salicylate 9. Determination of the molarity of a weak acid by means of acid/base titration 5 - Samples of fruit juice, vinegar, and carbonated beverages are titrated against a dilute sodium hydroxide solution 10. Determination of the effect of concentration and temperature on the rate of a reaction - The classic starch/iodine clock reaction is run – in the first half, students vary concentration and measure time, in the second half, they vary temperature and measure time It should also be noted that all first-year chemistry students complete an independent, individualized spring chemistry project involving both laboratory work and extensive research. These projects certainly help develop the laboratory skills of students who then subsequently enter the AP Chemistry course. Some of the topics assigned include: - the determination of an ionization constant for acetic acid - the determination of the strength of a bleach - the synthesis of alum, chrome alum - the determination of products formed when various solutions are electrolyzed - the determination of the Avogadro number by electrochemical means During the second-year Advanced Placement course, then, students complete additional formal experiments, as well as information activity-demonstrate labs which more quickly give a visual understanding of a particular chemical reaction. Following each experiment a formal lab report is completed. Students are asked frequently to employ Excel (or other spreadsheet/graphing programs) and to use graphing calculators to analyze data. Lab reports are formatted in this manner: I. II. III. IV. V. STATEMENT OF PURPOSE SUMMARY OF PROCEDURE DATA TABLE RESULTS, CALCULATIONS, AND QUESTIONS CONCLUSION AND ERROR ANALYSIS (a minimum one page in length) Advanced Placement Chemistry laboratory experiments include: 11. A Study of Density of Solids, Liquids and Solutions Students use direct measurement of mass, length, and volume, as well as water displacement, to study the density of aluminum foil, another metal solid, salt water solutions of varying percentage strength, water and another unknown liquid 12. Determination of the Empirical Formula of a Hydrated Compound Students determine the formula of a hydrated copper chloride salt 13. Determination of the Wavelength of Visible Spectral Lines of Hydrogen and Rydberg Constant 6 Students employ Young’s Law and a diffraction grating/gas discharge tube set up to measure the wavelengths of hydrogen’s spectral lines and graphically determine the value of the Rydberg constant 14. Construction of Styrofoam Models of a Variety of Molecules Students use Styrofoam balls, toothpicks and map tacks to construct models of 10 different molecules or ions, determining geometry, shape, polarity, resonance structures, bond order for each model 15. Survey of Oxidation-Reduction Reactions Students perform about fifty separate redox experiments, including the burning of magnesium and testing the pH of the oxide added to water, the establishment of an activity series of metals, the observation of a number of reactions of potassium permangnate, hydrogen peroxide, sodium nitrite, and potassium dichromate 16. Determination of the Molecular Weight of an Unknown Iron(II) Compound Students standardize a potassium permanganate solution using sodium oxalate, and then subsequently use that permanganate solution to determine the molecular weight of an unknown iron(II) compound by means of oxidation-reduction titration 17. Determination of the Molecular Weight of a Volatile Compound (Dumas Method) Students use the Dumas method of vaporizing an unknown liquid in a boiling water bath to determine its molecular weight. 18. Determination of the Molecular Weight of an Unknown Compound (Freezing Point Depression Method) A known mass of powdered sulfur is added to a sample of paradichlorobenzene, and the difference in freezing temperature between the sample (and that of pure pdB) is used to determine the molecular weight of sulfur. 19. Determination of a Rate Law The classic starch-iodine clock reaction is performed, varying the concentrations of the reactants. Graphical analysis reveals the rate order of both the iodide ion and the hydrogen peroxide used in the reaction. 20. Determination of an Equilibrium Constant Students spectrophotometrically measure absorbances and prepare a standard reference graph of absorbance v. concentration for the iron(III) thiocyanate equilibrium system. They then use that graph to determine the equilibrium constant for the reaction by preparing solutions of varying composition and color. 21. Determination of a Ka Students first determine the volume of standardized hydroxide solution needed to titrate a sample of dilute acetic acid. They then establish buffer solutions, measure their pH values, and use those values to determine an average ionization constant for acetic acid. 22. Determination of a Ksp 7 Students prepare a solution of calcium hydroxide (and also a solution of calcium hydroxide containing some addition calcium chloride as a common ion). They titrate the solution against hydrochloric acid, determine the Ksp and observe the impact of the common ion effect. 23. Survey of Electrolysis Reactions Students use 9-volt batteries to electrolyze solutions of potassium iodide, sulfuric acid, and lead nitrate. They also prepare and electrolyze with iron nails a gel containing phenolphthalein, potassium ferricyanide. FOLLOWING THE AP EXAM: 24. Synthesis of a Coordination Compound Students synthesize and then analyze for ion content the potassium iron oxalato coordination compound. 25. Individual Chemistry Projects Each student has the opportunity individually or with a partner to perform a demonstration or experiment. Course Outline: Although not an exhaustive list of topics covered, the following outline identifies the primary concepts and problems that are covered in each chapter or unit. ADVANCED PLACEMENT CHEMISTRY – First Semester Outline o [Chapter references which are given refer to the primary text. Students are also encouraged to work through Practice Problems Book . . . pages 1-39] o During the summer before the AP Chemistry course begins, students are assigned the task of memorizing a large group of ions and common compounds. They are also given a variety of problems to solve, based on algebraic formulas they would have learned in their first-year courses. 1. Introduction (1 week) CHAPTERS 1,2 safety density intensive vs. extensive properties atomic weight and isotopes [NOTE: This chapter draws significantly on the experience of the students from firstyear chemistry.] CHAPTER TO CHAPTER LINK: Now that students know the ‘bits and pieces’ of matter in nature, we begin to investigate their interactions. 8 2. Stoichiometry (2 weeks) CHAPTERS 3,4 ions and formulas for ionic compounds empirical formulas (from percentages, for hydrates, and also from combustion data) molecular formulas balancing chemical equations types of chemical reactions limiting reactant problems percentage yield v. theoretical yield chemical analysis and percentage purity [NOTE: This chapter draws significantly on the experience of the students from firstyear chemistry.] CHAPTER TO CHAPTER LINK: Now that students know the rudiments of the relationships that exist when substances interact and react, we begin to investigate why various substances demonstrate the properties that they do. 3. Atomic Structure and Quantum Mechanics (2 1/2 weeks) CHAPTERS 7,8 energy and photons, the electromagnetic spectrum spectral line evidence photoelectric effect cathode ray tube evidence gold foil scattering experiment deBroglie wavelength of particles wave mechanical view of the atom – Schrodinger equation electron configurations and the Aufbau process orbitals and their shapes hybridization periodic trends of electron configurations quantum numbers descriptive chemistry – applying the Periodic Table to reaction tendencies CHAPTER TO CHAPTER LINK: Now that students know how electrons behave and how they populate various orbitals within energy levels within atoms, we now move to investigate how those electron populations allow atoms to link together. 4. Chemical Bonding (2 1/2 weeks) CHAPTERS 9,10 9 Lewis structures (with instruction in resonance, formal charge, molecules that do and do not obey the octet rule) VSEPR types of interatomic bonds: nonpolar covalent, ionic, polar covalent bond polarity v. molecular polarity valence bond theory and hybridization MO theory, sigma and pi bonds, bonding and antibonding orb itals types of crystal lattices – density calculations CHAPTER TO CHAPTER LINK: Now that students know how atoms link together to become molecules, and that those molecules have polarity tendencies, we begin to investigate how the reactivity of molecules is revealed in aqueous solution. 5. Reactions in Solution (3 weeks) CHAPTERS 5,21 oxidation reduction reactions o balancing redox equations o equivalents, equivalent weight o predicting results of redox reactions o redox titrations • acid/base reactions o Arrhenius v. Bronsted-Lowry theories o weak v. strong acids/bases o acid and base anhydrides o writing acid/base equations o acid/base titrations precipitation reactions o solubility rules o identifying common gases (CO2, NH3 ) produced in reactions o net ionic equations descriptive chemistry – applying Periodic Table position/family to types of chemical reactions [NOTE: Once the students are given instruction is how to identify types of reactions and then to predict the products of chemical reactions, each test they subsequently take for the rest of the year includes a sample of equation prediction problems.] CHAPTER TO CHAPTER LINK: Now that students know that many chemical reactions occur in aqueous solution where particles are mobile, we begin to investigate the overall kinetic activity and energy of particles. 6. Gases (2 weeks) 10 CHAPTER 12 individual gas laws (Boyle’s, Charles’, Gay-Lussac’s) general gas law absolute zero and its significance Graham’s law of diffusion – molecular weight v. molecular speed gas stoichiometry ideal gas equation v. real gas equation applications of PV=nRT rms velocity of molecules (derivation of Boltzmann equation) CHAPTER TO CHAPTER LINK: Now that students know the principles of kinetic-molecular theory and that there is a temperature v. volume relationship, why don’t real materials follow the Charles Law all the way down to absolute zero? We begin to investigate. 7. Intermolecular Forces (2 weeks) CHAPTER 13 dispersion forces, dipole interactions, hydrogen bonds calorimetry calculations phase diagrams cooling and heating curves types of solids (molecular, ionic, metallic and covalent) CHAPTER TO CHAPTER LINK: Now that students know that intermolecular forces really determine the way that particles behave in a physical sense, what types of physical properties do various types of solutes impart to solutions? We begin to investigate. 8. Colligative Properties (2 weeks – this chapter is primarily done by students on their own over our Winter Break/Christmas Vacation) CHAPTER 14 calculations of concentrations Henry’s Law (gas solubility) Raoult’s Law (vapor pressure) freezing point depression/boiling point elevation osmotic pressure van’t Hoff factor ideal solutions fractional distillation CHAPTER TO CHAPTER LINK: 11 Now that students know so many varied properties of substances and solutions in nature, we begin to investigate the true driving forces or unifying and energizing principles behind the behavior of chemicals. 9. Thermodynamics (2 1/2 weeks) CHAPTERS 6,20 0th, 1st, 2nd and 3rd Laws of Thermodynamics state functions (and significance of positive and negative values) enthalpy calculations (calorimetry, heats of formation, Hess’ Law, bond energies) entropy Gibbs’ free energy and determination of spontaneity of reactions Gibbs-Helmholtz equation ADVANCED PLACEMENT CHEMISTRY - Second Semester Outline o [Practice Problems Book . . . pages 40ff] CHAPTER TO CHAPTER LINK: As the new semester unfolds, we begin to apply those principles of thermodynamics (and the “before and after” aspects of chemical reactions they teach) to investigate how chemical reactions really proceed. What factors determine how fast or slow reactions proceed? 10. Chemical Kinetics (2 weeks) CHAPTER 15 collision theory rate orders and rate laws (emphasis on first- and second-order) half-life equations which relate concentration to time Arrhenius equation (relationships between temperature and rate) catalysts reaction mechanisms CHAPTER TO CHAPTER LINK: Now that the principles of factors that determine reaction rates are established, we begin to investigate what happens to reactions happening in closed systems as time goes by and the reverse reaction begins to affect the overall success of a reaction. Chemical Equilibrium (2 1/2 weeks) CHAPTER 16 Kc and Kp G = -RTlnK 11. 12 LeChatelier’s Principle variety of problems CHAPTER TO CHAPTER LINK: Now that we understand the basic premises of chemical equilibrium, we begin to investigate the complex applications of equilibrium to water and to aqueous solutions. Acid-Base Equilibrium (3 1/2 weeks) CHAPTERS 17,18 definitions of acids and bases (Arrhenius, Bronsted, and Lewis) weak v. strong acids and bases KA and KB pH and the role of water (KW) conjugate acids and bases polyprotics acids hydrolysis buffers titrations (strong v. strong and weak v. strong) titration graphs/curves indicators 12. CHAPTER TO CHAPTER LINK: Now that we understand the basic premises of chemical equilibrium and their applications to water and to aqueous solutions, we begin to investigate equilibrium as it relates to slightly soluble materials. Solubility Equilibrium (1 1/2 weeks) CHAPTER 19 Ksp common ion effect complex ions simultaneous equilibria 13. CHAPTER TO CHAPTER LINK: One important aspect of acid-base equilibrium is its dependence on proton exchange between substances. We begin to investigate the chemical reactions are related to electron exchange. Electrochemistry (2 weeks) CHAPTER 21 oxidation reduction reactions galvanic cells (anode, cathode, etc.) 14. 13 electrolytic cells and prediction of electrolysis reactions Nernst equation practical applications of electrolytic cells relationships among G, Eo and K CHAPTER TO CHAPTER LINK: The remaining chapters are indeed not so closely interlinked, but simply chapters which help students survey special topics within chemistry. Organic Chemistry (1 week) CHAPTER 11 fundamental nomenclature of hydrocarbons common functional groups (including alcohols, carboxylic acids, amines, esters, aldehydes, ketones, ethers, etc.) isomers (structural, geometric and optical) common reactions (including addition, substitution, esterification and oxidation) 15. Nuclear Chemistry (1 week) CHAPTER 23 types of nucleons transmutations (predicting products of equations) binding energy and E = mc2 mass defect half-life and decay rates common decay reactions (238U) 16. Transition Metal Chemistry (as time allows) CHAPTER 22 ligands and coordination number nomenclature for coordination compounds enantiomers and optical isomerization 17. I schedule the year so as to allow somewhere between two and three weeks of concentrated review time before the AP exam comes in May. I have accumulated more than thirty years of old AP chemistry exams, and I selectively use them to prepare a study manual for the students. The manual contains about 16 years of exams. Each night during our intense review period, I assign the students theme-based homework problems. For example, one night might emphasize a review of thermodynamics, the next a review of kinetics. I use this time with the students to develop their ability to relearn material in a short period of time. We often will work in small study groups. 14 I have been teaching (and loving) AP Chemistry since 1983, and I have attended more than ten workshops during that time. I have also had the privilege of mentoring eight other teachers who are new to the world of teaching an advanced placement course, a number of them are my own former students who have found placement as teachers in local high schools. I have also had the privilege of working to develop teaching materials and coauthor books, both for first-year and AP chemistry courses. I continue to try to find new and better ways to more thoroughly, interestingly, accurately, and effectively teach the science of chemistry to my students. 15