ATOMIC STRUCTURE In this unit we will be describing elements and compounds. Both are made from atoms. Therefore by studying the atom (the basic building block of the universe) we study elements and compounds. MODELS A model is anything that represents the properties of another object or system. Some models are miniature copies of the things they represent, while other models represent things that can-not be seen. The model has been changed many times by many different scientists. As each new discovery occurred it described the atom with better precision and understanding. DEVELOPMENT OF ATOMIC MODELS We know that matter is anything that has mass and volume but what is matter made of? Atoms cannot actually be seen. We rely on _________________________ and create _________________ to explain our observations. EARLY GREEK MODEL: Read pages 111-118 in PS textbook to fill in blank spaces. The ancient Greeks believed that all matter was made up of 4 elements, ____________, ____________, ____________, and_______________________. Democritus is credited with providing the term atom. He believed that matter could only be broken down so far and eventually the smallest piece of matter would be obtained. He described this piece as _____________, which means, “not to be cut” or “indivisible.” We now call it the atom. (HINT: good essay question on a test) IT TOOK OVER 2000 YEARS FOR THIS TO BECOME ACCEPTED. THOMPSON’S MODEL He described his model as a pudding where positive and negatively charged particles were floating around like raisins in plum pudding. He is credited for discovering the __________________. Thompson knew that electrons are ____________charged. He also knew that all atoms must be _________. So he concluded that there must be something ___________________ also in an atom. He was never able to find it though. RUTHERFORD’S MODEL He is credited for finding the positively charged particle that Thompson could not find. He performed a very famous experiment called____________________________. He fired a stream of negatively charged particles at a very thin sheet of gold foil. Surrounding the gold foil was a screen to detect these particles. Diagram: If Thompson was correct in his theory the negatively charged particles would pass right through “the pudding” like “bullets” through tissue paper” with only a slight angle of deflection. What actually occurred was some particles passed through with ____________ deflection at all. Even more amazing was that some particles were deflected almost _______________________as if it hit something solid. Therefore Rutherford concluded that the positively charged particles were clustered together in a __________ packed center and called it the ______________________. The __________________ are scattered outside near the____________________ of the atom. He also stated that atoms were mostly__________________________________. (HINT: KNOW THAT) BOHR MODEL Bohr focused on finding where in the atom ____________________ are located. He stated that electrons orbit the nucleus in specific paths like planets orbit the sun. Energy determines the amount of distance an orbit can be from the nucleus. ________________ energy is required the farther away the orbital or shell is from the nucleus. Therefore an electron that is farther away from the nucleus the more energy it must have. EARLY MODERN MODEL The modern model is based primarily on Rutherford and Bohr’s model. The main difference is the location of electrons. Electrons actually travel in random paths at certain distances away from the nucleus. The exact location of the electron is impossible to know (right now). However using very complicated formulas we can predict the probability of where to find them. There is also densely packed center called the nucleus where protons and neutrons are found. Summary of the modern model All elements are composed of_______________. All atoms of the same element are alike in those________________________________ that determine the chemical properties of the element. However they can (and do) have different_______________. Atoms of different elements are ______________________. In particular they have a different number of ______________________. Atoms have detailed structure that temporarily changes during a _____________. Compounds are formed when 2 or more atoms are joined together. They are joined in a ______________. Atoms can be broken down physically (not chemically). The particles no longer have the same chemical composition as the original atom. These particles are called____________________________________. They are the _______________, _____________________, & ______________________. Nucleons are particles that make up the ____________________ of an atom. They are the Proton and the Neutron. Protons have a ____________________ charge. Neutrons have no charge. They are said to be ________________. Electrons are outside the nucleus and have a ________________________ charge. The mass of subatomic particles is measured in units called A.M.U. This stands for Atomic Mass Units. An A.M.U. is a standard measurement used in order to measure the mass of such small items. It is based on the mass of the carbon atom. A carbon atom has a mass of 12. So an A.M.U is defined as 1/12th the mass of a carbon atom. Protons have a mass of 1 AMU. Neutrons also have a mass of 1AMU. Electrons have a mass of 1/1836th of a proton. That is to say that an atom would need to have 1836 electrons to equal the mass of 1 proton. When calculating the mass of atom electrons are considered not to add any additional mass. PARTICLE MASS LOCATION CHARGE PERIODIC TABLE Atomic number is defined as the number of_______________________ only. So to find the number of protons find the atomic number. THE NUMBER OF PROTONS NEVER CHANGE IN A STABLE (NORMAL) ATOM It just so happens that the number of protons must equal the number of _________________. This is to ensure that all atoms remain neutral. This is also why the neutron must remain neutral. The mass number (atomic mass) is the mass of the atom. The mass is due to the mass of all the protons plus all the neutrons. Atomic Mass = # of Protons + # of Neutrons Therefore to calculate the Atomic mass add the # of protons plus the # of neutrons. To calculate the number of Neutrons: # of Neutrons = Atomic mass – Atomic Number Remember the atomic number is the # of protons. Isotopes Isotopes are atoms of the same element having different masses due to a different number of____________________. Example: Atomic mass is really the average atomic mass. It is the_________ of all the known ______________ based on ____________________ Example ELECTRONS Remember the number of electrons must equal the number of protons in an atom. Electrons cannot be located exactly. We use models to represent the area of highest probability of finding an electron (remember the cubes with dots). These areas are called _______________________________, __________________________, _______________________or________________________________________. For simplicity reasons we will use the Bohr model to show the location of the electrons. However it should be noted that this model is not specific and the current models can locate electrons much more exactly (ORBITAL MODEL). Both models are based on probability. Each Principal Energy Level (shell,orbit etc) shows where the electrons are. Remember the location is based on energy. Electrons can circle the nucleus anywhere inside these areas. They may also change shells. With these changes energy is released or absorbed by the electron. Electrons are said to be in the________________ when they absorb energy. Electrons cannot circle in the areas between the shells. Each Shell can accommodate only a very specific number of electrons. ACCORDING TO THE BOHR MODEL 1st Principal Energy Level or K Shell = 2 electrons 2nd Principal Energy Level or L Shell = 8 electrons 3rd Principal Energy Level or M Shell = 8 electrons 4th Principal Energy Level or N Shell = 8 electrons Drawing Atoms Using the Bohr Model Ions- If an atom loses or gains electrons the atom now has a _______________ and is called an ion. A positive charge is caused by ___________ electrons A negative charge is caused by ___________ electrons Examples: RADIOACTIVITY: The atom no longer remains stable. The Nucleus breaks down and releases particles and energy. The atom can change and become a different element. This is called___________________________. Alpha Decay: Beta Decay: Gamma Radiation: FORCES WITHIN THE ATOM Electromagnetic Force: Oppositely charged particles attract each other. Same charge particle repel each other. Strong Force: This is the strongest force. Over powers the electromagnetic force and allows protons to stay together. Only works when protons are close together and have limited range. Weak Force: This is responsible for radioactive decay (the breakdown of an atom). Then sun is powered by the weak force. (not actually the weakest force) Gravity This is the weakest force. All objects in nature attract each other. The role of gravity in the atom is uncertain. LAW OF CONSERVATION OF MATTER Matter exists and cannot be made from nothing. Also once matter exists it must always exist. This is called the Law of Conservation of Matter. It states: ______________________________________________________________________ ______________________________________________________________________ The law of conservation of matter demands that all matter must be accounted for in a chemical reaction. Therefore all chemical equations must be _________________. Balancing equations is done so that the law of conservation of energy is obeyed. HINT: you are responsible for knowing why equations are balanced and knowing whether an equation is balanced or not. Example: CHEMICAL EQUATIONS Chemical equations show chemical reactions. During a chemical reaction substances are ______________________________________________________. Examples: