Registration form Chlorination 303 CEU Training Course $200.00 48 HOUR RUSH ORDER PROCESSING FEE ADDITIONAL $50.00 Start and Finish Dates: ___________________________ You will have 90 days from this date in order to complete this course List number of hours worked on assignment must match State Requirement. ________ Name________________________________Signature___________________________ I have read and understood the disclaimer notice on page 2. Digitally sign XXX Address: _______________________________________________________________ City_________________________________State___________Zip__________________ Email______________________________ Fax (______) ________________________ Phone: Home (______) ______________________Work (______ ) ________________________ Operator ID# ______________________________________Exp Date____________ Please circle/check which certification you are applying the course CEU’s. Water Treatment _________ Distribution _______ Collection _________ Wastewater Treatment______ Other _______________________ Your certificate will be mailed to you in about two weeks. Technical Learning College TLC PO Box 3060, Chino Valley, AZ 86323 Toll Free (866) 557-1746 Fax (928) 272-0747 info@tlch2o.com If you’ve paid on the Internet, please write your Customer#_________________ Please invoice me, my PO#__________________________________________ Please pay with your credit card on our website under Bookstore or Buy Now. Or call us and provide your credit card information. We will stop mailing the certificate of completion so we need either your fax number or email address. We will e-mail the certificate to you, if no e-mail address; we will fax it to you. 1 Chlorination 303 11/7/2015 Assignment DISCLAIMER NOTICE I understand that it is my responsibility to ensure that this CEU course is either approved or accepted in my State for CEU credit. I understand State laws and rules change on a frequent basis and I believe this course is currently accepted in my State for CEU or contact hour credit, if it is not, I will not hold Technical Learning College responsible. I also understand that this type of study program deals with dangerous conditions and that I will not hold Technical Learning College, Technical Learning Consultants, Inc. (TLC) liable for any errors or omissions or advice contained in this CEU education training course or for any violation or injury caused by this CEU education training course material. I will call or contact TLC if I need help or assistance and double-check to ensure my registration page and assignment has been received and graded. State Approval Listing Link, check to see if your State accepts or has pre-approved this course. Not all States are listed. Not all courses are listed. If the course is not accepted for CEU credit, we will give you the course free if you ask your State to accept it for credit. Professional Engineers; Most states will accept our courses for credit but we do not officially list the States or Agencies. Please check your State for approval. State Approval Listing URL… http://www.tlch2o.com/PDF/CEU%20State%20Approvals.pdf You can obtain a printed version of the course from TLC for an additional $69.95 plus shipping charges. AFFIDAVIT OF EXAM COMPLETION I affirm that I personally completed the entire text of the course. I also affirm that I completed the exam without assistance from any outside source. I understand that it is my responsibility to file or maintain my certificate of completion as required by the state or by the designation organization. Grading Information In order to maintain the integrity of our courses we do not distribute test scores, percentages or questions missed. Our exams are based upon pass/fail criteria with the benchmark for successful completion set at 70%. Once you pass the exam, your record will reflect a successful completion and a certificate will be issued to you. 2 Chlorination 303 11/7/2015 Assignment Chlorination 303 CEU Course Answer Key Name ___________________________ Telephone # ________________ Did you check with your State agency to ensure this course is accepted for credit? Method of Course acceptance confirmation. Please fill this section Website __ Telephone Call___ Email____ Spoke to_________________________ Did you receive the approval number if Applicable? _____________ What is the approval number if Applicable? ____________________ Please circle, underline, bold or X only one correct answer 20. A B C D E F 39. A B C D E F 1. A B C D E F 2. A B C D E F 21. A B C D E F 40. A B C D E F 3. A B C D E F 22. A B C D E F 41. A B C D E F 4. A B C D E F 23. A B C D E F 42. A B C D E F 5. A B C D E F 24. A B C D E F 43. A B C D E F 6. A B C D E F 25. A B C D E F 44. A B C D E F 7. A B C D E F 26. A B C D E F 45. A B C D E F 8. A B C D E F 27. A B C D E F 46. A B C D E F 9. A B C D E F 28. A B C D E F 47. A B C D E F 10. A B C D E F 29. A B C D E F 48. A B C D E F 11. A B C D E F 30. A B C D E F 49. A B C D E F 12. A B C D E F 31. A B C D E F 50. A B C D E F 13. A B C D E F 32. A B C D E F 51. A B C D E F 14. A B C D E F 33. A B C D E F 52. A B C D E F 15. A B C D E F 34. A B C D E F 53. A B C D E F 16. A B C D E F 35. A B C D E F 54. A B C D E F 17. A B C D E F 36. A B C D E F 55. A B C D E F 18. A B C D E F 37. A B C D E F 56. A B C D E F 19. A B C D E F 38. A B C D E F 57. A B C D E F 3 Chlorination 303 11/7/2015 Assignment 58. A B C D E F 90. A B C D E F 122. A B C D E F 59. A B C D E F 91. A B C D E F 123. A B C D E F 60. A B C D E F 92. A B C D E F 124. A B C D E F 61. A B C D E F 93. A B C D E F 125. A B C D E F 62. A B C D E F 94. A B C D E F 126. A B C D E F 63. A B C D E F 95. A B C D E F 127. A B C D E F 64. A B C D E F 96. A B C D E F 128. A B C D E F 65. A B C D E F 97. A B C D E F 129. A B C D E F 66. A B C D E F 98. A B C D E F 130. A B C D E F 67. A B C D E F 99. A B C D E F 131. A B C D E F 68. A B C D E F 100. A B C D E F 132. A B C D E F 69. A B C D E F 101. A B C D E F 133. A B C D E F 70. A B C D E F 102. A B C D E F 134. A B C D E F 71. A B C D E F 103. A B C D E F 135. A B C D E F 72. A B C D E F 104. A B C D E F 136. A B C D E F 73. A B C D E F 105. A B C D E F 137. A B C D E F 74. A B C D E F 106. A B C D E F 138. A B C D E F 75. A B C D E F 107. A B C D E F 139. A B C D E F 76. A B C D E F 108. A B C D E F 140. A B C D E F 77. A B C D E F 109. A B C D E F 141. A B C D E F 78. A B C D E F 110. A B C D E F 142. A B C D E F 79. A B C D E F 111. A B C D E F 143. A B C D E F 80. A B C D E F 112. A B C D E F 144. A B C D E F 81. A B C D E F 113. A B C D E F 145. A B C D E F 82. A B C D E F 114. A B C D E F 146. A B C D E F 83. A B C D E F 115. A B C D E F 147. A B C D E F 84. A B C D E F 116. A B C D E F 148. A B C D E F 85. A B C D E F 117. A B C D E F 149. A B C D E F 86. A B C D E F 118. A B C D E F 150. A B C D E F 87. A B C D E F 119. A B C D E F 151. A B C D E F 88. A B C D E F 120. A B C D E F 152. A B C D E F 89. A B C D E F 121. A B C D E F 153. A B C D E F 4 Chlorination 303 11/7/2015 Assignment 154. A B C D E F 186. A B C D E F 218. A B C D E F 155. A B C D E F 187. A B C D E F 219. A B C D E F 156. A B C D E F 188. A B C D E F 220. A B C D E F 157. A B C D E F 189. A B C D E F 221. A B C D E F 158. A B C D E F 190. A B C D E F 222. A B C D E F 159. A B C D E F 191. A B C D E F 223. A B C D E F 160. A B C D E F 192. A B C D E F 224. A B C D E F 161. A B C D E F 193. A B C D E F 225. A B C D E F 162. A B C D E F 194. A B C D E F 226. A B C D E F 163. A B C D E F 195. A B C D E F 227. A B C D E F 164. A B C D E F 196. A B C D E F 228. A B C D E F 165. A B C D E F 197. A B C D E F 229. A B C D E F 166. 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A B C D E F 249. A B C D E F 5 Chlorination 303 11/7/2015 Assignment 250. A B C D E F 282. A B C D E F 314. A B C D E F 251. A B C D E F 283. A B C D E F 315. A B C D E F 252. A B C D E F 284. A B C D E F 316. A B C D E F 253. A B C D E F 285. A B C D E F 317. A B C D E F 254. A B C D E F 286. A B C D E F 318. A B C D E F 255. A B C D E F 287. A B C D E F 319. A B C D E F 256. A B C D E F 288. A B C D E F 320. A B C D E F 257. A B C D E F 289. A B C D E F 321. A B C D E F 258. A B C D E F 290. A B C D E F 322. A B C D E F 259. A B C D E F 291. A B C D E F 323. A B C D E F 260. A B C D E F 292. A B C D E F 324. A B C D E F 261. A B C D E F 293. A B C D E F 325. A B C D E F 262. A B C D E F 294. A B C D E F 326. A B C D E F 263. A B C D E F 295. A B C D E F 327. A B C D E F 264. A B C D E F 296. A B C D E F 328. A B C D E F 265. A B C D E F 297. A B C D E F 329. A B C D E F 266. A B C D E F 298. A B C D E F 330. A B C D E F 267. A B C D E F 299. A B C D E F 331. A B C D E F 268. A B C D E F 300. A B C D E F 332. A B C D E F 269. A B C D E F 301. A B C D E F 333. A B C D E F 270. A B C D E F 302. A B C D E F 334. A B C D E F 271. A B C D E F 303. A B C D E F 335. A B C D E F 272. A B C D E F 304. A B C D E F 336. A B C D E F 273. A B C D E F 305. A B C D E F 337. A B C D E F 274. A B C D E F 306. A B C D E F 338. A B C D E F 275. A B C D E F 307. A B C D E F 339. A B C D E F 276. A B C D E F 308. A B C D E F 340. A B C D E F 277. A B C D E F 309. A B C D E F 341. A B C D E F 278. A B C D E F 310. A B C D E F 342. A B C D E F 279. A B C D E F 311. A B C D E F 343. A B C D E F 280. A B C D E F 312. A B C D E F 344. A B C D E F 281. A B C D E F 313. A B C D E F 345. A B C D E F 6 Chlorination 303 11/7/2015 Assignment 346. A B C D E F 378. A B C D E F 410. A B C D E F 347. A B C D E F 379. A B C D E F 411. A B C D E F 348. A B C D E F 380. A B C D E F 412. A B C D E F 349. A B C D E F 381. A B C D E F 413. A B C D E F 350. A B C D E F 382. A B C D E F 414. A B C D E F 351. A B C D E F 383. A B C D E F 415. A B C D E F 352. A B C D E F 384. A B C D E F 416. A B C D E F 353. A B C D E F 385. A B C D E F 417. A B C D E F 354. A B C D E F 386. A B C D E F 418. A B C D E F 355. A B C D E F 387. A B C D E F 419. A B C D E F 356. A B C D E F 388. A B C D E F 420. A B C D E F 357. A B C D E F 389. A B C D E F 421. A B C D E F 358. A B C D E F 390. A B C D E F 422. A B C D E F 359. A B C D E F 391. A B C D E F 423. A B C D E F 360. A B C D E F 392. A B C D E F 424. A B C D E F 361. A B C D E F 393. A B C D E F 425. A B C D E F 362. A B C D E F 394. A B C D E F 426. A B C D E F 363. A B C D E F 395. A B C D E F 427. A B C D E F 364. A B C D E F 396. A B C D E F 428. A B C D E F 365. A B C D E F 397. A B C D E F 429. A B C D E F 366. A B C D E F 398. A B C D E F 430. A B C D E F 367. A B C D E F 399. A B C D E F 431. A B C D E F 368. A B C D E F 400. A B C D E F 432. A B C D E F 369. A B C D E F 401. A B C D E F 433. A B C D E F 370. A B C D E F 402. A B C D E F 434. A B C D E F 371. A B C D E F 403. A B C D E F 435. A B C D E F 372. A B C D E F 404. A B C D E F 436. A B C D E F 373. A B C D E F 405. A B C D E F 437. A B C D E F 374. A B C D E F 406. A B C D E F 438. A B C D E F 375. A B C D E F 407. A B C D E F 439. A B C D E F 376. A B C D E F 408. A B C D E F 440. A B C D E F 377. A B C D E F 409. A B C D E F 441. A B C D E F 7 Chlorination 303 11/7/2015 Assignment 442. A B C D E F 463. A B C D E F 484. A B C D E F 443. A B C D E F 464. A B C D E F 485. A B C D E F 444. A B C D E F 465. A B C D E F 486. A B C D E F 445. A B C D E F 466. A B C D E F 487. A B C D E F 446. A B C D E F 467. A B C D E F 488. A B C D E F 447. A B C D E F 468. A B C D E F 489. A B C D E F 448. A B C D E F 469. A B C D E F 490. A B C D E F 449. A B C D E F 470. A B C D E F 491. A B C D E F 450. A B C D E F 471. A B C D E F 492. A B C D E F 451. A B C D E F 472. A B C D E F 493. A B C D E F 452. A B C D E F 473. A B C D E F 494. A B C D E F 453. A B C D E F 474. A B C D E F 495. A B C D E F 454. A B C D E F 475. A B C D E F 496. A B C D E F 455. A B C D E F 476. A B C D E F 497. A B C D E F 456. A B C D E F 477. A B C D E F 498. A B C D E F 457. A B C D E F 478. A B C D E F 499. A B C D E F 458. A B C D E F 479. A B C D E F 500. A B C D E F 459. A B C D E F 480. A B C D E F 460. A B C D E F 481. A B C D E F 461. A B C D E F 482. A B C D E F 462. A B C D E F 483. A B C D E F Please fax the answer key to TLC (928) 272-0747 Rush Grading Service If you need this assignment graded and the results mailed to you within a 48-hour period, prepare to pay an additional rush service handling fee of $50.00. This fee may not cover postage costs. If you need this service, simply write RUSH on the top of your Registration Form. We will place you in the front of the grading and processing line. Thank you… 8 Chlorination 303 11/7/2015 Assignment Please e-mail or fax this survey along with your final exam CHLORINATION 303 CEU TRAINING COURSE CUSTOMER SERVICE RESPONSE CARD NAME: _________________________________ E-MAIL_________________________________PHONE_______________________ PLEASE COMPLETE THIS FORM BY CIRCLING THE NUMBER OF THE APPROPRIATE ANSWER IN THE AREA BELOW. Please rate the difficulty of your course. Very Easy 0 1 2 3 4 5 Very Difficult Please rate the difficulty of the testing process. Very Easy 0 1 2 3 4 5 Very Difficult Please rate the subject matter on the exam to your actual field or work. Very Similar 0 1 2 3 4 5 Very Different How did you hear about this Course?__________________________________ What would you do to improve the Course? _____________________________________________________________________ How about the price of the course? Poor __ Fair__ Average__ Good __ Great __ How was your customer service? Poor __ Fair__ Average__ Good __ Great __ Any other concerns or comments. _____________________________________________________________________ 9 Chlorination 303 8/9/2015 Assignment 10 Chlorination 303 8/9/2015 Assignment Chlorination 303 CEU Course Assignment The Chlorination 303 CEU Assignment is available in Word on the Internet for your Convenience, please visit www.ABCTLC.com and download the assignment and e mail it back to TLC. You will have 90 days from the start of this course to complete in order to receive your Professional Development Hours (PDHs) or Continuing Education Unit (CEU). A score of 70 % is necessary to pass this course. If you should need any assistance, please email all concerns and the completed manual to info@tlch2o.com. I would prefer that you utilize the enclosed answer sheet in the front, but if you are unable to do so, type out your own answer key. Please include your name and address on your manual and make copy for yourself. Multiple Choice, please select only one answer per question. There are no intentional trick questions. Principles of Modern Chemistry 1. The current model of atomic structure is the quantum mechanical model. _____________starts with the study of elementary particles, atoms, molecules, substances, metals, crystals and other aggregates of matter. This matter can be studied in solid, liquid, or gas states, in isolation or in combination. A. Nuclear chemistry D. Analytical chemistry B. Neurochemistry E. Traditional chemistry C. Organic chemistry F. None of the Above 2. The interactions, reactions and transformations that are studied in chemistry are usually the result of interactions between atoms, leading to rearrangements of the ________which hold atoms together. Such behaviors are studied in a chemistry laboratory. A. Chemical bonds D. Chemical compound B. Chemical substance(s) E. Physical chemistry C. Chemical(s) F. None of the Above 3. _____________is a transformation of some substances into one or more different substances. The basis of such a chemical transformation is the rearrangement of electrons in the chemical bonds between atoms. It can be symbolically depicted through a chemical equation, which usually involves atoms as subjects. A. Chemical element(s) D. A chemical reaction B. An electron E. Energy and entropy C. Atom F. None of the Above 4. The number of atoms on the left and the right in the equation for a _____________is equal. (When the number of atoms on either side is unequal, the transformation is referred to as a nuclear reaction or radioactive decay.) A. Chemical transformation D. The type of chemical reaction(s) B. Atom E. Mixture of substances C. Chemical propertie(s) F. None of the Above 11 Chlorination 303 8/9/2015 Assignment 5. _______________ a substance may undergo and the energy changes that may accompany it are constrained by certain basic rules, known as chemical laws. A. Chemical substance(s) D. The type of chemical reaction(s) B. Atom E. Mixture of substances C. Chemical propertie(s) F. None of the Above 6. A. B. C. Energy and entropy considerations are invariably important in_________. Chemical element(s) D. Mixture of substances An electron E. Almost all chemical studies The type of chemical reaction(s) F. None of the Above 7. ______________ are classified in terms of their structure, phase, as well as their chemical compositions. They can be analyzed using the tools of chemical analysis, e.g. spectroscopy and chromatography. Scientists engaged in chemical research are known as chemists. Most chemists specialize in one or more sub-disciplines. A. Chemical substance(s) D. The type of chemical reaction(s) B. Atom(s) E. Mixture of substances C. Chemical propertie(s) F. None of the Above Matter 8. In chemistry, matter is defined as anything that has rest mass and volume (it takes up space) and is made up of particles. The particles that make up matter have rest mass as well - not all particles have rest mass, such as____________. A. Chemical element(s) D. The photon B. An electron E. Energy and entropy C. Atom F. None of the Above 9. A. B. C. Matter can be a pure chemical substance or_________________. Chemical bond(s) D. Forms of energy Chemical substance(s) E. A mixture of substances Chemical(s) F. None of the Above Atom 10. The atom is the basic unit of chemistry. It consists of a dense core called the atomic nucleus surrounded by a space called the_____________. A. Chemical element(s) D. Photon B. An electron E. Electron cloud C. Atom F. None of the Above 11. The nucleus is made up of positively charged protons and uncharged neutrons (together called nucleons), while the electron cloud consists of negatively-charged electrons which orbit the nucleus. In a neutral atom, the negatively-charged electrons balance out the positive charge of the ______________. A. Nucleus D. Negatively-charged electrons B. Protons E. Positively charged protons C. Atom F. None of the Above (S) Means the answer can be plural or singular in nature 12 Chlorination 303 8/9/2015 Assignment 12. The nucleus is dense; the mass of a nucleon is 1,836 times that of an electron, yet the radius of ___________is about 10,000 times that of its nucleus. A. Nucleus D. Negatively-charged electrons B. An electron E. Positively charged protons C. An atom F. None of the Above 13. ________________is also the smallest entity that can be envisaged to retain the chemical properties of the element, such as electronegativity, ionization potential, preferred oxidation state(s), coordination number, and preferred types of bonds to form (e.g., metallic, ionic, covalent). A. Nucleus D. Negatively-charged electrons B. An electron E. Positively charged protons C. The atom F. None of the Above Element 14. The standard presentation of the ______________ is in the periodic table, which orders elements by atomic number. The periodic table is arranged in groups, or columns, and periods, or rows. The periodic table is useful in identifying periodic trends. A. Chemical element(s) D. Photon B. An electron E. Energy and entropy C. Atom F. None of the Above Compound 15. A compound is a pure chemical substance composed of more than one element. The properties of a compound bear little similarity to those of its_______________. A. Chemical bond(s) D. Forms of energy B. Elements E. Physical chemistry C. Chemical(s) F. None of the Above Chemical Compounds 16. A pure chemical compound is a chemical substance that is composed of a particular set of molecules or ions. Two or more elements combined into one substance through a chemical reaction form a chemical compound. All ______________are substances, but not all substances are compounds. A. Bulk chemical(s) D. Compound(s) B. Chemical(s) E. A pure chemical compound C. Mechanical processe(s) F. None of the Above 17. A chemical compound can be either atoms bonded together in molecules or crystals in which atoms, molecules or ions form a crystalline lattice. ____________ based primarily on carbon and hydrogen atoms are called organic compounds, and all others are called inorganic compounds. A. Bulk chemical(s) D. Compound(s) B. Chemical(s) E. A pure chemical compound C. Mechanical processe(s) F. None of the Above 18. Compounds containing bonds between carbon and a metal are called ____________. A. Organometallic compound(s) D. Mixture(s) B. Chemical substance(s) E. Chemical substance(s) C. Isomer(s) F. None of the Above 13 Chlorination 303 8/9/2015 Assignment 19. Compounds in which components share __________ are known as covalent compounds. Compounds consisting of oppositely charged ions are known as ionic compounds, or salts. A. Nucleus D. Negatively-charged electrons B. Electrons E. Positively charged protons C. The atom F. None of the Above 20. In organic chemistry, there can be more than one chemical compound with the same composition and molecular weight. Generally, these are called _______________. A. Organometallic compound(s) D. Mixture(s) B. Chemical substance(s) E. Chemical substance(s) C. Isomer(s) F. None of the Above 21. _________________usually have substantially different chemical properties, may be isolated and do not spontaneously convert to each other. A common example is glucose vs. fructose. A. Isomers D. Compound(s) B. Chemical(s) E. A pure chemical compound C. Mechanical processe(s) F. None of the Above Substances versus Mixtures 22. All matter consists of various elements and________________, but these are often intimately mixed together. A. Chemical compounds D. Mixture(s) B. Chemical substance(s) E. Chemical mixtures C. Isomer(s) F. None of the Above 23. _________________ contain more than one chemical substance, and they do not have a fixed composition. In principle, they can be separated into the component substances by purely mechanical processes. Butter, soil and wood are common examples of mixtures. A. Bulk chemical(s) D. Compound(s) B. Chemical(s) E. A pure chemical compound C. Mechanical processe(s) F. None of the Above Chemicals versus Chemical Substances 24. While the term _______________ is a precise technical term that is synonymous with "chemical" for professional chemists, the meaning of the word chemical varies for non-chemists within the English speaking world or those using English. A. Organometallic compound(s) D. Mixture(s) B. Chemical mixtures E. Chemical substance(s) C. Isomer(s) F. None of the Above 25. For industries, government and society in general in some countries, the word chemical includes a wider class of substances that contain many mixtures of such chemical substances, often finding application in many vocations. In countries that require a list of ingredients in products, the "chemicals" listed would be equated with "_________________". A. Chemical bond(s) D. Forms of energy B. Chemical substance(s) E. Physical chemistry C. Chemical(s) F. None of the Above (S) Means the answer can be plural or singular in nature 14 Chlorination 303 8/9/2015 Assignment 26. Within the chemical industry, manufactured "chemicals" are _______________, which can be classified by production volume into bulk chemicals, fine chemicals and chemicals found in research only: A. Organometallic compound(s) D. Mixture(s) B. Chemical substance(s) E. Chemical mixtures C. Isomer(s) F. None of the Above 27. _________________ are produced in very large quantities, usually with highly optimized continuous processes and to a relatively low price. A. Bulk chemical(s) D. Compound(s) B. Chemical(s) E. A pure chemical compound C. Mechanical processe(s) F. None of the Above 28. _______________are produced at a high cost in small quantities for special low-volume applications such as biocides, pharmaceuticals and specialty chemicals for technical applications. A. Organometallic compound(s) D. Fine chemicals B. Chemical mixtures E. Chemical substance(s) C. Isomer(s) F. None of the Above 29. ________________are produced individually for research, such as when searching for synthetic routes or screening substances for pharmaceutical activity. In effect, their price per gram is very high, although they are not sold. A. Bulk chemical(s) D. Compound(s) B. Chemical(s) E. Research chemicals C. Mechanical processe(s) F. None of the Above 30. The cause of the difference in production volume is the complexity of the molecular structure of the chemical. Bulk chemicals are usually much less complex. While fine chemicals may be more complex, many of them are simple enough to be sold as "_________________" in the synthesis of more complex molecules targeted for single use, as named above. A. Chemical bond(s) D. Forms of energy B. Chemical substance(s) E. Physical chemistry C. Building blocks F. None of the Above 31. The production of a chemical includes not only its synthesis but also its purification to eliminate _______________________ involved in the synthesis. The last step in production should be the analysis of batch lots of chemicals in order to identify and quantify the percentages of impurities for the buyer of the chemicals. A. Chemical bond(s) D. Chemical mixtures B. Chemical substance(s) E. Physical chemistry C. Chemical(s) F. None of the Above Molecule 32. A molecule is the smallest indivisible portion of a pure chemical substance that has its unique set of chemical properties, that is, its potential to undergo a certain set of ________________with other substances. A. Tetra atomic molecule(s) D. Existence of identifiable molecule(s) B. Ions E. Isolated chemical element(s) C. Chemical reactions F. None of the Above 15 Chlorination 303 8/9/2015 Assignment 33. Molecules are typically a set of atoms bound together by covalent bonds, such that the structure is electrically neutral and _______________ are paired with other electrons either in bonds or in lone pairs. A. Molecule(s) D. Charged polyatomic collection(s) B. Ionic compounds E. All valence electrons C. Structure F. None of the Above 34. Thus, molecules exist as electrically neutral units, unlike ions. When this rule is broken, giving the "molecule" a charge, the result is sometimes named a molecular ion or______________. A. Tetra atomic molecule(s) D. A polyatomic ion B. Ions E. Isolated chemical element(s) C. A molecule F. None of the Above 35. _________________ residing in solids (for example, common sulfate or nitrate ions) are generally not considered "molecules" in chemistry. A. Molecule(s) D. Charged polyatomic collection(s) B. Ionic compounds E. A chemical substance C. Structure F. None of the Above 36. The "inert" or noble gas elements (helium, neon, argon, krypton, xenon and radon) are composed of lone atoms as their smallest discrete unit, but the other isolated ____________ consist of either molecules or networks of atoms bonded to each other in some way. A. Tetra atomic molecule(s) D. Existence of identifiable molecule(s) B. Ions E. Chemical element(s) C. A molecule F. None of the Above 37. _______________compose familiar substances such as water, air, and many organic compounds like alcohol, sugar, gasoline, and the various pharmaceuticals. A. Identifiable molecules D. Existence of identifiable molecule(s) B. Ions E. Isolated chemical element(s) C. A molecule F. None of the Above 38. Not all substances or chemical compounds consist of discrete molecules, and indeed most of the solid substances that make up the solid crust, mantle, and core of the Earth are chemical compounds without _______________. A. Molecule(s) D. Charged polyatomic collection(s) B. Ionic compounds E. A chemical substance C. Structure F. None of the Above 39. These other types of substances, such as _______________and network solids, are organized in such a way as to lack the existence of identifiable molecules per se. Instead, these substances are discussed in terms of formula units or unit cells as the smallest repeating structure within the substance. A. Tetra atomic molecule(s) D. Existence of identifiable molecule(s) B. Ions E. Isolated chemical element(s) C. Ionic compounds F. None of the Above (S) Means the answer can be plural or singular in nature 16 Chlorination 303 8/9/2015 Assignment 40. One of the main characteristics of a __________________ is its geometry often called its structure. A. Molecule(s) D. Charged polyatomic collection(s) B. Ionic compounds E. A chemical substance C. Structure F. None of the Above 41. While the structure of diatomic, triatomic or tetra atomic molecules may be trivial, (linear, angular pyramidal etc.)_____________, that are constituted of more than six atoms (of several elements) can be crucial for its chemical nature. A. Tetra atomic molecule(s) D. Existence of identifiable molecule(s) B. Ions E. The structure of polyatomic molecules C. A molecule F. None of the Above Substance and Mixture 42. _____________________ is a kind of matter with a definite composition and set of properties. A collection of substances is called a mixture. Examples of mixtures are air and alloys. A. Molecule(s) D. Charged polyatomic collection(s) B. Ionic compounds E. A chemical substance C. Structure F. None of the Above Mole and Amount of Substance 43. The mole is a unit of measurement that denotes an amount of substance (also called_______________). A. An amount of substance D. Chemical amount B. A triple point E. Multipole balance C. Crystal structure F. None of the Above Phase 44. In addition to the specific chemical properties that distinguish different chemical classifications, chemicals can exist in several phases. For the most part, the chemical classifications are independent of these _____________ classifications; however, some more exotic phases are incompatible with certain chemical properties. A. An ionic bond D. Phase transition B. Another atom E. Bulk phase C. Multiple solid phases F. None of the Above 45. _______________of a chemical system that have similar bulk structural properties, over a range of conditions, such as pressure or temperature. A. An amount of substance D. A phase is a set of states B. A triple point E. Multipole balance C. Crystal structure F. None of the Above 46. Physical properties, such as density and refractive index tend to fall within values characteristic of the phase. The phase of matter is defined by______________, which is when energy put into or taken out of the system goes into rearranging the structure of the system, instead of changing the bulk conditions. A. An ionic bond D. The phase transition B. Another atom E. Bulk phase C. Multiple solid phases F. None of the Above 17 Chlorination 303 8/9/2015 Assignment 47. Sometimes the distinction between phases can be continuous instead of having a discrete boundary, in this case the matter is considered to be in__________________. When three states meet based on the conditions, it is known as a triple point and since this is invariant, it is a convenient way to define a set of conditions. A. An amount of substance D. A supercritical state B. A triple point E. Multipole balance C. Crystal structure F. None of the Above 48. The most familiar examples of phases are solids, liquids, and gases. Many substances exhibit multiple solid phases. There are three phases of solid iron (alpha, gamma, and delta) that vary based on_______________________. A. An ionic bond D. Phase transition B. Another atom E. Temperature and pressure C. Multiple solid phases F. None of the Above 49. Another phase commonly encountered in the study of chemistry is the____________________, which is the state of substances dissolved in aqueous solution (that is, in water). A. An amount of substance D. Aqueous phase B. A triple point E. Multipole balance C. Crystal structure F. None of the Above 50. Less familiar phases include plasmas, _______________condensates and fermionic condensates and the paramagnetic and ferromagnetic phases of magnetic materials. While most familiar phases deal with three-dimensional systems, it is also possible to define analogs in two-dimensional systems, which has received attention for its relevance to systems in biology. A. Bose–Einstein D. Phase transition B. Another atom E. Bulk phase C. Multiple solid phases F. None of the Above Bonding 51. Atoms sticking together in _____________are said to be bonded with one another. A chemical bond may be visualized as the multipole balance between the positive charges in the nuclei and the negative charges oscillating about them. A. An amount of substance D. Pressure or temperature B. A triple point E. Multipole balance C. Molecules or crystals F. None of the Above 52. More than simple attraction and repulsion, the energies and distributions characterize the availability of an electron to bond to_______________. A. Chemical element(s) D. Photon B. An electron E. A chemical bond C. Another atom F. None of the Above 18 Chlorination 303 8/9/2015 Assignment 53. A chemical bond can be a covalent bond, an ionic bond, a hydrogen bond or just because of Van der Waals force. Each of these kinds of bonds is ascribed to some potential. These potentials create the interactions which hold atoms together in_____________. A. Chemical element(s) D. Molecules or crystals B. An electron E. A chemical bond C. Another atom F. None of the Above 54. ________________ is formed when a metal loses one or more of its electrons, becoming a positively charged cation, and the electrons are then gained by the non-metal atom, becoming a negatively charged anion. A. An ionic bond D. Phase transition B. Another atom E. Bulk phase C. Multiple solid phases F. None of the Above Energy 55. In the context of chemistry, energy is an attribute of a substance as a consequence of its atomic, molecular or aggregate structure. Since a ________________transformation is accompanied by a change in one or more of these kinds of structures, it is invariably accompanied by an increase or decrease of energy of the substances involved. A. Chemical reaction(s) D. Breaking of chemical bonds B. Energy exchange E. Chemical C. Chemical equation F. None of the Above 56. Some ____________ is transferred between the surroundings and the reactants of the reaction in the form of heat or light; thus the products of a reaction may have more or less energy than the reactants. A. Oxidation D. Reorganization of chemical bonds B. Chemical reaction(s) E. Reaction in the form of heat or light C. Energy F. None of the Above Reaction 57. During _____________, bonds between atoms break and form, resulting in different substances with different properties. A. Chemical reaction(s) D. Breaking of chemical bonds B. Energy exchange E. Reaction mechanism(s) C. Chemical equation F. None of the Above 58. When a chemical substance is transformed as a result of its interaction with another substance or with energy, a _________________is said to have occurred. A. Oxidation D. Reorganization of chemical bonds B. Chemical reaction(s) E. Reaction in the form of heat or light C. Energy F. None of the Above 59. A _________________ is therefore a concept related to the "reaction" of a substance when it comes in close contact with another, whether as a mixture or a solution; exposure to some form of energy, or both. A. Chemical reaction(s) D. Breaking of chemical bonds B. Energy exchange E. Reaction mechanism(s) C. Chemical equation F. None of the Above 19 Chlorination 303 8/9/2015 Assignment 60. __________________ can result in the formation or dissociation of molecules, that is, molecules breaking apart to form two or smaller molecules, or rearrangement of atoms within or across molecules. A. Oxidation D. Reorganization of chemical bonds B. Chemical reaction(s) E. Reaction in the form of heat or light C. Energy F. None of the Above 61. Chemical reactions usually involve the making or breaking of_______________. A. Chemical reaction(s) D. Chemical bonds B. Energy exchange E. Reaction mechanism(s) C. Chemical equation F. None of the Above 62. ________________ reduction, dissociation, acid-base neutralization and molecular rearrangement are some of the commonly used kinds of chemical reactions. A. Oxidation D. Reorganization of chemical bonds B. Chemical reaction(s) E. Reaction in the form of heat or light C. Energy F. None of the Above 63. A chemical reaction can be symbolically depicted through a __________________. While in a non-nuclear chemical reaction the number and kind of atoms on both sides of the equation are equal, for a nuclear reaction this holds true only for the nuclear particles viz. protons and neutrons. A. Chemical reaction(s) D. Breaking of chemical bonds B. Energy exchange E. Reaction mechanism(s) C. Chemical equation F. None of the Above 64. The sequence of steps in which the reorganization of ___________ may be taking place in the course of a chemical reaction is called its mechanism. A. Oxidation D. Chemical bonds B. Chemical reaction(s) E. Reaction in the form of heat or light C. Energy F. None of the Above 65. A chemical reaction can be envisioned to take place in a number of steps, each of which may have a____________________. A. Oxidation D. Reorganization of chemical bonds B. Chemical reaction(s) E. Reaction in the form of heat or light C. Different speed F. None of the Above 66. Many reaction intermediates with variable stability can thus be envisaged during the course of a reaction. Reaction mechanisms are proposed to explain the ___________and the relative product mix of a reaction. A. Chemical reaction(s) D. Breaking of chemical bonds B. Energy exchange E. Kinetics C. Chemical equation F. None of the Above 20 Chlorination 303 8/9/2015 Assignment Acidity and Basicity 67. A substance can often be classified as an acid or a base. There are several different theories which explain acid-base behavior. The simplest is Arrhenius theory, which states than an acid is a substance that produces ______________when it is dissolved in water, and a base is one that produces hydroxide ions when dissolved in water. A. Acid D. pH measurement(s) B. Alkalinity E. Hydronium ions C. pH F. None of the Above 68. According to Brønsted–Lowry acid–base theory, ________________are substances that donate a positive hydrogen ion to another substance in a chemical reaction; by extension, a base is the substance which receives that hydrogen ion. A. Measurement of Ph D. Acids B. pH E. Acid-base behavior C. (Solvated) hydronium ion F. None of the Above 69. A third common theory is Lewis acid-base theory, which is based on the formation of new chemical bonds. Lewis theory explains that an acid is a substance which is capable of accepting a pair of electrons from another substance during the process of bond formation, while a base is a substance which can provide a pair of electrons to form a new bond. According to this theory, the crucial things being exchanged are__________________. A. Acid D. Charges B. Alkalinity E. Bond formation C. pH F. None of the Above pH Section 70. In chemistry, _______________ is a measure of the acidity or basicity of an aqueous solution. Solutions with a pH less than 7 are said to be acidic and solutions with a pH greater than 7 are basic or alkaline. Pure water has a pH very close to 7. A. Measurement of Ph D. Brønsted–Lowry acid–base theory B. pH E. Acid-base behavior C. (Solvated) hydronium ion F. None of the Above 71. ___________are determined using a concentration cell with transference, by measuring the potential difference between a hydrogen electrode and a standard electrode such as the silver chloride electrode. A. Primary pH standard values D. pH measurement(s) B. Alkalinity E. Measurement of pH C. pH F. None of the Above 72. ________________________for aqueous solutions can be done with a glass electrode and a pH meter, or using indicators. A. Primary pH standard values D. pH measurement(s) B. Alkalinity E. Measurement of pH C. pH F. None of the Above 21 Chlorination 303 8/9/2015 Assignment 73. _____________________ are important in medicine, biology, chemistry, agriculture, forestry, food science, environmental science, oceanography, civil engineering, chemical engineering, nutrition, water treatment & water purification, and many other applications. A. Primary pH standard values D. pH measurement(s) B. Alkalinity E. Measurement of pH C. pH F. None of the Above 74. Mathematically, pH is the negative logarithm of the activity of the (solvated) hydronium ion, more often expressed as the measure of the___________________. A. Primary pH standard values D. pH measurement(s) B. Alkalinity E. Measurement of pH C. Hydronium ion concentration F. None of the Above Alkalinity 75. Alkalinity is the name given to the quantitative capacity of an aqueous solution to neutralize an _________________. A. Acid D. pH measurement(s) B. Base E. Bond formation C. pH F. None of the Above 76. Measuring alkalinity is important in determining a stream's ability to neutralize acidic pollution from rainfall or wastewater. It is one of the best measures of the sensitivity of the stream to acid inputs. There can be long-term changes in the _________________ of rivers and streams in response to human disturbances. A. Acid D. pH measurement(s) B. Alkalinity E. Bond formation C. pH F. None of the Above pH Definition and Measurement 77. pH is defined as the decimal logarithm of the reciprocal of the_____________, aH+, in a solution. A. Hydrogen ion activity D. Brønsted–Lowry acid–base theory, B. pH E. Acid-base behavior C. (Solvated) hydronium ion F. None of the Above 78. When more than two buffer solutions are used the electrode is calibrated by fitting observed pH values to a straight line with respect to standard buffer values. Commercial standard buffer solutions usually come with information on the value at 25 °C and a correction factor to be applied for other temperatures. The pH scale is logarithmic and therefore pH is___________. A. Universal indicator D. Excess of alkaline earth metal concentrations B. A dimensionless quantity E. A set of non-linear simultaneous equations C. Spectrophotometer F. None of the Above pH Indicators 79. _______________may changes with pH. A. Indicators B. pH C. Spectrophotometer be used to measure pH, by making use of the fact that their color D. Excess of alkaline earth metal concentrations E. A set of non-linear simultaneous equations F. None of the Above 22 Chlorination 303 8/9/2015 Assignment 80. _________________of the color of a test solution with a standard color chart provides a means to measure pH accurate to the nearest whole number. A. Universal indicator D. Visual comparison B. pH E. A set of non-linear simultaneous equations C. Spectrophotometer F. None of the Above 81. More precise measurements are possible if the color is measured spectrophotometrically, using a_________________ . A. Universal indicator D. Excess of alkaline earth metal concentrations B. Colorimeter of spectrophotometer E. A set of non-linear simultaneous equations C. Spectrophotometer F. None of the Above 82. Universal indicator consists of a mixture of indicators such that there is a continuous color change from about pH 2 to pH 10. __________________ is made from absorbent paper that has been impregnated with universal indicator. A. Universal indicator D. Excess of alkaline earth metal concentrations B. Colorimeter of spectrophotometer E. A set of non-linear simultaneous equations C. Spectrophotometer F. None of the Above Calculations of pH 83. The calculation of the pH of a solution containing acids and/or bases is an example of a chemical speciation calculation, that is, a mathematical procedure for calculating the concentrations of all chemical species that are present in the solution. The complexity of the procedure depends on the____________________. A. Universal indicator D. Excess of alkaline earth metal concentrations B. pH E. A set of non-linear simultaneous equations C. Nature of the solution F. None of the Above 84. For strong acids and bases no calculations are necessary except in extreme situations. The pH of a solution containing a weak acid requires the solution of a quadratic equation. The pH of a solution containing a weak base may require the______________. The general case requires the solution of a set of non-linear simultaneous equations. A. Solution of a cubic equation D. Excess of alkaline earth metal concentrations B. pH E. A set of non-linear simultaneous equations C. Spectrophotometer F. None of the Above Strong Acids and Bases 85. Strong acids and bases are compounds that, for practical purposes, are completely dissociated in water. Under normal circumstances this means that the concentration of hydrogen ions in acidic solution can be taken to be equal to the concentration of the acid. The pH is then equal to minus the logarithm of__________. A. The concentration value D. Excess of alkaline earth metal concentrations B. The pH E. A set of non-linear simultaneous equations C. The Spectrophotometer F. None of the Above 23 Chlorination 303 8/9/2015 Assignment Alkalinity Introduction 86. Alkalinity of water is its acid-neutralizing capacity. It is the sum of all the titratable bases. The measured value may vary significantly with the ___________used. A. Acid D. pH measurement(s) B. Alkalinity E. End-point pH C. pH F. None of the Above 87. Alkalinity is a measure of _________and can be interpreted in terms of specific substances only when the chemical composition of the sample is known. A. Universal indicator D. Excess of alkaline earth metal concentrations B. pH E. A set of non-linear simultaneous equations C. An aggregate property of water F. None of the Above 88. Alkalinity is significant in many uses and treatments of natural waters and wastewaters. Because the alkalinity of ______________ it is taken as an indication of the concentration of these constituents. The measured values also may include contributions from borates, phosphates, silicates or other bases if these are present. A. Acid D. pH measurement(s) B. Alkalinity E. Bond formation C. pH F. None of the Above 89. Alkalinity in excess of _________ is significant in determining the suitability of water for irrigation. A. Universal indicator D. Alkaline earth metal concentrations B. pH E. A set of non-linear simultaneous equations C. Spectrophotometer F. None of the Above 90. __________________ measurements are used in the interpretation and control of water and wastewater treatment processes. A. Acid D. A set of non-linear simultaneous equation B. Alkalinity E. Bond formation C. pH F. None of the Above Hard Water Section 91. Water contains various amounts of__________________, some of which impart a quality known as hardness. Consumers frequently complain about problems attributed to hard water, such as the formation of scale on cooking utensils and hot water heaters. A. Water hardness D. Calcium (Ca) and magnesium (Mg) B. Carbonate hardness E. Dissolved minerals C. The calcium-magnesium distinction F. None of the Above Occurrence of Hard Water 92. Hard water is caused by soluble, divalent, _________, (positive ions having valence of 2). The principal chemicals that cause water hardness are calcium (Ca) and magnesium (Mg). A. Water hardness D. Calcium (Ca) and magnesium (Mg) B. Metallic cations E. Noncarbonate hardness C. Carbon dioxide (CO2) F. None of the Above 24 Chlorination 303 8/9/2015 Assignment Chlorine Basics 93. In 1774, in his small experimental laboratory, Swedish pharmacist Carl Wilhem Scheele released a few drops of hydrochloric acid onto a piece of manganese dioxide. Within seconds, a greenish-yellow gas arose. Although he had no idea at the time, he had just discovered_____________. A. Moon germs D. Manganese dioxide B. Bacteria and viruses E. Basic building blocks of our planet C. Chlorine F. None of the Above 94. The fact that the greenish-yellow gas was actually an element was only recognized several decades later by English chemist Sir Humphrey Davy. Until that time, people were convinced that the gas was a ________________. A. Chlorine chemistry D. Economical germ-killers B. Compound of oxygen E. Life-threatening infections, viruses, and bacteria C. Chlorine's powerful disinfectant qualities F. None of the Above 95. Davy gave the element its name on the basis of the Greek word khloros, for _______________. In 1810 he suggested the name "chloric gas" or "chlorine." A. Economical germ-killers D. Manganese dioxide B. Bacteria and viruses killer E. Basic building blocks C. Greenish-yellow F. None of the Above 96. One of the most effective and_______________, chlorine also destroys and deactivates a wide range of dangerous germs in homes, hospitals, swimming pools, hotels, restaurants, and other public places. A. Chlorine chemistry D. Economical germ-killers B. Compound of oxygen E. Life-threatening infections, viruses, and bacteria C. Chlorine's powerful disinfectant qualities F. None of the Above 97. Chlorine's powerful disinfectant qualities come from its ability to bond with and destroy the outer surfaces of _________________. A. Moon germs D. Manganese dioxide B. Bacteria and viruses E. Basic building blocks of our planet C. Salmonella and E. coli F. None of the Above 98. First used as a germicide to prevent the spread of "child bed fever" in the maternity wards of Vienna General Hospital in Austria in 1846, chlorine has been one of society's most potent weapons against a wide array of _______________________ for 150 years. A. Bacteria and viruses D. Economical germ-killers B. Compound of oxygen E. Life-threatening infections, viruses, and bacteria C. Chlorine's powerful disinfectant qualities F. None of the Above 99. When the first men to set foot on the moon returned to earth (Apollo 11 mission: 24.7.69) a hypochlorite solution was chosen as one of the disinfectants for destroying any possible __________. A. Moon germs D. Manganese dioxide B. Bacteria and viruses E. Basic building blocks of our planet C. Salmonella and E. coli F. None of the Above 25 Chlorination 303 8/9/2015 Assignment Chlorination Introduction 100. Microorganisms can be found in raw water from rivers, lakes and groundwater. While not all microorganisms are harmful to human health, there are some that may cause diseases in humans. These are called________________. A. Epidemics D. Pathogens B. Waterborne disease E. Microscopic agents of many diseases C. Microorganisms F. None of the Above 101. Pathogens present in water can be transmitted through a drinking water distribution system, causing _______________in those who consume it. A. Total Coliform (TC) D. Cryptosporidium B. Indicator organisms E. Waterborne disease C. Cholera, polio, typhoid, hepatitis F. None of the Above 102. Water chlorination is the process of adding the ___________to water as a method of water purification to make it fit for human consumption as drinking water. A. Halogen D. Chlorine B. Element chlorine E. Hypochlorous acid C. Chlorine as a disinfectant F. None of the Above 103. Water that has been treated with chlorine is effective in preventing the spread of _________. A. Epidemics D. Oxidation of organic molecules B. Waterborne disease E. Microscopic agents of many diseases C. Microorganisms F. None of the Above 104. A large amount of research and many studies have been conducted to ensure success in water treatment plants and various water producing wells using ______________. A. Halogen D. Chlorine B. Water chlorination E. Hypochlorous acid C. Chlorine as a disinfectant F. None of the Above 105. A leading advantage of chlorination is that it has proven effective against bacteria and viruses; however, it cannot inactivate all microbes. Some ____________are resistant to the effects of chlorine. A. Protozoan cysts D. Oxidation of organic molecules B. Waterborne disease E. Microscopic agents of many diseases C. Microorganisms F. None of the Above 106. As a halogen, chlorine is a highly efficient disinfectant, and is added to public water supplies to kill disease-causing pathogens, such as_______________, that commonly grow in water supply reservoirs, on the walls of water mains and in storage tanks. A. Epidemics D. Oxidation of organic molecules B. Waterborne disease E. Microscopic agents of many diseases C. Bacteria, viruses and protozoans F. None of the Above 26 Chlorination 303 8/9/2015 Assignment 107. The microscopic agents of many diseases such as ____________killed countless people annually before disinfection methods were employed routinely. A. Epidemics D. Oxidation of organic molecules B. Waterborne disease E. Cholera, typhoid fever, and dysentery C. Microorganisms F. None of the Above 108. _________ is obtained from salt (NaCl). It is a gas at atmospheric pressures but liquefies under pressure. The liquefied gas is transported and used as such. A. Halogen D. Chlorine B. Water chlorination E. Hypochlorous acid C. Chlorine as a disinfectant F. None of the Above 109. As a strong oxidizing agent, chlorine kills via the______________. A. Halogen D. Oxidation of organic molecules B. Water chlorination E. Hypochlorous acid C. Chlorine as a disinfectant F. None of the Above 110. Chlorine and its _______________are neutrally charged and therefore easily penetrate the negatively charged surface of pathogens. It is able to disintegrate the lipids that compose the cell wall and react with intracellular enzymes and proteins, making them nonfunctional. Microorganisms then either die or are no longer able to multiply. A. Halogen D. Hydrolysis product hypochlorous acid B. Water chlorination E. Hypochlorous acid C. Chlorine as a disinfectant F. None of the Above 111. In the past 30 years, the Safe Drinking Water Act (SDWA) has been highly effective in protecting public health and has also evolved to respond to new and emerging threats to safe drinking water. A. Cryptosporidium D. Emerging threats to safe drinking water B. Sodium hypochlorite E. Hypochlorous acid (HOCl), and hydrochloric acid (HCl) C. Bromoform F. None of the Above 112. Disinfection of drinking water is one of the major public health advances in the 20th century. One hundred years ago, _______________were common through American cities; disinfection was a major factor in reducing these epidemics. A. Epidemics D. Oxidation of organic molecules B. Waterborne disease E. Typhoid and cholera epidemics C. Microorganisms F. None of the Above 113. However, the disinfectants themselves can react with naturally-occurring materials in the water to form unintended byproducts which may pose health risks. In addition, in the past ten years, we have learned that there are specific microbial pathogens, such as ____________, which can cause illness and is resistant to traditional disinfection practices. A. Cryptosporidium D. Emerging threats to safe drinking water B. Sodium hypochlorite E. Hypochlorous acid (HOCl), and hydrochloric acid (HCl) C. Bromoform F. None of the Above 27 Chlorination 303 8/9/2015 Assignment Chlorination Principles 114. When dissolved in water, chlorine converts to an equilibrium mixture of chlorine, _________. A. Cryptosporidium D. Emerging threats to safe drinking water B. Sodium hypochlorite E. Hypochlorous acid (HOCl), and hydrochloric acid (HCl) C. Bromoform F. None of the Above 115. In acidic solution, the major species are Cl2 and HOCl while in alkaline solution effectively only ClO- is present. Very small concentrations of _____________are also found. We will cover this subject in greater detail. A. Dibromochloromethane D. An antioxidant formulation of Vitamin C B. Bromoform E. ClO2-, ClO3-, ClO4C. Cl2 and HOCl F. None of the Above Shock Chlorination 116. ______________is a process used in many swimming pools, water wells, springs, and other water sources to reduce the bacterial and algal residue in the water. A. Cryptosporidium D. Shock chlorination B. Sodium hypochlorite E. Hypochlorous acid (HOCl), and hydrochloric acid (HCl) C. Bromoform F. None of the Above 117. Shock chlorination is performed by mixing a large amount of sodium hypochlorite, which can be in the form of a powder or a liquid such as_____________, into the water. Water that is being shock chlorinated should not be swum in or drunk until the sodium hypochlorite count in the water goes down to three ppm or less. A. Cryptosporidium D. Chlorine bleach B. Sodium hypochlorite E. Hypochlorous acid (HOCl), and hydrochloric acid (HCl) C. Bromoform F. None of the Above Drawbacks to Water Chlorination 118. Disinfection by chlorination can be problematic, in some circumstances. ________ can react with naturally occurring organic compounds found in the water supply to produce compounds known as disinfection byproducts (DBPs). A. Halogen D. Chlorine B. Water chlorination E. Hypochlorous acid C. Chlorine as a disinfectant F. None of the Above 119. The most common DBPs are trihalomethanes (THMs) and__________________. A. Haloacetic acids (HAAs) D. Chlorine B. Water chlorination E. Hypochlorous acid C. Chlorine as a disinfectant F. None of the Above 120. _________________are the main disinfectant by-products created from chlorination with two different types, bromoform and dibromochloromethane, which are mainly responsible for health hazards. A. Dibromochloromethane D. An antioxidant formulation of Vitamin C B. Trihalomethanes E. A major public health concern C. Cl2 and HOCl F. None of the Above 28 Chlorination 303 8/9/2015 Assignment 121. Their effects depend strictly on the duration of their exposure to the chemicals and the amount ingested into the body. In high doses, ____________ mainly slows down regular brain activity, which is manifested by symptoms such as sleepiness or sedation. A. Cryptosporidium D. Dibromochloromethane B. Sodium hypochlorite E. Hypochlorous acid (HOCl), and hydrochloric acid (HCl) C. Bromoform F. None of the Above 122. Chronic exposure of _____________can cause liver and kidney cancer, as well as heart disease, unconsciousness or death in high doses. A. Dibromochloromethane D. An antioxidant formulation of Vitamin C B. Bromoform E. Both bromoform and dibromochloromethane C. Cl2 and HOCl F. None of the Above 123. Due to the________________, drinking water regulations across the developed world require regular monitoring of the concentration of these compounds in the distribution systems of municipal water systems. A. Halogen D. Chlorine B. Water chlorination E. Potential carcinogenicity of these compounds C. Chlorine as a disinfectant F. None of the Above 124. Chlorination of swimming pools can have adverse effects on the skin and hair of swimmers due to chlorine's oxidizing properties; various remedies have been developed, most recently_________. A. Dibromochloromethane D. An antioxidant formulation of Vitamin C B. Bromoform E. A major public health concern C. Cl2 and HOCl F. None of the Above Understanding Waterborne Viruses 125. ________________may be present in fecal-contaminated waters. A. Total Coliform (TC) D. Cryptosporidium B. Indicator organisms E. Giardia C. Cholera, polio, typhoid, hepatitis F. None of the Above 126. Treatment processes and watershed management strategies designed on the basis of bacteriological criteria do not necessarily protect against ______________because viruses are generally more persistent in the environment and are not removed as completely by treatment. A. F-specific coliphages D. Viruses B. Indicators of fecal contamination E. Viral infection C. Enteric viruses F. None of the Above 127. In addition, because of their smaller size, viruses (0.023 to 0.080 µm) are transported further in ground water than bacteria (0.5 to 3µ m) or ______________(4 to 15 µm). Because of the importance of viruses as a major public health concern, new methods for detection of enteric viruses and the search for indicators of viral contamination continue. A. Protozoan pathogens D. Viruses B. Indicators of fecal contamination E. Microorganisms C. Enteric viruses F. None of the Above 29 Chlorination 303 8/9/2015 Assignment 128. The current method for culturing ____________ under the ICR (U.S. Environmental Protection Agency, 1996c) is recognized as being difficult to implement; therefore, the ICR does not preclude the use of additional methods for research purposes. In addition, cell-culture methods are not available or suitable for all viruses of public health concern. A. Protozoan pathogens D. Viruses B. Indicators of fecal contamination E. Microorganisms C. Enteric viruses F. None of the Above 129. One method, reverse-transcriptase-polymerase chain reaction (RT-PCR), a gene-probe method that amplifies and recognizes the nucleic acids of____________, has been adequately validated by the USEPA (G. Shay Fout, U.S. Environmental Protection Agency, written commun., 1997) and is becoming widely used for environmental monitoring of enteric viruses. The RTPCR method, however, does not determine the infectivity of the virus, and it is technically demanding, time consuming, and costly for routine use. A. Enteric viruses D. Indicators of viral contamination B. F-specific coliphages E. Coliphages are bacteriophages C. Target viruses F. None of the Above 130. Because monitoring of enteric viruses is recognized as being difficult and time consuming, some researchers advocate the use of coliphage as___________________. A. F-specific coliphages D. Viruses B. Indicators of fecal contamination E. Indicator viruses for fecal contamination C. Enteric viruses F. None of the Above 131. _________________ that infect and replicate in coliform bacteria. The two main groups of coliphages that are considered as candidates for viral indicators are somatic and F-specific coliphages. A. Enteric viruses D. Indicators of viral contamination B. F-specific coliphages E. Coliphages are bacteriophages C. Viruses F. None of the Above 132. Somatic coliphages infect coliform bacteria by attachment to the outer cell membrane or cell wall. They are widely distributed in both fecal-contaminated and uncontaminated waters; therefore, they may not be reliable __________________. A. F-specific coliphages D. Viruses B. Indicators of fecal contamination E. Microorganisms C. Enteric viruses F. None of the Above 133. ________________ attach only to the F-pilus of coliforms that carry the F+ plasmid; F-pili are made only by bacteria grown at higher temperatures. A. Enteric viruses D. Indicators of viral contamination B. F-specific coliphages E. Coliphages are bacteriophages C. Viruses F. None of the Above 30 Chlorination 303 8/9/2015 Assignment 134. Hence, _______________ found in environmental samples presumably come from warmblooded animals or sewage. Although somatic and F-specific coliphages are not consistently found in feces, they are found in high numbers in sewage and are thought to be reliable indicators of the sewage contamination of waters (International Association of Water Pollution Research and Control, 1991). A. F-specific coliphages D. Viruses B. Indicators of fecal contamination E. Microorganisms C. Enteric viruses F. None of the Above 135. Coliphage is also recognized to be representative of the survival and transport of ___________ in the environment. To date, however, coliphage has not been found to correlate with the presence of pathogenic viruses. A. Enteric viruses D. Indicators of viral contamination B. F-specific coliphages E. Coliphages are bacteriophages C. Viruses F. None of the Above Sampling Procedures Streamwater Sample Collection 136. When designing a sampling plan, consider that the spatial and temporal distribution of microorganisms in surface water can be as variable as the distribution of ___________because microorganisms are commonly associated with solid particles. A. Suspended sediment D. Viruses B. Indicators of fecal contamination E. Microorganisms C. Enteric viruses F. None of the Above 137. The standard samplers used in by the majority of samplers can be used to collect streamwater samples for bacterial and viral indicators, __________providing that the equipment coming in contact with the water is properly cleaned and sterilized. A. Cryptosporidium, and Giardia D. Cryptosporidium B. Indicator organisms E. Giardia C. Cholera, polio, typhoid, hepatitis F. None of the Above Cryptosporidium and Giardia Analysis 138. For Cryptosporidium and Giardia analysis by Method 1623 (U.S. Environmental Protection Agency, 1999c), collect 10 L of streamwater for each protozoan pathogen using standard sampling techniques described in Myers and Sylvester (1997). Special sterilization procedures are needed for equipment used in the collection of samples for ________________. Autoclaving is not effective in neutralizing the epitopes on the surfaces of the oocysts and cysts that will react with the antibodies used for detection. A. Total Coliform (TC) D. Cryptosporidium B. Indicator organisms E. Cryptosporidium and Giardia C. Cholera, polio, typhoid, hepatitis F. None of the Above 139. Submerge the equipment in a vessel containing 12 percent hypochlorite solution for 30 minutes. Wash the equipment free of residual sodium hypochlorite solution with three rinses of filter-sterilized water; do not de-chlorinate the equipment using ____________. A. Dibromochloromethane D. Sodium hypochlorite solution B. Bromoform E. Sodium thiosulfate C. Cl2 and HOCl F. None of the Above 31 Chlorination 303 8/9/2015 Assignment 140. Composite the sample in a 10-L cubitainer that is pre-sterilized by the manufacturer. The cubitainer is sent in a cardboard box to laboratory for ___________analysis. The sample does not have to be kept on ice during transport. A. Total Coliform (TC) D. Cryptosporidium B. Indicator organisms E. Giardia C. Cholera, polio, typhoid, hepatitis F. None of the Above Understanding Bacteriophage 141. Bacteriophages may have a lytic cycle or a lysogenic cycle, and a few viruses are capable of carrying out both. With lytic phages such as the T4 phage, ______________are broken open (lysed) and destroyed after immediate replication of the virion. As soon as the cell is destroyed, the phage progeny can find new hosts to infect. Lytic phages are more suitable for phage therapy. A. Lysogenic cycle D. Phage virions B. Bacterial cells E. Myovirus bacteriophages C. Vibrio cholerae F. None of the Above 142. Some _______________undergo a phenomenon known as lysis inhibition, where completed phage progeny will not immediately lyse out of the cell if extracellular phage concentrations are high. This mechanism is not identical to that of temperate phage going dormant and is usually temporary. A. Podoviruses D. Phage lambda of E. coli B. Phage's host range E. Lytic phages C. Myovirus bacteriophages F. None of the Above 143. In contrast, the _____________ does not result in immediate lysing of the host cell. Those phages able to undergo lysogeny are known as temperate phages. A. Lysogenic cycle D. Phage virions B. Virus E. Myovirus bacteriophages C. Vibrio cholerae F. None of the Above 144. Their viral genome will integrate with ________________and replicate along with it fairly harmlessly, or may even become established as a plasmid. A. Podoviruses D. Phage lambda of E. coli B. Phage's host range E. Viral genome C. Host DNA F. None of the Above 145. The virus remains dormant until host conditions deteriorate, perhaps due to depletion of nutrients; then, the ____________________(known as prophages) become active. At this point they initiate the reproductive cycle, resulting in lysis of the host cell. A. Lysogenic cycle D. Phage virions B. Endogenous phages E. Myovirus bacteriophages C. Vibrio cholerae F. None of the Above 146. As the lysogenic cycle allows the host cell to continue to survive and reproduce, the virus is reproduced in all of the cell’s offspring. An example of a bacteriophage known to follow the lysogenic cycle and the lytic cycle is the ____________________. A. Podoviruses D. Phage lambda of E. coli B. Phage's host range E. Viral genome C. Myovirus bacteriophages F. None of the Above 32 Chlorination 303 8/9/2015 Assignment 147. Sometimes prophages may provide benefits to the host bacterium while they are dormant by adding new functions to the bacterial genome in a phenomenon called lysogenic conversion. An eminent example is the conversion of a harmless strain of _____________by a phage into a highly virulent one, which causes cholera. A. Lysogenic cycle D. Phage virions B. The virus E. Myovirus bacteriophages C. Vibrio cholerae F. None of the Above Attachment and Penetration 148. To enter a host cell, _____________________attach to specific receptors on the surface of bacteria, including lipopolysaccharides, teichoic acids, proteins, or even flagella. This specificity means a bacteriophage can infect only certain bacteria bearing receptors to which they can bind, which in turn determines the phage's host range. A. Podoviruses D. Bacteriophages B. Phage's host range E. Viral genome C. Myovirus bacteriophages F. None of the Above 149. Host growth conditions also influence the ability of the phage to attach and invade them. As ____________ do not move independently, they must rely on random encounters with the right receptors when in solution (blood, lymphatic circulation, irrigation, soil water, etc.). A. Lysogenic cycle D. Phage virions B. The virus E. Myovirus bacteriophages C. Vibrio cholerae F. None of the Above 150. ______________ use a hypodermic syringe-like motion to inject their genetic material into the cell. After making contact with the appropriate receptor, the tail fibers flex to bring the base plate closer to the surface of the cell; this is known as reversible binding. A. Podoviruses D. Phage lambda of E. coli B. Phage's host range E. Viral genome C. Myovirus bacteriophages F. None of the Above 151. Once attached completely, irreversible binding is initiated and the tail contracts, possibly with the help of ATP present in the tail, injecting __________through the bacterial membrane. A. Lysogenic cycle D. Phage virions B. Genetic material E. Myovirus bacteriophages C. Vibrio cholerae F. None of the Above 152. ______________ lack an elongated tail sheath similar to that of a myovirus, so they instead use their small, tooth-like tail fibers to enzymatically degrade a portion of the cell membrane before inserting their genetic material. A. Podoviruses D. Phage lambda of E. coli B. Phage's host range E. Viral genome C. Myovirus bacteriophages F. None of the Above 33 Chlorination 303 8/9/2015 Assignment Virions 153. _________________is a complete functional virus that has the capacity to infect living tissue. This means that it includes the genetic material, the capsid, the enveloppe and the membrane proteins that allow the virus to bind to its host and enter it. A virus will not have an enveloppe within a cell. A. Podoviruses D. Phage lambda of E. coli B. Phage's host range E. A virion C. Myovirus bacteriophages F. None of the Above 154. If the cell was burst artificially, then these virus particles cannot be called virion because they will lack certain proteins that will make them infectious even though the ___________is present. Not all viruses have enveloppes, but most viruses have certain proteins that are necessary to permit them to enter the host cell. A. Podoviruses D. Genetic material B. Phage's host range E. Viral genome C. Myovirus bacteriophages F. None of the Above 155. Biomolecules found in virions: genetic material, _____________, single or double stranded, nucleoprotein capsid, maybe an enveloppe usually receptor proteins or enzymes that permit binding or entry into the host. A viroid is a plant pathogen consisting of a circular piece of RNA without a protein coat. A. Either DNA or RNA D. Phage lambda of E. coli B. Phage's host range E. Viral genome C. Myovirus bacteriophages F. None of the Above Chlorine Gas (Some questions may appear to repat, this is for QA/QC purposes) 156. Upon introduction into the water stream, chlorine hydrolyzes into _____________. A. Chlorine D. Chlorine gas B. Sodium hypochlorite E. Hypochlorous acid (HOCl), and hydrochloric acid (HCl) C. Bromoform F. None of the Above 157. This hydrolization provides the active toxicant, _________, which is pH-dependent. In alkaline cooling systems, it readily dissociates to form the hypochlorite ion (OCl-). A. HCl D. pH of 7.0 than at pH 8.5 B. HOCl E. the hypochlorite ion (OCl-) C. High chlorine concentrations F. None of the Above 158. This dissociation phenomenon is important to remember when working with systems that will operate at a higher pH. In alkaline conditions, _____________becomes the predominant species and lacks the biocidal efficacy of the non-dissociated form. A. Chlorine D. Chlorine gas B. Sodium hypochlorite E. Hypochlorous acid (HOCl), and hydrochloric acid (HCl) C. OClF. None of the Above 159. Considerably more __________ is present at a pH of 7.0 than at pH 8.5. A. HCl D. pH of 7.0 than at pH 8.5 B. HOCl E. the hypochlorite ion (OCl-) C. High chlorine concentrations F. None of the Above 34 Chlorination 303 8/9/2015 Assignment 160. It is also widely known that chlorine is non-selective, making it very sensitive to contamination from either cooling water makeup or from in-plant process leaks.____________, organic acids and organic compounds, sulfides, iron and manganese all easily react with HOCl. A. Chlorine D. Chlorine gas B. Sodium hypochlorite E. Hypochlorous acid (HOCl), and hydrochloric acid (HCl) C. Ammonia F. None of the Above 161. The amount of chlorine needed to react with these contamination species is referred to as _____________and it must be satisfied before active HOCl is available to provide a free chlorine residual. A. Chlorine demand D. pH of 7.0 than at pH 8.5 B. HOCl E. The hypochlorite ion (OCl-) C. High chlorine concentrations F. None of the Above 162. The combination of high chlorine demand in process-contaminated systems and the dissociation process in alkaline systems creates the need for greater chlorine feed to obtain the same microbial efficacy. This results in a higher concentration of ______________in the cooling system. A. Chlorine D. HCl B. Sodium hypochlorite E. Hypochlorous acid (HOCl), and hydrochloric acid (HCl) C. Bromoform F. None of the Above 163. Since ___________ removes alkalinity, pH depression and system corrosion could occur. In low pH water the passive metal oxide layers protecting the metal may resolubulize, exposing the surface to corrosion. A. HCl D. pH of 7.0 than at pH 8.5 B. HOCl E. the hypochlorite ion (OCl-) C. High chlorine concentrations F. None of the Above 164. At free mineral acidity (pH <4.3), many passivating inhibitors become ineffective, and corrosion will proceed rapidly. Increased chloride may also have a negative impact on system corrosion. _______________can damage or penetrate the passive oxide layer, leading to localized damage of the metal surface. A. Chlorine D. Chlorine gas B. Sodium hypochlorite E. Hypochlorous acid (HOCl), and hydrochloric acid (HCl) C. The chloride ion (Cl-) F. None of the Above 165. High chlorine concentrations have also been shown to directly attack traditional organicbased corrosion inhibitors. When these inhibitors are "deactivated," the metal surface would then be susceptible to corrosion. Process Safety Management (PSM) guidelines dictated by the U.S. Occupational Safety and Health Administration (OSHA), discharge problems related to ____________such as trihalomethane (THM), dezincification of admiralty brass and delignification of cooling tower wood are other significant concerns associated with the use of chlorine. A. Chlorinated organic compounds D. Sodium hypochlorite solution B. Many disease-causing microorganisms E. Chlorine disinfectants C. Nitrogenous compounds F. None of the Above 35 Chlorination 303 8/9/2015 Assignment Pathophysiology 166. Chlorine is a greenish-yellow, noncombustible gas at room temperature and atmospheric pressure. The intermediate ___________of chlorine accounts for its effect on the upper airway and the lower respiratory tract. A. Generation of free oxygen radicals D. Water solubility B. Chlorine gas E. The odor threshold for chlorine C. Hydrochloric acid F. None of the Above 167. Exposure to ____________ may be prolonged because its moderate water solubility may not cause upper airway symptoms for several minutes. In addition, the density of the gas is greater than that of air, causing it to remain near ground level and increasing exposure time. A. Hydrochloric acid D. The chemical species produced B. Chlorine gas E. Plasma exudation C. The gas F. None of the Above 168. The odor threshold for chlorine is approximately 0.3-0.5 parts per million (ppm); however, distinguishing toxic air levels from ___________may be difficult until irritative symptoms are present. A. Generation of free oxygen radicals D. A greenish-yellow, noncombustible gas B. Chlorine gas E. Permissible air levels C. Hydrochloric acid F. None of the Above Mechanism of Activity 169. The mechanisms of the above biological activity are poorly understood and the predominant anatomic site of injury may vary, depending on the ____________produced. A. Hydrochloric acid D. Chemical species B. Chlorine gas E. Plasma exudation C. Gas F. None of the Above 170. Cellular injury is believed to result from the oxidation of functional groups in cell components, from reactions with tissue water to form_______, and from the generation of free oxygen radicals. A. Generation of free oxygen radicals D. A greenish-yellow, noncombustible gas B. Chlorine gas E. Hypochlorous and hydrochloric acid C. Hydrochloric acid F. None of the Above 171. Although the idea that ________ causes direct tissue damage by generating free oxygen radicals was once accepted, this idea is now controversial. A. Hydrochloric acid D. The chemical species produced B. Chlorine E. Plasma exudation C. The gas F. None of the Above 172. __________ comes out of the cylinder through a gas regulator. The cylinders are on a scale that operators use to measure the amount used each day. The chains are used to prevent the tanks from falling over. A. Hydrochloric acid D. The chemical species produced B. Chlorine gas E. Plasma exudation C. The gas F. None of the Above 36 Chlorination 303 8/9/2015 Assignment 173. ________________ is stored in vented rooms that have panic bar equipped doors. A. Generation of free oxygen radicals D. A greenish-yellow, noncombustible gas B. Chlorine gas E. The odor C. Hydrochloric acid F. None of the Above Solubility Effects 174. _____________acid is highly soluble in water. The predominant targets of the acid are the epithelia of the ocular conjunctivae and upper respiratory mucus membranes. A. Hydrochloric D. Hypochlorous B. Sulfuric E. Nitric C. Some F. None of the Above 175. Hypochlorous acid is also highly water soluble with an injury pattern similar to_________. A. Hydrochloric acid D. Sodium hypochlorite solution B. Many disease-causing microorganisms E. Chlorine disinfectants C. Nitrogenous compounds F. None of the Above 176. __________may account for the toxicity of elemental chlorine and hydrochloric acid to the human body. A. HCl D. pH of 7.0 than at pH 8.5 B. Hypochlorous acid E. The hypochlorite ion (OCl-) C. High chlorine concentrations F. None of the Above Early Response to Chlorine Gas 177. Chlorine gas, when mixed with ammonia, reacts to form___________. In the presence of water, chloramines decompose to ammonia and hypochlorous acid or hydrochloric acid. A. Generation of free oxygen radicals D. A greenish-yellow, noncombustible gas B. Chlorine gas E. Chloramine gas C. Hydrochloric acid F. None of the Above 178. The early response to ____________depends on the (1) concentration of chlorine gas, (2) duration of exposure, (3) water content of the tissues exposed, and (4) individual susceptibility. A. Chlorine exposure D. A greenish-yellow, noncombustible gas B. Chlorine gas E. The odor threshold for chlorine C. Hydrochloric acid F. None of the Above Immediate Effects 179. The immediate effects of ___________ toxicity include acute inflammation of the conjunctivae, nose, pharynx, larynx, trachea, and bronchi. A. Hydrochloric acid D. The chemical species produced B. Chlorine gas E. Chlorine exposure C. The gas F. None of the Above 180. Irritation of the airway mucosa leads to local edema secondary to active arterial and capillary hyperemia. ________________ results in filling the alveoli with edema fluid, resulting in pulmonary congestion. A. Hydrochloric acid D. The chemical species produced B. Chlorine gas E. Plasma exudation C. The gas F. None of the Above 37 Chlorination 303 8/9/2015 Assignment Pathological Findings 181. Chlorine is a highly reactive gas. It is a______________. Chlorine is produced in very large amounts (23 billion pounds in 1992) by eighteen companies in the United States. A. HCl D. Chlorine gas fumes B. HOCl E. Naturally occurring element C. High chlorine concentrations F. None of the Above 182. US demand for chlorine is expected to increase slightly over the next several years and then decline. The expected decline in US demand is due to environmental concerns for_________. A. Chlorinated organic chemicals D. Chlorine gas fumes B. HOCl E. The hypochlorite ion (OCl-) C. High chlorine concentrations F. None of the Above 183. The largest users of chlorine are companies that make ______________and other chlorinated solvents, polyvinyl chloride (PVC) resins, chlorofluorocarbons, and propylene oxide. Paper companies use chlorine to bleach paper. A. HCl D. Ethylene dichloride B. HOCl E. The hypochlorite ion (OCl-) C. High chlorine concentrations F. None of the Above 184. Water and wastewater treatment plants use _____________to reduce water levels of microorganisms that can spread disease to humans. A. HCl D. Chlorine B. HOCl E. The hypochlorite ion (OCl-) C. High chlorine concentrations F. None of the Above 185. Exposure to chlorine can occur in the workplace or in the environment following releases to air, water, or land. People who use laundry bleach and swimming pool chemicals containing ___________ are usually not exposed to chlorine itself. A. HCl D. Chlorine gas fumes B. Chlorine products E. The hypochlorite ion (OCl-) C. High chlorine concentrations F. None of the Above 186. Chlorine is generally found only in industrial settings. ___________ enters the body breathed in with contaminated air or when consumed with contaminated food or water. It does not remain in the body due to its reactivity. A. HCl D. Chlorine B. HOCl E. The hypochlorite ion (OCl-) C. High chlorine concentrations F. None of the Above Some questions appear to repeat for QA/QC purposes 187. Chlorine gas is greenish yellow in color and very toxic. It is heavier than air and will therefore sink to the ground if released from its container. It is the toxic effect of ________ that makes it a good disinfectant, but it is toxic to more than just waterborne pathogens; it is also toxic to humans. It is a respiratory irritant and it can also irritate skin and mucus membranes. A. HCl D. Chlorine gas B. HOCl E. The hypochlorite ion (OCl-) C. High chlorine concentrations F. None of the Above 38 Chlorination 303 8/9/2015 Assignment 188. Exposure to high volumes of ___________ can cause serious health problems, including death. A. HCl D. Chlorine gas fumes B. HOCl E. The hypochlorite ion (OCl-) C. High chlorine concentrations F. None of the Above 189. However, it is important to realize that ____________, once entering the water, changes into hypochlorous acid and hypochlorite ions, and therefore its human toxic properties are not found in the drinking water we consume. A. HCl D. Chlorine gas B. HOCl E. The hypochlorite ion (OCl-) C. High chlorine concentrations F. None of the Above 190. Chlorine gas is sold as a compressed liquid, which is amber in color. Chlorine, as a____________, is heavier (more dense) than water. If the chlorine liquid is released from its container it will quickly return back to its gas state. A. HCl D. Chlorine gas fumes B. HOCl E. The hypochlorite ion (OCl-) C. Liquid F. None of the Above 191. Chlorine gas is the least expensive form of chlorine to use. The typical amount of chlorine gas required for water treatment is 1-16 mg/L of water. Different amounts of chlorine gas are used depending on the _____________that needs to be treated. If the water quality is poor, a higher concentration of chlorine gas will be required to disinfect the water if the contact time cannot be increased. A. HCl D. pH of 7.0 than at pH 8.5 B. Quality of water E. the hypochlorite ion (OCl-) C. High chlorine concentrations F. None of the Above Where Chlorine is Found and How it is Used 192. Chlorine is one of the most commonly manufactured chemicals in the United States. Its most important use is as a bleach in the manufacture of paper and cloth, but it is also used to make pesticides (insect killers), rubber, and_________________. A. HCl D. Solvents B. HOCl E. The hypochlorite ion (OCl-) C. Chlorine liquid F. None of the Above 193. Chlorine is used in drinking water and swimming pool water to kill harmful bacteria. It is also as used as part of the sanitation process for________________. A. HCl D. Chlorine gas B. HOCl E. Industrial waste and sewage C. Chlorine liquid F. None of the Above 194. _______________can release chlorine gas if it is mixed with certain other cleaning agents. A. HCl D. Chlorine gas B. HOCl E. Household chlorine bleach C. Chlorine liquid F. None of the Above 39 Chlorination 303 8/9/2015 Assignment How People can be exposed to Chlorine 195. People’s risk for exposure depends on how close they are to the place where the ___________was released. A. HCl D. Chlorine B. HOCl E. The hypochlorite ion (OCl-) C. Chlorine liquid F. None of the Above 196. If ______________is released into the air, people may be exposed through skin contact or eye contact. They also may be exposed by breathing air that contains chlorine. A. Chlorine gas D. Sodium hypochlorite solution B. Many disease-causing microorganisms E. Chlorine disinfectants C. Nitrogenous compounds F. None of the Above 197. If ____________ is released into water, people may be exposed by touching or drinking water that contains chlorine. A. HCl D. Chlorine gas B. HOCl E. The hypochlorite ion (OCl-) C. Chlorine liquid F. None of the Above 198. If ___________ comes into contact with food, people may be exposed by eating the contaminated food. A. HCl D. Chlorine gas B. HOCl E. The hypochlorite ion (OCl-) C. Chlorine liquid F. None of the Above 190. ______________ is heavier than air, so it would settle in low-lying areas. A. HCl D. Chlorine gas B. HOCl E. The hypochlorite ion (OCl-) C. High chlorine concentrations F. None of the Above How Chlorine Works 191. The extent of poisoning caused by ___________depends on the amount of chlorine a person is exposed to, how the person was exposed, and the length of time of the exposure. A. HCl D. Chlorine gas B. HOCl E. The hypochlorite ion (OCl-) C. Chlorine liquid F. None of the Above 192. When ______________ gas comes into contact with moist tissues such as the eyes, throat, and lungs, an acid is produced that can damage these tissues. A. HCl D. Chlorine B. HOCl E. The hypochlorite ion (OCl-) C. Chlorine liquid F. None of the Above What the Long-Term Health Effects are 193. Long-term complications may occur after breathing in high concentrations of chlorine. Complications are more likely to be seen in people who develop severe health problems such as fluid in the lungs (pulmonary edema) following________________. A. Exposure to chlorine D. And get medical care as quickly as possible B. Odor thresholds E. Moisture, steam, and water C. The initial exposure F. None of the Above 40 Chlorination 303 8/9/2015 Assignment How People can Protect Themselves, and What they Should do if they are Exposed to Chlorine 194. Leave the area where the chlorine was released and get to fresh air. Quickly moving to an area where fresh air is available is highly effective in__________________. A. Reducing exposure to chlorine D. Get medical care as quickly as possible B. Odor thresholds E. Moisture, steam, and water C. A corrosive material F. None of the Above 195. If the _____________was outdoors, move away from the area where the chlorine was released. Go to the highest ground possible, because chlorine is heavier than air and will sink to low-lying areas. If the chlorine release was indoors, get out of the building. A. Hydrogen sulfide D. A characteristic pungent odor B. Oxomonosilane E. Chlorine release C. Chlorine in solution F. None of the Above 196. If you think you may have been exposed, remove your clothing, rapidly wash your entire body with soap and water, __________________. A. Exposure to chlorine D. And get medical care as quickly as possible B. Odor thresholds E. Moisture, steam, and water C. A corrosive material F. None of the Above How Chlorine Exposure is Treated 197. No antidote exists for____________________. Treatment consists of removing the chlorine from the body as soon as possible and providing supportive medical care such as inhaled breathing treatments for wheezing in a hospital setting. A. Hydrogen sulfide D. A characteristic pungent odor B. Chlorine exposure E. Chlorine release C. Chlorine in solution F. None of the Above Chlorine’s Appearance and Odor (QA/QC) 198. ___________ is a greenish-yellow gas with a characteristic pungent odor. It condenses to an amber liquid at approximately -34 degrees C (-29.2 degrees F) or at high pressures. A. Hydrogen sulfide D. A characteristic pungent odor B. Oxomonosilane E. Chlorine C. Chlorine in solution F. None of the Above 199. Odor thresholds ranging from 0.08 to part per million (ppm) parts of air have been reported. Prolonged exposures may result in______________________. A. Exposure to chlorine D. Olfactory fatigue B. Odor thresholds E. Moisture, steam, and water C. A corrosive material F. None of the Above Reactivity 200. Conditions Contributing to Instability: Cylinders of chlorine may burst when exposed to elevated temperatures. Chlorine in solution forms______________. A. Hydrogen sulfide D. A characteristic pungent odor B. Oxomonosilane E. A corrosive material C. Chlorine in solution F. None of the Above 41 Chlorination 303 8/9/2015 Assignment 201. Incompatibilities: Flammable gases and vapors form explosive mixtures with chlorine. Contact between chlorine and many combustible substances (such as gasoline and petroleum products, hydrocarbons, turpentine, alcohols, acetylene, hydrogen, ammonia, and sulfur), reducing agents, and finely divided metals may cause___________________ . A. Exposure to chlorine D. Fires and explosions B. Odor thresholds E. Moisture, steam, and water C. A corrosive material F. None of the Above 202. Contact between chlorine and arsenic, bismuth, boron, calcium, activated carbon, carbon disulfide, glycerol, hydrazine, iodine, methane, oxomonosilane, ________________, propylene, and silicon should be avoided. A. Hydrogen sulfide D. A characteristic pungent odor B. Potassium E. Chlorine release C. Chlorine in solution F. None of the Above 203. Chlorine reacts with hydrogen sulfide and water to form____________, and it reacts with carbon monoxide and sulfur dioxide to form phosgene and sulfuryl chloride. A. Hydrogen sulfide D. A characteristic pungent odor B. Oxomonosilane E. Hydrochloric acid C. Chlorine in solution F. None of the Above 204. Chlorine is also incompatible with ____________________. A. Exposure to chlorine D. Hydrogen sulfide B. Odor thresholds E. Moisture, steam, and water C. A corrosive material F. None of the Above Disinfection Essentials 205. Selecting the right ______________requires understanding the factors governing the particular site and the water or wastewater to be treated. In general, the selection of an appropriate disinfection system should be evaluated against the following six criteria… A. Operating costs D. Breathing apparatus and protective clothing B. Disinfection weapon E. Net-positive environmental benefit C. UV has safeguards F. None of the Above 206. Safety. How does the disinfectant work and what types of precautions are needed to transport, store, use, and operate the disinfectant system and associated chemicals? If a system will require significant safety protection—such as use of breathing apparatus and protective clothing—as well as high levels of operator training, it may be advisable to explore other,_____________. In addition, while the disinfectant may be relatively safe to use, consideration also has to be made for the effects of both intentional and unintentional releases to the environment. A. Operating costs D. Breathing apparatus and protective clothing B. Less intensive systems E. Net-positive environmental benefit C. UV has safeguards F. None of the Above 42 Chlorination 303 8/9/2015 Assignment 207. Effectiveness. How effective is the disinfectant against the pathogens present in the water or wastewater? Since the intent is to reduce the levels of pathogens to acceptable standards, understanding how effective the proposed disinfectant system is in achieving those_____________, as well as the system's ability to reliably achieve the result, will be important to selecting the right system. A. Target levels D. Net-positive environmental benefit B. Narrow tolerance E. Acceptable standards C. Desired parameters F. None of the Above 208. Cost. What are the costs associated with the disinfection system, both in terms of _____________and ongoing operations and maintenance? Operating costs can vary in terms of the time it takes to service the disinfectant system regularly, and the costs of supplies and components. A. Operating costs D. Breathing apparatus and protective clothing B. Capital outlay E. Net-positive environmental benefit C. UV F. None of the Above 209. Complexity of use. How does the system operate and does it take specialized training to keep the system within tolerances? Since the outflow from the treatment facility may be subject to various standards and regulations, if the system is too complex it may require additional staff time to ensure that it operates within the _______________. A. Disinfectant system D. Net-positive environmental benefit B. Narrow tolerance E. Acceptable standards C. Desired parameters F. None of the Above 210. Environmental/Adverse Effects. What are some of the potential downsides to the operation of the system as it relates to the distribution system or watershed in which the treated effluent is discharged? While some systems may provide a net-positive environmental benefit through increased ________________, other systems may need to have additional treatment of the disinfected effluent in order to render it benign when released. A. Operating costs D. Breathing apparatus and protective clothing B. Other than chlorine E. Oxygenation of the receiving waters C. Safeguards F. None of the Above 211. Flow and Water Characteristics. Can the system handle fluctuations within the flow or with changing characteristics of the water or wastewater being processed? If a system has a narrow tolerance for the amount of water or wastewater flow, this could impact the effectiveness of the overall system. In addition, if the system cannot adjust for ____________such as dry or wet weather flow rates of the receiving water body, this may also affect the system's appropriateness for your application. A. Off-site concerns D. Net-positive environmental benefit B. Narrow tolerance E. Acceptable standards C. Desired parameters F. None of the Above 212. With those criteria in mind, there are primarily four basic disinfection systems currently available—chlorination, ozone gas, ultraviolet radiation, and______________. A. Operating costs D. Chemical treatment other than chlorine B. Other than chlorine E. Net-positive environmental benefit C. UV has safeguards F. None of the Above 43 Chlorination 303 8/9/2015 Assignment 213. A variety of factors come into play in deciding which type of disinfectant system is right for your operation. The decision to install a system could be the result of local concerns and potential to mitigate health risks, as well as_____________. In any event, the operator of an onsite water or wastewater treatment plant needs to consider some of the safeguards that need to be in place as well. A. Improved community relations D. Net-positive environmental benefit B. Narrow tolerance E. Acceptable standards C. Desired parameters F. None of the Above 214. "Typical safeguards include operator training and instrumentation monitoring that will perform a shutdown function if something goes above a certain level," says Schilling. "If they detect [for example] an ozone leak, you can do an interconnect and do a plant shutdown. UV has safeguards where you have monitors that tell you what your ________________ is, and if you're over or under your dosage it will perform some kind of warning of whatever you want to do." A. Operating costs D. Dosage B. Other than chlorine E. Net-positive environmental benefit C. UV has safeguards F. None of the Above What Happens to Chlorine When it Enters the Environment? 224. When released to air, chlorine will react with water to form hypochlorous acid and hydrochloric acid, which are removed from the atmosphere by__________________. A. Generation of free oxygen radicals D. Manganese dioxide B. Chlorine gas E. Rainfall C. Hydrochloric acid F. None of the Above 225. Chlorine is____________. It reacts with water to form hypochlorous acid and hydrochloric acid. The hypochlorous acid breaks down rapidly. The hydrochloric acid also breaks down; its breakdown products will lower the pH of the water (makes it more acidic). A. Free oxygen radicals D. A greenish-yellow, noncombustible gas B. Slightly soluble in water E. Basicly hypochlorous and hydrochloric acid C. Hydrochloric acid F. None of the Above 226. Since chlorine is a gas it is rarely found in soil. If released to soil, chlorine will react with moisture forming ______________. These compounds can react with other substances found in soil. A. Generation of free oxygen radicals D. A greenish-yellow, noncombustible gas B. Chlorine gas E. Hypochlorous acid and hydrochloric acid C. Hydrochloric acid F. None of the Above 227. Chlorine does not accumulate in the____________. A. Food chain D. Manganese dioxide B. Bacteria and viruses E. Basic building blocks of our planet C. Salmonella and E. coli F. None of the Above 44 Chlorination 303 8/9/2015 Assignment Disinfectant Qualities 228. Restaurants and meat and poultry processing plants rely on chlorine bleach and other chlorine-based products to kill harmful levels of bacteria such as ___________ on food preparation surfaces and during food processing. A. Salmonella and E. coli D. Studying and synthesizing organic compounds B. Chlorine disinfection E. Animals C. Chemical bridges F. None of the Above 229. Chlorine is so important in poultry processing that the US Department of Agriculture requires an almost constant chlorine rinse for much of the cutting equipment. In fact, no proven economical alternative to chlorine disinfection exists for use in____________________. A. Salmonella and E. coli D. Harnessed innovatively for good use B. Chlorine disinfection E. Meat and poultry processing facilities C. Chemical bridging F. None of the Above Properties 230. Because it is highly reactive, chlorine is usually found in nature bound with other elements like sodium, potassium, and magnesium. When chlorine is isolated as___________, chlorine is a greenish yellow gas, which is 2.5 times heavier than air. It turns to a liquid state at -34°C (29°F), and it becomes a yellowish crystalline solid at -103°C (-153°F). A. A free oxygen radicals D. A free element B. A gas E. Hypochlorous acid and hydrochloric acid C. An acid F. None of the Above 231. Chemists began experimenting with chlorine and _______________in the 18th century. They learned that chlorine has an extraordinary ability to extend a chemical bridge between various elements and compounds that would not otherwise react with each other. A. Salmonella and E. coli D. Organic compounds B. Chlorine disinfection E. Animals C. Chlorine compounds F. None of the Above 232. Chlorine has been especially useful in studying and ____________ -- compounds that have at least one atom of the element carbon in their molecular structure. All living organisms, including humans, are composed of organic compounds. A. Synthesizing organic compounds D. Organic compounds B. Chlorine disinfection E. Most abundant chemical elements C. Chlorine compounds F. None of the Above 233. Chlorine is one of the _______________ on Earth. It is ubiquitous in soils, minerals, plants and animals. A. Synthesizing organic compounds D. Organic compounds B. Chlorine disinfection E. Most abundant chemical elements C. Chlorine compounds F. None of the Above 234. Seawater is a huge reservoir of ___________________from the continents and transported to the oceans by Earth's rivers. A. Workhorse chemical D. Useful chemical elements B. Chlorine-based disinfectants E. Dissolved chlorine weathered C. Ancient seawater F. None of the Above 45 Chlorination 303 8/9/2015 Assignment 235. Chlorine is also one of the most useful chemical elements. Each chemical element has its own set of unique properties and chlorine is known as _____________--so reactive, in fact, that it is usually found combined with other elements in the form of compounds. More than 3,500 naturally occurring chlorinated organic (associated with living organisms) compounds alone have been identified. A. Synthesizing organic compounds D. Organic compounds B. A very reactive element E. Most abundant chemical elements C. Chlorine compounds F. None of the Above 236. Chlorine's ________________have been harnessed innovatively for good use. For example, this element plays a huge role in public health. A. Synthesizing organic compounds D. Organic compounds B. A very reactive element E. Chemical properties C. Chlorine compounds F. None of the Above 237. _______________ are capable of removing a wide variety of disease-causing germs from drinking water and wastewater as well as from hospital and food production surfaces. A. Workhorse chemical D. Useful chemical elements B. Chlorine-based disinfectants E. Organic compounds C. Ancient seawater F. None of the Above 238. Additionally, chlorine plays an important role in the manufacture of thousands of products we depend upon every day, including such diverse items as cars, computers, pharmaceuticals and military flak jackets. As the ninth largest chemical produced in the U.S. by volume, chlorine is truly a "________ ." A. Workhorse chemical D. Useful chemical elements B. Chlorine-based disinfectants E. Organic compounds C. Ancient seawater F. None of the Above Released From the Salt of the Earth 239. Chlorine is produced industrially from the compound sodium chloride, one of the many salts found in geologic deposits formed from the slow evaporation of ______________. A. Workhorse chemical D. Useful chemical elements B. Chlorine-based disinfectants E. Organic compounds C. Ancient seawater F. None of the Above Chlorine’s Effectiveness 240. The effectiveness of ___________ depends on the chlorine demand of the water, the concentration of the chlorine solution added, the time that chlorine is in contact with the organism, and water quality. A. Chlorine residual D. Chlorination B. Color change E. Required contact time C. Chlorine demand F. None of the Above 241. As the concentration of the chlorine increases, the ________________ to disinfect decreases. A. pH increases D. Required contact time B. Chlorine level and water quality E. Not available for disinfection C. Free chlorine residual F. None of the Above 46 Chlorination 303 8/9/2015 Assignment 242. Chlorination is more effective as______________. A. Chlorine residual D. Chlorination B. Color change E. Water temperature increases C. Chlorine demand F. None of the Above 243. Chlorination is less effective as the _____________(becomes more alkaline). A. Water's pH increases D. Required contact time B. Chlorine level and water quality E. Is not available for disinfection C. Free chlorine residual F. None of the Above 244. Chlorination is less effective in___________. A. Chlorine residual D. Chlorination B. Color change E. Cloudy (turbid) water C. Chlorine demand F. None of the Above 245. When chlorine is added to the water supply, _____________in water (like iron, manganese, hydrogen sulfide, and ammonia) and is not available for disinfection. A. pH increases D. Required contact time B. Chlorine level and water quality E. Part of it combines with other chemicals C. Free chlorine residual F. None of the Above 246. The amount of chlorine that reacts with the other chemicals plus the amount required to achieve disinfection is the _____________ of the water. A. Chlorine residual D. Chlorination B. Color change E. Free chlorine residual C. Chlorine demand F. None of the Above 247. The safest way to be sure that the amount of chlorine added is sufficient is to add a little more than is required. This will result in ____________that can be measured easily. This chlorine residual must be maintained for several minutes depending on chlorine level and water quality. A. pH increases D. Required contact time B. Chlorine level and water quality E. A free chlorine residual C. Chlorine demand F. None of the Above 248. Kits are available for measuring the _________ by looking for a color change after the test chemical is added. The test is simple and easy for a homeowner to perform. A. Chlorine residual D. Free chlorine residual B. Color change E. Required contact time C. Chlorine demand F. None of the Above 249. If chlorination is required for the water supply, the chlorine residual should be tested regularly to make sure the system is working properly. The kit should specify that it measures the free chlorine residual and not the______________. A. pH increases D. Required contact time B. Chlorine level and water quality E. Total chlorine C. Free chlorine residual F. None of the Above (S) Means the answer can be plural or singular 47 Chlorination 303 8/9/2015 Assignment 250. Once chlorine has combined with other chemicals it is not effective as a disinfectant. If a test kit does not distinguish between free chlorine and __________with other chemicals, the test may result in an overestimation of the chlorine residual. A. Chlorine residual D. Chlorination B. Color change E. Chlorine combined C. Chlorine demand F. None of the Above 251. Chlorine will kill bacteria in water, but it takes some time. The time needed depends on the concentration of chlorine.__________: simple chlorination and superchlorination. A. pH increases D. Required contact time B. Chlorine level and water quality E. Two methods of chlorination are used to disinfect water C. Free chlorine residual F. None of the Above Oxidation Chemistry 252. Oxidation chemistry has long been an accepted and effective part of many water treatment programs. Oxidizing chemicals used in today's water treatment programs include: chlorine, chlorine dioxide, bromine, bromine/chlorine releasing compounds, ozone and_____________. A. Limit the effects of organic material D. An additional killing mechanism B. Hydrogen peroxide E. Limit the travel of pathogens C. Residual level of disinfection F. None of the Above 253. _____________are often found at the forefront of many cooling water treatment programs. In large volume or once-through cooling systems they are usually the primary biocide and often are the most cost-effective programs available to a plant. A. Oxidizing microbiocides D. The primary methods used for the disinfection B. Disinfection process E. Economical and versatile chemicals C. Environmental and regulatory impact F. None of the Above 254. When selecting these _______________, several factors should be considered before a technically sound program is implemented. A. As necessary D. The primary methods used for the disinfection B. Disinfection process E. Economical and versatile chemicals C. Environmental and regulatory impact F. None of the Above 255. Environmental and regulatory impact, ________, process contamination, and equipment capital and maintenance expense all play a role in the decision-making process. A. As necessary D. The primary methods used for the disinfection B. Disinfection process E. Economical and versatile chemicals C. System pH F. None of the Above 256. The primary killing mechanism these types of microbiocides use is oxidizing protein groups within a microorganism. Proteins are the basic components of ________that are necessary for life-sustaining cellular processes such as respiration. A. Total Coliform (TC) D. Cryptosporidium B. Indicator organisms E. Essential cellular enzymes C. Cholera, polio, typhoid, hepatitis F. None of the Above 48 Chlorination 303 8/9/2015 Assignment 257. The destruction of these proteins deprives the cell of its ability to carry out ______________and quickly kills it. One oxidant is chlorine dioxide, which appears to provide an additional killing mechanism. A. Limit the effects of organic material D. An additional killing mechanism B. Numerous alternative disinfection processes E. Fundamental life functions C. Residual level of disinfection F. None of the Above 258. Chlorine dioxide is able to diffuse readily through hydrophobic lipid layers of an organism, allowing it to react with__________, which directly inhibits protein synthesis. Since amino acids are the basic building blocks of all cellular proteins, destruction of these molecules has a devastating effect on the microorganism. A. Cellular amino acids D. The primary methods used for the disinfection B. Disinfection process E. Economical and versatile chemicals C. Environmental and regulatory impact F. None of the Above Understanding Disinfection Wastewater Disinfection 259. There are a number of chemicals and processes that will____________, but none are universally applicable. Most septic tanks discharge into various types of subsurface wastewater infiltration systems (SWIS), such as tile fields or leach fields. A. Limit the effects of organic material D. Disinfect wastewater B. Numerous alternative disinfection processes E. Limit the travel of pathogens C. Residual level of disinfection F. None of the Above 260. Aerobic treatment processes reduce pathogens, but not enough to qualify as a _______. A. As necessary D. Primary methods used for the disinfection B. Disinfection process E. Economical and versatile chemicals C. Environmental and regulatory impact F. None of the Above 261. Chlorination/dechlorination has been the most widely used disinfection technology in the U.S.; ozonation and UV light are emerging technologies." Each of these three methods have different considerations for the________. A. Disinfection of wastewater D. The primary methods used for the disinfection B. Disinfection process E. Economical and versatile chemicals C. Environmental and regulatory impact F. None of the Above Water Disinfection 262. Disinfection is usually the final stage in the __________in order to limit the effects of organic material, suspended solids and other contaminants. A. Limit the effects of organic material D. Water treatment process B. Numerous alternative disinfection processes E. Limit the travel of pathogens C. Residual level of disinfection F. None of the Above 263. Like the disinfection of wastewater, the primary methods used for the ________in very small (25-500 people) and small (501-3,300 people) treatment systems are ozone, ultraviolet irradiation (UV) and chlorine. A. Chlorates are powerful oxidizers D. Microbiological contamination B. Adverse health effects E. Sodium chloride C. Disinfection of water F. None of the Above 49 Chlorination 303 8/9/2015 Assignment 264. There are ____________ that have been less widely used in small and very small water treatment systems, including chlorine dioxide, potassium permanganate, chloramines and peroxone (ozone/hydrogen peroxide). A. Limit the effects of organic material D. Additional killing mechanism B. Numerous alternative disinfection processes E. Pathogens C. Residual level of disinfection F. None of the Above 265. Surface waters have been the focal point of ____________since their inception, as groundwaters (like wells) have been historically considered to be free of microbiological contamination. Current data indicates this to not be true. Amendments to the Safe Drinking Water Act in 1996 mandate the development of regulations to require disinfection of groundwater "as necessary”. A. Chlorates are powerful oxidizers D. Microbiological contamination B. Adverse health effects E. Sodium chloride C. Water disinfection regulations F. None of the Above Residual Disinfection 266. The EPA requires a residual level of disinfection of water in pipelines to prevent microbial re-growth and help protect treated water throughout the distribution system. ________are 4 mg/l for chlorine, 4 mg/l for chloramines and 0.8 mg/l for chlorine dioxide. A. Acid/base balance D. EPA”s maximum residual disinfection levels (MRDLs) B. Stable perchlorates E. Chemical formula CaCl2 C. Formula ClO-3 F. None of the Above 267. Although chlorine levels are usually significantly lower in tap water, EPA believes that levels as high as the ________________pose no risk of adverse health effects, allowing for an adequate margin of safety (U.S. EPA, 1998a). A. MRDLs D. Microbiological contamination B. Adverse health effects E. Sodium chloride C. The chloride ion F. None of the Above Chlorate Ion 268. The chlorate anion has the formula ClO-3. In this case, the chlorine atom is in the +5 oxidation state. "Chlorate" can also refer to chemical compounds containing this anion; chlorates are the salts of chloric acid. "Chlorate", when followed by a roman numeral in parentheses, e.g. chlorate (VII), refers to a particular oxyanion of chlorine. As predicted by VSEPR, chlorate anions have___________. A. Acid/base balance D. Trigonal pyramidal structures B. Stable perchlorates E. Chemical formula CaCl2 C. Formula ClO-3 F. None of the Above 269. ____________ and should be kept away from organics or easily oxidized materials. Mixtures of chlorate salts with virtually any combustible material (sugar, sawdust, charcoal, organic solvents, metals, etc.) will readily deflagrate. A. Chlorates are powerful oxidizers D. Microbiological contamination B. Adverse health effects E. Sodium chloride C. Formula ClO-3 F. None of the Above 50 Chlorination 303 8/9/2015 Assignment 270. Chlorates were once widely used in _________for this reason, though their use has fallen due to their instability. Most pyrotechnic applications which formerly used chlorates in the past now use the more stable perchlorates instead. A. Acid/base balance D. Pyrotechnics B. Stable perchlorates E. Chemical formula CaCl2 C. Formula ClO-3 F. None of the Above Chloride Ion 271. The chloride ion is formed when the_________, a halogen, gains an electron to form an anion (negatively-charged ion) Cl-. A. Chlorates are powerful oxidizers D. Microbiological contamination B. Adverse health effects E. Sodium chloride C. Element chlorine F. None of the Above 272. The salts of hydrochloric acid contain chloride ions and can also be called chlorides. The chloride ion, and its salts such as sodium chloride,_______________. A. Acid/base balance D. Are very soluble in water B. The stable perchlorates E. The chemical formula CaCl2 C. The formula ClO-3 F. None of the Above 273. The word chloride can also form part of the name of chemical compounds in which one or more chlorine atoms are covalently bonded. For example, methyl chloride, more commonly called chloromethane, (CH3Cl) is___________, which does not contain a chloride ion. A. Chlorates are powerful oxidizers D. An organic covalently bonded compound B. Adverse health effects E. Sodium chloride C. The chloride ion F. None of the Above 274. Chloride is used to form salts that can preserve food such as sodium chloride. Other salts such as calcium chloride, magnesium chloride, potassium chloride have varied uses ranging from medical treatments to________________. A. Chemical formula CaCl2 D. Corresponding anions Cl-, ClO-, ClO2-, ClO3-, or ClO4 B. Cement formation E. Chlorine dioxide C. Chlorite ion is ClO2-. F. None of the Above 275. An example is table salt, which is sodium chloride with the chemical formula______. In water, it dissociates into Na+ and Cl- ions. A. Chemical formula CaCl2 D. Corresponding anions Cl-, ClO-, ClO2-, ClO3-, or ClO4 B. NaCl E. Chlorine dioxide C. Chlorite ion is ClO2-. F. None of the Above 276. ___________is also the prosthetic group present in the amylase enzyme. Another example is calcium chloride with the chemical formula CaCl2. A. Chemical formula CaCl2 D. Corresponding anions Cl-, ClO-, ClO2-, ClO3-, or ClO4 B. A chloride ion E. Chlorine dioxide C. Chlorite ion is ClO2-. F. None of the Above 51 Chlorination 303 8/9/2015 Assignment 277. Calcium chloride is a salt that is marketed in pellet form for removing dampness from rooms. ____________ is also used for maintaining unpaved roads and for sanite fortifying roadbases for new construction. In addition, Calcium chloride is widely used as a deicer since it is effective in lowering the melting point when applied to ice. A. Chemical formula CaCl2 D. Corresponding anions Cl-, ClO-, ClO2-, ClO3-, or ClO4 B. Calcium chloride E. Chlorine dioxide C. Chlorite ion is ClO2-. F. None of the Above 278. In the petroleum industry, the ___________are a closely monitored constituent of the mud system. An increase of the chlorides in the mud system may be an indication of drilling into a high-pressure saltwater formation. Its increase can also indicate the poor quality of a target sand. A. Chemical formula CaCl2 D. Chlorides B. Chloride E. Chlorine dioxide C. Chlorite ion is ClO2-. F. None of the Above 279. ______________ is also a useful and reliable chemical indicator of river / groundwater fecal contamination, as chloride is a non-reactive solute and ubiquitous to sewage & potable water. Many water regulating companies around the world utilize chloride to check the contamination levels of the rivers and potable water sources. A. Chemical formula CaCl2 D. Corresponding anions Cl-, ClO-, ClO2-, ClO3-, or ClO4 B. Chloride E. Chlorine dioxide C. Chlorite ion is ClO2-. F. None of the Above Chlorite Ion 280. The chlorite ion is__________. A chlorite (compound) is a compound that contains this group, with chlorine in oxidation state +3. Chlorites are also known as salts of chlorous acid. A. Chemical formula CaCl2 D. Corresponding anions Cl-, ClO-, ClO2-, ClO3-, or ClO4 B. Chloride E. Chlorine dioxide C. ClO2F. None of the Above 281. Chlorine can assume oxidation states of -1, +1, +3, +5, or +7 within the corresponding anions Cl-, ClO-, ClO2-, ClO3-, or ClO4-, known commonly and respectively as__________ . A. Chemical formula CaCl2 D. Chloride, hypochlorite, chlorite, chlorate, and perchlorate B. Chloride E. Chlorine dioxide C. Chlorite ion is ClO2-. F. None of the Above 282. An additional oxidation state of +4 is seen in the neutral compound_________, which has a similar structure to chlorite ClO2- (oxidation state +3) and the cation chloryl (ClO2+) (oxidation state +5). A. Chemical formula CaCl2 D. Corresponding anions Cl-, ClO-, ClO2-, ClO3-, or ClO4 B. Chloride E. Chlorine dioxide ClO2 C. Chlorite ion is ClO2-. F. None of the Above 52 Chlorination 303 8/9/2015 Assignment Chlorine Dioxide 283. Chlorine dioxide is a chemical compound with the formula _________. This yellowishgreen gas crystallizes as bright orange crystals at -59 °C. As one of several oxides of chlorine, it is a potent and useful oxidizing agent used in water treatment and in bleaching. A. Chemical formula CaCl2 D. Corresponding anions Cl-, ClO-, ClO2-, ClO3-, or ClO4 B. Chloride E. ClO2 C. Chlorite ion is ClO2-. F. None of the Above 284. The molecule _________ has an odd number of valence electrons and it is therefore a paramagnetic radical. Its electronic structure has long baffled chemists because none of the possible Lewis structures are very satisfactory. In 1933 L.O. Brockway proposed a structure that involved a three-electron bond. A. Chemical formula CaCl2 D. Corresponding anions Cl-, ClO-, ClO2-, ClO3-, or ClO4 B. Chloride E. ClO2 C. Chlorite ion is ClO2-. F. None of the Above 285. Chemist Linus Pauling further developed this idea and arrived at two resonance structures involving a double bond on one side and a single bond plus three-electron bond on the other. In Pauling's view the latter combination should represent a bond that is slightly weaker than the double bond. In molecular orbital theory this idea is commonplace if the third electron is placed in an anti-bonding orbital. Later work has confirmed that the HOMO is_____________________. A. An anti-bonding orbital D. A common undesirable by-product B. A single halogen E. Indeed an incompletely-filled orbital C. Hypochlorite compounds F. None of the Above 286. ______________ is a highly endothermic compound that can decompose extremely violently when separated from diluting substances. As a result, preparation methods that involve producing solutions of it without going through a gas phase stage are often preferred. Arranging handling in a safe manner is essential. A. High-test calcium hypochlorite(s) D. Negative charge of the conjugate base B. Calcium hypochlorite tablets E. Chlorine dioxide C. Hypochlorous acid F. None of the Above Haloacetic Acids 287. Haloacetic acids are ____________________in which a halogen atom takes the place of a hydrogen atom in acetic acid. Thus, in a monohaloacetic acid, a single halogen would replace a hydrogen atom. For example, chloroacetic acid would have the structural formula CH2ClCO2H. A. An anti-bonding orbital D. Carboxylic acids B. A single halogen E. Calcium hypochlorite C. Hypochlorite compounds F. None of the Above 288. In the same manner, in dichloroacetic acid two chlorine atoms would take the place of two hydrogen atoms (CHCl2CO2H). The inductive effect caused by the _____________often result in the higher acidity of these compounds by stabilizing the negative charge of the conjugate base. A. High-test calcium hypochlorite(s) D. Electronegative halogens B. Calcium hypochlorite tablets E. Chlorine dioxide C. Hypochlorous acid F. None of the Above 53 Chlorination 303 8/9/2015 Assignment Contaminants in Drinking Water 289. Haloacetic acids (HAAs) are a common undesirable by-product of drinking water chlorination. Exposure to such ________________in drinking water has been associated with a number of health outcomes by epidemiological studies, although the putative agent in such studies has not been identified. A. An anti-bonding orbital D. Disinfection by-products B. A single halogen E. Calcium hypochlorite C. Hypochlorite compounds F. None of the Above Hypochlorites 290. Hypochlorites are calcium or sodium salts of hypochlorous acid and are supplied either dry or in liquid form (as, for instance, in commercial bleach). The same residuals are obtained as with gas chlorine, but the effect on the ____________of the treated water is different. A. High-test calcium hypochlorite(s) D. Negative charge B. Calcium hypochlorite tablets E. pH C. Hypochlorous acid F. None of the Above 291. Hypochlorite compounds contain an excess of ________and tend to raise the pH of the water. A. An anti-bonding orbital D. A common undesirable by-product B. Alkali E. Calcium hypochlorite C. Hypochlorite compounds F. None of the Above 292. Calcium hypochlorite tablets are the predominant form in use in the United States for swimming pools. _______________is the only liquid hypochlorite disinfectant in current use. There are several grades and proprietary forms available. A. High-test calcium hypochlorite(s) D. Sodium hypochlorite B. Calcium hypochlorite tablets E. Chlorine dioxide C. Hypochlorous acid F. None of the Above 293. Pound-for-pound of available chlorine, ______________have oxidizing powers equal to gas chlorine and can be employed for the same purposes in water treatment. A. Hypochlorite compounds D. And some undesirable by-product of drinking water B. And some acids E. With calcium hypochlorite C. Hypochlorous compounds F. None of the Above 294. Gas chlorination requires a larger initial investment for feed equipment than what is needed for ____________. A. High-test calcium hypochlorite(s) D. Negative charge of the conjugate base B. Calcium hypochlorite tablets E. Hypochlorite compounds C. Hypochlorous acid F. None of the Above 295. Calcium hypochlorite materials used in the water industry are chemically different from those materials variously marketed for many years as bleaching powder, chloride of lime, or chlorinated lime. Materials now in common use are ________containing about 70 percent available chlorine and marketed under several trade names. A. An anti-bonding orbital D. High-test calcium hypochlorites B. A single halogen E. Calcium hypochlorite C. Hypochlorite compounds F. None of the Above (S) Means the answer can be plural or singular 54 Chlorination 303 8/9/2015 Assignment 296. _______________ are white corrosive solids that give off a strong chlorine odor. Granular powdered or tablet forms are commercially available and all are readily soluble in water. A. High-test calcium hypochlorite(s) D. Negative charge of the conjugate base B. Calcium hypochlorite tablets E. Chlorine dioxide C. Hypochlorous acid F. None of the Above 297. __________________is sold only as a liquid and is normally referred to as liquid bleach. It is generally available in concentrations of 5 to 15 percent available chlorine. These solutions are clear, light yellow, strongly alkaline, and corrosive in addition to having a strong chlorine smell. A. Sodium hypochlorite D. High-test calcium hypochlorites B. A single halogen E. Calcium hypochlorite C. Hypochlorite compounds F. None of the Above 298. _____________, though highly active, are relatively stable throughout production, packaging, distribution, and storage. Storage at 86° F. for a year may reduce the available chlorine by about 10 percent. Storing at lower temperatures reduces the loss. A. High-test calcium hypochlorite(s) D. Negative charge of the conjugate base B. Calcium hypochlorite tablets E. Chlorine dioxide C. Hypochlorous acid F. None of the Above 299. ________________solutions are unstable to some degree and deteriorate more rapidly than the dry compounds. Most producers recommend a shelf life of 60 to 90 days. Because light and heat accelerate decomposition, containers should be stored in a dry, cool, and dark area. A. High-test calcium hypochlorite(s) D. All sodium-hypochlorite B. Calcium hypochlorite tablets E. Chlorine dioxide C. Hypochlorous acid F. None of the Above Disinfection Byproducts 300. ________________ are formed when disinfectants used in water treatment plants react with bromide and/or natural organic matter (i.e., decaying vegetation) present in the source water. Different disinfectants produce different types or amounts of disinfection byproducts. A. Disinfection byproducts D. Occurring organic and inorganic matter in water B. Other disinfectants E. Most prevalent THM C. Naturally occurring bromide F. None of the Above 301. _________________for which regulations have been established have been identified in drinking water, including trihalomethanes, haloacetic acids, bromate, and chlorite. A. Chlorine dioxide D. Trihalomethanes, haloacetic acids, bromate, and chlorite B. HAA5 E. Disinfection byproducts C. Trihalomethanes F. None of the Above Trihalomethanes (THM) 302. _______________are a group of four chemicals that are formed along with other disinfection byproducts when chlorine or other disinfectants used to control microbial contaminants in drinking water react with naturally occurring organic and inorganic matter in water. A. Disinfection byproducts D. Occurring organic and inorganic matter in water B. Other disinfectants E. Trihalomethanes (THM) C. Naturally occurring bromide F. None of the Above 55 Chlorination 303 8/9/2015 Assignment 303. The _____________ are chloroform, bromodichloromethane, dibromochloromethane, and bromoform. EPA has published the Stage 1 Disinfectants/Disinfection Byproducts Rule to regulate total trihalomethanes (TTHM) at a maximum allowable annual average level of 80 parts per billion. A. Chlorine dioxide D. Trihalomethanes, haloacetic acids, bromate, and chlorite B. HAA5 E. Chloroform C. Trihalomethanes F. None of the Above Haloacetic Acids (HAA5) 304. Haloacetic Acids (HAA5) are a group of chemicals that are formed along with other disinfection byproducts when chlorine or other disinfectants used to control _________in drinking water react with naturally occurring organic and inorganic matter in water. A. Disinfection byproducts D. Occurring organic and inorganic matter in water B. Other disinfectants E. Microbial contaminants C. Naturally occurring bromide F. None of the Above 305. The regulated haloacetic acids, known as _______________, are: monochloroacetic acid, dichloroacetic acid, trichloroacetic acid, monobromoacetic acid, and dibromoacetic acid. EPA has published the Stage 1 Disinfectants/Disinfection Byproducts Rule to regulate HAA5 at 60 parts per billion annual average. A. Chlorine dioxide D. Trihalomethanes, haloacetic acids, bromate, and chlorite B. HAA5 E. Chloroform C. Trihalomethanes F. None of the Above 306. Bromate is a chemical that is formed when ___________used to disinfect drinking water reacts with naturally occurring bromide found in source water. EPA has established the Stage 1 Disinfectants/Disinfection Byproducts Rule to regulate bromate at annual average of 10 parts per billion in drinking water. This standard will become effective for large public water systems by December 2001 and for small surface water and all ground public water systems in December 2003. A. Disinfection byproducts D. Occurring organic and inorganic matter in water B. Other disinfectants E. Ozone C. Naturally occurring bromide F. None of the Above Chlorite 307. _______________is a byproduct formed when chlorine dioxide is used to disinfect water. EPA has published the Stage 1 Disinfectants/Disinfection Byproducts Rule to regulate chlorite at a monthly average level of 1 part per million in drinking water. A. Chlorite D. Trihalomethanes, haloacetic acids, bromate, and chlorite B. HAA5 E. Chloroform C. Trihalomethanes F. None of the Above Chloroform 308. Chloroform, typically the most prevalent ________ measured in chlorinated water, is probably the most thoroughly studied disinfection byproduct. Toxicological studies have shown that high levels of chloroform can cause cancer in laboratory animals. A. Disinfection byproducts D. Occurring organic and inorganic matter in water B. Other disinfectants E. THM C. Naturally occurring bromide F. None of the Above 56 Chlorination 303 8/9/2015 Assignment 309. Extensive research conducted since the early 1990s provides a clearer picture of what this means for humans exposed to far lower levels through drinking water. One study (Larson et al. 1994a) conducted by the Centers for Health Research (CIIT) observed that a very large dose of _______, when given to mice once per day into the stomach (a procedure known as gavage), produced liver damage and eventually cancer. In a second CIIT cancer study (Larson et al., 1994b), mice were given the same daily dose of chloroform through the animals’ drinking water. This time, no cancer was produced. A. Chlorine dioxide D. Trihalomethanes, haloacetic acids, bromate, and chlorite B. HAA5 E. Chloroform C. Trihalomethanes F. None of the Above 310. In its most recent risk assessment, EPA considered the wealth of available information on chloroform, including the important work done at CIIT. EPA concludes that exposure to chloroform below the threshold level that causes cell damage is unlikely to increase the risk of cancer. While __________is likely to be carcinogenic at a high enough dose, exposures below a certain dose range are unlikely to pose any cancer risk to humans (US EPA, 2002a). For drinking water meeting EPA standards, chloroform is unlikely to be a health concern. A. Disinfection byproducts D. Chloroform B. Other disinfectants E. Most prevalent THM C. Naturally occurring bromide F. None of the Above Sodium Chlorate 311. Sodium chlorate is a chemical compound with the chemical formula (NaClO3). When pure, it is a white crystalline powder that is readily soluble in water. It is hygroscopic. It decomposes above 250 °C to release oxygen and leave______________. Industrially, sodium chlorate is synthesized from the electrolysis of a hot sodium chloride solution in a mixed electrode tank. A. Sodium chlorate D. Electrolysis of a hot sodium chloride solution B. Ascorbic acid E. Sodium chloride C. Phosphorus F. None of the Above 312. It can also be synthesized by passing ______into a hot sodium hydroxide solution. It is then purified by crystallization. A. Chlorate D. Sodium metaborate or ammonium phosphates B. Oxygen E. The free acid, chlorous acid, HClO2 C. Chlorine gas F. None of the Above Chemical Oxygen Generation 313. Chemical oxygen generators, such as those in commercial aircraft, provide emergency oxygen to passengers to protect them from drops in cabin pressure by catalytic decomposition of ___________. The catalyst is normally iron powder. A. Sodium chlorate D. Electrolysis of a hot sodium chloride solution B. Ascorbic acid E. Sodium chlorate C. Phosphorus F. None of the Above (S) Means the answer can be plural or singular 57 Chlorination 303 8/9/2015 Assignment 314. ____________is used to absorb the chlorine which is a minor product in the decomposition. Iron powder is mixed with sodium chlorate and ignited by a charge which is activated by pulling on the emergency mask. The reaction produces more oxygen than is required for combustion. Similarly, the Solidox welding system used pellets of sodium chlorate mixed with combustible fibers to generate oxygen. A. Chlorate D. Sodium metaborate or ammonium phosphates B. Oxygen E. Barium peroxide (BaO2) C. Hot sodium hydroxide solution F. None of the Above Toxicity in Humans 315. Due to its oxidative nature, sodium chlorate can be very toxic if ingested. The oxidative effect on hemoglobin leads to methaemoglobin formation, which is followed by denaturation of the globin protein and a cross-linking of ___________with resultant damage to the membrane enzymes. A. Sodium chlorate D. Electrolysis of a hot sodium chloride solution B. Ascorbic acid E. Erythrocyte membrane proteins C. Phosphorus F. None of the Above 316. This leads to increased permeability of the membrane, and severe hemolysis. The denaturation of hemoglobin overwhelms the capacity of the G6PD metabolic pathway. In addition, this enzyme is directly denatured by ___________ reducing its activity. A. Chlorate D. Sodium metaborate or ammonium phosphates B. Oxygen E. The free acid, chlorous acid, HClO2 C. Hot sodium hydroxide solution F. None of the Above 317. Therapy with ____________ and methylene blue are frequently used in the treatment of methemoglobinemia. However, since methylene blue requires the presence of NADPH that requires normal functioning of G6PD system, it is less effective than in other conditions characterized by hemoglobin oxidation. A. Sodium chlorate D. Electrolysis of a hot sodium chloride solution B. Ascorbic acid E. Catalytic decomposition of sodium chlorate C. Phosphorus F. None of the Above Formulations 318. Sodium chlorate comes in dust, spray and granule formulations. There is a risk of fire and explosion in dry mixtures with other substances, especially organic materials, and__________, sulfur, phosphorus, powdered metals, strong acids. In particular, when mixed with sugar, it has explosive properties. A. Sodium chlorate D. Electrolysis of a hot sodium chloride solution B. Ascorbic acid E. Other herbicides C. Phosphorus F. None of the Above 319. If accidentally mixed with one of these substances it should not be stored in human dwellings. Marketed formulations contain a fire retardant, but this has little effect if deliberately ignited. Most commercially available chlorate weedkillers contain approximately __________with the balance being a fire depressant such as sodium metaborate or ammonium phosphates. A. Chlorate D. 53% sodium chlorate B. Oxygen E. The free acid, chlorous acid, HClO2 C. Hot sodium hydroxide solution F. None of the Above 58 Chlorination 303 8/9/2015 Assignment Sodium Chlorite 320. Sodium chlorite, like many oxidizing agents, should be protected from inadvertent contamination by organic materials to avoid the formation of________. The chemical explodes on percussive impact, and will ignite if combined with a strong reducing agent. A. Sodium chlorate D. An explosive mixture B. Ascorbic acid E. Catalytic decomposition of sodium chlorate C. Phosphorus F. None of the Above Toxicity 321. _____________is a strong oxidant and can therefore be expected to cause clinical symptoms similar to the well-known sodium chlorate: methemoglobinemia, hemolysis, renal failure. A. Sodium chlorate D. Electrolysis of a hot sodium chloride solution B. Ascorbic acid E. Sodium chlorite C. Phosphorus F. None of the Above 322. A dose of 10-15 grams of _________ can be lethal. Methemoglobemia had been demonstrated in rats and cats, and recent studies by the EMEA have confirmed that the clinical symptomatology is very similar to the one caused by sodium chlorate in the rat, mouse, rabbit, and the green monkey. A. Sodium chlorate D. Electrolysis of a hot sodium chloride solution B. Ascorbic acid E. Catalytic decomposition of sodium chlorate C. Phosphorus F. None of the Above 323. There is only one human case in the medical literature of____________. It seems to confirm that the toxicity is equal to sodium chlorate. A. Sodium chlorate D. Chlorite poisoning B. Ascorbic acid E. Catalytic decomposition of sodium chlorate C. Phosphorus F. None of the Above 324. From the analogy with ________, even small amounts of about 1 gram can be expected to cause nausea, vomiting and even life-threatening hemolysis in Glucose-6-Phosphate Dehydrogenase deficient persons. A. Sodium chlorate D. Electrolysis of a hot sodium chloride solution B. Ascorbic acid E. Catalytic decomposition of sodium chlorate C. Phosphorus F. None of the Above Manufacture 325. The free acid, chlorous acid, HClO2, is only stable at low concentrations. Since it cannot be concentrated, it is not a commercial product. However, the corresponding sodium salt, sodium chlorite, _____________is stable and inexpensive enough to be commercially available. A. Chlorate D. Sodium metaborate or ammonium phosphates B. Oxygen E. NaClO2 C. Hot sodium hydroxide solution F. None of the Above 326. The corresponding salts of heavy metals (Ag+, Hg+, Tl+, Pb2+, and also Cu2+ and NH4+) decompose explosively with heat or shock. Sodium chlorite is derived indirectly from_________. A. Chlorate D. Sodium metaborate or ammonium phosphates B. Oxygen E. The free acid, chlorous acid, HClO2 C. Sodium chlorate, NaClO3 F. None of the Above 59 Chlorination 303 8/9/2015 Assignment 327. First, the explosive (only at concentrations greater than 10% in atmosphere) ______is produced by reducing sodium chlorate in a strong acid solution with a suitable reducing agent (for example, sodium sulfite, sulfur dioxide, or hydrochloric acid). A. Sodium chlorate D. Chlorine dioxide, ClO2 B. Ascorbic acid E. Catalytic decomposition of sodium chlorate C. Phosphorus F. None of the Above 328. The chlorine dioxide is then absorbed into an alkaline solution and reduced with hydrogen peroxide (H2O2), yielding____________________. A. Sodium chlorate D. Electrolysis of a hot sodium chloride solution B. Ascorbic acid E. Catalytic decomposition of sodium chlorate C. Phosphorus F. None of the Above Stachybotrys 329. Stachybotrys is a genus of molds, or asexually-reproducing, filamentous fungi. Closely related to the genus Memnoniella, most Stachybotrys species inhabit materials rich in cellulose. The genus has a widespread distribution, and contains about 50 species. The most infamous species, S. chartarum (also known as S. atra) and S. chlorohalonata are known as _____________in the U.S. and are frequently associated with poor indoor air quality that arises after fungal growth on water-damaged building materials A. Salmonella and E. coli D. Organic compounds B. Mycotoxins E. Stachybotrys C. "Black mold" or "toxic black mold" F. None of the Above Symptoms of Stachybotrys Exposure in Humans 330. Exposure to the mycotoxins present in Stachybotrys chartarum or ________ atra can have a wide range of effects. A. Salmonella and E. coli D. Organic compounds B. Mycotoxins E. Stachybotrys C. Exposure and volume of spores F. None of the Above 331. Depending on the length of exposure and volume of _________inhaled or ingested, symptoms can manifest as chronic fatigue or headaches, fever, irritation to the eyes, mucous membranes of the mouth, nose and throat, sneezing, rashes, and chronic coughing. In severe cases of exposure or cases exacerbated by allergic reaction, symptoms can be extreme including nausea, vomiting, and bleeding in the lungs and nose. A. Salmonella and E. coli D. Organic compounds B. Mycotoxins E. Stachybotrys C. Spores F. None of the Above Understanding Commonly Used Water Disinfectants 332. Almost all U.S. systems that disinfect their water use some type of chlorine-based process, either alone or in combination with _______________. A. Other disinfectants D. Disease-causing organisms B. Residual disinfectant E. Eliminates slime bacteria C. Removes chemical compounds F. None of the Above 60 Chlorination 303 8/9/2015 Assignment 333. In addition to controlling disease-causing organisms, chlorination offers a number of benefits including:…. Reduces many_______________________; A. Combination with other disinfectants D. Disease-causing organisms B. Residual disinfectant E. Disagreeable tastes and odors C. Removes chemical compounds F. None of the Above 334. Eliminates _______________that commonly grow in water supply reservoirs, on the walls of water mains and in storage tanks; A. Combination with other disinfectants D. Disease-causing organisms B. Residual disinfectant E. Slime bacteria, molds and algae C. Removes chemical compounds F. None of the Above 335. Removes chemical compounds that have unpleasant tastes and______________; and…. A. Combination with other disinfectants D. Disease-causing organisms B. Residual disinfectant E. Hinder disinfection C. Removes chemical compounds F. None of the Above 336. Helps remove _______________ from raw water. A. Combination with other disinfectants D. Disease-causing organisms B. Residual disinfectant E. Eliminates slime bacteria C. Iron and manganese F. None of the Above 337. As importantly, only chlorine-based chemicals provide “_____________” levels that prevent microbial re-growth and help protect treated water throughout the distribution system. A. Combination with other disinfectants D. Disease-causing organisms B. Residual disinfectant E. Eliminates slime bacteria C. Removes chemical compounds F. None of the Above The Risks of Waterborne Disease 338. Where adequate water treatment is not readily available, the impact on public health can be devastating. Worldwide, about 1.2 billion people lack access to safe drinking water, and twice that many lack adequate sanitation. As a result, the World Health Organization estimates that 3.4 million people, mostly children, die every year from______________________. A. Total Coliform (TC) D. Cryptosporidium B. Water-related diseases E. Giardia C. Cholera, polio, typhoid, hepatitis F. None of the Above 339. Even where water treatment is widely practiced, constant vigilance is required to guard against waterborne disease outbreaks. Well-known pathogens such as ________ are easily controlled with chlorination, but can cause deadly outbreaks given conditions of inadequate or no disinfection. A striking example occurred in May 2000 in the Canadian town of Walkerton, Ontario. A. Total Coliform (TC) D. Cryptosporidium B. E. coli E. Giardia C. Cholera, polio, typhoid, hepatitis F. None of the Above 61 Chlorination 303 8/9/2015 Assignment 340. Seven people died and more than 2,300 became ill after ________and other bacteria infected the town’s water supply. A report published by the Ontario Ministry of the Attorney General concludes that, even after the well was contaminated, the Walkerton disaster could have been prevented if the required chlorine residuals had been maintained. A. Total Coliform (TC) D. Cryptosporidium B. Indicator organisms E. E. coli C. Cholera, polio, typhoid, hepatitis F. None of the Above 341. Some emerging pathogens such as Cryptosporidium are resistant to chlorination and can appear even in high quality water supplies. __________ was the cause of the largest reported drinking water outbreak in U.S. history, affecting over 400,000 people in Milwaukee in April 1993. More than 100 deaths are attributed to this outbreak. A. Total Coliform (TC) D. Cryptosporidium B. Indicator organisms E. Giardia C. Cholera, polio, typhoid, hepatitis F. None of the Above 342. New regulations from the U.S. Environmental Protection Agency (EPA) will require water systems to monitor __________ and adopt a range of treatment options based on source water Cryptosporidium concentrations. Most water systems are expected to meet EPA requirements while continuing to use chlorination. A. Total Coliform (TC) D. Cryptosporidium B. Indicator organisms E. Giardia C. Cholera, polio, typhoid, hepatitis F. None of the Above The Benefits of Chlorine Potent Germicide 343. Chlorine disinfectants can reduce the level immeasurable levels. A. Cryptosporidium parvum and Giardia lamblia B. Many disease-causing microorganisms C. Nitrogenous compounds of ___________ in drinking water to almost D. Sodium hypochlorite solution E. Chlorine disinfectants F. None of the Above 344. Chlorine is added to drinking water to destroy pathogenic (disease-causing) organisms. It can be applied in several forms:______________, sodium hypochlorite solution (bleach) and dry calcium hypochlorite. A. Cryptosporidium parvum and Giardia lamblia D. Sodium hypochlorite solution B. Many disease-causing microorganisms E. Chlorine disinfectants C. Elemental chlorine (chlorine gas) F. None of the Above 345. When applied to water, each of these forms “free chlorine” (see Sidebar: How Chlorine Kills Pathogens). One pound of elemental chlorine provides approximately as much _________as one gallon of sodium hypochlorite (12.5% solution) or approximately 1.5 pounds of calcium hypochlorite (65% strength). A. Free available chlorine D. Sodium hypochlorite solution B. Many disease-causing microorganisms E. Chlorine disinfectants C. Nitrogenous compounds F. None of the Above 62 Chlorination 303 8/9/2015 Assignment 346. While any of these forms of chlorine can effectively disinfect drinking water, each has distinct advantages and limitations for_______________. Almost all water systems that disinfect their water use some type of chlorine-based process, either alone or in combination with other disinfectants. A. Cryptosporidium parvum and Giardia lamblia D. Sodium hypochlorite solution B. Many disease-causing microorganisms E. Chlorine disinfectants C. Particular applications F. None of the Above Taste and Odor Control 347. Chlorine disinfectants reduce many disagreeable tastes and odors. Chlorine oxidizes many naturally occurring substances such as____________, sulfides and odors from decaying vegetation. A. Cryptosporidium parvum and Giardia lamblia D. Sodium hypochlorite solution B. Many disease-causing microorganisms E. Foul-smelling algae secretions C. Nitrogenous compounds F. None of the Above Biological Growth Control 348. Chlorine disinfectants eliminate __________that commonly grow in water supply reservoirs, on the walls of water mains and in storage tanks. A. Cryptosporidium parvum and Giardia lamblia D. Slime bacteria, molds and algae B. Many disease-causing microorganisms E. Chlorine disinfectants C. Nitrogenous compounds F. None of the Above Chemical Control 349. Chlorine disinfectants destroy __________(which has a rotten egg odor) and remove ammonia and other nitrogenous compounds that have unpleasant tastes and hinder disinfection. They also help to remove iron and manganese from raw water. A. Cryptosporidium parvum and Giardia lamblia D. Hydrogen sulfide B. Many disease-causing microorganisms E. Chlorine disinfectants C. Nitrogenous compounds F. None of the Above Water Treatment 350. Every day, approximately 170,000 (U.S. EPA, 2002) ____________treat and convey billions of gallons of water through approximately 880,000 miles (Kirmeyer, 1994) of distribution system piping to U.S. homes, farms and businesses. A. Chlorine residual D. Low levels of color and turbidity (cloudiness) B. Public water systems E. Distribution system piping C. Chemical or biological contamination F. None of the Above 351. Broadly speaking, water is treated to render it suitable for human use and consumption. While the primary goal is to produce a biologically (disinfected) and chemically safe product, other objectives also must be met, including: no objectionable taste or odor; ___________(cloudiness); and chemical stability (non-corrosive and non-scaling). Individual facilities customize treatment to address the particular natural and manmade contamination characteristic of their raw water. A. Chlorine residual D. Low levels of color and turbidity B. Sediments E. Distribution system piping C. Chemical or biological contamination F. None of the Above 63 Chlorination 303 8/9/2015 Assignment 352. Surface water usually presents a greater treatment challenge than groundwater, which is naturally filtered as it percolates through _______________. A. Chlorine residual D. Low levels of color and turbidity (cloudiness) B. Sediments E. Distribution system piping C. Chemical or biological contamination F. None of the Above 353. Surface water is laden with organic and mineral particulate matter, and may harbor protozoan parasites such as______________. A. Total Coliform (TC) D. Cryptosporidium parvum and Giardia lamblia B. Indicator organisms E. Giardia C. Cholera, polio, typhoid, hepatitis F. None of the Above Water Distribution 354. In storage and distribution, drinking water must be kept safe from microbial contamination. Frequently, slippery films of bacteria, known as biofilms, develop on the inside walls of pipes and storage containers. Among__________________, chlorination is unique in that a predetermined chlorine concentration may be designed to remain in treated water as a measure of protection against harmful microbes encountered after leaving the treatment facility. A. Microbial contamination D. Disinfection techniques B. Potential threats E. Cost-effective methods C. Critical assets F. None of the Above 355. In the event of a significant intrusion of pathogens resulting, for example, from a broken water main, the level of the average “____________” will be insufficient to disinfect contaminated water. In such cases, it is the monitoring of the sudden drop in the chlorine residual that provides the critical indication to water system operators that there is a source of contamination in the system. A. Chlorine residual D. Low levels of color and turbidity (cloudiness) B. Potential threats E. Distribution system piping C. Chemical or biological contamination F. None of the Above The Challenge of Disinfection Byproducts 356. While protecting against microbial contamination is the top priority, water systems must also control disinfection byproducts (DBPs), ________________when chlorine and other disinfectants react with natural organic matter in water. In the early 1970s, EPA scientists first determined that drinking water chlorination could form a group of byproducts known as trihalomethanes (THMs), including chloroform. EPA set the first regulatory limits for THMs in 1979. A. Microbial contamination D. Chemical compounds formed unintentionally B. Potential threats E. Cost-effective methods C. Critical assets F. None of the Above 357. While the available evidence does not prove that ___________in drinking water cause adverse health effects in humans, high levels of these chemicals are certainly undesirable. Cost-effective methods to reduce DBP formation are available and should be adopted where possible. A. Microbial contamination D. Vulnerability assessments B. Potential threats E. DBPs C. Critical assets F. None of the Above 64 Chlorination 303 8/9/2015 Assignment Chlorine and Water System Security 358. The prospect of a terrorist attack has forced all water systems, large and small, to reevaluate and upgrade______________. Since September 11th, 2001, water system managers have taken unprecedented steps to protect against possible attacks such as chemical or biological contamination of the water supply, disruption of water treatment or distribution, and intentional release of treatment chemicals. A. Chlorine residual D. Low levels of color and turbidity (cloudiness) B. Existing security measures E. Vulnerability assessments C. Chemical or biological contamination F. None of the Above 359. With passage of the Public Health Security and Bioterrorism Response Act of 2002, Congress required community water systems to assess their vulnerability to a terrorist attack and other intentional acts. As part of these vulnerability assessments, systems assess______________. A. Microbial contamination D. The transportation, storage and use of treatment chemicals B. Potential threats E. Cost-effective methods C. Critical assets F. None of the Above 360. These chemicals are both critical assets (necessary for delivering safe water) and ______________ (may pose significant hazards, if released). A. Microbial contamination D. Vulnerability assessments B. Potential threats E. Potential vulnerabilities C. Critical assets F. None of the Above 361. Water systems using elemental chlorine, in particular, must determine whether existing protection systems are adequate. If not, they must consider additional measures to reduce the likelihood of an attack or to mitigate the______________________. A. Microbial contamination D. Vulnerability assessments B. Potential threats E. Potential consequences C. Critical assets F. None of the Above 362. Disinfection is crucial to water system security, providing the “front line” of defense against biological contamination. However, _______________in no way guarantee safety from biological attacks. Additional research and funding are needed to improve prevention, detection and responses to potential threats. A. Microbial contamination D. Vulnerability assessments B. Potential threats E. Cost-effective methods C. Conventional treatment barriers F. None of the Above The Future of Chlorine Disinfection 363. Despite a range of new challenges, drinking water chlorination will remain a cornerstone of waterborne disease prevention. ___________ cannot be provided by any other single disinfectant. A. Potential DBP risks D. Many trihalomethanes B. THM(s) E. Chlorine’s wide array of benefits C. THMs and HAAs F. None of the Above 65 Chlorination 303 8/9/2015 Assignment 364. While _____________ (including chlorine dioxide, ozone, and ultraviolet radiation) are available, all disinfection methods have unique benefits, limitations, and costs. Water system managers must consider these factors, and design a disinfection approach to match each system’s characteristics and source water quality. A. Haloforms D. Alternative disinfectants B. Trihalomethane(s) E. Stage 1 Disinfectants and Disinfection Byproducts C. Total concentration F. None of the Above Understanding Disinfection Byproducts (DBPS) 365. _____________ have been widely used by public water systems (along with filtration) to protect the public from microbial pathogens in drinking water. DBPs are formed when certain disinfectants react with DBP precursors (organic and inorganic materials) in source waters. A. Potential DBP risks D. Many trihalomethanes B. THM(s) E. Chlorine and other chemical disinfectants C. THMs and HAAs F. None of the Above 366. In most cases, natural organic matter (NOM) is an important factor that affects the levels of DBPs that form (NOM is usually measured as TOC). The levels of _________ in drinking water can vary significantly from one point in a distribution system to another, as many continue to form in the distribution system. DBP levels are generally higher in surface water systems because surface water usually contains higher DBP precursor levels and requires stronger disinfection. A. Haloforms D. Alternative disinfectants B. Trihalomethane(s) E. DBPs C. Total concentration F. None of the Above Updating the Safe Drinking Water Act Regulations 367. EPA has regulated DBPs in drinking water since 1979. The first DBP standards limited __________ to 100 parts per billion (ppb) for systems serving more the 10,000 people. In the 1996 Safe Drinking Water Act (SDWA) reauthorization, Congress called for EPA to revise its standards for disinfectants and DBPs in two stages. The revised regulations are designed to reduce potential DBP risks, while ensuring that drinking water is protected from microbial contamination. A. Potential DBP risks D. Many trihalomethanes B. THM levels E. Enforceable Maximum Contaminant Levels (MCLs) C. THMs and HAAs F. None of the Above Stage 1 DBP Rule 368. In December 1998 USEPA issued the ______________ (Stage 1 DBP) rule. The regulations are based on an agreement between members of a Federal Advisory Committee that included representatives from water utilities, the Chlorine Chemistry Division of the American Chemistry Council, public health officials, environmentalists and other stakeholder groups. This diverse group of experts developed a consensus set of recommendations to costeffectively reduce DBP levels, without compromising protection from microbial contaminants. A. Haloforms D. MCL(s) B. Trihalomethane(s) E. Stage 1 Disinfectants and Disinfection Byproducts C. Total concentration F. None of the Above 66 Chlorination 303 8/9/2015 Assignment 369. ______________ mandates a process called enhanced coagulation to remove natural organic matter, reducing the potential for DBPs to form. The rule also sets enforceable Maximum Contaminant Levels (MCLs) for total trihalomethanes at 80 ppb and the sum of five Haloacetic Acids (HAAs) at 60 ppb. A. Potential DBP risks D. Many trihalomethanes B. The Stage 1 DBP rule E. Enforceable Maximum Contaminant Levels (MCLs) C. THMs and HAAs F. None of the Above 370. These ____________ are based on system-wide running annual averages, meaning that concentrations may be higher at certain times and at certain points in the system, as long as the system-wide average for the year is below the MCL. In developing the Stage 1 DBP rule, EPA was very cautious about encouraging the use of alternative disinfectants. A. Haloforms D. MCLs B. Trihalomethane(s) E. Stage 1 Disinfectants and Disinfection Byproducts C. Total concentration F. None of the Above 371. The Agency recognized that alternative disinfectants might reduce ________________, but produce other, less understood, byproducts. The Agency also avoided making recommendations that would encourage utilities to reduce the level of disinfection currently being practiced. A. Potential DBP risks D. Many trihalomethanes B. THM(s) E. Enforceable Maximum Contaminant Levels (MCLs) C. THMs and HAAs F. None of the Above Total Trihalomethanes 372. _________________are chemical compounds in which three of the four hydrogen atoms of methane (CH4) are replaced by halogen atoms. A. Haloforms D. MCL(s) B. Trihalomethanes (THMs) E. Stage 1 Disinfectants and Disinfection Byproducts C. Total concentration F. None of the Above 373. Many trihalomethanes find uses in industry as solvents or refrigerants. _________ are also environmental pollutants, and many are considered carcinogenic. A. Potential DBP risks D. Many trihalomethanes B. THMs E. Enforceable Maximum Contaminant Levels (MCLs) C. THMs and HAAs F. None of the Above 374. Trihalomethanes with all the same halogen atoms are called ______________. A. Haloforms D. MCL(s) B. Trihalomethane(s) E. Stage 1 Disinfectants and Disinfection Byproducts C. Total concentration F. None of the Above 375. Trihalomethanes are formed as a by-product predominantly when chlorine is used to disinfect water for drinking. They represent one group of chemicals generally referred to as__________. They result from the reaction of chlorine and/or bromine with organic matter present in the water being treated. A. Haloforms D. MCL(s) B. Disinfection by-products E. Stage 1 Disinfectants and Disinfection Byproducts C. Total concentration F. None of the Above 67 Chlorination 303 8/9/2015 Assignment 376. The THMs produced have been associated through epidemiological studies with some adverse health effects. Many governments set limits on the amount permissible in drinking water. However, trihalomethanes are only one group of many hundreds of__________—the vast majority of which are not monitored—and it has not yet been clearly demonstrated which of these are the most plausible candidate for causation of these health effects. A. Potential DBP risks D. Many trihalomethanes B. THM(s) E. Possible disinfection by-products C. THMs and HAAs F. None of the Above 377. In the United States, the EPA limits the total concentration of the four chief constituents (chloroform, bromoform, bromodichloromethane, and dibromochloromethane), referred to as__________, to 80 parts per billion in treated water. A. Haloforms D. MCL(s) B. Trihalomethane(s) E. Total trihalomethanes (TTHM) C. Total concentration F. None of the Above THM Treatment 378. THM levels tend to increase with pH, temperature, time, and the level of "____________" present. Precursors are organic material which reacts with chlorine to form THM's. One way to decrease THM's is to eliminate or reduce chlorination before the filters and to reduce precursors. A. Haloforms D. MCL(s) B. Trihalomethane(s) E. Precursors C. Total concentration F. None of the Above 379. There are more precursors present before filtration, so we want to reduce or eliminate the time chlorine is in contact with this water. If some oxidation before filtration is required, an alternative disinfectant like ___________________could be considered. Note that this may not be an option if prechlorination is necessary to achieve required CT values. A. Haloforms D. Potassium permanganate or peroxide B. Trihalomethane(s) E. Disinfectants and Disinfection Byproducts C. Total concentration F. None of the Above 380. The EPA has indicated that the best available technology for THM control at treatment plants is removal of_______________ through "enhanced coagulation". A. Haloforms D. MCL(s) B. Trihalomethane(s) E. Precursors C. Total concentration F. None of the Above 381. Enhanced coagulation refers to the process of optimizing the filtration process to maximize removal of _____________________. A. Potential DBP risks D. Many trihalomethanes B. THM(s) E. Precursors C. THMs and HAAs F. None of the Above 382. Removal is improved by decreasing pH (to levels as low as 4 or 5), increasing the feed rate of __________________ , and possibly using ferric coagulants instead of alum. A. Potential DBP risks D. Many trihalomethanes B. THM(s) E. Enforceable Maximum Contaminant Levels (MCLs) C. THMs and HAAs F. None of the Above 68 Chlorination 303 8/9/2015 Assignment Understanding Cryptosporidiosis 383. Cryptosporidium is __________________because its transmission has increased dramatically over the past two decades. Evidence suggests it is newly spread in increasingly popular day-care centers and possibly in widely distributed water supplies, public pools and institutions such as hospitals and extended-care facilities for the elderly. A. Cryptosporidium D. An emerging parasitic protozoan pathogen B. Chlorine-based disinfectants E. Emerging waterborne pathogen C. Giardia lamblia F. None of the Above 384. Recognized in humans largely since 1982 and the start of the AIDS epidemic, Cryptosporidium is able to cause potentially life-threatening disease in the growing number of immunocompromised patients. ________________ was the cause of the largest reported drinking water outbreak in U.S. history, affecting over 400,000 people in Milwaukee in April, 1993. More than 100 deaths are attributed to this outbreak. Cryptosporidium remains a major threat to the U.S. water supply (Ibid.). A. Cryptosporidium D. An emerging parasitic protozoan pathogen B. Chlorine-based disinfectants E. Emerging waterborne pathogen C. Giardia lamblia F. None of the Above 385. The EPA is developing new drinking water regulations to reduce ___________ and other resistant parasitic pathogens. Key provisions of the Long Term 2 Enhanced Surface Water Treatment Rule include source water monitoring for Cryptosporidium, inactivation by all unfiltered systems; and additional treatment for filtered systems based on source water Cryptosporidium concentrations. A. Cryptosporidium D. An emerging parasitic protozoan pathogen B. Chlorine-based disinfectants E. Emerging waterborne pathogen C. Giardia lamblia F. None of the Above 386. EPA will provide a range of treatment options to achieve the inactivation requirements. Systems with high concentrations of ________________ in their source water may adopt alternative disinfection methods (e.g., ozone, UV, or chlorine dioxide). A. Cryptosporidium D. An emerging parasitic protozoan pathogen B. Chlorine-based disinfectants E. Emerging waterborne pathogen C. Giardia lamblia F. None of the Above 387. However, most water systems are expected to meet EPA requirements while continuing to use chlorination. Regardless of the primary disinfection method used, water systems must continue to maintain residual levels of ______________in their distribution systems. A. High-test calcium hypochlorite(s) D. Chlorine-based disinfectants B. Calcium hypochlorite tablets E. Chlorine dioxide C. Hypochlorous acid F. None of the Above Understanding Giardia lamblia 388. _____________, discovered approximately 20 years ago, is another emerging waterborne pathogen. This parasitic microorganism can be transmitted to humans through drinking water that might otherwise be considered pristine. A. Cryptosporidium D. An emerging parasitic protozoan pathogen B. Chlorine-based disinfectants E. Emerging waterborne pathogen C. Giardia lamblia F. None of the Above 69 Chlorination 303 8/9/2015 Assignment 389. There is a distinct pattern to the emergence of____________. First, there is a general recognition of the effects of the pathogen in highly susceptible populations such as children, cancer patients and the immunocompromised. Next, practitioners begin to recognize the disease and its causative agent in their own patients, with varied accuracy. A. Cryptosporidium D. New pathogens B. Chlorine-based disinfectants E. Emerging waterborne pathogen C. Giardia lamblia F. None of the Above 390. At this point, some may doubt the proposed agent is the causative agent, or insist that the disease is restricted to certain types of patients. Finally, a single or series of large outbreaks result in improved attention to preventive efforts. From the 1960’s to the 1980’s this sequence of events culminated in the recognition of ______________ as a cause of gastroenteritis (Lindquist, 1999). A. Cryptosporidium D. An emerging parasitic protozoan pathogen B. Chlorine-based disinfectants E. Emerging waterborne pathogen C. Giardia lamblia F. None of the Above Understanding Waterborne Diseases 391. Detection and investigation of waterborne disease outbreaks is the primary responsibility of local, state and territorial public health departments, with voluntary reporting to the CDC. The CDC and the U.S. Environmental Protection Agency (EPA) collaborate to track ________________of both microbial and chemical origins. Data on drinking water and recreational water outbreaks and contamination events have been collected and summarized since 1971. A. Waterborne disease outbreaks D. Amounts of disinfection byproducts B. Diagnosed cases of waterborne illness E. Waterborne disease outbreaks C. Treatment measures F. None of the Above 392. While useful, statistics derived from surveillance systems do not reflect the true incidence of _______________because many people who fall ill from such diseases do not consult medical professionals. A. Waterborne disease outbreaks D. An emerging parasitic protozoan pathogen B. Chlorine-based disinfectants E. Emerging waterborne pathogen C. Giardia lamblia F. None of the Above 393. For those who do seek medical attention, attending physicians and laboratory and hospital personnel are required to report diagnosed cases of _____________to state health departments. Further reporting of these illness cases by state health departments to the CDC is voluntary, and statistically more likely to occur for large outbreaks than small ones. A. Waterborne disease outbreaks D. Amounts of disinfection byproducts B. Diagnosed cases of waterborne illness E. Waterborne illness C. Treatment measures F. None of the Above 394. Despite these limitations, surveillance data may be used to evaluate the relative degrees of risk associated with different types of_____________, problems in current technologies and operating conditions, and the adequacy of current regulations. (Craun, Nwachuku, Calderon, and Craun, 2002). A. Source water and systems D. An emerging parasitic protozoan pathogen B. Chlorine-based disinfectants E. Emerging waterborne pathogen C. Giardia lamblia F. None of the Above 70 Chlorination 303 8/9/2015 Assignment Disinfection Rules Disinfection Byproduct Regulations 395. In December 1998, the EPA established the Stage 1 Disinfectants/Disinfection Byproducts Rule that requires public water systems to use treatment measures to reduce the formation of disinfection byproducts and to meet the following specific standards: Currently trihalomethanes are regulated at a maximum allowable annual average level of 100 parts per billion for water systems serving over 10,000 people under the ____________finalized by the EPA in 1979. A. Waterborne disease outbreaks D. Amounts of disinfection byproducts B. Total Trihalomethane Rule E. Trihalomethanes C. Treatment measures F. None of the Above 396. The Stage 1 Disinfectant/Disinfection Byproduct Rule standards became effective for trihalomethanes and _____________listed above in December 2001 for large surface water public water systems. Those standards became effective in December 2003 for small surface water and all ground water public water systems. A. Other disinfection byproducts D. An emerging parasitic protozoan pathogen B. Chlorine-based disinfectants E. Emerging waterborne pathogen C. Giardia lamblia F. None of the Above 397. Disinfection byproducts are formed when disinfectants used in water treatment plants react with bromide and/or natural organic matter (i.e., decaying vegetation) present in the source water. Different disinfectants produce different types or __________________. A. Waterborne disease outbreaks D. Amounts of disinfection byproducts B. Diagnosed cases of waterborne illness E. Trihalomethanes C. Treatment measures F. None of the Above 398. _________________ for which regulations have been established have been identified in drinking water, including trihalomethanes, haloacetic acids, bromate, and chlorite. A. Waterborne disease outbreaks D. Disinfection byproducts B. Diagnosed cases of waterborne illness E. Trihalomethanes C. Treatment measures F. None of the Above Bromate 399. Bromate is a chemical that is formed when ozone used to disinfect drinking water reacts with naturally occurring bromide found in source water. The EPA has established the Stage 1 Disinfectants/Disinfection Byproducts Rule to regulate _________at annual average of 10 parts per billion in drinking water. A. Chlorine dioxide D. Trihalomethanes, haloacetic acids, bromate, and chlorite B. Bromate E. Disinfection byproducts C. Trihalomethanes F. None of the Above 400. This standard became effective for large public water systems by December 2001 and for small surface water and _____________back in December 2003. A. Waterborne disease outbreaks D. Amounts of disinfection byproducts B. Diagnosed cases of waterborne illness E. All ground public water systems C. Treatment measures F. None of the Above 71 Chlorination 303 8/9/2015 Assignment Microbial Regulations 401. One of the key regulations developed and implemented by the United States Environmental Protection Agency (USEPA) to counter pathogens in drinking water is the ____________. Among its provisions, the rule requires that a public water system, using surface water (or ground water under the direct influence of surface water) as its source, have sufficient treatment to reduce the source water concentration of Giardia and viruses by at least 99.9% and 99.99%, respectively. A. Long Term 1 Rule D. Surface Water Treatment Rule B. Maximum Contaminant Level Goal (MCLG) E. Interim Enhanced Surface Water C. Stage 1 Byproducts Rule F. None of the Above 402. The ______________ specifies treatment criteria to assure that these performance requirements are met; they include turbidity limits, disinfectant residual, and disinfectant contact time conditions. A. Long Term 1 Rule D. Surface Water Treatment Rule B. Maximum Contaminant Level Goal (MCLG) E. Interim Enhanced Surface Water C. Stage 1 Byproducts Rule F. None of the Above 403. The ______________ was established in December 1998 to control Cryptosporidium, and to maintain control of pathogens while systems lower disinfection byproduct levels to comply with the Stage 1 Disinfectants/Disinfection Byproducts Rule. A. Long Term 1 Enhanced Surface Water Treatment Rule B. Maximum Contaminant Level Goal (MCLG) C. Stage 1 Disinfectants/Disinfection Byproducts Rule D. Surface Water Treatment Rule E. Interim Enhanced Surface Water Treatment Rule F. None of the Above 404. The EPA established a ________________ of zero for all public water systems and a 99% removal requirement for Cryptosporidium in filtered public water systems that serve at least 10,000 people. The new rule will tighten turbidity standards by December 2001. Turbidity is an indicator of the physical removal of particulates, including pathogens. A. Long Term 1 Enhanced Surface Water Treatment Rule B. Maximum Contaminant Level Goal (MCLG) C. Stage 1 Disinfectants/Disinfection Byproducts Rule D. Surface Water Treatment Rule E. Interim Enhanced Surface Water Treatment Rule F. None of the Above 405. The EPA is also planning to develop other rules to further control pathogens. The EPA has promulgated a Long Term 1 Enhanced Surface Water Treatment Rule, for systems serving fewer than 10,000 people. This is to improve physical removal of Cryptosporidium, and to maintain control of pathogens while systems comply with _______________________. A. Long Term 1 Enhanced Surface Water Treatment Rule B. Maximum Contaminant Level Goal (MCLG) C. Stage 1 Disinfectants/Disinfection Byproducts Rule D. Surface Water Treatment Rule E. Interim Enhanced Surface Water Treatment Rule F. None of the Above 72 Chlorination 303 8/9/2015 Assignment Microbes - More Information in the water Monitoring Section 406. __________________ are common in the environment and are generally not harmful. However, the presence of these bacteria in drinking water is usually a result of a problem with the treatment system or the pipes which distribute water, and indicates that the water may be contaminated with germs that can cause disease. A. Fecal Coliform and E coli D. Cryptosporidiosis B. Giardia lamblia E. Coliform bacteria C. Microorganisms F. None of the Above 407. _______________ are bacteria whose presence indicates that the water may be contaminated with human or animal wastes. Microbes in these wastes can cause short-term effects, such as diarrhea, cramps, nausea, headaches, or other symptoms. A. Fecal Coliform and E coli D. Cryptosporidiosis B. Giardia lamblia E. Coliform bacteria C. Microorganisms F. None of the Above 408. Cryptosporidium is a parasite that enters lakes and rivers through sewage and animal waste. It causes cryptosporidiosis, a mild gastrointestinal disease. However, the disease can be severe or fatal for people with severely weakened immune systems. The EPA and CDC have prepared advice for those with severely compromised immune systems who are concerned about_____________ . A. Fecal Coliform and E coli D. Cryptosporidiosis B. Giardia lamblia E. Cryptosporidium C. Microorganisms F. None of the Above 409. Giardia lamblia is a parasite that enters lakes and rivers through sewage and animal waste. It causes ________________(e.g. diarrhea, vomiting, and cramps). A. Fecal Coliform and E coli D. Cryptosporidiosis B. Gastrointestinal illness E. Coliform bacteria C. Microorganisms F. None of the Above Chlorine Review 410. Chlorine Demand: The minimum amount of _____________needed to react in a water purification system; used as a monitoring measurement by system operators. A. Chlorine D. Monitoring measurement B. Liquid E. Ammonia or organic amines C. Total chlorine F. None of the Above 411. Chlorine Residual: The concentration of chlorine in the water after the chlorine demand has been satisfied. The concentration is normally expressed in terms of total chlorine residual, which includes both the free and combined or______________________________. A. Fusible plug D. Total chlorine B. Chlorine cylinder E. Residual chlorine C. Chemically bound chlorine residuals F. None of the Above 73 Chlorination 303 8/9/2015 Assignment 412. Combined Chlorine Residual: The amount of chlorine used up in a water purification system; used as a monitoring measurement by system operators. _________________is defined as the residual chlorine existing in water in chemical combination with ammonia or organic amines which can be found in natural or polluted waters. Ammonia is sometimes deliberately added to chlorinated public water supplies to provide inorganic chloramines. A. Combined chlorine D. Monitoring measurement B. Liquid E. Ammonia or organic amines C. Total chlorine F. None of the Above 413. Free Chlorine: Free chlorine is defined as the concentration of ______________ in water present as dissolved gas (Cl2), hypochlorous acid (HOCl), and/or hypochlorite ion (OCl-). A. Chlorine Demand D. Total chlorine B. Chlorine total E. Residual chlorine C. Chlorinator F. None of the Above 414. Their relative proportions are determined by the pH value and temperature. Regardless of whether pre-chloration is practiced or not, a ______________of at least 10 mg/L should be maintained in the clear well or distribution reservoir immediately downstream from the point of post-chlorination and .2 mg/L in the distribution system to guard against backflow. A. Chlorine Demand D. Total chlorine B. Chlorine total E. Residual chlorine C. Free chlorine residual F. None of the Above 415. Total Chlorine Residual: The total of free residual and combined residual chlorine in a water purification system; used as a monitoring measurement by system operators. _____________ is the sum of free and combined chlorine. A. Chlorine Demand D. Total chlorine B. Chlorine total E. Residual chlorine C. Chlorinator F. None of the Above 416. When chlorinating most potable water supplies, total chlorine is essentially equal to free chlorine since the concentration of ammonia or organic nitrogen compounds (needed to form______________) will be very low. When chloramines are present in the municipal water supply, then total chlorine will be higher than free chlorine. A. Chlorine Demand D. Total chlorine B. Chlorine total E. Residual chlorine C. Combined chlorine F. None of the Above 417. What is the purpose of a fusible plug, at what temperature does it melt, and where is it located on 150-lb. and 1-ton cylinders? _______________ is a safety device that melts. If the temperature of a full Cl2 cylinder is increased by 50o F or 30o C, a rupture may occur. It will melt at 158 to 165 degrees F. It is found on the side of a 1 ton container and on top of the 150 pound cylinder and is located in the valve below the valve seat. A. Fusible plug D. Chlorine valve B. Chlorine cylinder E. Yoke C. Chlorinator F. None of the Above 74 Chlorination 303 8/9/2015 Assignment 418. What is the correct procedure to follow in changing a chlorine cylinder and what item should always be replaced with a new one in doing so? Hook up the __________ to the container or cylinder with the chlorine valve turned off. Use the gas side not the liquid if using a 1 ton container. Remove the cylinder valve outlet cap and check the valve face or damage. A. Fusible plug D. Chlorine valve B. Chlorine cylinder E. Yoke C. Chlorinator F. None of the Above 419. Clean with wire brush if necessary. If the valve face is smooth, clean proceed with hooking up the cylinder. Check the inlet face of the ____________ and clean if necessary. A. Fusible plug D. Chlorine valve B. Chlorine cylinder E. Yoke C. Chlorinator F. None of the Above 420. Place a new lead gasket on the chlorinator inlet, place the chlorinator on the cylinder valve, install the yoke clamp and slowly tighten the _______until the two faces are against the lead gasket. Tighten the yoke, compressing the gasket one half to three quarters turn, do not over tighten. Replace the lead gasket with every change out. A. Fusible plug D. Chlorine valve B. Chlorine cylinder E. Yoke clamp C. Chlorinator F. None of the Above Halides 421. These elements are diatomic molecules in their natural form. They require one more electron to fill their outer electron shells, and so have a tendency to form a singly-charged negative ion. This negative ion is referred to as a halide ion; ____________ containing these ions are known as halides. A. Salts D. Many synthetic organic compounds B. CXT values E. Neither fluorine nor bromine C. Primary disinfectant F. None of the Above 422. Halide ions combined with single hydrogen atoms form the hydrohalic acids (i.e., HF, HCl, HBr, HI), a series of particularly strong acids. (HAt, or "__________________", should also qualify, but it is not typically included in discussions of hydrohalic acid due to astatine's extreme instability toward alpha decay.)They react with each other to form interhalogen compounds. A. HCl D. Chlorine gas B. HOCl E. The hypochlorite ion (OCl-) C. Hydrastatic acid F. None of the Above 423. Diatomic interhalogen compounds (BrF, ICl, ClF, etc.) bear strong superficial resemblance to the pure halogens. Many synthetic organic compounds such as plastic polymers, and a few natural ones, contain halogen atoms; these are known as halogenated compounds or____________________. A. Organic halides D. Many synthetic organic compounds B. CXT values E. Neither fluorine nor bromine C. Primary disinfectant F. None of the Above 75 Chlorination 303 8/9/2015 Assignment Chlorine 424. Chlorine is by far the most abundant of the halogens, and the only one needed in relatively large amounts (as chloride ions) by humans. For example, chloride ions play a key role in brain function by mediating the action of the _______________and are also used by the body to produce stomach acid. Iodine is needed in trace amounts for the production of thyroid hormones such as thyroxine. A. Chloramines D. Halogens B. Chlorine dioxide E. Inhibitory transmitter GABA C. CXT formula F. None of the Above 425. On the other hand, neither fluorine nor bromine are believed to be really essential for humans, although small amounts of _____________can make tooth enamel resistant to decay. A. Salts D. Many synthetic organic compounds B. CXT values E. Fluoride C. Primary disinfectant F. None of the Above Halogens 426. All ______________ have 7 electrons in their outer shells, giving them an oxidation number of -1. The halogens exist, at room temperature, in all three states of matter: A. Chloramines D. Halogens B. Chlorine dioxide E. Chlorine concentrations C. CXT formula F. None of the Above Factors in Chlorine Disinfection: Concentration and Contact Time 427. In an attempt to establish more structured operating criteria for water treatment disinfection, the ______________ came into use in 1980. Based on the work of several researchers, CXT values [ final free chlorine concentration (mg/L) multiplied by minimum contact time (minutes)], offer water operators guidance in computing an effective combination of chlorine concentration and chlorine contact time required to achieve disinfection of water at a given temperature. A. CXT concept D. Many synthetic organic compounds B. CXT values E. Neither fluorine nor bromine C. CXT formula F. None of the Above 428. The ___________ demonstrates that if an operator chooses to decrease the chlorine concentration, the required contact time must be lengthened. Similarly, as higher strength chlorine solutions are used, contact times may be reduced (Connell, 1996). A. CXT concept D. Many synthetic organic compounds B. CXT values E. Neither fluorine nor bromine C. CXT formula F. None of the Above Chloramines 429. ________________ are chemical compounds formed by combining a specific ratio of chlorine and ammonia in water. Because chloramines are relatively weak as a disinfectant, they are almost never used as a primary disinfectant. A. Chlorine dioxide D. Trihalomethanes, haloacetic acids, bromate, and chlorite B. Bromate E. Disinfection byproducts C. Chloramines F. None of the Above 76 Chlorination 303 8/9/2015 Assignment 430. Chloramines provide a durable residual, and are often used as a secondary disinfectant for long distribution lines and where free chlorine demand is high. _______________ may also be used instead of chlorine in order to reduce chlorinated byproduct formation and to remove some taste and odor problems. A. Chlorine dioxide D. Trihalomethanes, haloacetic acids, bromate, and chlorite B. Bromate E. Disinfection byproducts C. Chloramines F. None of the Above Chlorine Dioxide 431. ________________is generated on-site at water treatment facilities. In most generators sodium chlorite and elemental chlorine are mixed in solution, which almost instantaneously forms chlorine dioxide. A. Chlorine dioxide (ClO2) D. Trihalomethanes, haloacetic acids, bromate, and chlorite B. Bromate E. Disinfection byproducts C. Chloramines F. None of the Above 432. Chlorine dioxide characteristics are quite different from chlorine. In solution it is a dissolved gas, which makes it largely unaffected by pH but volatile and relatively easily stripped from ___________________. A. Chlorine D. Chlorine gas B. Sodium hypochlorite E. Solution C. Chlorine dioxide F. None of the Above 433. Chlorine dioxide is also a strong disinfectant and a selective oxidant. While chlorine dioxide does produce _____________________ . A. Chlorine D. Chlorine gas B. Sodium hypochlorite E. A residual it is only rarely used for this purpose C. Chlorine dioxide F. None of the Above Factors in Chlorine Disinfection: Concentration and Contact Time 434. In an attempt to establish more structured operating criteria for water treatment disinfection, the CXT concept came into use in 1980. Based on the work of several researchers, _____________ [ final free chlorine concentration (mg/L) multiplied by minimum contact time (minutes)], offer water operators guidance in computing an effective combination of chlorine concentration and chlorine contact time required to achieve disinfection of water at a given temperature. A. CXT concept D. Many synthetic organic compounds B. CXT values E. Neither fluorine nor bromine C. CXT formula F. None of the Above 435. The _____________ demonstrates that if an operator chooses to decrease the chlorine concentration, the required contact time must be lengthened. Similarly, as higher strength chlorine solutions are used, contact times may be reduced (Connell, 1996). A. CXT concept D. Many synthetic organic compounds B. CXT values E. Neither fluorine nor bromine C. CXT formula F. None of the Above 77 Chlorination 303 8/9/2015 Assignment Conclusion 436. Emerging waterborne pathogens constitute a major health hazard in both developed and developing nations. A new dimension to the global epidemiology of cholera-an ancient scourgewas provided by the emergence of__________________. A. Cholera D. Vibrio cholerae O139 B. Legionella pneumophila E. Campylobacter C. Shigellosis F. None of the Above 437. Also, water-borne enterohaemorrhagic Escherichia coli (E. coli O157:H7), although regarded as a problem of the industrialized west, has recently caused outbreaks in Africa. Outbreaks of chlorine-resistant ___________ have motivated water authorities to reassess the adequacy of current water-quality regulations. A. Campylobacter D. Cryptosporidium B. Pathogen E. Shigella dysenteriae C. Pontiac fever F. None of the Above 438. Of late, a host of other organisms, such as hepatitis viruses (including hepatitis E virus), Campylobacter jejuni, microsporidia, cyclospora, _______________, calciviruses and environmental bacteria like Mycobacterium spp, aeromonads, Legionella pneumophila and multidrug-resistant Pseudomonas aeruginosa have been associated with water-borne illnesses. A. Yersinia enterocolitica D. Emergence of disinfection resistant variants B. Legionella pneumophila E. Campylobacter C. Shigellosis F. None of the Above 439. The protection and enhancement of our nation’s water quality remains a chief concern of the U.S. Environmental Protection Agency. The Office of Research and Development is committed, through the ________________ efforts earlier described, to ensure that the most effective and efficient methods are developed to identify, detect, and inactivate/remove pathogens that may be present in our drinking water supplies. A. Optimal pathogen removal techniques D. Primary methods used for the disinfection B. Disinfection process E. Extensive waterborne disease research C. Environmental and regulatory impact F. None of the Above 440. Life cycles, mechanisms of infection, protective or dormant states, emergence of disinfection resistant variants, __________________, regrowth in distribution lines…all are areas that must be investigated and understood to afford the water quality safeguards that are so often taken for granted. The successes and failures of these research efforts, relayed to the public and appropriate federal, state, and local agencies, have helped to ensure safe drinking water. A. Optimal pathogen removal techniques D. Primary methods used for the disinfection B. Disinfection process E. Extensive waterborne disease research C. Environmental and regulatory impact F. None of the Above Salmonella Typhi 441. Salmonella typhi, the basics. It's a bacteria. It causes diarrheal illness, also known as ____________. And humans are the reservoir for this pathogen. A. Campylobacter D. Typhoid fever B. Pathogen E. Shigella dysenteriae C. Pontiac fever F. None of the Above 78 Chlorination 303 8/9/2015 Assignment 442. Salmonella typhi, prevention. Prevention strategies for this pathogen include source protection, halogenation of water, and___________________. A. Chlorine D. Chlorine gas B. Sodium hypochlorite E. Boiling water for one minute C. Chlorine dioxide F. None of the Above Shigella Species 443. Shigella species, the basics. It's a bacteria. It causes diarrheal illness known as shigellosis. Humans and primates are the reservoir for this pathogen. Shigella species, in the United States two-thirds of the shigellosis in the U.S. is caused by___________, and the remaining one-third is caused by Shigella flexnieri. In developing countries, Shigella dysenteriae is the primary cause of illness associated with this pathogen. A. Campylobacter D. Shigella sonnei B. Pathogen E. Shigella dysenteriae C. Pontiac fever F. None of the Above 444. Shigella species prevention. Prevention strategies for this pathogen include source protection, halogenation of water, and ________________. A. Chlorine D. Chlorine gas B. Sodium hypochlorite E. Boiling water for one minute C. Chlorine dioxide F. None of the Above Campylobacter 445. Campylobacter, the basics. It's a bacteria. It causes diarrheal illness. And Campylobacter is primarily associated with poultry, animals, and humans. Campylobacter prevention. Prevention strategies for this pathogen include source protection, halogenation of water, and __________________. A. Chlorine D. Chlorine gas B. Sodium hypochlorite E. Boiling water for one minute C. Chlorine dioxide F. None of the Above Vibrio Cholerae 446. Vibrio cholerae, the basics. It's a bacteria. It causes diarrheal illness, also known as cholera. It is typically associated with aquatic environments, shell stocks, and human. Vibrio cholerae has also been associated with ship ballast water. A. Campylobacter D. Typhoid fever B. Pathogen E. Shigella dysenteriae C. Pontiac fever F. None of the Above 447. Vibrio cholerae prevention. Prevention strategies for this pathogen include source protection, halogenation of water, and __________________. A. Chlorine D. Chlorine gas B. Sodium hypochlorite E. Boiling water for one minute C. Chlorine dioxide F. None of the Above 79 Chlorination 303 8/9/2015 Assignment Legionella 448. Legionella, the basics. It's a bacteria. It causes a respiratory illness known as legionellosis. There are two illnesses associated with legionellosis: the first, Legionnaire's disease, which causes a severe pneumonia, and the second, _____________, which is a nonpneumonia illness; it's typically an influenza-like illness, and it's less severe. Legionella is naturally found in water, both natural and artificial water sources. A. Campylobacter D. Typhoid fever B. Pathogen E. Shigella dysenteriae C. Pontiac fever F. None of the Above 449. Legionella, prevention. ______________at or above 50 degrees Centigrade and cold water below 20 degrees Centigrade can prevent or control the proliferation of Legionella in water systems. Hot water in tanks should be maintained between 71 and 77 degrees Centigrade. A. Maintaining hot water systems D. Chlorine gas B. Sodium hypochlorite E. Boiling water for one minute C. Chlorine dioxide F. None of the Above Pseudomonas 450. Pseudomonas, the basics. It's a bacteria. It is caused by dermal contact with water. It can cause dermatitis, which is an inflammation of the skin, or it can cause otitis, which is an infection of the ear. __________________ is typically associated with soil and water. A. Hepatitis A virus D. Pseudomonas B. Diarrheal illness E. Waterborne outbreaks C. Cryptosporidium F. None of the Above 451. Pseudomonas prevention. Proper maintenance and disinfection of recreational water systems is important in preventing ____________________. A. Pathogen D. Pseudomonas B. Cryptosporidium E. Salmonellosis C. Hepatitis A virus F. None of the Above Hepatitis A 452. Hepatitis A, the basics. It's a virus. It causes inflammation of the liver. And the reservoir for ___________ is humans. A. Hepatitis A virus D. Hepatitis B B. Diarrheal illness E. Waterborne outbreaks C. Cryptosporidium F. None of the Above Hepatitis A, Prevention 453. Prevention strategies for this pathogen include source protection and adequate disinfection. Fecal matter can protect ______________ from chlorine. Additionally, Hepatitis A virus is resistant to combined chlorines, so it is important to have an adequate free chlorine residual. A. Hepatitis A virus D. Hepatitis B B. Diarrheal illness E. Waterborne outbreaks C. Cryptosporidium F. None of the Above 80 Chlorination 303 8/9/2015 Assignment Norovirus 454. Norovirus, the basics. It's a virus. It causes diarrheal illness. And humans are the reservoir for this virus. Norovirus, prevention. Prevention strategies for this pathogen include_______________. A. Maintaining hot water systems D. Chlorine gas B. Source protection E. Boiling water for one minute C. Chlorine dioxide F. None of the Above Cryptosporidium 455. Cryptosporidium, the basics. It's a parasite. It causes diarrheal illness known as____________. It is typically associated with animals and humans, and it can be acquired through consuming fecally contaminated food, contact with fecally contaminated soil and water. A. Pathogen D. Cryptosporidiosis B. Cryptosporidium E. Salmonellosis C. Hepatitis A virus F. None of the Above 456. Cryptosporidium, prevention. Prevention strategies for this pathogen include source protection. A CT value of 9,600 is required when dealing with fecally accidents. CT equals a concentration, in parts per million, while time equals a contact time in minutes. _______________ can also be prevented or eliminated by boiling water for one minute. A. Hepatitis A virus D. Pseudomonas B. Diarrheal illness E. Waterborne outbreaks C. Cryptosporidium F. None of the Above 457. Filtration with an "absolute" pore size of one micron or smaller can eliminate _________. And reverse osmosis is known to be effective as well. A. Pathogen D. Pseudomonas B. Cryptosporidium E. Salmonellosis C. Hepatitis A virus F. None of the Above Giardia 458. Giardia, the basics. It is a parasite. It causes diarrheal illness known as giardiasis. It is typically associated with water. It is the most common pathogen in waterborne outbreaks. It can also be found in soil and food. And humans and animals are the reservoir for this pathogen. Giardia prevention. Prevention strategies for this pathogen include _____________; filtration, coagulation, and halogenation of drinking water. A. Maintaining hot water systems D. Chlorine gas B. Source protection E. Boiling water for one minute C. Chlorine dioxide F. None of the Above Schistosomatidae 459. Schistosomatidae, the basics. It is a parasite. It is acquired through dermal contact, cercarial dermatitis. It is commonly known as___________________. The reservoir for this pathogen are aquatic snails and birds. A. Swimmer's itch D. Pseudomonas B. Cryptosporidium E. Salmonellosis C. Hepatitis A virus F. None of the Above 81 Chlorination 303 8/9/2015 Assignment 460. Schistosomatidae, prevention. Prevention strategies for this pathogen include ______________ or interrupting the life cycle of the parasite by treating birds with an antihelmetic drug. A. Maintaining hot water systems D. Eliminating snails with a molluscicide B. Source protection E. Boiling water for one minute C. Chlorine dioxide F. None of the Above E-Coli Section 461. Escherichia coli. There are several pathogenic strains of Escherichia coli, which are classified under enterovirulent E. coli. They are enterohemorrhagic, enteroinvasive, enterotoxigenic, enteropathogenic, and enteroaggregative. Escherichia coli O157:H7, the basics. It's a bacteria. It causes diarrheal illness, and it's classified as___________________________. A. An enterohemorrhagic E. coli D. Pseudomonas B. Escherichia coli O157:H7 E. Salmonellosis C. Bacteria F. None of the Above 462. In its most severe form, it can cause_______________. The reservoir for this bacteria are cattle, deer, goats, and sheep. Humans can also be a reservoir. It is typically associated with contaminated food and water. A. Hemorrhagic colitis D. Pseudomonas B. Escherichia coli O157:H7 E. Salmonellosis C. Bacteria F. None of the Above 463. E. coli O157:H7 prevention. Prevention strategies for this pathogen include _____________, halogenation of water, or boiling water for one minute. A. Maintaining hot water systems D. Eliminating snails with a molluscicide B. Source protection E. Boiling water for one minute C. Chlorine dioxide F. None of the Above 464. Salmonella species, the basics. It's a bacteria. It causes diarrheal illness known as ___________. Humans and animals are the reservoir, and it's typically associated with contaminated food and water. A. Pathogen D. Pseudomonas B. Escherichia coli O157:H7 E. Salmonellosis C. Bacteria F. None of the Above 465. Salmonella species, prevention. Prevention strategies for this pathogen include source protection, halogenation of water, and also ____________________. A. Maintaining hot water systems D. Eliminating snails with a molluscicide B. Source protection E. Boiling water for one minute C. Chlorine dioxide F. None of the Above Alternatives Methods for Water Disinfection 466. Chlorine in water is over three times more effective as a disinfectant against Escherichia coli than an equivalent concentration of bromine, and over six times more effective than an equivalent concentration of______________ . A. Bromine D. Iodine B. UV rays E. Chemical process C. UV disinfection F. None of the Above 82 Chlorination 303 8/9/2015 Assignment Ultraviolet Disinfection 467. This process involves exposing water to_________________, which inactivates various microorganisms. The technique has enjoyed increased application in wastewater treatment but very limited application in potable water treatment. A. Sterilizer D. Ultraviolet (UV) radiation B. UV rays E. Electromagnetic energy C. UV disinfection F. None of the Above 468. The lamp itself does not come in to contact with water, the lamp is placed inside a quartz tube, and the water is in contact with the outside of the quartz tube. Quartz is used in this case since practically none of the UV rays are absorbed by the quartz, allowing all of the rays to reach the water. Ordinary glass cannot be used since it will absorb the _______________, leaving little for disinfection. A. Bromine D. UV reactor B. UV rays E. Chemical process C. UV disinfection F. None of the Above 469. The ____________will consist of a various number of lamps and tubes, depending upon the quantity of water to be treated. As water enters the sterilizer, it is given a tangential flow pattern so that the water spins over and around the quartz sleeves. A. UV sterilizer D. UV reactor B. UV rays E. Electromagnetic energy C. UV disinfection F. None of the Above 470. In this way the microorganisms spend maximum time and contact with the outside of the quartz tube and the source of the _______________. A. Sterilizer D. UV reactor B. UV rays E. Electromagnetic energy C. UV disinfection F. None of the Above 471. The basic design flow of water of certain ___________is in the order of 2.0 gpm for each inch of the lamp. Further, the units are designed so that the contact or retention time of the water in the unit is not less than 15 seconds. A. UV units D. UV reactor B. UV rays E. Chemical process C. UV disinfection F. None of the Above 472. UV disinfection transfers electromagnetic energy from a mercury arc lamp to a pathogen's DNA material, thus affecting its ability to replicate itself. UV's effectiveness depends on the characteristics of the wastewater, the intensity of the ____________being emitted, the length of time that the wastewater comes in contact with the UV radiation, and the arrangement of the UV reactor. A. UV radiation D. UV reactor B. UV rays E. Electromagnetic energy C. UV disinfection F. None of the Above 83 Chlorination 303 8/9/2015 Assignment 473. UV has the advantage of being effective at inactivating viruses and, because it's a physical process rather than a chemical process, there are no residual constituents remaining in the treated wastewater after exposure to UV. Also, the contact time for the wastewater with the ____________is the shortest of any of the disinfectant strategies, lasting no longer than 20 to 30 seconds. A. UV source D. UV reactor B. UV rays E. Electromagnetic energy C. UV disinfection F. None of the Above 474. Disadvantages include the effects of turbidity in the water reducing the infiltration and therefore the effectiveness of _____________ and the need to provide an effective cleaning and replacement program for the UV components. A. UV D. UV reactor B. UV rays E. Ballasts and shields C. UV disinfection F. None of the Above 475. Ensuring that the _________ maintains good contact with the water requires control of the water level within the channel to ensure that the UV is making total contact at the designed depths. A. UV D. UV reactor B. UV rays E. Ballasts and shields C. UV disinfection F. None of the Above 476. Also, because of the heat generated by the electric components of the system, adequate ventilation and cooling must be applied to the ___________to reduce heat build-up, otherwise the ballasts could fail. A. UV arrays D. UV reactor B. UV rays E. Electromagnetic energy C. UV disinfection F. None of the Above 477. UV lamps have a rated life of up to 14,000 hours, and should be routinely replaced at 12,000 hours or roughly every 1.5 years of continuous operation. The electrical consumption of this system, combined with the cost of routine replacement of ________________, should be considered against other systems. A. UV D. UV reactor B. UV rays E. Ballasts and shields C. UV disinfection F. None of the Above 478. The germicidal effect of ___________ is thought to be associated with its absorption by various organic components essential to the cell’s functioning. A. Sterilizer D. UV reactor B. UV E. Electromagnetic energy C. UV disinfection F. None of the Above 479. For effective use of_____________, the water to be disinfected must be clean, and free of any suspended solids. The water must also be colorless and must be free of any colloids, iron, manganese, taste, and odor. These are conditions that must be met. A. Ultraviolet D. UV reactor B. UV rays E. Ballasts and shields C. UV disinfection F. None of the Above 84 Chlorination 303 8/9/2015 Assignment Strongest Oxidizing Agent 480. Ozone (O3) is probably the strongest oxidizing agent available for water treatment. Although it is widely used throughout the world, is has not found much application in the United States. _________is obtained by passing a flow of air or oxygen between two electrodes that are subjected to an alternating current in the order of 10,000 to 20,000 volts. A. Carcinogens D. Oxygen and nascent oxygen B. THMs E. Strongest oxidizing agent C. Ozone F. None of the Above 481. Liquid ozone is very unstable and can readily explode. As a result, it is not shipped and must be manufactured on-site. Ozone is a ____________ at room temperature. A. Carcinogens D. Oxygen and nascent oxygen B. THMs E. Strongest oxidizing agent C. Light blue gas F. None of the Above 482. It has a ____________similar to that sometimes noticed during and after heavy electrical storms. In use, ozone breaks down into oxygen and nascent oxygen. A. Self-policing pungent odor D. Oxygen and nascent oxygen B. THMs E. Strongest oxidizing agent C. Light blue gas F. None of the Above 483. It is the nascent oxygen that produces the high oxidation and disinfections, and even sterilization. Each water has its own_____________, in the order of 0.5 ppm to 5.0 ppm. Contact time, temperature, and pH of the water are factors to be determined. A. Carcinogens D. Oxygen and nascent oxygen B. THMs E. Strongest oxidizing agent C. Ozone demand F. None of the Above 484. Ozone acts as a complete disinfectant. It is an excellent aid to the flocculation and coagulation process, and will remove practically all color, taste, odor, iron, and manganese. It does not form chloramines or ______________, and while it may destroy some THMs, it may produce others when followed by chlorination. A. Carcinogens D. Oxygen and nascent oxygen B. THMs E. Flocculation and coagulation C. Complete disinfectant F. None of the Above 485. Ozone is not practical for complete removal of chlorine or chloramines, or of THM and other inorganics. Further, because of the possibility of formation of other carcinogens (such as aldehydes or phthalates) it falls into the same category as other disinfectants in that it can produce____________. A. Carcinogens D. Oxygen and nascent oxygen B. THMs E. Strongest oxidizing agent C. DBPs F. None of the Above 85 Chlorination 303 8/9/2015 Assignment Alternate Disinfectants Section Summary Chloramines 486. Chloramine is a very weak disinfectant for ____________ reduction. It is recommended that it be used in conjunction with a stronger disinfectant. It is best utilized as a stable distribution system disinfectant. A. Cryptosporidium D. Giardia and virus B. Chlorine-based disinfectants E. Emerging waterborne pathogen C. Giardia lamblia F. None of the Above 487. In the production of chloramines the ammonia residuals in the finished water, when fed in excess of stoichiometric amount needed, should be limited to inhibit growth of______________. A. Cryptosporidium D. An emerging parasitic protozoan pathogen B. Chlorine-based disinfectants E. Nitrifying bacteria C. Giardia lamblia F. None of the Above Chlorine Dioxide 488. Chlorine dioxide may be used for either taste and odor control or as_______________ . A. Post disinfectant D. Total residual oxidants B. ClO2/chlorite/chlorate E. A pre-disinfectant C. An oxidant F. None of the Above 489. Total residual oxidants (including______________, but excluding chlorate) shall not exceed 0.30 mg/L during normal operation or 0.50 mg/L (including chlorine dioxide, chlorite and chlorate) during periods of extreme variations in the raw water supply. A. Pre-disinfectant D. Chlorine dioxide and chlorite B. ClO2/chlorite/chlorate E. 25% aqueous solution of sodium chlorite (NaClO2) C. An oxidant F. None of the Above 490. Chlorine dioxide provides good ___________________protection but its use is limited by the restriction on the maximum residual of 0.5 mg/L ClO2/chlorite/chlorate allowed in finished water. This limits usable residuals of chlorine dioxide at the end of a process unit to less than 0.5 mg/L. A. Pre-disinfectant D. Total residual B. ClO2/chlorite/chlorate E. Giardia and virus C. An oxidant F. None of the Above 491. Where chlorine dioxide is approved for use as an oxidant, the preferred method of generation is to entrain chlorine gas into a packed reaction chamber with a _____________________. A. Pre-disinfectant D. Total residual oxidants B. ClO2/chlorite/chlorate E. 25% aqueous solution of sodium chlorite (NaClO2) C. An oxidant F. None of the Above 492. Warning: Dry sodium chlorite is _______________in feed equipment if leaking solutions or spills are allowed to dry out. A. Pre-disinfectant D. Oxidant B. ClO2/chlorite/chlorate E. Explosive and can cause fires C. An oxidant F. None of the Above 86 Chlorination 303 8/9/2015 Assignment Ozone 493. Ozone is a very effective disinfectant for both Giardia and viruses. ______________(Contact time) values must be determined for the ozone basin alone; an accurate T10 value must be obtained for the contact chamber, residual levels measured through the chamber and an average ozone residual calculated. A. Ozone CT D. Oxygen and nascent oxygen B. Free and/or combined chlorine E. Strongest oxidizing agent C. Residual levels F. None of the Above 494. Ozone does not provide a ________________and should be used as a primary disinfectant only in conjunction with free and/or combined chlorine. A. Ozone CT D. System residual B. Free and/or combined chlorine E. Strongest oxidizing agent C. Residual levels F. None of the Above 495. Ozone does not produce ___________________(such as trihalomethanes) but it may cause an increase in such byproduct formation if it is fed ahead of free chlorine; ozone may also produce its own oxygenated byproducts such as aldehydes, ketones, or carboxylic acids. A. Carcinogens D. Oxygen and nascent oxygen B. THMs E. Chlorinated byproducts C. Carboxylic acids F. None of the Above 496. Ozone may also be used as applied as a pre-disinfectant. A. An oxidant B. Free and/or combined chlorine C. Residual levels _____________for removal of taste and odor, or may be D. System residual E. Strongest oxidizing agent F. None of the Above Waterborne Pathogens Section The reason we disinfect. 497. Bacteria, viruses and protozoan that cause disease are known as pathogens. Most pathogens are generally associated with diseases that _________and affect people in a relatively short amount of time, generally a few days to two weeks. A. Limit the effects of organic material D. An additional killing mechanism B. Numerous alternative disinfection processes E. Limit the travel of pathogens C. Cause intestinal illness F. None of the Above How Diseases are Transmitted. 498. Pathogens that may cause waterborne outbreaks through drinking water have one thing in common: they are spread by the_________________. A. Fecal-oral, or feces-to-mouth, route D. An additional killing mechanism B. Numerous alternative disinfection processes E. Waterborne outbreaks C. Residual level of disinfection F. None of the Above 499. Pathogens may get into water and spread when infected humans or animals pass the bacteria, viruses, and _____________________in their stool. For another person to become infected, he or she must take that pathogen in through the mouth. A. Fecal Coliform and E coli D. Cryptosporidiosis B. Protozoa E. Coliform bacteria C. Microorganisms F. None of the Above 87 Chlorination 303 8/9/2015 Assignment 500. Waterborne pathogens are different from other types of pathogens such as the viruses that cause influenza (the flu) or the bacteria that cause tuberculosis. __________________are spread by secretions that are coughed or sneezed into the air by an infected person. A. Fecal Coliform and E coli D. Influenza virus and tuberculosis bacteria B. Giardia lamblia E. Coliform bacteria C. Microorganisms F. None of the Above You are finished with your assignment. Please fax or email the answer key and registration page to us. 88 Chlorination 303 8/9/2015 Assignment 89 Chlorination 303 8/9/2015 Assignment