2nd quarter review Chemistry Name: _KEY_____________________________________ Date: _________________________ Write the electron configurations for the following elements. 1. O: 1s22s22p4 2. Ca:1s22s22p63s23p64s2 3. Cu: 1s22s22p63s23p64s23d9 4. Sn: 1s22s22p63s23p64s23d104p65s24d105p2 5. Rn: 1s22s22p63s23p64s23d104p65s24d105p66s24f145d106p6 Name the groups of the periodic table. 1. __Alkali Metals________________ 2. ___Alkaline Earth Metals_________ 17. __Halogens_______________ 18. ___Noble Gases_____________ D-Block: ___Transition Metals________ 4f: __Lanthanide___________ 5f: ___Actinide_________________ Circle the element that fits the statement Li N K S Al Ga V Te Si Li As H Hg Na Pb B Ca Si P Ca Cl Si Al Nb I Ge Be Se Li Tl Mg Bi C Sc S As Sc Ar P Si Ta Xe Sn B Br Na Pb Al Po N Ti metal smallest ionization energy largest atomic mass member of the halogen family greatest electron affinity largest atomic radius largest atomic number member of noble gases 4 energy levels member of alkali metals 6 valence electrons nonmetal member of transition metals electron distribution ending in s2p1 metalloid gas at room temperature electron distribution ending in s2d2 Chemistry 2nd quarter review Trend Review 1. Rank the following elements by increasing atomic radius: carbon, aluminum, oxygen, potassium. O, C, Al, K 2. Rank the following elements by increasing electronegativity: sulfur, oxygen, neon, aluminum. Ne, Al, S, O 3. Why does fluorine have a higher ionization energy than iodine? Effective nuclear charge is higher – the + charge of the nucleus is stronger for F than I – the nucleus of F is able to attract electrons to it better than I. 4. Why do elements in the same family generally have similar properties? They have the same number of valence electrons. 5. Indicate whether the following properties increase or decrease from left to right across the periodic table. a. atomic radius (excluding noble gases) Decreases b. first ionization energy Increases c. electronegativity Increases 6. What trend in atomic radius occurs down a group on the periodic table? What causes this trend? It increases because of electron shielding – the core electrons block the valence electrons from feeling the pull of the + nucleus and it allows the valence electrons to get further and further from the nucleus thus expanding the size of the atom. 7. What trend in ionization energy occurs across a period on the periodic table? What causes this trend? It increases because of effective nuclear charge – the atoms are more able to remove an electron from an atom because the nucleus is gaining + protons and the atom is getting smaller. As you move across the table, the atoms want to gain electrons more and more (until you get to the noble gases). 8. Circle the atom in each pair that has the largest atomic radius. a. Al or B c. S or O e. Br or Cl b. Na or Al d. O or F f. Mg or Ca 9. Circle the atom in each pair that has the greater ionization energy. a. Li or Be c. Na or K e. Cl or Si b. Ca or Ba d. P or Ar f. Li or K Chemistry 2nd quarter review 10. Define electronegativity. Electronegativity is the ability of a bonded atom (one that is bonded to something else already) to attract electrons to it. 11. Circle the atom in each pair that has the greater electronegativity. a. Ca or Ga c. Li or O e. Cl or S b. Br or As d. Ba or Sr f. O or S Bonding Review 12. List three differences between ionic and covalent compounds: Ionic bonds transfer electrons and covalent bonds share electrons. Ionic bonds are stronger. Ionic bonds have a metal bonded to a nonmetal (they are far apart on the PT) and covalent bonds are between 2 nonmetals (close together on the PT). 13. Explain why ionic compounds are formed when a metal bonds with a nonmetal but covalent compounds are formed when two nonmetals bond. The metal and nonmetal in an ionic bond have a large electronegativity difference so 1 atom takes the other atoms electrons. The 2 nonmetals in a covalent bond doesn’t have a large electronegativity difference so 1 atom doesn’t pull the other atom’s electrons off of it – they still share the electron. Naming review 1) Na2CO3 ____sodium carbonate____________________ 2) NaOH _____sodium hydroxide_____________________________ 3) MgBr2 ____magnesium bromide_____________________________ 4) KCl ____potassium chloride______________________________ 5) FeCl2 ____iron (II) chloride_________________________________ 6) FeCl3 ____iron (III) chloride_________________________________ 7) Zn(OH)2 zinc (II) hydroxide__ the (II) could be omitted b/c zinc is a constant charge 8) BeSO4 __beryllium sulfate_____________________________ 9) CrF2 ____chromium (II) fluoride_______________________________ 10) Al2S3 ___aluminum sulfide_____________________________ 2nd quarter review Chemistry 11) sodium phosphide ___Na3P_________________ 12) magnesium nitrate _____Mg(NO3)2___________________________ 13) lead (II) sulfite ____PbSO3______________________________ 14) calcium phosphate ___Ca3(PO4)2_____________________________ 15) ammonium sulfate __(NH4)2SO4____________________________ 16) silver cyanide _____AgCN Ag is a constant charge of +1 ___ 17) aluminum sulfide __Al2S3_______________________________ 18) beryllium chloride __BeCl2________________________________ 19) copper (I) arsenide _Cu3As______________________________ 20) iron (III) oxide ____Fe2O3__________________________________