Chemistry Water B Reading Name_______________________________ Read pages 25-30. 1. Did preliminary water sample analysis show a likely cause for the fish kills? 2. What does DO stand for? How is this related to fish kills? 3. What are 2 factors EPA chemists will have to consider when examining the possibility that a dissolved substance may be responsible for the fish kill? 4. Was any illness reported from drinking water in Riverwood? 5. Define “physical properties”. 6. One ______________ of water at 25°C has a mass of one ________________. 7. One __________________ of volume = ____________________ (See figure 1.20) 8. What is the freezing point of water? 9. Why is water that seems pure never really entirely so? 10. What is an aqueous solution? 11. Pure water is clear, __________________________, __________________________, and ______________________________. 12. Please answer the questions B.2 on page 28 here: 1. 2. 3. 1 13. Which state of matter (solid, liquid, or gas) is usually the densest form of a substance? (Note! water is an exception to this!) 14. Define “mixture”. 15. A solution is a ____________________________ mixture in which the particles are so small they cannot be seen even with magnification. 16. Define “solute”. 17. Define “solvent”. 18. Describe a suspension: 19. Describe a colloid: 20. Why is milk a colloid? 21. What is the Tyndall effect? 22. If the Tyndall effect is apparent, the mixture is a ____________________________. If you cannot see the Tyndall effect, the mixture is a ___________________________. Note: study the chart on page 30!! 2 Water Part B Physical properties of water ______________molecules dissolve many substances Clear, colorless, odorless, tasteless Boiling point = ______________ Melting/freezing point = ___________ Density = ________________ Density of liquid water _____density of ice High _________________ _______________ Most solids sink in their liquids! Defining matter according to makeup Homogeneous- ____________________properties throughout Heterogeneous- has parts with ___________________properties Appearance alone cannot always distinguish heterogeneous matter from homogeneous. Heterogeneous Matter Made of more than one type of substance. Easily separated by _______________________such as evaporation, magnetic separation, or picking pieces apart. What is a mixture? 2 or more substances, ___________________combined Mixtures may be __________________or _________________________ Homogenous mixtures are called ___________________ 3 Salt waterHomogeneous mixture, Solution How do we know this is a mixture? It can be separated by physical means: evaporation. Other examples of solutions Rootbeer is a solution of water, sugar, carbon dioxide, and other flavorings Brass is a solution of Copper and zinc Air is a _________________ It is a homogenous mixture of nitrogen, oxygen, carbon dioxide and other gases. Homogeneous matter Homogeneous matter may be ________________or________________. Pure substances ____________________be separated by physical means. A ____________________ ____________________must occur to separate the parts. Pure substances are ________________if they are separable by chemical means. They are _________________if they can not be further broken down. 4 Water is a pure substance Water (H2O) can be broken into ____________________and ________________________by electrolysis. It cannot be separated into hydrogen and oxygen by any physical method. Hydrogen gas is a pure substance Hydrogen may be a ________________(H2) or an _____________________(H). Hydrogen gas as it normally exists is the compound H2 . Classifying matter according to make-up Pure Substances Compounds Elements Mixtures Homogeneous Solutions or Colloids Heterogeneous Suspension What type of matter? Classifying mixtures by particle size _________________: particles too small to see or separate out. No Tyndall effect. _________________: Tiny particles produce a cloudy appearance. Shows Tyndall effect _________________: Big particles you can see and that will settle out. 5 Solutions ________________________mixtures Have different parts which are uniformly distributed and are too small to distinguish with the eye. Examples:____________________________________ Solid solutions are called________________; they are a mixture of metals Examples: ________________________________________ Made of 2 parts- solute and solvent ____________________dissolve in things _____________________do the dissolving Colloids Can’t see the particles Foggy or _________________appearance Show Tyndall effect Particles too small to see, evenly distributed, cloudy appearance 6 Suspensions Particles _____________enough to see and settle out Many medicines are suspensions Rivers have particles suspended in their water Particles big enough to see that may settle out Colloid, suspension, or solution? 7 CLASSIFYING MATTER FLOWCHART 8 Water B-2 Atoms and molecules, Polar molecules, Ions and Chemical formulas Let’s review the molecule! 2 or more atoms ______________ __________together make a molecule. Let’s review the molecule! The water molecule consists of ________ hydrogen atoms, and __________oxygen atom. Its formula is _________________ The ethane molecule consists of ________carbon atoms and __________ hydrogen atoms. Its formula is ______________________ 9 Let’s review molecular formulas: How many atoms of each element are in the following molecules? 1. H2SO4 __________________________________ 2. Ca(OH)2 __________________________________ 3. NaCl __________________________________ 4. (NH3)3P04 __________________________________ 5. 3 H2O (this means 3 water molecules) __________________________________ 6. 4 Al2(CO3)3 (4 aluminum carbonate molecules) __________________________________ Do an atom inventory for this equation: NaOH + HCl NaCl + H2O Interpret this equation in terms of molecules (Tell in words what is happening in this reaction) 2H2 + O2 2H2O _________________________________________ ______________________ Do an atom inventory: 2H2 + O2 2H2O 10 Interpret this equation in terms of molecules 3N2 + H2 2 NH3 _________________________________________________ _____________________________ Interpret this equation in terms of molecules: Do an atom inventory 11 Please read pages 34-36 in your text and do the exercises B.7 #1-3 on pages 3637 here, then also answer questions 4 - 6 on the next page: 12 4. What are diatomic molecules? 5. List the elements that exist as diatomic molecules. 6. Look up these elements on your periodic table. Trace the positions of all except hydrogen. What shape do they make ( if you don’t include hydrogen)? It will be easy to remember them, because there are 7 elements and they make the number 7 on the periodic table (plus you have to remember hydrogen!) Or, you can just remember the magic word… HNOFClBrI Ions and chemical formulas Let’s review the atom: The atom has 3 subatomic particles _________-in the nucleus, + charge _________- in the nucleus, neutral __________- outside the nucleus, - charge (moving!) IONS Elements that have gained or lost an electron Cations are positive They have lost an electron They have gained an electron Anions are negative 13 Is this sodium ion a cation or an anion? Chlorine gains an electron when it ionizes. Is it a cation or an anion? When the two combine, you get sodium chlorideeverybody’s happy! Ionic bonds Na+ ClMakes the ionic compound ________________ 14 Question: Calcium prefers to lose 2 electrons. What kind of ion would calcium be? ____________, a ____________________ Question: Fluorine would like an extra electron. What kind of ion will it become? ____________, a fluoride ___________________ Question: What compound is made from calcium and fluoride ions? Calcium fluoride, _______________ Question: Why are 2 F’s needed for one Ca? FCa2+ F- The charges need to______________________! Atoms prefer a full outer shell of electrons! Draw some atoms and ions! Draw some atoms as Neils Bohr represented them. Then you will draw some ions as you see if atoms prefer to gain or lose electrons to fill their outer shell. 15 Names and formulas of ionic compounds Molecular- ______________bonds, electrons are _____________ Ionic- ionic bonds, electrons are _________________ Ionic Covalent or ionic? bonds form between a _________and a ________________ Covalent bonds form between 2 ______________or a nonmetal and ____________ Na and Cl C and H Covalent or ionic? ________________ _______________________________ C and S _____________________________________ N and N ________________________________________ Ca and S ___________________________________________ Fe and Cl ____________________________________________ 16 Naming ionic compounds The first name is the name of the _______________ – Example: CaCl2 has first name ______________ The last name has the name of the____________. Anion names always end in “__________” unless they are from your polyatomic ion chart. – Example: CaCl2 has last name chloride, so is CaCl2 __________________ ____________ 1. 2. 3. 4. 5. Name these ionic compounds BaF2_________________________________ K2Se_________________________________ CaS__________________________________ AlF3_________________________________ LiH__________________________________ 1) MgS ___________________________ 2) KBr ____________________________ 3) Ba3N2 ___________________________ 4) Al2O3 ___________________________ 5) NaI ____________________________ 6) SrF2 _____________________________ 17 Some Naming ionic compounds-more compounds need __________ _______________________to distinguish between possible first names. For example, a compound of iron and chloride may be iron (II) chloride or iron (III) chloride. The roman numeral is equal to the ___________on the ion Name these ionic compounds using roman numerals: 1. A compound of Mn3+ and Cl________________________________ 2. NiN _________________________________ 3. SnO ____________________________________________ 4. SnO2 _______________________________ 5. PbO _________________________________ CrCl3 ______________________________________ CoO ______________________________________ Mn2O3 ______________________________________ Co2S3 ______________________________________ AuF ______________________________________ CrBr2 ___________________________________________________ 18 Which elements need roman numerals in their names? Any All elements listed as _________________metals ________________________metals except zinc, cadmium, and silver. – Zinc and cadmium always form _________ions, silver always forms a ___________ion. Naming ionic compounds that contain more than 2 elements Compounds containing polyatomic ions are named by using your _____________ __________chart. Name these ionic compounds that contain polyatomic ions: 1. NH4Cl __________________________________ 2. NH4OH – __________________________________ 3. (NH4 )3PO3 _____________________________________________________________ 4. AlPO4 – ________________________________ 5. Fe(NO2) 2 _________________________________ 19 1. N a Cl Mixed practice naming ionic compounds! ________________________________________________________ 2. Fe2O3 _________________________________________________________ 3. CuCl2 __________________________________________________________ 4. CuCl __________________________________________________________ 5. (NH4)2CO3 ___________________________________________________________ 6. Ca3(PO4) 2 ____________________________________________________________ Rule for writing ionic formulas: ________________________________________________________________________ Practice writing ionic formulas 1. Ca2+ combined with F-_____________________ 2. Co3+ combined with PO43-_______________________ 3. Ni2+ combined with OH-______________________ 20 More practice 1. calcium combined with oxygen ____________________________ 2. potassium combined with oxalate _____________________________ 3. chromium (II) hydrogen sulfate __________________________________________________ Write formulas for these! Tin (II) oxide ____________________ Tin (IV) oxide ____________________ Tin (II) hydroxide ____________________ Tin (II) dichromate ____________________ Tin (II) phosphate ____________________ Ammonium phosphite ____________________ 21 NAMING COVALENT (MOLECULAR) COMPOUNDS 22 LAB B8 Water Testing 1. Define: a. Qualitative tests: Read pages 42- 45 b. Quantitative tests: c. Precipitate: 2. Cations: a. definition: (from previous notes) b. the cations we will be testing for in this lab are: c. Why must we call the iron ion we will be testing for “iron III”? 3. Anions: a. definition: (from previous notes) b. the anions we will be testing for in this lab are: 4. Why are you using distilled water as one of the solutions that you will test? 5. What is a reference solution? 6. List the 4 reference solutions you will use. The reference solutions are named the same as the ions for which you will be testing. 7. Since the reference solutions contain the ions we are testing for, should you always see some sort of reaction when you test the reference solutions? 8. What will you use as your unknown solutions? 9. How will you tell if the ion you are testing for is present in the tap water? 10. Will any ions be present in the distilled water? If not, then why are you testing for them? 23 Read suggestions on page 43!!! GOGGLES ARE REQUIRED!!!!!! All solutions except distilled, tap water and natural water are in pipettes. Thoroughly wash, rinse, and dry 3 small beakers. Put distilled water in one, tap water in another, and natural (pond) water in the third. Follow procedures in book. CLEAN UP: Rinse excess chemicals in pipettes down drain with tap H20 running. Rinse insides of pipettes thoroughly with tap water twice and then with distilled water. DO NOT DISCARD PIPETTES!! 24 Naming Ionic Compounds Name These: 1. MgCl2 _________________ 2. K2O____________________ 3. Be3S2 __________________ 4. NH4Cl __________________ 5. NH4OH_________________ 6. Ba(CN) 2 _________________ 7. Na2SO3 _________________ 8. (NH4) 3PO4 _______________ 9. (NH4) 3PO3 ______________ 10. NaBr ___________________ 11. NH4Br _______________ 12. H2O ___________________ 13. Ar ____________________ 14. CuSO4 __________________ 15. CuOH _________________ 16. Cu(OH) 2 _________________ 17. Pb(OH) 2 _______________ 18. Pb(OH) 4 _________________ 19. MnSO4 ________________ 20. MnPO4 __________________ 21. SnO___________________ 22. SnO2____________________ 25 Write formulas for these ionic compounds: 1. Calcium hydroxide: _____________ 2. Calcium bromide: ______________ 3. Copper (I) sulfate: ______________ 4. Copper (II) sulfate: ______________ 5. Ammonium nitrate: ______________ 6. Tin (II) oxide: __________________ 7. Tin (IV) oxide: _________________ 8. Chromium (II) dichromate: ______________ 9. Barium Phosphate ______________ 10. Ammonium Carbonate: ______________ 11. Strontium bromide________________ 12. Cadmium sulfide ____________________ 13. Cadmium phosphate___________________ 14. Iridium (III) oxide ___________________ 15. Iridium (II) phosphate_________________ 16. Vanadium(IV) phosphide_______________ 18. Mercury(I) selenide___________________ 19. Mercury(I) selenate____________________ 20. Mercury(II) selenate___________________ 26 Chem worksheet: names Your name is:________________________________ Write the correct chemical name for: 1) MgS 2) KBr 3) Ba3N2 4) Al2O3 5) NaI 6) SrF2 7) Li2S 8) RaCl2 9) CaO 10) AlP 11) K2S 12) LiBr 13) Sr3P2 14) BaCl2 15) NaBr 27 Write the correct name for: (these need roman numerals) 1) CuS 2) PbBr4 3) Pb3N2 4) Fe2O3 5) FeI2 6) Sn3P4 7) Cu2S 8) SnCl2 9) HgO 10) Hg2F2 11) CuCl2 12) CuBr 13) PbO 14) Fe2S3 15) PbCl2 16) SnO 17) Cu2O 18) PbO2 19) FeO 20) SnO2 21) Hg2O 22) Hg2I2 23) AuCl3 24) MnO 28 POLYATOMIC IONS: Write the correct name for: 1) AlPO4 2) KNO2 3) NaHCO3 4) CaCO3 5) Mg(OH)2 6) Na2CrO4 7) Ba(CN)2 8) K2SO4 9) NaH2PO4 10) NH4NO3 These formulas involve the use of a polyatomic ion. The cations are all of variable oxidation state, so Roman numerals are needed. Write the correct name for: 11) Sn(NO3)2 12) FePO4 13) Cu2SO4 14) Ni(C2H3O2)2 15) HgCO3 16) Pb(OH)4 17) Cu2Cr2O7 18) Cu(ClO3)2 19) FeSO4 20) Hg2(ClO4)2 29 Chemical Formula Writing Worksheet Write chemical formulas for the compounds in each box. The names are found by finding the intersection between the cations and anions. Example: The first box is the intersection between the “zinc” cation and the “chloride” anion, so you should write “ZnCl2”, as shown. zinc chloride iron (II) iron (III) gallium silver lead (IV) ZnCl2 acetate nitrate oxide nitride sulfate Write the formulas for the following compounds: 1) copper (II) chloride ____________________________________ 2) lithium acetate ____________________________________ 3) vanadium (III) selenide ____________________________________ 4) manganese (IV) nitride ____________________________________ 5) beryllium oxide ____________________________________ 6) sodium sulfate ____________________________________ 7) aluminum arsenide ____________________________________ 8) potassium permanganate ____________________________________ 9) chromium (VI) cyanide ____________________________________ 10) tin (II) sulfite ____________________________________ 11) vanadium (V) fluoride ____________________________________ 12) ammonium nitrate ____________________________________ 30 Polyatomic Ions Note: The charge on the ions below is the net charge. For example, PO4 has a -3 charge because the oxidation number of the oxygen (O4) is -2 x 4 = -8 and the oxidation number of the phosphorus (P) is +5. -8 + 5 = -3. Therefore, when writing formulas with polyatomic ions, simply use the charge given in the column above the ion. +1 ion -1 Formula Name Formula NH4 Ammonium H2PO4 C2H3O2 HSO3 HSO4 HCO3 NO2 NO3 CN OH MnO4 ClO ClO2 ClO3 ClO4 SCN -2 Formula HPO4 C2O4 SO3 SO4 CO3 CrO4 Cr2O7 SiO3 SeO4 ions Name Dihydrogen phosphate Acetate Hydrogen sulfite (or bisulfite) Hydrogen sulfate (or bisulfate) Hydrogen carbonate (or bicarbonate) Nitrite Nitrate Cyanide Hydroxide Permanganate Hypochlorite Chlorite Activity series of metals Chlorate Li Lithium Perchlorate K Potassium Thiocyanate Ba Barium Ca Calcium ions Na Sodium Mg Magnesium Name Al Aluminum Hydrogen phosphate Zn Zinc Oxalate -3 ions Fe Iron Sulfite Formula Name Ni Nickel Sulfate Sn Tin Carbonate PO4 Phosphate Pb Lead Chromate PO3 Phosphite (H) Hydrogen Dichromate Fe(CN)6 Ferricyanide Cu Copper Silicate Hg Mercury Selenate Ag Silver Acid names Au Gold anion acid name ending (metals from Li to Na will replace H -ide -ite -ate hydro----ic acid -------ous acid -------ic acid from acids and water, from Mg to Pb they will replace H from acids only) 31 32