Advanced Placement Chemistry 2010-2011 Unit Unit 1: Review of Honors Chemistry I, Basic Tools of Chemistry, Part I (2.0 weeks) Sets1 Text chapters1 Topics Problem Tests and 1 Chemistry The Study of Change: Scientific Method, Classifying Matter, States of Matter, Physical and Chemical Properties, Units of Measurement, Making Measurements, Dimensional Analysis Practice Problem Set ch 1-3: p. 32-37 #58, 76, 78, 92; p. 71-76 #36, 50, 58, 60, 100; p. 110-119 #30, 52, 86, 100 2 Atoms, Molecules and Ions: Development of Atomic Structure, Elements and Atoms,Atomic Number and Atomic Mass, Isotopes, Atomic Weight, Periodic Table, Compounds and Molecules, Ions, Chemical Formulas and Naming Compounds, Intro to Organic Labs2 – all the experiments below, except where noted with *, will require hands-on work in the laboratory Additional Resources3,4 Lab safety, use and care of equipment* Lab Report: Synthesis and Analysis of an Alum (Labs #2+3): synthesize a crystal, calculate theoretical and percent yields, analyze characteristics of a crystal, determine percent water in a hydrate, compare analytical techniques for effectiveness Chang Text Review http://www.glencoe.com/ch ang10 Multiple-Choice & FreeResponse Questions in Preparation for the AP Chemistry Examination: ch 5 #1, 2, 3, 5, 7, 10, 11, 12, 16, 20, 21, 22, 25, 28 3 Mass Relationships in Chemical Reactions: Atomic Mass, Avogadro's Number and Molar Mass, Moles, Mass Spectrometer, Percent Composition, Experimental Determination of Empirical Formulas, Chemical Reactions and Chemical Equations, Hydrates, Limiting Reactants, Percent Yield 17 Chemistry in the Atmosphere: Earth's Atmosphere, Phenomena in the Outer Layers, Ozone Depletion in the Stratosphere, Volcanoes, Greenhouse Effect, Acid Rain, Photochemical Smog, Indoor Pollution history of atomic structure http://www.particleadventur e.org/atom_search.html review questions and answers http://www.jce.divched.org/ JCEDLib/QBank/collection/ ConcepTests/atomsh.html Test: Unit 1 Ultimate Chemical Equations Handbook ch. 1-4: Symbols and Nomenclature, Inorganic Formulas and Nomenclature, Oxidation Numbers, Anions and Cations, Acids and Salts Nomenclature Problem Set Packet Chang Text Review Unit 2: Review of Honors Chemistry I, Basic Tools of Chemistry, Part II (2.5 4 Reactions in Aqueous Solutions: Properties of Compounds in Aqueous Solution, Precipitation Reactions, Acids and Bases and their Reactions, OxidationReduction Reactions, Concentration Measurements, Gravimetric Analysis and Titrations Practice Problem Set ch 4-6 p.160-169 #9, 18, 46, 74, 86, 95, 110, 121; p. 215-225 #110, 125, 142, 147, 152, 154; p. 262-271 #35, 48, 64, 82, 86, 98, 119 Lab Report: Introduction to Qualitative Analysis: (lab #1) research and organize data on solubility, color change, gas reaction, and other physical characteristics used in qualitative analysis; determine the presence or absence of ions in unknown solutions http://www.glencoe.com/ch ang10 Multiple-Choice & FreeResponse Questions in Preparation for the AP Chemistry Examination: ch 3, 4, 5, 8 (esp. ch 3 #6, 7, 8, 9, 10, 11, 16, 17, 18, 19, 20, 24; ch 4 #6, 10, 11, 12, 13; ch 5 #4, 6, 9, 13, 14, 17, 23, 24, 26, 27; ch 8 #10, 14, 16, 21) weeks) 5 6 Unit 3: Structure of Atoms and Molecules, Part I (1.5 weeks) Gases: Substances that Exist as Gases, Pressure, Gas Laws, Stoichiometry, partial Pressures, Kinetic Molecular Theory, Deviations from Ideal Behavior Thermochemistry: Energy and Types of Energy, Energy Changes in Chemical Reactions, Thermodynamics, Enthalpy Changes, Calorimetry, Standard Enthalpies of Formation and Change, Heats of Solution and Dilution 7 Quantum Theory and the Electronic Structure of Atoms: History and Quantum Theory, Photoelectric Effect, Bohr, Dual Nature of the Electron, Quantum Mechanics and Quantum Numbers, Atomic Orbitals, Electron Configurations 8 Periodic Relationships Among the Elements: Periodic Table, Classification of Elements, Periodic Trends in Physical Properties, Ionization Energy, Electron Affinity, Periodic Trends in Chemical Properties Hand warmer lab activity (teacher- designed activity) Test: Unit 2 and bits of Unit 1 Practice Problem Set ch 7-8: p. 312-319 #9, 17, 29, 34, 54, 56, 58, 65, 91, 92, 96, 100, 102, 107, 114, 124; p. 356-363 #5, 23, 27, 29, 31, 38, 44, 46, 51, 61, 72, 77, 83, 103, 114, 120, 131 real vs. ideal gases http://intro.chem.okstate.ed u/1314F97/Chapter10/Real Gas.html Lab Report: Hess's Law: Determining the Enthalpy Change of a Reaction: (lab #4) collect experimental data from which to calculate enthalpy for certain reactions; use Hess’s law to calculate enthalpy of formation indirectly for MgO; determine and explain percent error for the calculation Emission Spectra (teacherdesigned activity) Lab Report: Job's Method of Continuous Variation: (lab #7) determine the stoichiometry of a chemical reaction experimentally; determine the chemical formula of a precipitate; determine the oxidation state of an ion in solution Ultimate Chemical Equations Handbook ch. 7-10: Balancing Molecular Equations, Single Replacement, Double Replacement, Aqueous Solutions and Ionic Equations Chang Text Review Test: Unit 3 and selected bits of Units 1-2 http://www.glencoe.com/ch ang10 Multiple-Choice & FreeResponse Questions in Preparation for the AP Chemistry Examination: ch 1 (esp. ch 1 #110, 13-16, 19, 20, 22-24, 26-28) Unit 4: Structure of Atoms and Molecules, Part II (2.0 weeks) Unit 5: States of Matter and Their Properties, Part I (1.0 week) 21 Nonmetallic Elements and Their Compounds: Properties of Nonmetals, Hydrogen, Carbon, Nitrogen, Phosphorus, Oxygen, Sulfur, Halogens Problem Set Packet 9 Chemical Bonding I: Lewis Dot Symbols, Ionic Bond, Lattice Energy of Ionic Compounds, Covalent Bond, Electronegativity, Lewis Structures, Formal Charge, Resonance, Exceptions of the Octet Rule, Bond Enthalpy Practice Problem Set ch 9-10: p. 400-406 #14, 36, 40, 44, 47, 52, 55, 63 a-b, 65, 66 ,73, 79, 90, 109, 120; p. 453-459 #12, 38, 41, 69, 73, 76 a-d, 78, 81, 82, 99, 105 10 Chemical Bonding II: Molecular Geometry, Dipole Moment, Valence Bond Theory, Hybridization of Atomic Orbitals, Hybridization of Molecules Containing Double and Triple Bonds Test: Unit 4 and review of Units 1-3 11 Intermolecular Forces and Liquids and Solids: Kinetic Molecular Theory, Intermolecular Forces, Properties of Liquids, Crystal Structure, X-Ray Diffraction, Types of Crystals, Amorphous Solids, Phase Changes, Phase Diagrams Practice Problem Set: p. 503-511 #12,13, 15, 19, 31, 53, 55, 78, 81, 94, 95, 96, 107, 115, 128, 146 Test: Unit 5 and selected questions from Units 1-4 Lab Report: Chromatography of a Popular Beverage: (lab #15) use paper chromatography to separate the food dyes in a popular colored beverage; determine the identities of the dyes in food coloring using the known dyes in the beverage as standards Lab Report: Analysis of a Volatile Liquid: (lab #6) determine the molecular mass, density, and boiling point of an unknown volatile liquid; calculate and explain the percent error of the calculations on the volatile liquid; determine the applicability of certain techniques for the analysis and identification of various Chang Text Review http://www.glencoe.com/ch ang10 Multiple-Choice & FreeResponse Questions in Preparation for the AP Chemistry Examination: ch 2 (esp. ch 2 #612, 15-17, 20-25, 27-28) Chang Text Review http://www.glencoe.com/ch ang10 Multiple-Choice & FreeResponse Questions in Preparation for the AP Chemistry Examination: ch 2, 3 (esp ch 2 #1-5, 18-19, 26; ch 3 #1-5, 12, 14-15, 22-23, 28) compounds END QUARTER 1 Unit 6: States of Matter and Their Properties, Part II (2.0 weeks) Unit 7: Chemical Kinetics (2.5 Weeks) 12 Physical Properties of Solutions: Types of Solutions, Molecular View of Solution Process, Concentration Units, Effect of Temperature on Solubility, Effect of Pressure on Solubility of Gases, Colligative Properties, Colloids Practice Problem Set: p. 545-553 #11, 18, 22, 56, 58, 71, 73, 74, 89, 94, 99, 109, 116 Take Home Test: Unit 6 and bits of Units 1-5 23 Nuclear Chemistry: Nature of Nuclear Reactions, Nuclear Stability, Natural Radioactivity, Nuclear Transmutation, Nuclear Fission, Nuclear Fusion, Use of Isotopes, Biological Effects of Radiation Problem Set Packet 13 Chemical Kinetics: Rate of a Reaction, Rate Law, Relation Between Reactant Concentration and Time, Practice Problem Set: p. 602-613 #8, 11, 13, 16, 20, 26, 28, 34, 35, 39, 43, 46, 51, 52, 54, Lab Report: Determining Molar Mass by Freezing Point Depression: (lab #14) compare freezing points of a pure solvent and a known solution of the solvent to determine the change in freezing point; calculate the molal freezing point depression constant for the solvent; determine the molar mass of an unknown solute from experimental data Chang Text Review http://www.glencoe.com/ch ang10 Multiple-Choice & FreeResponse Questions in Preparation for the AP Chemistry Examination: ch 4 (esp. Ch 4 #1-5, 8-10, 11, 21-22, 24-26, 28) Ultimate Chemical Equations Handbook Practice Handouts 14 Lab Report: Kinetics: Differential and Integrated Rate Laws: (lab #13) observe and compare the effects of Chang Text Review http://www.glencoe.com/ch ang10 Activation Energy and Temperature Dependence of Rate Constants, Reaction Mechanisms, Catalysis 56, 65, 67, 70ab, 72, 74, 75ab, 78, 86, 88, 89, 99 Test: Unit 7 and review of Units 1-6 24 Unit 8: Chemical Equilibria (2.5 Weeks) Review Semester 1/ End Quarter 2 14 Organic Chemistry: Classes of Organic Compounds, Aliphatic Hydrocarbons, Aromatic Hydrocarbons, Functional Groups Chemical Equilibrium: Concept of Equilibrium and Equilibrium Constant, Equilibrium Constant Expressions, Relationship Between Chemical Kinetics and Chemical Equilibrium, Factors that Affect Equilibrium Problem Set Packet Practice Problem Set: p. 648 #7, 14, 16, 18, 30, 44, 48, 53, 54, 77, 78, 26, 46 Test: Unit 8 and review of Units 1-7 Midterm Exam: Practice AP Exam homogeneous and heterogeneous catalysts on the decomposition of hydrogen peroxide; measure the reaction rates to determine the order of reaction with respect to various reactants; analyze experimental data to write a differential rate law expressions *Kinetics of Radioactive Decay – Integrated Rate Law: analyze decay data to determine the integrated rate law constant for a radioactive substance Multiple-Choice & FreeResponse Questions in Preparation for the AP Chemistry Examination: ch 6 (esp Ch 6 #117, 20-21, 23-28) Ultimate Chemical Equations Handbook Practice Handouts 58 Ultimate Chemical Equations Handbook ch. 6 Organic Nomenclature and Simple Reactions Multiple-Choice & FreeResponse Questions in Preparation for the AP Chemistry Examination: ch 11 all Chang Text Review http://www.glencoe.com/ch ang10 Multiple-Choice & FreeResponse Questions in Preparation for the AP Chemistry Examination: ch 7 (esp. Ch 7 #1-3, 5-8, 10-14, 1624, 26, 28) Review topics/ quiz/ answers http://www.avogadro.co.uk/ chemist.htm 25 Unit 9: Chemistry of Acids and Bases (2.5 Weeks) 15 20 Unit 10: Aqueous Equilibria cont. (2.0 Weeks) 16 Synthetic and Natural Organic Polymers: Properties of Polymers, Synthetic Organic Polymers, Proteins, Nucleic Acids Acids and Bases: Bronsted Acids and Bases, Acid-Base Properties of Water, pH, Strength of Acids and Bases, Weak Acids and Bases and Ionization Constants, Reltaionship Between Ionization Constant of Acids and Conjugate Bases, Diprotic and Polyprotic Acids, Molecular Structure and Strength of Acids, Acid-Base Properties of Salts, Acid-Base Properties of Oxides and Hydroxides, Lewis Acids and Bases Metallurgy and the Chemistry of Metals: Occurrence of Metals, Metallurgical Processes, Band Theory of Electrical Conductivity, Periodic Trends in Metallic Properties, Alkali Metals, Alkaline Earth Metals, Aluminum Acid-Base Equilibria and Solubility Equilibria: Homogeneous vs. Heterogeneous Solution Equilibria, Common Ion Effect, Buffer Solutions, Acid-Base Titrations, Acid-Base Indicators, Solubility Equilibria, Separation of Ions by Fractional Problem Set Packet Practice Problem Set: p. 702-709 #3, 4, 5, 11, 16, 18, 20, 25, 34, 37, 38, 43, 44, 45, 46, 54, 64, 70, 76, 80, 92 Test: Unit 9 and review AP exam questions Lab Report: Determination of Acid Ionization Constant of a Weak Acid: (lab #10) calculate the Ka of a weak monoprotic acid given its pH and initial concentration; calculate the Ka of a weak monoprotic acid from pH of a solution of known amounts of acetic acid and sodium acetate; determine the Ka of a monoprotic or diprotic acid from a titration curve using various analytic methods Multiple-Choice & FreeResponse Questions in Preparation for the AP Chemistry Examination: ch 7, 9 , 12 (esp. ch 9 #1-17, 19-27) Ultimate Chemical Equations Handbook Practice Handouts 912 Problem Set Packet Practice Problem Set: p. 757-765 #2, 6, 10, 14, 18, 20, 24, 30, 32, 34, 42, 50, 56, 66, 68 Chang Text Review http://www.glencoe.com/ch ang10 Lab Report: Determination of Equilibrium Constant of an Indicator: (lab #11) calculate the molar extinction coefficient of the protonated and unprotonated forms of bromocresol green; determine experimentally the equilibrium constant for bromocresol Ultimate Chemical Equations Handbook ch 5 + 13: Complex Ion Formulas and Nomenclature, Complex Ion Reactions Precipitation, Common Ion Effect and Solubility, pH and Solubility, Complex Ion Equilibria and Solubility, Application of the Solubility Product Principle to Qualitative Analysis green and compare the result with the theoretical Kin value (after exam, if needed) Test: Unit 10 and review AP exam questions Unit 11: Entropy and Free Energy (2.0 Weeks) 18 22 Entropy, Free Energy, and Equilibrium: Three Laws of Thermodynamics, Spontaneous Processes, Entropy, Second Law of Thermodynamics, Gibbs Free Energy, Free Energy and Chemical Equilibrium, Thermodynamics in Living Systems Transition Metals Chemistry and Coordination Compounds: Properties of the Transition Metals, Chemistry of Iron and Copper, Coordination Compounds, Structure of Coordination Compounds, Bonding in Coordination Compounds, Reactions of Coordination Compounds, Applications of Coordination Compounds Practice Problem Set: p. 829-835 #5, 10, 12, 14, 18, 20, 24, 28, 32 Test: Unit 11 and review AP exam questions Problem Set Packet Lab Report: Preparation of a Buffer Solution at a Given pH: (lab #12) choose and make a buffer of given pH by dissolving known masses of solid salts in water; make a buffer of given pH by mixing a predetermined volume of strong base with a salt solution Chang Text Review http://www.glencoe.com/ch ang10 Multiple-Choice & FreeResponse Questions in Preparation for the AP Chemistry Examination: ch 7, 9 , (esp Ch 7 #1, 3, 4, 15, 25, 27; Ch 9 #14, 18, 26, 28) Chang Text Review http://www.glencoe.com/ch ang10 Multiple-Choice & FreeResponse Questions in Preparation for the AP Chemistry Examination: ch 8, 12 (esp Ch 8 #1-18, 20-28) Unit 12: Electron Transfer Reactions (2.0 Weeks) 19 Electrochemistry: Redox Reactions, Galvanic Cells, Standard Reduction Potentials, Thermodynamics of Redox Reactions, Effects of Concentration of Cell Emf, Batteries, Corrosion, Electrolysis Practice Problem Set: p. 874 #2a,d, 12, 14, 16, 18, 22, 30a, 46, 60 Test: Unit 12 and review AP exam questions Lab Report: Analysis by Redox Titration: (lab #9) standardize potassium permanganate solution using FAS as a standard; determine the concentration of a preparation of hydrogen peroxide; calculate the mass percent of iron in an iron supplement (dry lab) Lab Report: Exploring Electrochemistry: (lab #17) create a galvanic cell and determine the voltage generated by it; create a concentration cell and use the Nernst equation to calculate the concentration of an unknown solution Lab Report: Electrolytic Synthesis of Iodoform: (lab #16) perform an electroysis of potassium iodide with acetone in basic solution to form iodoform; analyze and explain the products of oxidation and reduction in the experimental electrolysis Chang Text Review http://www.glencoe.com/ch ang10 Multiple-Choice & FreeResponse Questions in Preparation for the AP Chemistry Examination: ch 10 1-28 electrochemistry review http://library.kcc.hawaii.edu/ external/chemistry/ Ultimate Chemical Equations Handbook ch 11 + 12: Redox Equation Balancing and Reactions, Electrolysis in Aqueous Solutions End Quarter 3 Unit 13: Exam Practice and Review (1.5 Weeks) Nightly Problems, Daily Quizzes, Practice Exams Multiple-Choice & FreeResponse Questions in Preparation for the AP Chemistry Examination: practice exams Review of Labs Ultimate Chemical Equations Handbook Practice Equations Handouts Practice writing equations http://dwb4.unl.edu/ap2/index.ht ml Unit 17: Implications of Science and Written Projects, Various depending on student Labs will be selected to Technology/ Presentations interest support various topics Independent Research (3.0 Weeks) End Semester 2/ End Quarter 4 1 Chang, Chemistry 10th ed. 2 Hostage and Fossett, Laboratory Investigations: AP Chemistry, unless otherwise indicated 3Hague and Smith, The Ultimate Chemical Equations Handbook, for all Chemical Equation assignments 4Demmin and Hostage, Multiple-Choice & Free-Response Questions in Preparation for the AP Chemistry Examination, 5 th ed