Unit 4 Review Naming and formula writing 1) Identify the following compounds as ionic, molecular, then name them. Formula What kind of compound? Name P2O5 ___I ___C (NH4)2CO3 ___I ___C Fe(OH)3 ___I ___C 2) Identify the following compounds as ionic, molecular, acid, or hydrate and write the formulas. Name What kind of compound? Formula Copper (II) Phosphate ___I ___C Dinitrogen tetroxide ___I ___C Boron trichloride ___I ___C Barium chloride ___I ___C 3) Identify the cation and anion in the following compounds a) NaCl cation ______ anion ______ e) Al2O3 cation ______ anion ______ b) Ca3(PO4)2 cation ______ anion ______ f) NH4OH cation ______ anion ______ c) PbSO4 cation ______ anion ______ g) H2S cation ______ anion ______ d) Ba(HCO3)2 cation______ anion ______ h) Fe(NO3)3 cation ______ anion ______ 4) Count the number of each atom in the following compounds or groups of compounds: a) Cu(NO3)2 Cu _____ N _____ O _____ b) PbSO4 Pb _____ S _____ O _____ c) Fe2(CO3)3 Fe _____ C _____ O _____ d) 4CaCl2 Ca _____ Cl _____ e) 3CO2 + 5H2O C _____ H _____ O _____ f) 3Sn(SO3)2 Sn _____ S O _____ _____ #5-10) Use a factor-label expression to solve the following problems. 5) When you weigh out 15.5 g of copper in the penny lab, how many moles of copper are you weighing out? 6) If you need to measure out 0.20 moles of sodium chloride, how many grams should you weigh out? 7) How many molecules of water are there in 75.0 g of water? 8) How many moles of iron atoms are 5.50x1025 Fe atoms? 9) How many grams of carbon dioxide contains 4.50x1023 molecules of CO2? 10) How many molecules of sulfur trioxide are in 4.33 moles of sulfur trioxide? 11) Calculate the % composition of each element in the following compounds Aluminum Carbonate = ________ %Al ________ %C ________ %O Barium Cyanide = _______ %Ba ________ %C ________ %N Iron (III) Hydroxide = ________ %Fe ________ %O ________ %H Copper (II) Nitrate = _______ %Cu ________ %N ________ %O 12) Calculate the empirical formulas of the following compounds given their percent compositions. a) 5.926% H, 94.07% O b) 70.057%C, 5.923%H, 23.50%O c) 47.35%C, 10.60% H, 42.05% O d) What acid contains 3.69%H, 37.77%P, and 58.54%O? 13) Given the following molecular formulas, give the empirical formula a) C6H12O6 _________________ d) H2O2 __________________ b) C12H22O11 _________________ e) Ba3(PO4)2 __________________ c) C2H4Br2 _________________ f) C6H3N3O6 __________________ 14) Given the following empirical formulas and molecular masses, calculate the molecular formulas g mol g b) CH2O, 150.1 mol g c) CHCl3, 119.4 mol g d) C2H3O2, 118.1 mol a) C2H4O, 88.1 molecular formula = ____________ molecular formula = ____________ molecular formula = ____________ molecular formula = ____________ 15) If a compound has a molar mass of 88.1 g/mol and is composed of 9.15% H, 36.32% O, and 54.53% C, what is the molecular formula of the compound? 16) If a compound has a molar mass of 164.3 g/mol and is composed of 12.27% H and 87.73% C, what is the molecular formula of the compound? 17) Given the following lab data, determine the empirical formula of the compound. A 2.50 g sample of a hydrate containing copper, chlorine and water was measured out. It was heated until it came to a constant mass of 1.50 g. The remaining solid was allowed to react with a metal to produce 0.71 g of copper. The remainder of the compound was assumed to be chlorine. a) What was the mass of water in the compound? b) What was the number of moles of water in the compound? c) What was the mass of copper in the compound? d) What was the number of moles of copper in the compound? e) What was the mass of chlorine in the compound? f) What was the number of moles of chlorine in the compound? Equations and Reaction Types 1) What fundamental law of chemistry requires that equations be balanced? 2) a) b) c) d) What do the following symbols mean in a chemical equation? D (g) e) ¾ ¾® (l) f) (s) g) (aq) KI h) ¾¾® 3) Fill in the table to remind you of how to recognize a type of reaction based on just the reactants. When the Reactants Are:__________ It Means the Reaction is:__________ A hydrocarbon and oxygen Combustion 4) Identify the diatomic elements. 5) Balance the following equations by adding coefficients. Identify the type of each reaction. a) _____Ca(OH)2 + _____HBr _____CaBr2 + _____H2O Type: ____________ b) _____Mg + _____AlI3 _____MgI2 + _____Al Type: ____________ c) _____C3H8 + _____O2 _____CO2 + _____H2O Type: ____________ d) _____AgOH _____Ag2O + _____H2O Type: ____________ e) _____Cl2 + _____Fe _____FeCl3 Type: ____________ f) _____Ba(NO3)2 + _____Al2(SO4)3 _____Al(NO3)3 + _____BaSO4 Type: ____________ 6) Given the following description, write a balanced chemical equation. a) Copper will react with bromine to make copper(I)bromide. b) Sodium carbonate reacts with silver nitrate to make silver carbonate and sodium nitrate. c) Cyclohexane (C6H12) burns in the presence of oxygen to give carbon dioxide and water vapor. d) Zinc will react with lead (IV) bromide to make lead and zinc bromide. e) Calcium carbonate decomposes to calcium oxide and a gas. f) Hydrochloric acid reacts with magnesium hydroxide to make magnesium chloride and water. 7) Given just the reactants, identify the type of reaction and write a balanced equation. a) _____CaCl2 + _____AgNO3 Type: ____________ b) _____N2 + _____Mg Type: ____________ c) _____Zn + _____CuNO3 Type: ____________ d) _____C5H12 + _____O2 Type: ____________ e) _____Sr(OH)2 + _____H2SO4 Type: ____________ f) _____Cu(OH)2 Type: ____________ 1) Given the equation for the reaction of copper (II) chloride and aluminum 3CuCl2 (aq) + 2Al(s) 2AlCl3 (aq) + 3Cu(s) a) How many moles of CuCl2 will react with 0.54 moles of aluminum? b) How many moles of copper would precipitate when 1.2 moles of aluminum react? 2) For the reaction of hydrochloric acid and barium hydroxide, 2HCl(aq) + Ba(OH)2 (s) BaCl2 (aq) + 2H2O(l) a) How many moles of hydrochloric acid will react with 0.750 grams of barium hydroxide. b) How many grams of barium hydroxide should be used to produce 3.40 moles of water? 3) For the reaction of lead (II) nitrate and potassium iodide to produce lead (II) iodide and potassium nitrate, write a balanced equation: a) How many grams of potassium nitrate are needed to cause 0.450 grams of lead (II) nitrate to completely react? 5) If you are making hamburgers and you have the following ingredients: 16 buns, 24 hamburger patties, 36 pickle slices, 16 slices of cheese, and 30 strips of bacon… How many bacon cheeseburgers can you make if each one requires 1 bun, 1 hamburger, 3 pickles, 1 slice of cheese and 3 strips of bacon? How many pickle slices will you have left over? Conversion factors Grams Grams Moles Reactant Moles Product Liters Liters 3-Step Stoichiometry 1. If needed, __________________ the equation. 2. If you are not given moles, find ____________ by _______________ the given number by the conversion factor for the given unit. 3. ________________ by the mole ratio. The mole ratio is the ________________________ of the product divided by the reactant. 4. ________________ by the conversion factor needed to find the unit requested for the product in the problem. Mg(s) + HCl(aq) MgCl2(aq) + H2(g) How many grams of magnesium chloride are formed from 4.95g of magnesium? 4.95g Mg x __________________ x ___________________x__________________ = g MgCl2 How many grams of hydrogen gas are formed from 2.56g of magnesium? 2.56g Mg x ___________________ x ___________________ x ___________________ = H2(g) + O2(g) g H2 H2O(g) How many grams of water vapor are formed from 1.7 grams of hydrogen gas? 1.7g H2 x ___________________ x ____________________ x ___________________ = g H2O Limiting Reactants & Theoretical Yield Theoretical yield is the amount of product in______________ that should ideally be formed in a reaction. To Percent Yield _____________________________ x 100 A ___________ percent yield is good! Actual Yield is the amount of ________________ in grams measured at the end of an experiment and is ______________ in a word problem. Possible phrases that are given with the actual yield value include: grams were _______________, grams were _______________, or grams _______________. For more SOL practice online go to: http://education.jlab.org/solquiz/index.html Click on “Chemistry” and “More options, please.” Then select “Molar Relationships” 2. Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s) When copper reacts with silver nitrate according to the equation, the number of grams of copper required to produce 432 grams of silver is — A 31.5 g B 127 g _ C 216 g D 252 g 3. H2(g) + I2 (g) 2HI(g) Ten moles of hydrogen and ten moles of iodine were put into a sealed 1 L container at 490C and allowed to react. After a while, there were still small amounts of unreacted hydrogen and iodine, but the hydrogen iodide concentration became constant. This is because — F there was not enough H to react with all of the I H the reaction reached a state of equilibrium G the hydrogen iodide was reacting with the container J iodine loses its reactivity at high temperature 6. A solution contains 225 g of glucose, C6H12O6, dissolved in enough water to make 0.825 L of solution. What is the molarity of the solution? A 0.66 M B 0.97 M C 1.03 M D 1.52 M 4. 2C2H6 + 7O2 → 4CO2 + 6H2O To produce 12 mol of water, how many mol of oxygen gas are needed? A2 B7 C9 D 14 5. The number of grams of oxygen required for the complete combustion of 4.00 g of methane (CH4) is — F 4.00 g G 8.00 g H 16.0 g _ J 32.0 g 3. Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s) When copper reacts with silver nitrate according to the equation, the number of grams of copper required to produce 432 grams of silver is — A 31.5 g B 127 g _ C 216 g D 252 g 12. Carbon disulfide is prepared industrially by reacting carbon with sulfur dioxide according to this equation. 5C + 2SO2 CS2 + 4CO If 5.9 moles of carbon react, how many moles of CS2 are produced? F 0.077 moles G 1.2 moles _ H 1.5 moles J 30 moles Check your answers: 1= 2= 8= 9= 3= 10 = 4= 11 = 5= 12 = 6= 13 = 7=