WHITE PAPER Equations and Example Benchmark Calculations within the aspenONE® Engineering Safety Analysis Environment V8.8: Two-phase Orifice Sizing, Vapor Noise and Reaction Forces Craig Powers, Principal Software Developer, Aspen Technology, Inc. Introduction Introduced in Aspen HYSYS® V8.3, the Safety Analysis Environment provides a tool for adding pressure relief devices and calculating relief loads inside Aspen HYSYS. Leveraging this tool within the rigorous Aspen HYSYS simulator, and in combination with Aspen Flare System Analyzer, provides an integrated solution for pressure relief analysis (PRA) work. This white paper contains hand calculations for two-phase orifice sizing and vapor noise and reaction forces inside the Safety Analysis Environment, helping you to validate the calculations of this tool within Aspen HYSYS. Leung Omega Method There are two forms of the Leung Omega Method that are implemented in the Safety Analysis Environment. One form is for cases that are saturated or two-phase at relief conditions, upstream of the relief valve. The other form is for cases that are subcooled liquid upstream of the relief valve, with flashing occurring across the valve that produces a twophase stream at the valve outlet. Non-Subcooled Omega Method Equations The governing equations for the application of the Omega Method are obtained from Appendix C of API Standard 520 Part I.1 It is a two-point method, meaning that physical properties are required at two thermodynamic state points. For the non-subcooled method, the first state point is relief conditions. The second state point is obtained by an isentropic flash to 90% of the relief pressure. Aspen HYSYS® uses an isenthalpic flash to 90% of the relief pressure in place of an isentropic flash. With this information, the required orifice area may be obtained using the following equations below. Eq. 1 ππ = 9× π£π£! ππ! − 1 = 9× − 1 π£π£! ππ! In the equation above, ω is the Omega parameter, v0 and v9 are specific volumes at upstream and 90% conditions, respectively, and ρ0 and ρ9 are density at upstream and 90% conditions, respectively. Eq. 2 Eq. 3 ππ! = ππ! ≅ 1 + 1.0446 − 0.0093431 ππ ×ππ !!.!"#"$ ππ! !!.!"#$%!!.!"#$%& !" ! ππ! = ππ! ππ! In the equation above, ηc is the critical pressure ratio, Pc is the pressure corresponding to critical flow at the nozzle throat in the relief valve in absolute units, Pa is the total back pressure at the outlet of the valve in absolute units, and P0 is the upstream relief pressure in absolute units. If ηc exceeds ηa, then the flow through the relief valve is critical, and the following equation should be used to calculate the maximum mass flux, where G is the maximum mass flux through the valve in lb/s-ft² or kg/s-m², P0 is in psia or Pa, v0 is in ft³/lb or m³/kg, and ρ0 is in lb/ft³ or kg/m³. C1 = 68.09 in U.S. customary units, or 1.0 in SI units. 2 Equations and Example Benchmark Calculations within the aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215 Eq. 4 πΊπΊ = πΆπΆ! ππ! ππ! ππ! ππ! = ππ! π£π£! ππ ππ If ηc does not exceed ηa, then the flow through the relief valve is subcritical, and the following equation should be used to calculate the maximum mass flux, where units are as in (Eq. 4). Eq. 5 πΊπΊ = πΆπΆ! ππ! ππ! 1 ππ −1 +1 ππ! −2 ππ ln ππ! + ππ − 1 1 − ππ! Once the maximum mass flux has been obtained, the required effective discharge area may be calculated by using Equation 6, where A is the required effective discharge area in mm², w is the required relief load in kg/h, Kd is the discharge coefficient of the valve, Kb is the backpressure correction factor (applicable to balanced bellows valves only), Kc is the combination capacity factor, and Kv is the viscosity correction factor. C2 = 0.04 for U.S. customary units, 277.8 for SI units. Eq. 6 π΄π΄ = πΆπΆ! π€π€ πΎπΎ! πΎπΎ! πΎπΎ! πΎπΎ! πΊπΊ When an orifice area has been selected, Equation 6 may be rearranged to find the rated capacity of the valve, shown in Equation 7: Eq. 7 π€π€!"# = π΄π΄ πΎπΎ! πΎπΎ! πΎπΎ! πΎπΎ! πΊπΊ 277.8 Example with Critical Flow The example is based on the following conditions: Composition 15% propane, 25% n-butane, 30% n-pentane, 30% n-heptane using the Aspen HYSYS PR package for physical properties Relief conditions 8.03 barg / 101.2 C Required relief load 63,000 kg/h 63,000 kg/h Based on the relief pressure of 8.03 barg, the 90% intermediate flash pressure is at 7.227 barg. Setting up a stream in Aspen HYSYS at the relief conditions and running it through an isenthalpic flash will yield the following properties: ρ0 = 112.0 kg/m³ ρ9 = 90.73 kg/m³ 3 Equations and Example Benchmark Calculations within the aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215 The Omega parameter may be calculated using (Eq. 1): 112.0 − 1 = 2.110 90.73 ππ = 9× The critical pressure ratio and backpressure ratio may be calculated using (Eq. 2) and (Eq. 3): ππ! = ππ! = 0.6989 1.01325 = 0.1120 8.03 + 1.01325 Figure 1: Two-phase critical flow case calculated in Aspen HYSYS Because ηc is larger than ηa, flow across the relief valve is choked; therefore, the maximum mass flux is calculated using (Eq. 4). πΊπΊ = 0.6989 112 9.043 ×100,000 ππππ/ππππππ = 4,844 kg/s-­βm² 2.110 Assuming that all capacity coefficients are 1.0, aside from the discharge coefficient which is 0.85 in accordance with guidance from API, the required area is calculated using (Eq. 6): π΄π΄ = 4 277.8 63,000 = 4,250 mm² 0.85 4,844 Equations and Example Benchmark Calculations within the aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215 For a selected Q orifice with an effective area of 7129 mm², the rated capacity is calculated using (Eq. 7): π€π€!"# = 0.85 4,844 7,129 = 105,700 kg/h 277.8 The results calculated above are compared to results obtained in Aspen HYSYS in Table 1. Variable Units Example Calculation Aspen HYSYS kg/h 63,000 63,000 Relief Pressure (P0) barg 8.03 8.03 Mass Density at 90% (ρ9) Required Relief Load (w) 90% Pressure (P9) Mass Density at Relief (ρ0) 7.227 barg kg/m 3 112.0 112.0 kg/m 3 90.73 88.34 Omega Parameter (ω) Critical Flow Ratio (ηc) 2.110 0.6989 Flow Type Maximum Mass Flux (G) Required Area (A) Rated Capacity (wmax) Critical kg/s-m mm 2 2 kg/h Blue = Calculation input Critical 4,844 4,250 4,448 105,700 101,000 Gray = Calculated value Table 1: Comparison of example calculation and Aspen HYSYS calculation for critical two-phase flow Example with Subcritical Flow The example is based on the following conditions: Composition 15% propane, 25% n-butane, 30% n-pentane, 30% n-heptane using the Aspen HYSYS PR package for physical properties Relief conditions 154 kPag / 85 C Required relief load 20,000 kg/h Back pressure 60 kPa superimposed Based on the relief pressure of 1.54 barg, the 90% intermediate flash pressure is at 1.28 barg. Setting up a stream in Aspen HYSYS at the relief conditions and running it through an isenthalpic flash will yield the following properties: ρ0 = 8.264 kg/m³ ρ9 = 7.335 kg/m³ 5 Equations and Example Benchmark Calculations within the aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215 The Omega parameter may be calculated using (Eq. 1): 8.264 − 1 = 1.140 7.335 ππ = 9× The critical pressure ratio and backpressure ratio may be calculated using (Eq. 2) and (Eq. 3): ππ! = ππ! = 0.6234 1.01325 + 0.6 = 0.6318 1.54 + 1.01325 Figure 2: Two-phase subcritical flow case calculated in Aspen HYSYS Because ηc is smaller than ηa, flow across the relief valve is unchoked, and the maximum mass flux is calculated using (Eq. 5), yielding a maximum mass flux G = 830 kg/m²-s. Assuming that all capacity coefficients are 1.0, aside from the discharge coefficient which is 0.85 in accordance with guidance from API, the required area is calculated using (Eq. 6): π΄π΄ = 277.8 20,000 = 7,870 mm² 0.85 830 For a selected R orifice with an effective area of 10322.5 mm², the rated capacity is calculated using (Eq. 7): π€π€!"# = 0.85 830 10322.5 = 26,230 kg/h 277.8 The results calculated above are compared to results obtained in Aspen HYSYS in Table 2. 6 Equations and Example Benchmark Calculations within the aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215 Variable Units Example Calculation Aspen HYSYS Required Relief Load (w) kg/h 20,000 20,000 Relief Pressure (P0) barg 1.54 1.54 Mass Density at 90% (ρ9) kg/m3 90% Pressure (P9) Mass Density at Relief (ρ0) 1.28 barg kg/m 3 Omega Parameter (ω) Critical Flow Ratio (ηc) 8.264 8.264 7.335 7.337 1.140 0.6234 Flow Type Subcritical Maximum Mass Flux (G) Required Area (A) Rated Capacity (wmax) kg/s-m mm 2 2 kg/h Blue = Calculation input Subcritical 830 7,870 7,710 26,230 26,780 Gray = Calculated value Table 2: Comparison of example calculation and Aspen HYSYS calculation for subcritical two-phase flow Subcooled Omega Method Equations As with the non-subcooled Omega Method, the subcooled Omega Method is a two-point method. The first point remains the same with the conditions at the PRV inlet. For the second point, the relief stream is flashed isentropically to 90% of its saturation pressure corresponding to the PRV inlet temperature T0. As with the non-subcooled method, flow may be critical or subcritical; however, the subcooled Omega Method also requires a determination as to whether the relief conditions correspond to “high” or “low” subcooling; that is, whether the fluid will begin to flash in the inlet line, or whether it will flash at the valve throat. The omega parameter is calculated using a similar equation to (Eq. 1), where ρβ0 is the liquid density at the PRV inlet in kg/m³. Eq. 8 ππ! = 9× ππβππ" − 1 ππ! “High” or “low” subcooling is determined via the transition saturation pressure ratio, which is calculated below in Equation 9 and 10, where ηst is the transition saturation pressure ratio, ηs is the saturation pressure ratio, Ps is the saturation pressure in absolute units, and P0 is the upstream pressure in absolute units. Eq. 9 Eq. 10 7 ππ!" = ππ! = 2ππ! 1 + 2ππ! ππ! ππ! Equations and Example Benchmark Calculations within the aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215 If ηst exceeds ηs, then relief is considered to lie in the “high” subcooling region, and flow will necessarily be critical unless the total back pressure exceeds the saturation pressure (but in this case, the fluid is liquid across the valve, and the API liquid sizing will be sufficient to calculate the orifice size). Otherwise, relief is considered to lie in the “low” subcooling region, and a check must be made to determine if the flow across the PRV is critical or subcritical. The critical pressure ratio may be estimated as shown below in Equation 11. Eq. 11 ππ! ≅ ππ! 2ππ! 2ππ! − 1 1− 1− 1 2ππ! − 1 ππ! 2ππ! The back pressure ratio ηa is calculated using (Eq. 3) as with the non-subcooled method. For “low” subcooling, the maximum mass flux is calculated using Equation 12 below. Eq. 12 πΊπΊ = πΆπΆ! ππ! ππ! ππ! ππβππ" 2 1 − ππ! + 2 ππ! ππ! ln − ππ! − 1 ππ! − ππ ππ! ππ −1 +1 ππ For critical flow, η=ηc; for subcritical flow, η=ηa. Pressure is in psia or Paa. C1 = 68.09 for U.S. customary units, 1.0 for SI units. For “high” subcooling, the maximum mass flux is calculated using Equation 13 below. Eq. 13 πΊπΊ = πΆπΆ! 2 ππβππ" ππ! − ππ! The pressure is measured in psia or Paa. Given a required relief load in lb/h or kg/h, the required area and rated capacity may be calculated using (Eq. 6) and (Eq. 7). Example with Low Subcooling, Critical Flow The example is based on the following conditions: Composition 15% propane, 30% isobutane, 30% n-butane, 25% isopentane using the Aspen HYSYS PRSV package for physical properties Relief conditions 242 psig, 205 F Required relief load 92,590 lb/h Setting up a stream in Aspen HYSYS at the relief conditions and flashing appropriately, yields the following properties: ρβ0 = 29.23 lb/ft³ Ps = 241.4 psia P9 = 217.3 psia ρ9 = 17.53 lb/ft³ 8 Equations and Example Benchmark Calculations within the aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215 The omega parameter is calculated using (Eq. 8): ππ! = 9× 29.23 − 1 = 6.011 17.53 Figure 3: Low subcooled critical flow case calculated in Aspen HYSYS The transition saturation pressure ratio is calculated using (Eq. 9): ππ!" = 2 6.011 = 0.923 1 + 2 6.011 The saturation pressure ratio is 0.956. Because this is greater than the transition ratio, this case involves “low” subcooling, and the critical pressure ratio is calculated using (Eq. 11): ππ! ≅ 0.923 2 6.011 2 6.011 − 1 1− 1− 1 2 6.011 − 1 0.923 2 6.011 = 0.8633 The back pressure ratio of 0.0573 is much lower than the critical pressure ratio, so the flow is critical. The maximum mass flux is calculated using (Eq. 12) with η=ηc. The result shows that G = 2,150 lb/s-ft². Assuming that all capacity coefficients are 1.0, aside from the discharge coefficient which is 0.65 in accordance with guidance from API, the required area is calculated using (Eq. 6): π΄π΄ = 9 0.04 92,590 = 2.651 in² 0.65 2,150 Equations and Example Benchmark Calculations within the aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215 For a selected L orifice with an effective area of 2.853 in², the rated capacity is calculated using (Eq. 7): π€π€!"# = 0.65 2,150 2.853 = 99,640 lb/h 0.04 The results calculated above are compared to results obtained in Aspen HYSYS in Table 3. Variable Units Example Calculation Aspen HYSYS Required Relief Load (w) lb/h 92,590 92,590 Relief Pressure (P0) psig 242 242.0 226.7 psig 241.4 psia psig 202.6 Mass Density at Relief (ρβ0) lb/ft3 29.23 lb/ft 17.53 Saturation Pressure (Ps) 90% Pressure (P9) Mass Density at 90% (ρ9) 3 Omega Parameter (ω) 6.011 Transition Subcool Ratio (ηst) Critical Flow Ratio (ηc) 0.923 0.8633 Flow Type Maximum Mass Flux (G) Required Area (A) Rated Capacity (wmax) 17.51 Low Subcool, Critical lb/s-ft in 2 2 lb/h Blue = Calculation input Critical 2,150 2.651 2.663 99,640 99,180 Gray = Calculated value Table 3: Comparison of example calculation and Aspen HYSYS calculation for low subcooled critical flow Example with Low Subcooling, Subcritical Flow The example is based on the following conditions: Composition 15% propane, 30% isobutane, 30% n-butane, 25% isopentane using the Aspen HYSYS PRSV package for physical properties Relief conditions 44 psig, 87.5 F Required relief load 92,590 lb/h Back pressure 40 psi superimposed Setting up a stream in Aspen HYSYS at the relief conditions and flashing appropriately yields the following properties: ρβ0 = 35.17 lb/ft³ Ps = 57.13 psia P9 = 51.4 psia ρ9 = 13.72 lb/ft³ Equations and Example Benchmark Calculations within the 10 aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215 Figure 4: Low subcooled subcritical flow case calculated in Aspen HYSYS The omega parameter is calculated using (Eq. 8): ππ! = 9× 35.17 − 1 = 14.07 13.72 The transition saturation pressure ratio is calculated using (Eq. 9): ππ!! = 2 14.07 = 0.9657 1 + 2 14.07 The saturation pressure ratio is 0.9733. Because this is greater than the transition ratio, this case involves “low” subcooling. The critical pressure ratio is calculated using (Eq. 11): ππ! ≅ 0.9733 2 14.07 2 14.07 − 1 1− 1− 1 2 14.07 − 1 0.9733 2 14.07 = 0.9130 The back pressure ratio of 0.9319 is higher than the critical pressure ratio, so the flow is subcritical. The maximum mass flux is calculated using (Eq. 12) with η=ηa=0.9319. The result is that G = 765.4 lb/s-ft². Assuming that all capacity coefficients are 1.0, aside from the discharge coefficient which is 0.65 in accordance with guidance from API, the required area is calculated using (Eq. 6): π΄π΄ = 11 0.04 92,590 = 7.444 in² 0.65 765.4 Equations and Example Benchmark Calculations within the aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215 For a selected Q orifice with an effective area of 11.05 in², the rated capacity is calculated using (Eq. 7): π€π€!"# = 0.65 765.4 11.05 = 137,400 lb/h 0.04 The results calculated above are compared to results obtained in Aspen HYSYS in Table 4. Variable Units Example Calculation Aspen HYSYS Required Relief Load (w) lb/h 92,590 92,590 Relief Pressure (P0) psig 44 44.00 42.43 psig 57.13 psia psig 36.7 Mass Density at Relief (ρβ0) lb/ft3 35.17 lb/ft3 13.72 Saturation Pressure (Ps) 90% Pressure (P9) Mass Density at 90% (ρ9) Omega Parameter (ω) 14.07 Transition Subcool Ratio (ηst) Critical Flow Ratio (ηc) 0.9657 0.9130 Flow Type Maximum Mass Flux (G) Required Area (A) Rated Capacity (wmax) 13.75 Low Subcool, Critical lb/s-ft in 2 2 lb/h Blue = Calculation input Critical 765.4 7.444 7.450 137,400 137,300 Gray = Calculated value Table 4: Comparison of example calculation and Aspen HYSYS calculation for low subcooled, subcritical flow Example with High Subcooling The example is based on the following conditions: Composition 15% propane, 30% isobutane, 30% n-butane, 25% isopentane using the Aspen HYSYS PRSV package for physical properties Relief conditions 242 psig, 188.3 F Required relief load 92,590 lb/h Setting up a stream in Aspen HYSYS at the relief conditions and flashing appropriately, yields the following properties: ρβ0 = 30.34 lb/ft³ Ps = 203.1 psia P9 = 182.8 psia ρ9 = 17.40 lb/ft³ Equations and Example Benchmark Calculations within the 12 aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215 Figure 5: High subcooled critical flow case calculated in Aspen HYSYS The omega parameter is calculated using (Eq. 8): ππ! = 9× 30.34 − 1 = 6.693 17.4 The transition saturation pressure ratio is calculated using (Eq. 9): ππ!" = 2 6.693 = 0.9305 1 + 2 6.693 The saturation pressure ratio is 0.7912. Because this is less than the transition ratio, this case involves “high” subcooling. The critical pressure ratio is equal to the saturation pressure ratio. The maximum mass flux is calculated using (Eq. 13): πΊπΊ = 68.09 2 30.34 256.7 − 203.1 = 3,883 lb/s-­βft² Assuming that all capacity coefficients are 1.0, aside from the discharge coefficient which is 0.65 in accordance with guidance from API, the required area is calculated using (Eq. 6): π΄π΄ = 0.04 92,590 = 1.467 in² 0.65 3,883 For a selected K orifice with an effective area of 1.838 in², the rated capacity is calculated using (Eq. 7): π€π€!"# = 0.65 3,883 1.838 = 116,000 lb/h 0.04 The results calculated above are compared to results obtained in Aspen HYSYS in Table 5. Equations and Example Benchmark Calculations within the 13 aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215 Variable Units Example Calculation Aspen HYSYS Required Relief Load (w) lb/h 92,590 92,590 Relief Pressure (P0) psig 242 242.0 188.4 psig 203.1 psia psig 168.1 Mass Density at Relief (ρβ0) lb/ft3 30.34 lb/ft3 17.40 Saturation Pressure (Ps) 90% Pressure (P9) Mass Density at 90% (ρ9) Omega Parameter (ω) 6.693 Transition Subcool Ratio (ηst) 0.9305 Flow Type Maximum Mass Flux (G) Required Area (A) Rated Capacity (wmax) 17.38 High Subcool, Critical lb/s-ft in 2 2 lb/h Blue = Calculation input Critical 3,883 1.467 1.473 116,000 115,600 Gray = Calculated value Table 5: Comparison of example calculation and Aspen HYSYS calculation for high subcooled, critical flow Direct Integration Method The direct integration method involves evaluating thermodynamic properties of the relieving stream at a number of state points and then numerically integrating the nozzle equation to determine the maximum mass flux. This equation is the theoretical basis for every orifice method, so the direct integration method is applicable to any type of flow, single or multi-phase. Equations The nozzle equation is shown below, where G is the mass flux in lb/ft²-s or kg/m²-s, v is the specific volume in ft³/lb or m³/kg, and dp is the differential pressure increment in lbf/ft² or Pa. Eq. 14 πΊπΊ ! = −2ππ! π£π£ ! π£π£ ππππ This is approximated as shown below, where vΜ is the average specific volume over the pressure increment Δp. Eq. 15 πΊπΊ ! ≅ −2ππ! π£π£ ! π£π£ βππ The sum is performed from the relief pressure until either a maximum value of G is reached or the back pressure Pa is reached. If the maximum in G occurs above Pa, then the flow is choked. Equations and Example Benchmark Calculations within the 14 aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215 Example The example is based on the following conditions: Composition 25% n-octane, 35% n-decane, 30% n-C11, 10% nitrogen using the Aspen HYSYS SRK package for physical properties Relief conditions 176 psig, 122 F Required relief load 138,900 lb/h A property table may be used to obtain the mass density along an isentropic path for numerical integration, as shown below. Pressure psia Mass Density lb/ft3 Specific Volume ft3/lb gcvΜ βP ft²/s² Mass Flux lb/ft2-s 190.7 23.21 0.0431 0.0 0.0 180.7 22.48 0.0445 2028 1432 170.7 21.71 0.0461 2098 1972 160.7 20.90 0.0478 2175 2347 150.7 20.06 0.0499 2263 2625 140.7 19.18 0.0521 2363 2835 130.7 18.25 0.0548 2477 2988 120.7 17.28 0.0579 2610 3092 110.7 16.25 0.0615 2766 3150 100.7 15.17 0.0659 2952 3164 90.7 14.04 0.0712 3177 3133 Note that the mass flux reaches a maximum at a pressure of 100.7 psia, indicating that flow is choked and the relief mass flux is 3164 lb/ft²-s. Equations and Example Benchmark Calculations within the 15 aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215 Figure 6: Direct integration case calculated in Aspen HYSYS Assuming that all capacity coefficients are 1.0, aside from the discharge coefficient which is 0.85 in accordance with guidance from API for two-phase flow at relief conditions, the required area is calculated using (Eq. 6): π΄π΄ = 0.04 138,900 = 2.066 in² 0.85 3,164 For a selected L orifice with an effective area of 2.853 in², the rated capacity is calculated using (Eq. 7): π€π€!"# = 0.85 3,164 2.853 = 191,800 lb/h 0.04 The results calculated above are compared to results obtained in Aspen HYSYS in Table 6. Variable Units Example Calculation Aspen HYSYS Required Relief Load (w) lb/h 138,900 138,900 psig 176 176.0 122 122.0 3,164 3,114 Relief Pressure (P0) Relief Temperature (T0) F Rated Capacity (wmax) lb/h Maximum Mass Flux (G) Required Area (A) lb/s-ft in 2 2 Blue = Calculation input 2.066 2.099 191,800 188,800 Gray = Calculated value Table 6: Comparison of example calculation and Aspen HYSYS calculation for direct integration Equations and Example Benchmark Calculations within the 16 aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215 Noise Equations The equations for computing noise level for atmospheric relief valves are given in section 5.8.10.3 of API Standard 521.2 The noise level at 30 m from the point of discharge is calculated using the following equation below, where w is the mass flow through the valve in kg/h, c is the speed of sound in the gas at the valve in m/s, and L is the sound level in decibels. Eq. 16 πΏπΏ!" = πΏπΏ + 10 log!" 1 π€π€ ππ ! 7200 The speed of sound may be computed as shown below, where k is the ideal specific heat ratio in the gas, T is the temperature in K, and M is the molecular weight of the gas. Eq. 17 ππ = 91.2 ππ ππ ππ The value of L in (Eq. 16) is read from a figure in the text. It may be approximated using two semilog curve fits shown below, where X is the pressure ratio across the pressure relief valve. Eq. 18 πΏπΏ = 39.461 ln ππ + 12.648 βΆ ππ ≤ 2.866 2.1716 ln ππ + 51.914 βΆ ππ > 2.866 Example The example is based on the following conditions: Composition 100% air using the Aspen HYSYS PR package for physical properties Relief conditions 330 kPaa, 311 K Required relief load 52,560 kg/h Setting up a stream in Aspen HYSYS at the relief conditions will yield the following properties: M = 28.95 k = 1.404 Equations and Example Benchmark Calculations within the 17 aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215 Figure 7: Noise example calculated in Aspen HYSYS The speed of sound may be calculated using (Eq. 17) as: ππ = 91.2 1.404 311 = 354.2 m/s 28.95 Based on a pressure ratio of 330⁄101.325=3.26, the contribution due to pressure ratio may be estimated by (Eq. 18) to be 54.5 dB. Then, the total noise level is calculated using (Eq. 16): πΏπΏ!" = 54.5 + 10 log!" 1 52,560 354.2 7200 ! = 114.1 dB The results calculated above are compared to results obtained in Aspen HYSYS in Table 7. Variable Units Example Calculation Aspen HYSYS Required Relief Load (w) kg/h 52,560 52,560 330 kPaa 2.287 barg 311 K 37.85 C 114.1 114.1 Relief Pressure (P0) Relief Temperature (T0) Sound Level (L30) dB Blue = Calculation input Gray = Calculated value Table 7: Comparison of example calculation and Aspen HYSYS calculation for noise Figure 8: Reaction force example calculated in Aspen HYSYS Equations and Example Benchmark Calculations within the 18 aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215 Reaction Forces Equations The equations for computing reaction forces on the outlet piping of atmospheric relief valves are given in section 4.4.1 of API Recommended Practice 520 Part II.3 The reaction force due to vapor discharge is calculated using the following equation below, where F is the reaction force in N, w is the required relief load in kg/h, k is the ideal specific heat ratio of the gas, T is the discharge temperature in K, M is the molecular weight of the gas, A is the area of the pipe at the point of discharge in mm², and p3 is the static pressure at the outlet in barg (that is, 0 for flow that is unchoked at the outlet, or the choke pressure for flow that is choked at the outlet). Eq. 19 πΉπΉ = 1 π€π€ 27.9 ππ ππ + 0.1 π΄π΄ ππ! ππ + 1 ππ Example The example is based on the following conditions: Composition 30% propane, 70% n-butane using the Aspen HYSYS SRK package for physical properties Relief conditions 4.4 barg, 92.15 C Required relief load 36,970 kg/h Fluid properties at relief may be observed to be: M = 53.92 k = 1.081 P* = 0.8201 bara The reaction force may be calculated using (Eq. 19), as shown below. Because the choke pressure is less than atmospheric pressure, the second term may be neglected. πΉπΉ = 1 37,150 27.9 1.081 92.15 + 273.15 = 2,498 N 2.081 53.92 The results calculated above are compared to results obtained in Aspen HYSYS in Table 8. Variable Units Example Calculation Aspen HYSYS Required Relief Load (w) kg/h 37,150 37,150 C 92.15 92.15 N 2,498 2,497 Relief Temperature (T) Reaction Force (F) Blue = Calculation input Gray = Calculated value Table 8: Comparison of example calculation and Aspen HYSYS calculation for reaction force Equations and Example Benchmark Calculations within the 19 aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215 Conclusion Safety is of the highest priority to every process, and ensuring accurate, validated calculations is a key component of this work. To view additional validation papers, access tutorial documents and videos, and learn more information about the tools AspenTech provides to address process safety work, please visit the safety page on our company website, today! References 1. American Petroleum Institute, API Standard 520 Part I 9th Ed.: Sizing, Selection, and Installation of Pressure-relieving Devices, Washington, DC: API Publishing Services, 2014. 2. American Petroleum Institute, API Standard 521 6th Ed.: Pressure-relieving and Depressuring Systems, Washington, DC: API Publishing Services, 2014. 3. American Petroleum Institute, API Recommended Practice 520 Part II 5th Ed., Reaffirmed, Washington: API Publishing Services, 2011. Equations and Example Benchmark Calculations within the 20 aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-8231-1215 AspenTech is a leading supplier of software that optimizes process manufacturing—for energy, chemicals, engineering and construction, and other industries that manufacture and produce products from a chemical process. With integrated aspenONE® solutions, process manufacturers can implement best practices for optimizing their engineering, manufacturing, and supply chain operations. As a result, AspenTech customers are better able to increase capacity, improve margins, reduce costs, and become more energy efficient. To see how the world’s leading process manufacturers rely on AspenTech to achieve their operational excellence goals, visit www.aspentech.com. Worldwide Headquarters Aspen Technology, Inc. 20 Crosby Drive | Bedford, MA 01730 | United States phone: +1-781-221-6400 | fax: +1-781-221-6410 | info@aspentech.com Regional Headquarters Houston, TX | United States phone: +1-281-584-1000 São Paulo | Brazil phone: +55-11-3443-6261 Reading | United Kingdom phone: +44-(0)-1189-226400 Singapore | Republic of Singapore phone: +65-6395-3900 Manama | Bahrain phone: +973-13606-400 For a complete list of offices, please visit www.aspentech.com/locations Equations and Example Benchmark Calculations within the 21 aspenONE® Engineering Safety Analysis Environment ©2015 Aspen Technology Inc. 11-7852-0915