Chemistry I Exam 1 review Name:_______________________ For the multiple choice problems, mark the correct answer on the scantron with the corresponding problem number. For the open ended problems, show your work on the test, and make certain units are present in all responses. 1. The distance between carbon atoms in ethylene is 134 picometers. Which of the following expresses that distance in meters? A) 1.34 × 10–13 m B) 1.34 × 10–12 m C) 1.34 × 10–10 m D) 1.34 × 10–7 m E) 1.34 × 10–6 m 2. A) B) C) D) E) A large pizza has a diameter of 15 inches. Express this diameter in centimeters. 38 cm 24 cm 18 cm 9.3 cm 5.9 cm 3. A flask has a mass of 78.23 g when empty and 593.63 g when filled with water. When the same flask is filled with concentrated sulfuric acid, H2SO4, its mass is 1026.57 g. What is the density of concentrated sulfuric acid? (Assume water has a density of 1.00 g/cm3 at the temperature of the measurement.) A) 1.992 g/cm3 B) 1.840 g/cm3 C) 1.729 g/cm3 D) 1.598 g/cm3 E) 0.543 g/cm3 4. Acetone, which is used as a solvent and as a reactant in the manufacture of Plexiglas®, boils at 56.1°C. What is the boiling point in degrees Fahrenheit? A) 159°F B) 133°F C) 101°F D) 69.0°F E) 43.4°F Page 1 1143 Summer 2004 5. Isopropyl alcohol, commonly known as rubbing alcohol, boils at 82.4°C. What is the boiling point in kelvins? A) 387.6 K B) 355.6 K C) 323.6 K D) 190.8 K E) –190.8 K 6. Select the answer that expresses the result of this calculation with the correct number of significant figures. 13.602 × 1.90 × 3.06 = 4.2 × 1.4097 A) B) C) D) E) 13.3568 13.357 13.36 13.4 13 7. A) B) C) D) E) Express 96,342 m using 2 significant figures. 9.60 × 104 m 9.6 × 104 m 9.60 × 10-4 m 9.6 × 10-4 m 96000. m 8. Kaolinite, a clay mineral with the formula Al4Si4O10 (OH)8, is used as a filler in slick-paper for magazines and as a raw material for ceramics. Analysis shows that 14.35 g of kaolinite contains 8.009 g of oxygen. Calculate the mass percent of oxygen in kaolinite. A) 1.792 mass % B) 24.80 mass % C) 30.81 mass % D) 34.12 mass % E) 55.81 mass % Page 2 1143 Summer 2004 9. Iodine pentafluoride reacts slowly with glass and violently with water. Determine its molecular mass. A) 653.52 amu B) 259.89 amu C) 221.90 amu D) 202.90 amu E) 145.90 amu 10. A) B) C) D) E) Which one of the following combinations of names and formulas is incorrect? H3PO4 phosphoric acid HNO3 nitric acid NaHCO3 sodium carbonate H2CO3 carbonic acid KOH potassium hydroxide 11. A) B) C) D) E) What is the name of the acid formed when HClO4 liquid is dissolved in water? hydrochloric acid perchloric acid chloric acid chlorous acid hydrochlorate acid 12. Iron (III) chloride hexahydrate is used as a coagulant for sewage and industrial wastes. What is its formula? A) Fe(Cl⋅6H2O)3 B) Fe3Cl⋅6H2O C) FeCl3(H2O)6 D) Fe3Cl(H2O)6 E) FeCl3⋅6H2O 13. The substance, KClO3, is a strong oxidizer used in explosives, fireworks, and matches. What is its name? A) potassium chlorite B) potassium chloride C) potassium(I) chlorite D) potassium(I) chlorate E) potassium chlorate Page 3 1143 Summer 2004 14. A) B) C) D) E) Calculate the molar mass of (NH4)3AsO4. 417.80 g/mol 193.03 g/mol 165.02 g/mol 156.96 g/mol 108.96 g/mol 15. Magnesium fluoride is used in the ceramics and glass industry. What is the mass of 1.72 mol of magnesium fluoride? A) 43.3 g B) 62.3 g C) 74.5 g D) 92.9 g E) 107 g 16. Potassium dichromate, K2Cr2O7, is used in tanning leather, decorating porcelain and water proofing fabrics. Calculate the number of chromium atoms in 78.82 g of K2Cr2O7. A) 9.490 × 1025 Cr atoms B) 2.248 × 1024 Cr atoms C) 1.124 × 1024 Cr atoms D) 3.227 × 1023 Cr atoms E) 1.613 × 1023 Cr atoms 17. A) B) C) D) E) Calculate the mass in grams of 8.35 × 1022 molecules of CBr4. 0.0217 g 0.139 g 7.21 g 12.7 g 46.0 g Page 4 1143 Summer 2004 21. In the combustion analysis of 0.1127 g of glucose (C6H12O6), what mass, in grams, of CO2 would be produced? A) 0.0451 g B) 0.0825 g C) 0.1652 g D) 0.4132 g E) 1.466 g Open ended problems: SHOW YOUR WORK! 27. An evacuated 276 mL glass bulb weighs 129.6375 g. Filled with an unknown gas, the bulb weighs 130.0318 g. Calculate the gas density in g/L, and express it with an appropriate number of significant figures. Page 5 1143 Summer 2004 28. Fill in the blank spaces and write out all the symbols in the left hand column in full,in the A form Z X (i.e. include the appropriate values of Z and A as well as the correct symbol X). Symbol # protons # neutrons # electrons 17 18 Au 118 20 20 29. a. Give the names of the following ions: (i) NH4+ (ii) SO32b. Write down the formulas of the following ions: (i) aluminum (ii) carbonate 30. For each of the following names, write down the corresponding formula, including charge where appropriate (atomic numbers and mass numbers are not required): a. zinc ion b. nitrite ion c. carbonic acid d. cyanide ion 31. For each of the following elements, indicate next to the symbol whether it is a metal, a non-metal or a metalloid: a. S b. Ge c. Hg d. H e. I f. Si Page 6 1143 Summer 2004 Answer Key 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. C A B B B E B E C C B E E B E D E A B D C A C C A a. 0.0444 mol DDT b. Chlorobenzene is the limiting reagent. c. 77.2% 27. 1.43 g/L 28. Symbol # protons # neutrons 35 17 Cl 197 79 40 20 17 18 # electrons 17 Au 79 118 79 Ca 20 20 20 29. a. (i) ammonium (ii) sulfite b. (i) Al3+ (ii) CO3230. a. Zn2+ b. NO2c.H2CO3 d.CN- Page 7 1143 Summer 2004 31. a. nonmetal b. metalloid c. metal d. nonmetal e. nonmetal f. metalloid Page 8 1143 Summer 2004