Chemistry 231 – Elementary Organic Chemistry Problem Set – The Structure of Molecules 1. For each of the given molecular formulae, draw the most stable (lowest energy) Lewis Dot Structure. a. b. c. d. e. f. g. h. i. j. NH2OH H2CO3 H3PO3 SO3 POCl3 CHNO CHNS HCN SO2 HN3 2. For each of the given molecular formulae, draw the most stable (lowest energy) Lewis Dot Structure. a. b. c. d. e. f. g. h. H2SO4 (CO2H)2 HNO2 H2O2 HClO4 Cr2O72P2O74N2O4 3. For each of the following compound names, draw a corresponding line structure. Be certain to indicate absolute stereochemistry. a. b. c. d. e. f. 1-methyl-1-bromocyclopentane 3,3-dimethyl-1-butene (S)-1-bromo-1-iodomethane 1,5-diazabicyclo[4.3.0]non-5-ene meso-1,3-diethylcyclohexane n-butyllithium 4. For each of the following compound names, draw a corresponding line structure. Be certain to indicate absolute stereochemistry. a. b. c. d. e. Cyclohexyl fluoride n-Butyl bromide tert-Pentyl chloride Allyl chloride Benzyl iodide 5. Write a valid Lewis structure for each of the following compounds: a. Amide anion, NH2b. Nitrous oxide (laughing gas), N2O (arranged N—N—O) c. Bicarbonate anion, HCO36. For each of the compounds shown below, draw all valid resonance structure. Circle the most important structure that contributes to the overall resonance hybrid. a. b. c. 7. Ozone is an allotrope of oxygen. Its molecular weight is 48.0 g mol-1. a. What is the molecular formula of ozone? b. Draw a valid Lewis structure for the formula indicated above. Be certain to indicate formal charges (if any) within the molecule. c. Are there any resonance forms of ozone that correspond to your structure from part (b)? If so, what are they and how are they formed?