Chemistry Reference Tables Name Value Standard temperature 6.022 10 23 particles/mole 0.0821 L atm mole K L mmHg 62.4 mole K 8.314 L kPa mole K 1.00 atm = 101.3 kPa = 760. mmHg = 760. torr 0C or 273K Volume of 1 mole of any gas at STP 22.4 L Avogadro’s number Gas constant (R) Standard pressure Thermodynamic Constants Symbol Value Heat of fusion of water H f (water) 334 J/g Heat of vaporization of water Hv (water) 2,260 J/g J for ice, 2.02 J g°C g°C for steam, 4.18 J for liquid g°C 2.05 C p (water) Specific heat of water Metal Specific Heat J g°C Density (g/cm3) Melting Point (°C) Aluminum 0.897 2.702 Copper 0.385 8.92 1083 Gold 0.129 19.31 1064 Iron 0.449 7.86 1535 Lead 0.129 Magnesium 1.023 Mercury 0.140 Nickel 0.444 8.90 1455 Titanium 0.523 4.5 1660 Zinc 0.388 7.14 NCDPI Reference Tables for Chemistry (2012) Stock No. 14155 11.3437 1.74 13.5939 660 328 649 –39 420 Page 1 Organic Substances Name Ethanol (CH3CH2OH) Glucose (C 6H12O 6) Density 0.7893 g/cm3 Melting Point (°C) 114 Boiling Point (°C) 79 1.56 g/cm3 146 Hexane (C 6H14) 0.6603 g/cm3 95 69 Methane (CH4) 0.716 g/L 182 161 98 65 Methanol (CH3OH) Sucrose (C12H22O11) 0.7914 g/cm3 1.58 g/cm3 86 Decomposes Decomposes Inorganic Substances *Density @ STP Melting Point (°C) Chlorine 3.21 g/L 101 35 Hydrogen 0.0899 g/L 259 253 Hydrogen chloride 1.640 g/L 115 85 Hydrogen sulfide 1.54 g/L 85 61 Nitrogen 1.25 g/L 210 196 Nitrogen monoxide 1.34 g/L 164 152 Oxygen 1.43 g/L 218 183 Sodium carbonate 2.532 g/cm3 851 Decomposes Sodium chloride 2.165 g/cm3 801 1413 Sulfur dioxide 2.92 g/L 73 10 *Water (at 4°C) 1.00 g/cm3 0 100 Name NCDPI Reference Tables for Chemistry (2012) Boiling Point (°C) Page 2 Formulas D m V D = density K C 273 m = mass P1V1 PV 2 2 T1 T2 V = volume Pt P1 P2 P3 ... K = Kelvin M1V1 M2V2 P = pressure PV nRT R = gas constant M moles of solute liter of solution T = temperature q mC pT M = molarity q mHv n = number of moles q mH f q = quantity of heat energy pH pOH 14 C p = specific heat pH log[H ] Hv = heat of vaporization pOH log[OH ] H f = heat of fusion K w [H ][OH ] 1 10 14 K w = equilibrium constant for the ionization of water [H ] 10 pH [OH ] 10 pOH NCDPI Reference Tables for Chemistry (2012) Page 3 PERIODIC TABLE 1 IA 1 H 1.008 2 IIA 3 Li 4 Be Hydrogen Lithium Beryllium 6.941 9.012 11 Na 12 Mg Sodium Magnesium 22.99 24.31 3 IIIB 4 IVB 5 VB 6 VIB 7 VIIB 8 VIIIB 9 VIIIB 19 K 20 Ca 21 Sc 22 Ti 23 V 24 Cr 25 Mn 26 Fe 27 Co Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt 39.10 40.08 44.96 47.88 50.94 51.99 54.94 55.85 58.93 37 Rb 38 Sr 39 Y 40 Zr 41 Nb 42 Mo 43 Tc 44 Ru 45 Rh Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium 85.47 87.62 88.91 91.22 92.91 95.94 (98) 101.07 102.91 55 Cs 56 Ba 57 La 72 Hf 73 Ta 74 W 75 Re 76 Os 77 Ir Cesium Barium Lanthanum Hafnium Tantalum Tungsten Rhenium Osmium Iridium 132.91 137.38 138.91 178.49 180.95 183.84 186.21 190.23 192.22 87 Fr 88 Ra 89 Ac 104 Rf 105 Db 106 Sg 107 Bh 108 Hs 109 Mt Francium Radium Actinium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium (223) (226) (227) (261) (262) (263) (264) (269) (268) 58 Ce 59 Pr 60 Nd 61 Pm 62 Sm 63 Eu 64 Gd Promethium Samarium Europium Gadolinium 140.12 140.91 144.24 (145) 150.36 151.96 157.25 90 Th 91 Pa 92 U 93 Np 94 Pu 95 Am 96 Cm Thorium Protactinium Uranium Neptunium Plutonium Americium Curium 232.04 231.04 238.04 (237) (244) (243) (247) Cerium Praseodymium Neodymium © 2011 North Carolina Department of Public Instruction NCDPI Reference Tables for Chemistry (2012) Page 4 OF THE ELEMENTS 18 VIIIA 2 He 13 IIIA 14 IVA 15 VA 16 VIA 17 VIIA 4.003 5 B 6 C 7 N 8 O 9 F 10 Ne Boron Carbon Nitrogen Oxygen Fluorine Neon 10.81 12.01 14.01 16.00 19.00 20.18 13 Al 14 Si 15 P 16 S 17 Cl 18 Ar Helium 10 VIIIB 11 IB 12 IIB Aluminum Silicon Phosphorus Sulfur Chlorine Argon 26.98 28.09 30.97 32.07 35.45 39.95 28 Ni 29 Cu 30 Zn 31 Ga 32 Ge 33 As 34 Se 35 Br 36 Kr Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton 58.69 63.55 65.39 69.72 72.61 74.92 78.96 79.90 83.80 46 Pd 47 Ag 48 Cd 49 In 50 Sn 51 Sb 52 Te 53 I 54 Xe Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon 106.42 107.87 112.41 114.82 118.71 121.76 127.60 126.90 131.29 78 Pt 79 Au 80 Hg 81 Tl 82 Pb 83 Bi 84 Po 85 At 86 Rn Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon 195.08 196.97 200.59 204.38 207.20 208.98 (209) (210) (222) 110 Ds 111 Rg 112 Cn Darmstadtium Roentgenium Copernicium (271) (272) (285) 65 Tb 66 Dy 67 Ho 68 Er 69 Tm 70 Yb 71 Lu Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium 158.93 162.50 164.93 167.26 168.93 173.04 174.97 97 Bk 98 Cf 99 Es 100 Fm 101 Md 102 No 103 Lr Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium (247) (251) (252) (257) (258) (254) (262) NCDPI Reference Tables for Chemistry (2012) Page 5 SOLUBILITY RULES Soluble: All Nitrates, Acetates, Ammonium, and Group 1 (IA) salts All Chlorides, Bromides, and Iodides, except Silver, Lead, and Mercury(I) All Fluorides except Group 2 (IIA), Lead(II), and Iron(III) All Sulfates except Calcium, Strontium, Barium, Mercury, Lead(II), and Silver Insoluble (0.10 M or greater): All Carbonates and Phosphates except Group 1 (IA) and Ammonium All Hydroxides except Group 1 (IA), Strontium, Barium, and Ammonium All Sulfides except Group 1 (IA), 2 (IIA), and Ammonium All Oxides except Group 1 (IA) Guidelines for Predicting the Products of Selected Types of Chemical Reactions Key: M = Metal NM = Nonmetal 1. 2. SYNTHESIS: a. Formation of binary compound: A + B AB b. Metal oxide and water: MO + H2O base c. Nonmetal oxide and water: (NM)O + H2O acid DECOMPOSITION: a. Binary compounds: AB A + B b. Metallic carbonates: MCO3 MO + CO2 c. Metallic hydrogen carbonates: MHCO3 MCO3 (s) + H2O (l) + CO2 (g) d. Metallic hydroxides: MOH MO + H2O e. Metallic chlorates: MClO3 MCl + O2 f. Oxyacids decompose to nonmetal oxides and water: acid (NM)O + H2O 3. SINGLE REPLACEMENT: a. Metal-Metal replacement: A + BC AC + B b. Active metal replaces H from water: M + H2O MOH + H2 c. Active metal replaces H from acid: M + HX MX + H2 d. Halide-Halide replacement: D + BC BD + C 4. DOUBLE REPLACEMENT: AB + CD AD + CB a. Formation of a precipitate from solution b. Acid-Base neutralization 5. COMBUSTION REACTION Hydrocarbon + oxygen carbon dioxide + water NCDPI Reference Tables for Chemistry (2012) Page 6 ACTIVITY SERIES of Halogens: NH F2 Cl2 Br2 I2 BrO Sb Bi Cu Hg Ag Pt Au Ammonium 3 CN C 2H3O2 (CH3COO ) ACTIVITY SERIES of Metals Li Rb K Ba Sr Ca Na Mg Al Mn Zn Cr Fe Cd Co Ni Sn Pb [ H2 ] Polyatomic Ions + 4 Replace hydrogen from cold water Perchlorate ClO3 Chlorate ClO2 Chlorite ClO IO3 Hypochlorite MnO Iodate 4 React with oxygen to form oxides NCDPI Reference Tables for Chemistry (2012) Permanganate NO 3 Nitrate NO 2 Nitrite SCN CO23 Hydroxide Hydrogen carbonate Hydrogen sulfate Thiocyanate Carbonate Cr2O27 Dichromate HCO3 Replace hydrogen from acids Acetate ClO 4 OH Replace hydrogen from steam Bromate Cyanide HSO 4 CrO SO 2 4 2 4 Chromate Sulfate SO23 Sulfite PO34 Phosphate Page 7 Bohr Model for Hydrogen Atom (measurement in nanometers) n n n n n = = = = = 6 5 4 3 2 n=1 UV = Ultraviolet IR = Infrared 1282 656 434 1094 1875 IR 486 410 Visible 122 97 103 UV Electromagnetic Spectrum (measurement in meters) 104 103 102 101 100 10–1 10–2 10–3 10–4 10–5 10–6 10–7 10–8 10–9 10–1010–1110–12 10–13 X rays Microwaves Infrared Ultraviolet Gamma rays Radio waves Shorter Wavelength Longer Wavelength Visible Light Red Orange Yellow Green Blue Violet 7.0 ´ 10 –7 6.5 ´ 10 –7 5.9 ´ 10 –7 5.7 ´ 10–7 4.9 ´ 10 –7 4.2 ´ 10 –7 4.0 ´ 10–7 NCDPI Reference Tables for Chemistry (2012) Page 8